CN106762631B - A kind of scroll compressor thermomechanical components and its manufacturing method and scroll compressor - Google Patents

A kind of scroll compressor thermomechanical components and its manufacturing method and scroll compressor Download PDF

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Publication number
CN106762631B
CN106762631B CN201710109901.8A CN201710109901A CN106762631B CN 106762631 B CN106762631 B CN 106762631B CN 201710109901 A CN201710109901 A CN 201710109901A CN 106762631 B CN106762631 B CN 106762631B
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scroll compressor
main body
layer
thermomechanical components
ceramic layer
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CN106762631A (en
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陈晓晓
史正良
单彩侠
康小丽
朱劲波
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Zhuhai Gree Energy Saving Environmental Protection Refrigeration Technology Research Center Co Ltd
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Zhuhai Gree Energy Saving Environmental Protection Refrigeration Technology Research Center Co Ltd
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04CROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT PUMPS
    • F04C18/00Rotary-piston pumps specially adapted for elastic fluids
    • F04C18/02Rotary-piston pumps specially adapted for elastic fluids of arcuate-engagement type, i.e. with circular translatory movement of co-operating members, each member having the same number of teeth or tooth-equivalents
    • F04C18/0207Rotary-piston pumps specially adapted for elastic fluids of arcuate-engagement type, i.e. with circular translatory movement of co-operating members, each member having the same number of teeth or tooth-equivalents both members having co-operating elements in spiral form
    • F04C18/0215Rotary-piston pumps specially adapted for elastic fluids of arcuate-engagement type, i.e. with circular translatory movement of co-operating members, each member having the same number of teeth or tooth-equivalents both members having co-operating elements in spiral form where only one member is moving
    • F04C18/0223Rotary-piston pumps specially adapted for elastic fluids of arcuate-engagement type, i.e. with circular translatory movement of co-operating members, each member having the same number of teeth or tooth-equivalents both members having co-operating elements in spiral form where only one member is moving with symmetrical double wraps
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/024Anodisation under pulsed or modulated current or potential
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/026Anodisation with spark discharge
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/06Anodisation of aluminium or alloys based thereon characterised by the electrolytes used
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04CROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT PUMPS
    • F04C18/00Rotary-piston pumps specially adapted for elastic fluids
    • F04C18/02Rotary-piston pumps specially adapted for elastic fluids of arcuate-engagement type, i.e. with circular translatory movement of co-operating members, each member having the same number of teeth or tooth-equivalents
    • F04C18/0207Rotary-piston pumps specially adapted for elastic fluids of arcuate-engagement type, i.e. with circular translatory movement of co-operating members, each member having the same number of teeth or tooth-equivalents both members having co-operating elements in spiral form
    • F04C18/0246Details concerning the involute wraps or their base, e.g. geometry
    • F04C18/0269Details concerning the involute wraps
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05CINDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2201/00Metals
    • F05C2201/90Alloys not otherwise provided for
    • F05C2201/903Aluminium alloy, e.g. AlCuMgPb F34,37
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05CINDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2203/00Non-metallic inorganic materials
    • F05C2203/08Ceramics; Oxides
    • F05C2203/0865Oxide ceramics
    • F05C2203/0869Aluminium oxide
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05CINDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2251/00Material properties
    • F05C2251/14Self lubricating materials; Solid lubricants

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Rotary Pumps (AREA)

Abstract

The present invention relates to a kind of scroll compressor thermomechanical components, including dynamic vortex part and quiet scroll;Dynamic vortex part includes the first main body, and quiet scroll includes the second main body;Surface opposite with the second main body in the first main body is defined as first surface, the surface opposite with the first main body is second surface in the second main body;Ceramic layer is formed by differential arc oxidation processing at first surface, and/or second surface, to reduce the service wear of dynamic vortex part and quiet scroll.The wear-resisting property of the ceramic layer is good, and hardness is high, and surface roughness is low, and the working performance of high cooperation precision and stabilization can be kept by making the scroll compressor thermomechanical components in the long-term use.The invention further relates to a kind of scroll compressor with the scroll compressor thermomechanical components and the manufacturing methods of the scroll compressor thermomechanical components.The scroll compressor reliability is high, and service life is long;The manufacturing method is simple, efficient, energy saving, advantageously reduces pollution.

Description

A kind of scroll compressor thermomechanical components and its manufacturing method and scroll compressor
Technical field
The present invention relates to Compressor Technology fields, and in particular to a kind of scroll compressor thermomechanical components and its manufacturing method and Scroll compressor.
Background technology
Scroll compressor is as a kind of positive displacement compressor of novel, energy saving, material saving and low noise, by more and more extensive It uses, cardinal principle is that the consecutive variations of dead volume are formed using the opposite revolution motion of dynamic and static scroll plate, to realize pressure The purpose of contracting gas.The cooperation precision of the wherein material of orbiter and fixed scroll, machining quality and the two directly determines It gas compression amount and then influences the Performance And Reliability of complete machine.
Demand based on energy-saving and emission-reduction, more and more orbiters and fixed scroll are all made of casting or forged aluminium at present Alloy material.It generally, need to be to orbiter and quiet whirlpool to avoid generating adhesive wear when same type material is secondary as friction At least one carry out surface modification treatment in capstan, but can there are problems that following three:First, by the modified component in surface Surface forms weaker zone, will produce larger friction coefficient when the weaker zone is with the break-in in the early stage of another scroll plate.It is more tight The situation of weight is, it is possible to since the hard particles of modified rear surface make freezing with TRANSIENT HIGH TEMPERATURE is generated when scroll plate break-in Machine oil is carbonized, and causes to freeze deterioration of oil, to cause to seriously affect to compressor performance and reliability;Second is that compressor exists Actual motion for a period of time after, since coating abrasion amount gradually increases, the cooperation precision of dynamic and static scroll plate and the cooperation before assembly Precision difference is larger, this can lead to the leakage of compressed gas and then influence the performance of compressor;Third, due to compressor permanent worker The vortex pan coating for making to cause surface modified gradually grinds off and leaks out the aluminium base of scroll plate, at this time with same type aluminium alloy conduct Adhesive wear is easily generated when friction is with pair, two kinds of parts is made to occur to be engaged final complete machine failure.Therefore dynamic whirlpool how is reduced The leakage of compressed gas caused by friction coefficient, reduction when capstan and fixed scroll initial stage break-in are worn due to coating avoids Due to compressor failure caused by coating Fast Wearing, it is of great significance to the performance and reliability that improve compressor.
Chinese patent literature CN2519859Y and CN1065025C has carried out hard anode to orbiter or fixed scroll Oxidation or anodized.But it should be noted that hard anodizing surface quality and material chemical composition, microscopic structure point Cloth, moulding process, process for machining, condition of heat treatment etc. have much relations, higher for the accuracy requirement of reaction condition, compared with Small condition, which changes, may lead to hard oxygen poor surface quality and cannot be satisfied reliability test requirement, and hard anodic oxygen The roughness for changing film layer is 1-2 grades low compared with machining state, and dynamic and static scroll plate belongs to high-precision mating parts, especially scroll wrap The high roughness in top and substrate position can all influence the gas compression amount in compression chamber, so cause the overall performance of compressor by To influence.Although anode oxide film surface quality is slightly good, the soft of anode oxide film is also that can not change, Wu Faman Demand of the sufficient compressor scroll plate for long-term wearability.
Chinese patent literature CN1212332A carries out Ni-P-B surface treatments to aluminium base orbiter surface, although the coating Section hardness is higher, this kind of coating is that attachment is arranged except matrix, although its with matrix have certain adhesive force but It is easier to fall off, and falling off the sheet coating fallen can be as the Performance And Reliability of impurity effect compressor.
Meanwhile the above mode being surface-treated for compressor orbiter or fixed scroll is required to or part needs The operations such as one or many pickling, alkali cleaning are carried out, cause processing step cumbersome, processing procedure energy expenditure and quantity of wastewater effluent It is larger, do not meet the environmental protection concept of energy-saving and emission-reduction.
Invention content
In order to solve the above problem of the existing technology, the present invention provides a kind of scroll compressor thermomechanical components and its systems Make method and scroll compressor.Purpose is, the surface of dynamic vortex part and/or quiet scroll is made to have good wearability Energy and rock-steady structure not easily to fall off.
The technical solution adopted in the present invention is:
A kind of scroll compressor thermomechanical components, including dynamic vortex part and quiet scroll;
The dynamic vortex part includes the first main body, and the quiet scroll includes the second main body;It defines in first main body The surface opposite with second main body is first surface, and the surface opposite with first main body is the in second main body Two surfaces;
Ceramic layer is formed by differential arc oxidation processing at the first surface, and/or the second surface, described in reduction The service wear of dynamic vortex part and the quiet scroll.
Preferably, first main body and second main body are made of aluminum alloy materials, the aluminum alloy materials Constituent includes (by weight percentage):9-14%Si, 0.5-3%Cu, Mg≤1%, Fe > 1%, Zn≤0.8%, Ni ≤ 0.5%, remaining is Al;
The ceramic layer is al oxide layer.
Preferably, the thickness of the ceramic layer is 5-30 μm.
Preferably, the thickness of the ceramic layer is 10-20 μm.
Preferably, the section vickers microhardness of the ceramic layer is not less than 900HV.
Preferably, the surface roughness of the ceramic layer is not more than 1 μm.
Preferably, polishing treatment is passed through on the surface of the ceramic layer, and polishing thickness is 2-5 μm.
Preferably, the surface of the ceramic layer is provided with lubricant layer, and the surface roughness of the lubricant layer is not more than 1 μm.
Preferably, the thickness of the lubricant layer is 5-15 μm.
Preferably, the lubricant layer is one kind in silicone layer, polytetrafluoroethylene ethylene layer or layer of molybdenum-disulfide.
A kind of scroll compressor, including the scroll compressor thermomechanical components.
A kind of manufacturing method of the scroll compressor thermomechanical components, includes the following steps:
The second surface of first surface, and/or second main body to first main body carries out differential arc oxidation processing, Make to form the ceramic layer at the first surface, and/or at the second surface.
Preferably, first main body, and/or second main body are placed in progress differential arc oxidation processing in electrolyte, The constituent of the electrolyte includes:
Phosphate 10-15g/L, wolframic acid 2-5g/L, sodium hydroxide 0.2-1.5g/L, EDETATE SODIUM 1.5-5g/L.
Preferably, the reaction condition of progress differential arc oxidation processing is:
Power pulse frequency 400-700Hz, pulse duty factor 10-20%, current density 2.5-6.5A/dm2, voltage 300- 500V, differential arc oxidation time are 10-30min, and the temperature of used electrolyte is 20-40 DEG C.
Preferably, the manufacturing method is further comprising the steps of:
The ceramic layer is polished, the surface roughness Ra of the ceramic layer after polishing is made to be not more than 1 μm.
Preferably, it is 2-5 μm to the polishing thickness that the ceramic layer is polished.
Preferably, when including the lubricant layer, the manufacturing method of the scroll compressor thermomechanical components further includes following step Suddenly:
The lubricant layer is formed in the surface baking-curing of the ceramic layer;The lubricant layer is silicone layer, polytetrafluoro One kind in pvdf layer or layer of molybdenum-disulfide;And the surface roughness of the lubricant layer is made to be not more than 1 μm, thickness is 5-15 μm.
Beneficial effects of the present invention are:
1, ceramic layer is formed by way of differential arc oxidation processing at the first surface and/or the second surface, institute Ceramic layer structure densification is stated, hardness is high, and wear-resisting property is good, can reduce the abrasion of dynamic vortex part and quiet scroll at work Speed, reduce wear extent, to avoid due to caused by abrasion compressor arrangement cooperation precision be deteriorated, leakage of compressed gas or Adhesive wear and occlusion failure are led to the problem of, service life of equipment is conducive to extend.Meanwhile the ceramic layer is by the first main body And/or second material of main part growth in situ obtain, and the combination of the first main body and/or the second main body is very secured, thus can It falls off and the problem of damage compressor operating reliability to avoid there is ceramic layer.
2, the ceramic layer has good surface quality, can reduce between the dynamic vortex part and the quiet scroll The friction coefficient of progress initial stage break-in, advantageously reduces running-in time, and prevent due to the larger hard particles of surface size with Matched scroll plate friction leads to the problem of TRANSIENT HIGH TEMPERATURE and refrigerator oil carbonization is made to go bad, and ensures the reliable and stable fortune of compressor Turn.
3, the manufacturing method of the scroll compressor thermomechanical components is easy to operate, and process stabilizing is reliable, and equipment cost is relatively low, easily In operation, reaction can carry out at normal temperatures, and without carrying out follow-up pickling or alkali cleaning processing, and the reagent used is environment-friendly type examination Agent meets environment protection emission requirement, and quantity of wastewater effluent is smaller, and energy expenditure is less, is conducive to energy conservation and environmental protection.
Description of the drawings
Fig. 1 is the front view of dynamic vortex part of the present invention;
Fig. 2 is cross-sectional view (including the ceramic layer and the lubrication of dynamic vortex part of the present invention Layer);
Fig. 3 is the front view of quiet scroll of the present invention;
Fig. 4 is that (ceramic layer and the lubricant layer do not show for the cross-sectional view of quiet scroll of the present invention Go out);
Fig. 5 is the part section structural representation of scroll compressor of the present invention;
Fig. 6 shows the wear rate test result of the test specimen obtained by a variety of different surface treatment modes.
In figure:1, dynamic vortex part;11, the first main body;2, quiet scroll;21, the second main body;3, ceramic layer;4, lubricant layer; 5, case top lid;6, shell lower cover;7, upper bracket;8, bent axle.
Specific implementation mode
For the present invention is further explained to reach the technological means and effect that predetermined purpose is taken, below in conjunction with attached drawing with And specific implementation mode, structure, feature and its effect applied according to the present invention is described in detail as after in preferred embodiment. In following the description, special characteristic, structure or feature in one or more embodiments can be combined by any suitable form.
A kind of scroll compressor thermomechanical components, including dynamic vortex part 1 (see Fig. 1, Fig. 2) and quiet scroll 2 (see Fig. 3, Fig. 4);
Generally for common scroll compressor, the dynamic vortex part 1 is orbiter, and the quiet scroll 2 is Fixed scroll.The dynamic vortex part 1 and the quiet scroll 2 are equipped with, and to form compression chamber between, are being compressed When machine is run, the dynamic vortex part 1 is driven and is translatable along certain track, with quiet scroll 2 according to designed clearance fit, Opposite revolution motion is formed, to form the compression chamber of the continuous mechanical periodicity of volume, refrigerant gas can be in this kind of compression chamber Air-breathing, compression and exhaust process are completed, to realize the purpose of compressed gas.
The dynamic vortex part 1 includes the first main body 11, and the quiet scroll 2 includes the second main body 21;Define described first The surface opposite with second main body 21 is first surface in main body 11, in second main body 21 with first main body 11 Opposite surface is second surface;Ceramics are formed by differential arc oxidation processing at the first surface, and/or the second surface Layer 3, to reduce the service wear of the dynamic vortex part 1 and the quiet scroll 2.Fig. 1, Fig. 2 shows have the ceramic layer 3 The dynamic vortex part 1 structural schematic diagram.
The ceramic layer 3 is formed at least one in the first surface and the second surface so that in compressor work During work, first main body 11 and second main body 21 are not directly contacted with, and can be prevented and are made of same material First main body 11 and second main body, 21 phase mutual friction cause adhesive wear, even occur occlusion failure the problem of. Moreover, importantly, the structure of the ceramic layer 3 handled by differential arc oxidation is very fine and close, have high rigidity and Good wearability advantageously reduces the abrasion of the dynamic vortex part 1 and 2 phase mutual friction of quiet scroll generation, effectively drops Low abrasion speed reduces wear extent, to ensure that the dynamic vortex part 1 and the quiet scroll 2 can be protected in long-term work Hold precise match, avoid coordinating precision to be deteriorated with component wear due to compressor assembly structure, caused by compress intracavity gas The problem of leakage.Meanwhile improved wear-resisting property can also prevent the ceramic layer 3 be worn through when compressor assembly works and Expose basis material, to avoid first main body 11 and second main body 21 from being in direct contact and recurring structure occlusion failure The problem of.
In addition, the ceramic layer 3 obtained by differential arc oxidation processing mode, is by the first main body 11 and/or Wearing layer on two main bodys, 21 basis material obtained by growth in situ, and the first main body 11 and/or the second main body 21 combination ten It is point secured, it is difficult to fall off, thus in compressor operation, can avoid the occurrence of that ceramic layer 3 falls off, fragment enters compression chamber The problem of Deng compressor arrangement and operational reliability is damaged.
It is by institute it should be noted that carrying out differential arc oxidation processing to the first surface and/or the second surface It states first surface and the second surface is long-term phase mutual friction can occur during the work time for compressor surface.To described One surface and the second surface carry out selecting a processing, advantageously reduce production cost.But this does not represent and handles differential arc oxidation Position be confined at the first surface and/or the second surface.More specifically, in actual production manufacturing process, It can (such as first main body 11 be whole to the greater area of surface that in first main body 11 includes the first surface A surface), and/or second main body 21 on include the second surface greater area of surface (such as it is described second master The whole surface of body 21) differential arc oxidation processing is carried out, to simplify the operating procedure of differential arc oxidation processing, production efficiency is improved, and Improve the planarization and aesthetics of the dynamic vortex part 1 and 2 surface of quiet scroll.
As a kind of preferable embodiment, first main body 11 and second main body 21 are by aluminum alloy materials system At the constituent of the aluminum alloy materials includes (by weight percentage):9-14%Si, 0.5-3%Cu, Mg≤1%, Fe > 1%, Zn≤0.8%, Ni≤0.5%, remaining is Al;The ceramic layer 3 is al oxide layer.Aluminum alloy materials density compared with It is small, and there is good intensity and toughness, manufacturing first main body 11 and second main body 21 using aluminum alloy materials has Energy expenditure when conducive to reduction compressor operation, meets the environmental requirement of energy-saving and emission-reduction.In above-mentioned preferable embodiment, With the aluminum alloy materials for preferably constituting ingredient with good manufacture and processing performance, casting or forging may be used Mode be made first main body 11 and second main body 21, and obtain precision size by the aftertreatment technologies such as finishing Part, advantageously reduce manufacture processing cost using the aluminum alloy materials, improve production efficiency, while obtaining intensity and tough Property etc. is satisfied by the parts of scroll compressor requirement.The ceramic layer 3 is to be reacted by differential arc oxidation, described in oxidation The al oxide layer that aluminum alloy materials are formed also has high temperature resistant, matter in addition to the above a variety of excellent performances Measure the characteristics such as light.
As a kind of preferable embodiment, the thickness of the ceramic layer 3 is 5-30 μm (see h is marked in Fig. 2), further Preferably, the thickness of the ceramic layer 3 is 10-20 μm, with the various aspects factor such as combination weight, mechanical performance, production cost, is obtained Obtain the ceramic layer 3 with good comprehensive performance.Improved wear-resisting property makes the design thickness of the ceramic layer 3 reduce, Be conducive to improve manufacture efficiency, reduce production cost, reduce pts wt, extends service life of equipment.
As a kind of preferable embodiment, the section vickers microhardness of the ceramic layer 3 is not less than 900HV.It is described The hardness of ceramic layer 3 is higher, and the ceramic layer 3 can be prevented damaged by scratching in assembling and the course of work.
As a kind of preferable embodiment, the surface roughness Ra of the ceramic layer 3 is not more than 1 μm.The ceramic layer 3 Surface it is smooth, roughness is low, the rubbing when initial stage between the dynamic vortex part 1 and the quiet scroll 2 of advantageously reducing coordinates Coefficient is wiped, running-in time is reduced.And do not have larger-size hard particles at 3 surface of ceramic layer, because without in institute Local Instantaneous high temperature is generated when stating the 2 progress initial stage cooperation of dynamic vortex part 1 and the quiet scroll, avoids the occurrence of refrigerator oil The rotten problem of carbonization, ensures compressor operating reliability.
Specifically, the good surface quality of the ceramic layer 3 can obtain in several ways, for example, by adjusting The reaction condition of differential arc oxidation reaction, so that the ceramic layer 3 that differential arc oxidation reaction generates has the table no more than 1 μm Surface roughness, alternatively, sequent surface processing operation is carried out by the ceramic layer 3 generated for differential arc oxidation reaction, to Further improve the surface quality of the ceramic layer 3, sequent surface processing operation described herein can there are many, may be, for example, Polishing treatment, polishing thickness are preferably 2-5 μm.Alternatively, as a kind of preferable embodiment, it can be in the ceramic layer 3 Surface be arranged lubricant layer 4, and make the lubricant layer 4 surface roughness Ra be not more than 1 μm, with improve the dynamic vortex part 1 and/ Or the surface quality of the quiet scroll 2.Preferably, the thickness of the lubricant layer 4 is 5-15 μm (see l is marked in Fig. 1).It is described The material of lubricant layer 4 can be selected according to the prior art, it is preferable that the lubricant layer 4 is silicone layer, polytetrafluoroethylene (PTFE) Layer or layer of molybdenum-disulfide in any one.The silicone layer, polytetrafluoroethylene ethylene layer, layer of molybdenum-disulfide have good lubrication Performance and chemical inertness, and there is good tolerance, structure, property to stablize hot conditions, service life is longer.
As shown in figure 5, the invention further relates to a kind of scroll compressor, including the scroll compressor thermomechanical components.
The invention further relates to a kind of manufacturing methods of the scroll compressor thermomechanical components, include the following steps:
The second surface of first surface, and/or second main body 21 to first main body 11 carries out differential arc oxidation Processing, makes to form the ceramic layer 3 at the first surface, and/or at the second surface.
More specifically, the first preferred embodiment of the manufacturing method is:
Oil removal treatment is carried out to pending first main body 11 and second main body 21, water is carried out to the two later It washes, dry;Oil removal treatment and washing drying operation are conducive to obtain cleaner surface before carrying out oxidation reaction, to keep away Exempt from the impurity at first main body 11 and 21 surface of the second main body to participate in oxidation reaction, reduce the ceramic layer generated 3 quality;
By after drying first main body 11 and second main body 21 be placed in the differential arc oxidation slot for filling electrolyte, The constituent of the electrolyte includes:Phosphate 10g/L, wolframic acid 2g/L, sodium hydroxide 0.2g/L, EDETATE SODIUM 1.5g/L, The temperature of the electrolyte is 20 DEG C;
First main body 11 being opposite in the electrolyte and second main body 21 carry out differential arc oxidation processing, place The reaction condition of reason is:It is power pulse frequency 400Hz, pulse duty factor 10%, current density 2.5A/dm2, voltage 300V, micro- Arc oxidization time is 10min;
After reaction, it is dry that first main body 11 and second main body 21 to gained carry out washing to differential arc oxidation It is dry to get the dynamic vortex part 1 and the quiet scroll 2 with the ceramic layer 3.It is handled by this kind of preferred embodiment To first main body 11 and the thickness of the ceramic layer 3 on 21 surface of the second main body be about 9.2 μm, ceramic layer 3 is cut Face vickers microhardness average value is 950HV.
Second preferred embodiment of the manufacturing method is:
To simplify manufacturing process, saving manufacturing cost, this preferred embodiment only carries out differential arc oxidation to the dynamic vortex part 1 Processing, that is, oil removal treatment is carried out to pending first main body 11, washed, dried later;
First main body 11 after drying is placed in the differential arc oxidation slot for filling electrolyte, the composition of the electrolyte Ingredient includes:Phosphate 12g/L, wolframic acid 3.5g/L, sodium hydroxide 1g/L, EDETATE SODIUM 3g/L, the temperature of the electrolyte are 30℃;
First main body 11 being opposite in the electrolyte carries out differential arc oxidation processing, and the reaction condition of processing is: Power pulse frequency 500Hz, pulse duty factor 15%, current density 4A/dm2, voltage 400V, differential arc oxidation time are 20min;
Differential arc oxidation carries out washing and drying to get with the pottery after reaction, to first main body 11 of gained The dynamic vortex part 1 of enamel coating 3.Pass through the ceramic layer on 11 surface of the first main body that this kind of embodiment is handled 3 thickness is about 15.6 μm, and 3 section vickers microhardness average value of ceramic layer is 1086HV;
The ceramic layer 3 of gained in this preferred embodiment is processed by shot blasting, polishing thickness is 2-5 μm, to remove through micro- The of a relatively loose weaker zone of the structure on 3 surface of ceramic layer that arc oxidation processes obtain, improves the smooth journey on 3 surface of the ceramic layer Degree makes its surface roughness Ra be not more than 1 μm, reduces the friction when dynamic vortex part 1 and 2 initial stage of the quiet scroll break-in Coefficient to reduce running-in time, and prevents the dynamic vortex part 1 and 2 matched position of the quiet scroll from generating part TRANSIENT HIGH TEMPERATURE.
To illustrate through the dynamic vortex with the ceramic layer 3 made from the manufacturing method described in this preferred embodiment The wear-resisting property of part 1 tests the wear-resisting property of the dynamic vortex part 1, and is compared with other surface treatment methods, That is, hard anodizing, chemical nickel plating processing and differential arc oxidation processing are carried out respectively to identical test specimen, in identical friction testing Under the conditions of, as shown in fig. 6, the wear rate of the dynamic vortex part 1 obtained by this preferred embodiment is only 2.5%, it is significantly small In the wear rate of the wear rate (37.5%) and the test specimen handled by chemical nickel plating of the test specimen by hard anodizing processing (14.4%).
Experiments have shown that using this preferred embodiment, it can make the abrasion of the quiet scroll 2 and the dynamic vortex part 1 Rate substantially reduces, to significantly improve the reliability and service life of scroll compressor.
The third preferred embodiment of the manufacturing method is:
To simplify manufacturing process, saving manufacturing cost, this preferred embodiment only carries out differential arc oxidation to the quiet scroll 2 Processing, that is, oil removal treatment is carried out to pending second main body 21, washed, dried later;
Second main body 21 after drying is placed in the differential arc oxidation slot for filling electrolyte, the composition of the electrolyte Ingredient includes:Phosphate 15g/L, wolframic acid 5g/L, sodium hydroxide 1.5g/L, EDETATE SODIUM 5g/L, the temperature of the electrolyte are 40℃;
Second main body 21 being opposite in the electrolyte carries out differential arc oxidation processing, and the reaction condition of processing is: Power pulse frequency 700Hz, pulse duty factor 20%, current density 6.5A/dm2, voltage 500V, differential arc oxidation time is 30min;
After reaction, to treated, second main body 21 carries out washing and drying to get with described to differential arc oxidation The quiet scroll 2 of ceramic layer 3.Pass through the ceramics on 21 surface of the second main body that this kind of embodiment is handled The thickness of layer 3 is about 24.3 μm, and 3 section vickers microhardness average value of ceramic layer is 1265HV.
For the surface property for further improving by differential arc oxidation treated the quiet scroll 2, this preferred embodiment On the surface of the ceramic layer 3, coating is used to form the material of the lubricant layer 4, and makes the profit by the way of baking-curing Slip layer 4 is firmly secured to the surface of the ceramic layer 3, and specifically, the lubricant layer 4 can be silicone layer, polytetrafluoroethylene (PTFE) Any one in layer or layer of molybdenum-disulfide, the surface roughness of the lubricant layer 4 is not more than 1 μm, and thickness is 5-15 μm.
It should be noted that for the part compressor assembly, when the dynamic vortex part 1 and the quiet scroll 2 are equal When handling to obtain the ceramic layer 3 by differential arc oxidation, can only the dynamic vortex part 1 and the quiet scroll 2 wherein it One 3 surface of the ceramic layer prepares lubricant layer 4, can have while achieving the effect that the friction coefficient of reduction initial stage friction Conducive to saving cost.
The above preferred embodiment of the manufacturing method of the scroll compressor thermomechanical components is easy to operate, and process stabilizing is reliable, Equipment cost is relatively low, easily operated, and reaction can carry out at normal temperatures, and disappears without carrying out follow-up pickling or alkali cleaning operation, energy Consume less, quantity of wastewater effluent is smaller, and the reagent used is environment-friendly type reagent, meets environment protection emission requirement, is conducive to energy saving Environmental protection.It should be noted that the protection domain that preferred embodiment above is not intended to restrict the invention, in one or more embodiments Special characteristic, structure or feature can be combined by any suitable form.
Operation principle and preferred embodiment of the invention is described below:
The technique effect of technical way and acquirement that the present invention uses for:
1. will be one of in the dynamic and static scroll in scroll compressor or the whole or local surfaces of the two are done Differential arc oxidation processing, forms ceramic layer 3, and the wearability of the ceramic layer 3 is splendid, can greatly reduce parts depreciation amount and gradually increases and lead The problem of causing dynamic and static scroll cooperation precision to deviate preset value, and compressed gas is caused to be revealed, promotes the property of integrating compressor Energy;The minimum service life for extending scroll plate of wear extent of coating simultaneously, and then the use of entire compressor can be substantially improved Service life;
Cause ceramic layer 3 worn out 2. avoiding compressor long-term work, the aluminium base exposed and same type aluminium alloy conduct Adhesive wear is generated when friction is with pair, dynamic and static scroll is made to kill the phenomenon that eventually leading to complete machine failure;
3. greatly reducing dynamic and static scroll surface abrasion amount, the reliability of compressor is greatly improved;
4. reducing 3 surface of ceramic layer and friction coefficient when scroll plate break-in in the early stage, thrown when by differential arc oxidization surface Light or surface coat one layer of lubricant coating when, the friction system of the initial stage break-in between dynamic and static scroll can be further decreased Number avoids generating Local Instantaneous high temperature so that refrigerator oil occurs rotten and seriously affects showing for compressor performance and reliability As;
5. micro-arc oxidation process is simple, efficient, energy saving, pollution is reduced.
A preferred embodiment of the present invention is:
The present invention screw compressor the characteristics of be by dynamic and static scroll any one some or all of surface into The processing of row differential arc oxidation, treated, and surface can be polished or coat again one layer of lubricant coating, have reduction initial stage break-in Time, reduce initial stage break-in when friction coefficient, avoid refrigerator oil go bad, reduce compressed gas leakage, improve pressure Contracting machine performance and the wear rate for greatly reducing scroll plate, improve the service life of compressor.
As shown in figure 5, by taking automobile-used scroll compressor as an example, the scroll compressor includes case top lid 5, quiet vortex Part 2, compression chamber, dynamic vortex part 1, shell lower cover 6, upper bracket 7, bent axle 8.
It will be placed in differential arc oxidation slot after 2 oil removing of dynamic vortex part 1 and/or quiet scroll through washing and drying, through the differential of the arc The ceramic layer 3 of obtained densification has ultrahigh hardness and is to grow on base material in situ after oxidation, has excellent resistance to Mill property and good roughness.The constituent of the electrolyte of differential arc oxidation includes phosphate 10-15g/L, wolframic acid 2-5g/L, hydrogen Sodium oxide molybdena 0.2-1.5g/L, EDETATE SODIUM 1.5-5g/L.When differential arc oxidation:The pulse frequency 400-700HZ of power supply, pulse duration Than 10-20%, current density 2.5-6.5A/dm2, voltage 300-500V, electrolyte temperature is 20-40 DEG C, differential arc oxidation Time is 10-30min.Workpiece is washed and dried after differential arc oxidation.
The material of first main body 11 and second main body 21 is all made of forging or cast aluminium alloy gold, the aluminium alloy Constituent includes (being calculated in mass percent):Si:9-14%, Cu:0.5-3%, Mg are not more than 1%, Fe not more than 1%, Zn It is not more than 0.5% more than 0.8%, Ni, remaining is Al.To the two, the surface of one of them carries out differential arc oxidation processing.
The thickness of the obtained ceramic layer of micro-arc oxidation process described in the scheme of the invention 3 is 5-30 microns, preferably 10- 20 microns.
Dynamic vortex part 1 described in the scheme of the invention or quiet scroll 2, the 3 section vickers microhardness of ceramic layer on surface Not less than 900HV.
In the scheme of the invention, in addition propose 1 or quiet scroll 2 of dynamic vortex part be polished again after differential arc oxidation or Differential arc oxidization surface one layer of organosilicon of baking-curing or polytetrafluoroethylene (PTFE) (PTFE) or molybdenum disulfide (MoS2) lubricant coating again One kind, polishing thickness are best at 2-5 microns, and the thickness of the lubricant layer 4 of coating is 5-15 microns.
Dynamic vortex part 1 or quiet scroll 2 described in the scheme of the invention by micro-arc oxidation process or differential arc oxidation and after It handles obtained surface roughness Ra and is not more than 1 micron.
To sum up, it will be readily appreciated by those skilled in the art that under the premise of not conflicting, above-mentioned each advantageous manner can be certainly By combining, being superimposed.
The above, only better embodiment of the invention, not do limitation in any form to the present invention.It is any People can obtain other various forms of products under the inspiration of the present invention, however, making any change in its shape or structure Change, it is every that there is technical solution identical or similar to the present application, it is within the scope of the present invention.

Claims (16)

1. a kind of scroll compressor thermomechanical components, which is characterized in that including dynamic vortex part (1) and quiet scroll (2);
The dynamic vortex part (1) includes the first main body (11), and the quiet scroll (2) includes the second main body (21);Described in definition The surface opposite with second main body (21) is first surface in first main body (11), on second main body (21) with it is described The opposite surface of first main body (11) is second surface;
Ceramic layer (3) is formed by differential arc oxidation processing at the first surface and the second surface, to reduce the dynamic whirlpool The service wear of rotating part (1) and the quiet scroll (2);
First main body (11) and second main body (21) are made of aluminum alloy materials, the composition of the aluminum alloy materials Ingredient includes (by weight percentage):9-14%Si, 0.5-3%Cu, Mg≤1%, Fe > 1%, Zn≤0.8%, Ni≤ 0.5%, remaining is Al;
The ceramic layer (3) is al oxide layer.
2. scroll compressor thermomechanical components according to claim 1, which is characterized in that the thickness of the ceramic layer (3) is 5- 30μm。
3. scroll compressor thermomechanical components according to claim 2, which is characterized in that the thickness of the ceramic layer (3) is 10- 20μm。
4. according to claim 1-3 any one of them scroll compressor thermomechanical components, which is characterized in that the ceramic layer (3) Section vickers microhardness is not less than 900HV.
5. according to claim 1-3 any one of them scroll compressor thermomechanical components, which is characterized in that the ceramic layer (3) Surface roughness is not more than 1 μm.
6. scroll compressor thermomechanical components according to claim 5, which is characterized in that the surface of the ceramic layer (3) is passed through Polishing treatment, polishing thickness are 2-5 μm.
7. according to claim 1-3 or 6 any one of them scroll compressor thermomechanical components, which is characterized in that the ceramic layer (3) Surface be provided with lubricant layer (4), the surface roughness of the lubricant layer (4) is not more than 1 μm.
8. scroll compressor thermomechanical components according to claim 7, which is characterized in that the thickness of the lubricant layer (4) is 5- 15μm。
9. scroll compressor thermomechanical components according to claim 7, which is characterized in that the lubricant layer (4) be silicone layer, One kind in polytetrafluoroethylene ethylene layer or layer of molybdenum-disulfide.
10. a kind of scroll compressor, which is characterized in that including claim 1-9 any one of them scroll compressor units Part.
11. a kind of manufacturing method of claim 1-9 any one of them scroll compressor thermomechanical components, which is characterized in that including Following steps:
The second surface of first surface and second main body (21) to first main body (11) carries out differential arc oxidation processing, Make to form the ceramic layer (3) at the first surface and at the second surface.
12. the manufacturing method of scroll compressor thermomechanical components according to claim 11, which is characterized in that led described first Body (11), and/or second main body (21) are placed in progress differential arc oxidation processing, the constituent of the electrolyte in electrolyte Including:
Phosphate 10-15g/L, wolframic acid 2-5g/L, sodium hydroxide 0.2-1.5g/L, EDETATE SODIUM 1.5-5g/L.
13. the manufacturing method of scroll compressor thermomechanical components according to claim 12, which is characterized in that carry out differential arc oxidation The reaction condition of processing is:
Power pulse frequency 400-700Hz, pulse duty factor 10-20%, current density 2.5-6.5A/dm2, voltage 300- 500V, differential arc oxidation time are 10-30min, and the temperature of used electrolyte is 20-40 DEG C.
14. according to the manufacturing method of claim 11-13 any one of them scroll compressor thermomechanical components, which is characterized in that also Include the following steps:
The ceramic layer (3) is polished, the surface roughness Ra of the ceramic layer (3) after polishing is made to be not more than 1 μm.
15. the manufacturing method of scroll compressor thermomechanical components according to claim 14, which is characterized in that the ceramic layer (3) polishing thickness being polished is 2-5 μm.
16. being existed according to claim 11-13 or the manufacturing method of 15 any one of them scroll compressor thermomechanical components, feature In when including lubricant layer (4), the manufacturing method of the scroll compressor thermomechanical components is further comprising the steps of:
The lubricant layer (4) is formed in the surface baking-curing of the ceramic layer (3);The lubricant layer (4) is silicone layer, gathers One kind in tetrafluoroethene layer or layer of molybdenum-disulfide;And the surface roughness of the lubricant layer (4) is made to be not more than 1 μm, thickness is 5-15μm。
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