CN107227977B - Metal blade and processing method - Google Patents
Metal blade and processing method Download PDFInfo
- Publication number
- CN107227977B CN107227977B CN201610176522.6A CN201610176522A CN107227977B CN 107227977 B CN107227977 B CN 107227977B CN 201610176522 A CN201610176522 A CN 201610176522A CN 107227977 B CN107227977 B CN 107227977B
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- Prior art keywords
- metal blade
- arc oxidation
- differential arc
- solid lubricant
- blade
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/26—Anodisation of refractory metals or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/30—Anodisation of magnesium or alloys based thereon
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D25/00—Component parts, details, or accessories, not provided for in, or of interest apart from, other groups
- F01D25/18—Lubricating arrangements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04C—ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT PUMPS
- F04C29/00—Component parts, details or accessories of pumps or pumping installations, not provided for in groups F04C18/00 - F04C28/00
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04C—ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT PUMPS
- F04C29/00—Component parts, details or accessories of pumps or pumping installations, not provided for in groups F04C18/00 - F04C28/00
- F04C29/02—Lubrication; Lubricant separation
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating By Spraying Or Casting (AREA)
- Structures Of Non-Positive Displacement Pumps (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
Abstract
The invention discloses a kind of metal blade and accordingly to the processing method of metal blade, comprising: carry out differential arc oxidation to metal blade;Solid lubricant is applied to the metal blade, wherein supporting body of the micropore of the differential arc oxidation layer on the metal blade as the solid lubricant.Treated the metal blade has differential arc oxidation layer;The differential arc oxidation layer has solid lubricant, wherein supporting body of the micropore of the differential arc oxidation layer as the solid lubricant.Using the present invention, the higher fretting wear resistance property of metal blade, the performance of the metal blade anti-fretting wear with higher are realized with lower cost, and preparation cost is lower.
Description
Technical field
The present invention relates to industrial equipment manufacturing fields, more particularly to a kind of metal blade and processing method.
Background technique
Compared with stainless steel, titanium alloy, such as TC4 and Ti-6Al-4V, there is excellent corrosion resistance and strength-weight
Than.Therefore, titanium alloy has been widely used for steam turbine and compressor blade, especially for limiting the large-sized of centrifugal stress
Blade.
Although titanium alloy has excellent chemically and physically mechanical performance, usual hardness is low, and wearability is poor.Especially
It is the schematic diagram of the fretting wear as shown in Figure 1 between metal blade and fine motion system, when titanium alloy is applied in turbine leaf
When on piece, there are contact movements between metal blade 101 and wheel disc 102.The abrasion of contact surface 103 under load and material
Transfer and relative motion, will lead to so-called fretting wear.The fatigue that the fretting wear will affect blade contact surface 103 is strong
Spend and will lead to small fatigue crack, i.e. fine motion crackle.The diffusion of this fine motion crackle finally will lead to blade fault.
Fretting Fatigue Damage caused by fretting wear is a kind of most common failure of turbo blade, blade made of titanium alloy
(referred to as titanium blade) is even more so.A variety of solutions have been proposed in industry at present, to protect titanium alloy blade far from micro-
It is dynamic to wear caused failure.
A kind of typical prior art is: by way of plating or thermal spraying, increasing in the contact surface 103 hard
The coating of matter ceramics.However, the hard ceramic is usually extremely fragile, and has relatively low bonding force with titanium blade,
This will lead to solid-ceramic coating and is easy to produce crackle, or even remove from titanium blade.
Another prior art is: spraying more soft coarse cupro-nickel in the contact surface by thermal spraying mode
Indium (CuNiIn) material is fixed as sliding thin layer of lubricant.But the limitation of this protective coating is lower highest work
Temperature and service life.In addition, the main component indium of CuNiIn material is a kind of rare earth element, supply is few, at high cost, this
It is a main problem.Researcher is look for the solution of the fretting wear of substitution CuNiIn coating at present.
Further more, the titanium oxide layer of one layer of hard can be generated in surface of metal titanium oxidation, this titanium oxide layer is had been used for titanium
The anti-corrosion protection of blade.However, the oxide layer that generates of traditional anodic oxidation usually very thin (several or tens microns) is very crisp,
It is weaker with parent metal binding force, it is not suitable for the long-time protection of fretting wear.
Summary of the invention
Embodiment of the present invention proposes a kind of processing methods of metal blade, to realize metal blade with lower cost
Higher fretting wear resistance property.
Embodiment of the present invention proposes a kind of metal blade, the performance of higher anti-fretting wear can have, and prepare
Cost is relatively low.
It is described that technical scheme is as follows:
A kind of processing method of metal blade, comprising:
Differential arc oxidation is carried out to metal blade;
Solid lubricant is applied to the metal blade, wherein the micropore conduct of the differential arc oxidation layer on the metal blade
The supporting body of the solid lubricant.
In a kind of preferred embodiment of processing method of the present invention, solid lubricant is applied to the metal blade
During step includes: the differential arc oxidation described to metal blade, solid is directly added in the electrolyte of differential arc oxidation
Lubricant.
In a kind of preferred embodiment of processing method of the present invention, solid lubricant is applied to the metal blade
Step includes: after carrying out differential arc oxidation to the metal blade, and the differential arc oxidation layer of Xiang Suoshu metal blade sprays solid lubrication
Agent.
In a kind of preferred embodiment of processing method of the present invention, to metal blade carry out differential arc oxidation the step of packet
It includes: differential arc oxidation is carried out to the leaf root part of the metal blade and sheave contact.
In a kind of preferred embodiment of processing method of the present invention, the metal blade include: titanium alloy blade or
Aluminium alloy vane or magnesium alloy blade.
In a kind of preferred embodiment of processing method of the present invention, the solid lubricant includes: graphite or nitridation
Boron or molybdenum disulfide or calcirm-fluoride.
A kind of metal blade, the metal blade have differential arc oxidation layer;The differential arc oxidation layer has solid lubricant,
Wherein supporting body of the micropore of the differential arc oxidation layer as the solid lubricant.
In a kind of preferred embodiment of metal blade of the present invention, the blade root with sheave contact of the metal blade
Part has the differential arc oxidation layer.
In a kind of preferred embodiment of metal blade of the present invention, the metal blade include: titanium alloy blade or
Aluminium alloy vane or magnesium alloy.
In a kind of preferred embodiment of metal blade of the present invention, the solid lubricant includes: graphite or nitridation
Boron or molybdenum disulfide or calcirm-fluoride.
It can be seen from the above technical proposal that in embodiments of the present invention, using micro-arc oxidation process to metal leaf
Piece has carried out differential arc oxidation, by differential arc oxidation at the protective layer as anti-fretting wear, CuNiIn material layer compared with prior art,
The present invention can be prepared with simple equipment, and production cost is cheaper;Moreover, because between differential arc oxidation layer and metal blade
Combination belong to metallurgical bonding, to have very high adhesion strength, there is good adhesive property to metal blade, compared to existing
The solid-ceramic coating of technology is stronger and good toughness, the performance of anti-fretting wear are stronger;Meanwhile the differential arc oxidation layer tool
There is porous structure, micropore therein can be used for carrying additional solid lubricant, so as to improve wear-out life, because described
Solid lubricant can constantly come out from the micropore of differential arc oxidation layer, constantly play lubricating action.
Metal blade of the present invention, not only can be adapted for titanium alloy blade, be readily applicable to aluminium alloy vane,
The metal blade is particularly applicable in the blade of steam turbine, compressor, gas turbine.
Detailed description of the invention
Fig. 1 show the schematic diagram of the fretting wear between metal blade and fine motion system;
Fig. 2 is a kind of implementation flow chart of the processing method of metal blade of the present invention;
Fig. 3 is the schematic diagram of differential arc oxidation production equipment;
Fig. 4 is the surface of the oxide layer of traditional anodic oxidation and differential arc oxidation generation and the contrast schematic diagram of cross section.
Wherein, appended drawing reference is as follows:
Specific embodiment
In order to which technical solution of the present invention and advantage is more clearly understood, below in conjunction with drawings and the embodiments, to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are only used to illustrative illustrate originally
Invention, is not intended to limit the scope of protection of the present invention.
In embodiments of the present invention, a kind of processing method of metal blade is proposed.Fig. 2 is metal leaf of the present invention
A kind of implementation flow chart of the processing method of piece, referring to fig. 2, a kind of embodiment of the processing method of the metal blade are mainly wrapped
It includes:
201, differential arc oxidation is carried out to metal blade.
202, solid lubricant is applied to the metal blade, wherein the micropore of the differential arc oxidation layer on the metal blade
Supporting body as the solid lubricant.
By processing of the invention, the metal blade has following feature: the metal blade has differential arc oxidation
Layer;The differential arc oxidation layer has solid lubricant, wherein the micropore of the differential arc oxidation layer is as the solid lubricant
Supporting body.
The differential arc oxidation (MAO) is a kind of plasma electrolysis deposition technology, is by electrolyte and corresponding electrical parameter
Combination, aluminium, magnesium, titanium and its alloy surface by arc discharge generate TRANSIENT HIGH TEMPERATURE high pressure effect, grow with matrix
Ceramic film based on metal oxide.Differential arc oxidization technique breaches the voltage limitation of traditional anodic oxidation, can be quick
Generate thicker oxide layer.
Fig. 3 is the schematic diagram of differential arc oxidation production equipment.Referring to Fig. 3, the production process of differential arc oxidation is relatively easy, will not
It is related to costly and complicated equipment, compared with prior art CuNiIn material layer, the present invention can be prepared with simple equipment, production
Cost is cheaper.The equipment being directed to include multifunctional power 301, stainless steel sink 302, blender 303, thermometer 304,
Cooling system 305, has electrolyte in the stainless steel sink 302, and metal blade 306 is placed in the electrolytic solution, by multi-functional electricity
The power supply of source 301 carries out differential arc oxidation to the metal blade 306.
The thickness for the oxide layer that the differential arc oxidation generates can by time of differential arc oxidation, electrolyte concentration, with
And the mode for applying voltage (up to 2kV) to selected electrolyte is adjusted, and in the preferred embodiment, the gold
The preferred thickness for belonging to the differential arc oxidation layer of blade can be 100 to 500 microns.
The hardness for the oxide layer that the differential arc oxidation generates can be by the concentration of electrolyte and to selected electrolyte
It applies alive mode to be adjusted, the hardness of the differential arc oxidation layer can be up to 1000-4000 Vickers hardness (Hv).
Since the differential arc oxidation layer of the metal blade has preferable thickness and hardness, have outstanding wear-resisting
Property, especially have outstanding fretting wear resistance property.
Moreover, differential arc oxidation layer is since the differential of the arc dissolves, meeting and metal blade unlike other existing thermal Sperayed Ceramic Coatings
Surface carry out metallurgical bonding, to have very high adhesion strength, not cracky.If Fig. 4 is traditional anodic oxidation and the differential of the arc
Aoxidize the surface of the oxide layer generated and the contrast schematic diagram of cross section.Left side 401 generates in Fig. 4 for traditional anodic oxidation
Oxide layer, top half 411 are the surface of the oxide layer, and lower half portion 412 is the cross section of the oxide layer.Right side 402 in Fig. 4
For differential arc oxidation differential arc oxidation layer generated, top half 421 is the surface of the differential arc oxidation layer, and lower half portion 422 is should
The cross section of differential arc oxidation layer.Compare traditional anodic oxidation and oxide layer cross section that differential arc oxidation generates this it appears that
The oxide layer of differential arc oxidation is even closer in conjunction with parent metal.
In addition, differential arc oxidation layer also shows less defect and good toughness.The toughness refers to: can be according to need
The power of adjustment differential arc oxidation and the ingredient of electrolyte are asked, so that differential arc oxidation layer generates in corresponding structure
Change, to be suitable for different scene demands.By taking aluminium alloy as an example, different from the amorphous structure that anodic oxidation is formed, the differential of the arc
Oxidation is formed by ceramic structure mainly by γ-Al2O3Phase and α-Al2O3Phase composition, wherein α-Al2O3Mutually make film hardness it is high,
Wearability is good, and γ-Al2O3The toughness for mutually having had film layer can accordingly adjust two-phase by adjusting differential arc oxidation parameter
Ratio, to optimize the comprehensive performance of oxidation film.These features of differential arc oxidation make differential arc oxidation layer be suitable for metal leaf
The protection of piece fretting wear.
Meanwhile electrolyte used in the differential arc oxidation is neutral or weakly alkaline solution, wherein heavy metal is not added, because
This pollution on the environment is small, and opposite conventional anodization or chromaking surface treatment are environmental-friendly.And differential arc oxidation is forever
For night temperature based on room temperature, variation range is wider, easily operated.In addition, because not being related to the high-temperature heat treatment to parent metal
Process, thus will not shape to blade and mechanical performance adversely affect.
One feature of differential arc oxidation layer be oxide layer it is thicker and have porosity, it is from Fig. 4 it will be clear that micro-
There are many micropores on the surface of arc oxide layer 421, these micropores may be certain defect of differential arc oxidation layer, example in some aspects
As these micropores may influence whether the corrosion resistance of differential arc oxidation layer.However, differential arc oxidation is but dexterously utilized in the present invention
These micropores on layer.I.e. the present invention applies solid lubricant to the metal blade, wherein the differential of the arc on the metal blade
Supporting body of the micropore of oxide layer as the solid lubricant.That is, the protection of the fretting wear for metal blade
For, the micropore on the differential arc oxidation layer is a kind of advantage instead, these micropores can be used as additional solid lubricant
Supporting body.
Micropore on the differential arc oxidation layer can be used as the complete supporting body of the solid lubricant, the differential of the arc oxygen
Changing the micropore on layer can also be used as the part supporting body of the solid lubricant.
So-called complete supporting body refers to that the solid lubricant is not applied on the surface of the differential arc oxidation layer, and
It is consequently exerted in the micropore of the differential arc oxidation layer, in abrasion, the solid lubricant can be constantly from differential arc oxidation layer
Micropore in release, lubricating action is constantly played, to improve wear-out life.
So-called part supporting body refers to a part of table that can be applied to the differential arc oxidation layer of the solid lubricant
On face, a part can be applied in the micropore of the differential arc oxidation layer.Since the differential arc oxidation layer of metal blade applies
Solid lubricant, therefore the present invention can further decrease fretting damage, the differential arc oxidation layer has porous structure, wherein
Micropore can be used for carrying additional fraction solids lubricant, the solid lubricant in differential arc oxidation layer surface can first be worn,
After having worn to the solid lubricant in differential arc oxidation layer surface, the solid lubricant can be constantly from differential arc oxidation layer
Micropore in release, lubricating action is constantly played, to improve wear-out life.
In the present invention, the solid lubricant be can specifically include: graphite or boron nitride or molybdenum disulfide or calcirm-fluoride
Equal lubricants, can choose according to actual conditions such as operating temperatures.
In one preferred embodiment of the invention, described that solid lubricant is applied to the metal blade, it is specific real
The mode of applying can include at least two kinds:
The first applies the mode of solid lubricant are as follows: during the differential arc oxidation to metal blade, micro-
Solid lubricant is directly added in the electrolyte of arc oxidation.As shown in figure 3, straight in electrolyte into the stainless steel sink 302
Addition solid lubricant is connect, then during differential arc oxidation, added solid lubricant can adhere to automatically in electrolyte
On the surface for being formed by differential arc oxidation layer and/or in micropore.
The mode of second of application solid lubricant are as follows: differential arc oxidation first is carried out to the metal blade, in metal blade
After generating differential arc oxidation layer, the differential arc oxidation layer of Xiang Suoshu metal blade sprays solid lubricant, and the solid lubricant is sprayed
It is coated on the surface of differential arc oxidation layer and/or in micropore.
Optionally, metal blade of the present invention carries out differential arc oxidation, can be and carries out to the entirety of the metal blade
The differential arc oxidation, the metal blade has the differential arc oxidation layer on the whole, and the differential arc oxidation layer moistens with solid
Lubrication prescription, wherein supporting body of the micropore of the differential arc oxidation layer as the solid lubricant.
In another embodiment, for save the cost, as shown in Figure 1, can also be only to the metal blade 101 and wheel
The leaf root part that disk 102 contacts carries out the differential arc oxidation, i.e., the leaf root part of the described metal blade has the differential arc oxidation
Layer, and blade-section does not have the differential arc oxidation layer, the differential arc oxidation layer of the leaf root part has solid lubricant, wherein
Supporting body of the micropore of the differential arc oxidation layer as the solid lubricant.
Processing of the present invention to metal blade, metal blade therein can be titanium alloy blade, be also possible to
Aluminium alloy or magnesium alloy blade are also possible to other a certain specified metal blades certainly if there is specific demand.The gold
Belong to blade to be particularly applicable in the blade of steam turbine, compressor, gas turbine.Using metal blade of the present invention,
Quality and the service life of blade can be improved, reduce manufacture, maintenance and repair expense, and can also allow for higher operating temperature
To improve system effectiveness.
In addition, specific functional components can also be added directly into the electrolyte of differential arc oxidation by the present invention, thus
It can be further improved the performance of differential arc oxidation layer.
In conclusion differential arc oxidation has been carried out to metal blade present invention employs micro-arc oxidation process, by differential of the arc oxygen
Change protective layer of the layer as anti-fretting wear, CuNiIn material layer, the present invention can use simple equipment system compared with prior art
Standby, production cost is cheaper;Moreover, because the combination between maintenance oxide layer and metal blade belongs to metallurgical bonding, thus
With very high adhesion strength, there is good adhesive property to metal blade, solid-ceramic coating compared with prior art is more
Securely, the performance of anti-fretting wear is stronger;Meanwhile the differential arc oxidation layer has porous structure, micropore therein can be used for holding
Additional solid lubricant is carried, so as to improve wear-out life, because the solid lubricant can be constantly from differential of the arc oxygen
Change in the micropore of layer and come out, constantly plays lubricating action.Metal blade of the present invention not only can be adapted for titanium alloy leaf
Piece, is readily applicable to aluminium alloy vane, and the metal blade is particularly applicable to the leaf of steam turbine, compressor, gas turbine
In piece.
The foregoing is only a preferred embodiment of the present invention, is not intended to limit the scope of the present invention.It is all
Within the spirit and principles in the present invention, any modification, equivalent replacement, improvement and so on should be included in protection of the invention
Within the scope of.
Claims (10)
1. a kind of processing method of metal blade characterized by comprising
Differential arc oxidation is carried out to metal blade;
Solid lubricant is applied to the metal blade, wherein described in the micropore conduct of the differential arc oxidation layer on the metal blade
The supporting body of solid lubricant.
2. the method according to claim 1, wherein the step of applying solid lubricant to the metal blade is wrapped
It includes: during the differential arc oxidation to metal blade, directly adding solid lubricant in the electrolyte of differential arc oxidation.
3. the method according to claim 1, wherein the step of applying solid lubricant to the metal blade is wrapped
Include: after carrying out differential arc oxidation to the metal blade, the differential arc oxidation layer of Xiang Suoshu metal blade sprays solid lubricant.
4. the method according to claim 1, wherein the step of carrying out differential arc oxidation to metal blade packet
It includes: differential arc oxidation is carried out to the leaf root part of the metal blade and sheave contact.
5. method according to any one of claims 1 to 4, which is characterized in that the metal blade includes: titanium alloy leaf
Piece or aluminium alloy vane or magnesium alloy blade.
6. method according to any one of claims 1 to 4, which is characterized in that the solid lubricant include: graphite or
Boron nitride or molybdenum disulfide or calcirm-fluoride.
7. a kind of metal blade, which is characterized in that
The metal blade has differential arc oxidation layer;
The differential arc oxidation layer has solid lubricant, wherein the micropore of the differential arc oxidation layer is as the solid lubricant
Supporting body.
8. metal blade according to claim 7, which is characterized in that the blade root with sheave contact of the metal blade
Dividing has the differential arc oxidation layer.
9. metal blade according to claim 7 or 8, which is characterized in that the metal blade include: titanium alloy blade,
Or aluminium alloy vane or magnesium alloy.
10. metal blade according to claim 7 or 8, which is characterized in that the solid lubricant includes: graphite or nitrogen
Change boron or molybdenum disulfide or calcirm-fluoride.
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CN108468075A (en) * | 2018-03-27 | 2018-08-31 | 杭州电子科技大学 | A kind of electrolyte and its application process of differential arc oxidation self-lubricating composite ceramic coating |
CN109576542A (en) * | 2018-12-29 | 2019-04-05 | 安徽鑫发铝业有限公司 | A kind of wear-resisting outer casing of power supply aluminum profile |
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CN102011166A (en) * | 2010-10-20 | 2011-04-13 | 安泰科技股份有限公司 | Aluminum-based composite material with ultra-low friction coefficient and preparation method thereof |
CN102021629A (en) * | 2010-12-30 | 2011-04-20 | 南昌航空大学 | Method for preparing titanium-alloy surface micro-arc oxidation antifriction compound film layer |
CN103103597A (en) * | 2013-01-23 | 2013-05-15 | 西北工业大学 | Titanium alloy self-lubricating composite film and preparation method thereof |
CN103384728A (en) * | 2011-01-18 | 2013-11-06 | 马勒国际公司 | Thermal spray coating with a dispersion of solid lubricant particles |
CN103498181A (en) * | 2013-09-04 | 2014-01-08 | 沈阳理工大学 | Preparation method of self-lubricating wear-resistant coating on surfaces of titanium and titanium alloy |
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CN102011166A (en) * | 2010-10-20 | 2011-04-13 | 安泰科技股份有限公司 | Aluminum-based composite material with ultra-low friction coefficient and preparation method thereof |
CN102021629A (en) * | 2010-12-30 | 2011-04-20 | 南昌航空大学 | Method for preparing titanium-alloy surface micro-arc oxidation antifriction compound film layer |
CN103384728A (en) * | 2011-01-18 | 2013-11-06 | 马勒国际公司 | Thermal spray coating with a dispersion of solid lubricant particles |
CN103103597A (en) * | 2013-01-23 | 2013-05-15 | 西北工业大学 | Titanium alloy self-lubricating composite film and preparation method thereof |
CN103498181A (en) * | 2013-09-04 | 2014-01-08 | 沈阳理工大学 | Preparation method of self-lubricating wear-resistant coating on surfaces of titanium and titanium alloy |
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