CN106758530B - Blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent and its application process - Google Patents

Blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent and its application process Download PDF

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Publication number
CN106758530B
CN106758530B CN201611129456.3A CN201611129456A CN106758530B CN 106758530 B CN106758530 B CN 106758530B CN 201611129456 A CN201611129456 A CN 201611129456A CN 106758530 B CN106758530 B CN 106758530B
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China
Prior art keywords
paper
resisting
treating agent
blue
humidity
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CN201611129456.3A
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CN106758530A (en
Inventor
钟善
黄倩
侯可禹
宋存雪
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Shinva Medical Instrument Co Ltd
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Shinva Medical Instrument Co Ltd
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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/04—Physical treatment, e.g. heating, irradiating
    • D21H25/06—Physical treatment, e.g. heating, irradiating of impregnated or coated paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/675—Oxides, hydroxides or carbonates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/143—Agents preventing ageing of paper, e.g. radiation absorbing substances

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Paper (AREA)

Abstract

The present invention relates to a kind of blue high-temp resisting high-humidity resisting U.S.'s line paper paper treating agent and its application processes, belong to speciality paper processing technology field.Blue high-temp resisting high-humidity resisting U.S. of the present invention line paper paper treating agent, is made of the raw material of following weight percentage：Anatase thpe white powder 45~60%；Rutile type titanium white 20~35%；Quaternary ammonium salt 5~8%；Anti-aging agent 3~5%；Cobalt blue 10~15%.Blue high-temp resisting high-humidity resisting U.S. of the present invention line paper paper treating agent, raw material environmental protection are easy to get, and the use condition of high temperature and humidity, performance and colour stable are met with its processed U.S. line paper；Invention also provides simple and practicable application processes.

Description

Blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent and its application process
Technical field
The present invention relates to a kind of blue high-temp resisting high-humidity resisting U.S.'s line paper paper treating agent and its application processes, belong to speciality paper Processing technology field.
Background technology
Speciality paper refers to the paper for manufacturing or being transformed for specific final use, and the paper of this grade is generally simply possible to use in it Scheduled specific use.In view of the excellent flexible and tensile property of U.S. line paper, in the form of packaging material, label, adhesive tape, It is widely applied during hospital disinfection supply room sterilization, as non-woven fabrics is in the large area of field of disinfection and sterilization Using a kind of blue high-temp resisting high-humidity resisting U.S. line paper speciality paper of urgent need.And existing paper treating agent, it is beautiful after the processing of U.S. line paper The performance and color of line paper are simultaneously unstable, have much room for improvement.
Invention content
The object of the present invention is to provide a kind of blue high-temp resisting high-humidity resisting U.S. line paper paper treating agents, and raw material environmental protection is easily , the use condition of high temperature and humidity, performance and colour stable are met with its processed U.S. line paper；Invention also provides letters Single easy application process.
Blue high-temp resisting high-humidity resisting U.S. of the present invention line paper paper treating agent, by the raw material of following weight percentage Composition：
Anatase thpe white powder 45~60%；
Rutile type titanium white 20~35%；
Quaternary ammonium salt 5~8%；
Anti-aging agent 3~5%；
Cobalt blue 10~15%.
Preferably, it is made of the raw material of following weight percentage：
Anatase thpe white powder 45%；
Rutile type titanium white 35%；
Quaternary ammonium salt 5%；
Anti-aging agent 3%；
Cobalt blue 12%.
Preferably, it is made of the raw material of following weight percentage：
Anatase thpe white powder 52%；
Rutile type titanium white 28%；
Quaternary ammonium salt 6%；
Anti-aging agent 4%；
Cobalt blue 10%.
Preferably, anti-aging agent 4010NA.
The granularity of the anatase thpe white powder and rutile type titanium white≤1 micron, impurity content≤0.1%.
Quaternary ammonium salt is preferably hexadecyltrimethylammonium chloride or dodecyl benzyl dimethyl ammonium chloride.
The application process of blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent, includes the following steps：
(1) solvent is made with absolute ethyl alcohol, first the raw material of the paper treating agent is mixed, then use three-roll grinder It is ground to≤6 microns；
(2) after the ground paper treating agent of step (1) being dissolved with latex, impregnation U.S. line paper body paper；
(3) by the U.S. line paper body paper of step (2) impregnation after baking oven is dried, treated finished product is obtained.
The latex is acrylic emulsion, NBR latex or polychloroprene latex.The compatibility of the inorganic agent and latex is good, can Improve the performances such as tensile strength, heatproof and the solvent resistant of paper.
To obtained at royal blue high-temp resisting high-humidity resisting U.S. line paper, the high temperature of 140 ± 5 DEG C of experience, the special type of saturated vapor After condition, the performance and color of U.S. line paper will not change, and meet in hospital disinfection sterilization process to the need of extraordinary U.S. line paper It asks.
In blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent, the good rutile type titanium of heat resistance is added White powder, and the flexibility of paper is preferably adjusted with hexadecyltrimethylammonium chloride is cooperateing with work with other formula components Under, it is applied to U.S. line paper, the product being had excellent performance.
The invention has the advantages that：
(1) blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent described in, raw material environmental protection is easy to get, processed with its U.S. line paper meets the use condition of high temperature and humidity, has heat resistance, barrier performance and good toughness, and performance and color are steady It is fixed.
(2) invention also provides the application processes of simple and practicable paper treating agent.
Specific implementation mode
With reference to embodiment, the present invention is further illustrated, but it is not intended to limit the implementation of the present invention.
Embodiment 1
Blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent, is made of the raw material of following weight percentage：
Anatase thpe white powder 45%；
Rutile type titanium white 35%；
Hexadecyltrimethylammonium chloride 5%；
Anti-aging agent 3%；
Cobalt blue 12%.
The application process of blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent, includes the following steps：
(1) solvent is made with absolute ethyl alcohol, first the raw material of the paper treating agent is mixed, then use three-roll grinder It is ground to 6 microns；
(2) after the ground paper treating agent of step (1) being dissolved with acrylic emulsion, impregnation U.S. line paper body paper；
(3) by the U.S. line paper body paper of step (2) impregnation after baking oven is dried, treated finished product is obtained.
Embodiment 2
Blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent, is made of the raw material of following weight percentage：
Anatase thpe white powder 52%；
Rutile type titanium white 28%；
Hexadecyltrimethylammonium chloride 6%；
Anti-aging agent 4%；
Cobalt blue 10%.
The application process of blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent, includes the following steps：
(1) solvent is made with absolute ethyl alcohol, first the raw material of the paper treating agent is mixed, then use three-roll grinder It is ground to≤6 microns；
(2) after the ground paper treating agent of step (1) being dissolved with NBR latex, impregnation U.S. line paper body paper；(3) By the U.S. line paper body paper of step (2) impregnation after baking oven is dried, treated finished product is obtained.
Embodiment 3
Blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent, is made of the raw material of following weight percentage：
Anatase thpe white powder 60%；
Rutile type titanium white 20%；
Dodecyl benzyl dimethyl ammonium chloride 5%；
Anti-aging agent 3%；
Cobalt blue 12%.
The application process of blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent, includes the following steps：
(1) solvent is made with absolute ethyl alcohol, first the raw material of the paper treating agent is mixed, then use three-roll grinder It is ground to 6 microns；
(2) after the ground paper treating agent of step (1) being dissolved with polychloroprene latex, impregnation U.S. line paper body paper；
(3) by the U.S. line paper body paper of step (2) impregnation after baking oven is dried, treated finished product is obtained.
Embodiment 4
Blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent, is made of the raw material of following weight percentage：
Anatase thpe white powder 55%；
Rutile type titanium white 20%；
Hexadecyltrimethylammonium chloride 8%；
Anti-aging agent 4%；
Cobalt blue 13%.
The application process of blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent, includes the following steps：
(1) solvent is made with absolute ethyl alcohol, first the raw material of the paper treating agent is mixed, then use three-roll grinder It is ground to 6 microns；
(2) after the ground paper treating agent of step (1) being dissolved with polychloroprene latex, impregnation U.S. line paper body paper；
(3) by the U.S. line paper body paper of step (2) impregnation after baking oven is dried, treated finished product is obtained.
By blue high-temp resisting high-humidity resisting U.S. line paper that inorganic agent processing obtains made from embodiment 1-4, product parameters are as follows Table：

Claims (8)

1. a kind of blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent, it is characterised in that by the raw material of following weight percentage Composition：
Anatase thpe white powder 45~60%；
Rutile type titanium white 20~35%；
Quaternary ammonium salt 5~8%；
Anti-aging agent 3~5%；
Cobalt blue 10~15%；
The application process of blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent, includes the following steps：
(1) solvent is made with absolute ethyl alcohol, first the raw material of the paper treating agent is mixed, then is ground with three-roll grinder Mill；
(2) after the ground paper treating agent of step (1) being dissolved with latex, impregnation U.S. line paper body paper；
(3) by the U.S. line paper body paper of step (2) impregnation after baking oven is dried, treated finished product is obtained；
In step (2), latex is acrylic emulsion, NBR latex or polychloroprene latex.
2. blue high-temp resisting high-humidity resisting U.S. according to claim 1 line paper paper treating agent, it is characterised in that by following heavy Measure the raw material composition of percentage composition：
Anatase thpe white powder 45%；
Rutile type titanium white 35%；
Quaternary ammonium salt 5%；
Anti-aging agent 3%；
Cobalt blue 12%.
3. blue high-temp resisting high-humidity resisting U.S. according to claim 1 line paper paper treating agent, it is characterised in that by following heavy Measure the raw material composition of percentage composition：
Anatase thpe white powder 52%；
Rutile type titanium white 28%；
Quaternary ammonium salt 6%；
Anti-aging agent 4%；
Cobalt blue 10%.
4. according to blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent described in claim 1,2 or 3, it is characterised in that：It is anti- Old agent is 4010NA.
5. according to blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent described in claim 1,2 or 3, it is characterised in that：It is sharp The granularity of titanium-type titanium dioxide and rutile type titanium white≤1 micron, impurity content≤0.1%.
6. according to blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent described in claim 1,2 or 3, it is characterised in that：Season Ammonium salt is hexadecyltrimethylammonium chloride.
7. according to blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent described in claim 1,2 or 3, it is characterised in that：Season Ammonium salt is dodecyl benzyl dimethyl ammonium chloride.
8. the application process of blue high-temp resisting high-humidity resisting U.S. according to claim 1 line paper paper treating agent, feature exist In：In step (1) ,≤6 microns are ground to three-roll grinder.
CN201611129456.3A 2016-12-09 2016-12-09 Blue high-temp resisting high-humidity resisting U.S. line paper paper treating agent and its application process Active CN106758530B (en)

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CN108411704A (en) * 2018-01-18 2018-08-17 华南理工大学 A kind of high interfacial bonding strength dumb light U.S. line paper and preparation method thereof
CN113529476A (en) * 2021-06-29 2021-10-22 山东新华医疗器械股份有限公司 Soft high-temperature-resistant high-humidity-resistant textured paper treating agent and application method thereof

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KR20140063624A (en) * 2011-07-27 2014-05-27 쓰리엠 이노베이티브 프로퍼티즈 컴파니 Hand-tearable masking tape with low adhesion backsize
CN103015258A (en) * 2012-12-25 2013-04-03 浙江晶鑫特种纸业有限公司 Manufacturing process for macerative masking tape
CN103305154B (en) * 2013-07-15 2016-01-20 张家港康得新光电材料有限公司 A kind of adhesive tape high temperature resistant pressure sensitive adhesive, adhesive tape and preparation method
CN104499371A (en) * 2014-11-25 2015-04-08 南通四通林业机械制造安装有限公司 High strength impregnation textured paper production process
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