CN109971279A - A kind of antibiotic paint formula for plasthetics surface - Google Patents

A kind of antibiotic paint formula for plasthetics surface Download PDF

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Publication number
CN109971279A
CN109971279A CN201910276290.5A CN201910276290A CN109971279A CN 109971279 A CN109971279 A CN 109971279A CN 201910276290 A CN201910276290 A CN 201910276290A CN 109971279 A CN109971279 A CN 109971279A
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China
Prior art keywords
parts
powder
epoxy resin
agent
curing agent
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Pending
Application number
CN201910276290.5A
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Chinese (zh)
Inventor
张振天
黄龙
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Jiangsu Xicheng New Mstar Technology Ltd
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Jiangsu Xicheng New Mstar Technology Ltd
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Publication of CN109971279A publication Critical patent/CN109971279A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0893Zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/28Nitrogen-containing compounds
    • C08K2003/282Binary compounds of nitrogen with aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of antibiotic paint formulas for plasthetics surface, the A for being 20~30% including weight percent forms the B composition for being 70~80% with weight percent, wherein, in parts by weight, the A composition includes: 10~15 parts of acrylic acid ester emulsion, 8~12 parts of epoxy resin latex, 3~8 parts of curing agent, 60~70 parts of zinc powder, the B composition includes: 30~40 parts of acrylic acid ester emulsion, 10~20 parts of epoxy resin latex, 5~10 parts of curing agent, 20~30 parts of ceramic nitriding aluminium powder, 3~5 parts of Neon SiC powder, 2~4 parts of nano grade silica particles, 1~3 part of inorganic antiseptic, 2~5 parts of defoaming agent, 1~3 part of levelling agent, 70~80 parts of deionized water.Coating in the present invention has good anti-microbial property, can reduce the growth of bacterium, while having certain wearability, excellent combination property has broad application prospects in the use aspect of plasthetics.

Description

A kind of antibiotic paint formula for plasthetics surface
Technical field
The present invention relates to plastic surface technical field of coatings, apply more particularly to a kind of antibacterial for plasthetics surface Material formula.
Background technique
With the rapid development and continuous improvement of people's living standards of China's economy, pursuit of the people to quality of life Also it is increasingly stringenter, good home environment is the main target that people pursue now.
Existing people fit up house before inhabitation, and Decoration Design field is calculated inside building trade at present It is more showing tremendous enthusiasm industry, the personnel for being engaged in finishing also compare more.It is well known that coating is that one kind must not in finishing field The finishing material that can lack, coating is generally brushed and plastic rubber member surface, still, after existing coating is using completing, inside house It generates a large amount of pernicious gas and plastic parts use for a long time can breed bacterium with rear surface, seriously affected the human body of people Health brings certain inconvenience to the use of people.
For this reason, it is necessary in view of the above-mentioned problems, propose a kind of antibiotic paint formula for plasthetics surface, it can Solve problems of the prior art.
Summary of the invention
The purpose of the present invention is to provide a kind of antibiotic paint formulas for plasthetics surface, to overcome the prior art In deficiency.
To achieve the above object, the invention provides the following technical scheme:
A kind of antibiotic paint formula for plasthetics surface, including weight percent be 20~30% A composition and The B that weight percent is 70~80% is formed, wherein in parts by weight, A composition include: acrylic acid ester emulsion 10~ 15 parts, 8~12 parts of epoxy resin latex, 3~8 parts of curing agent, 60~70 parts of zinc powder, the B composition includes: acrylic acid ester emulsion 30~40 parts, 10~20 parts of epoxy resin latex, 5~10 parts of curing agent, 20~30 parts of ceramic nitriding aluminium powder, nanometer silicon carbide 3~5 parts of powder, 2~4 parts of nano grade silica particles, 1~3 part of inorganic antiseptic, 2~5 parts of defoaming agent, 1~3 part of levelling agent, 70~80 parts of deionized water.
Preferably, the partial size of the Neon SiC powder and the nano grade silica particles is respectively 50~100nm With 80~120nm.
Preferably, the inorganic antiseptic is the mixture of zinc oxide and silver oxide.
Preferably, the mass ratio of the zinc oxide and the silver oxide is 1.1~2:1.
Preferably, the weight percent of the A composition is 25%, and the weight percent of the B composition is 75%.
Preferably, in parts by weight, the A composition includes: 11~14 parts of acrylic acid ester emulsion, epoxy resin latex 9 ~11 parts, 4~6 parts of curing agent, 62~68 parts of zinc powder, the B composition includes: 32.5~37.5 parts of acrylic acid ester emulsion, epoxy 13~18 parts of resin emulsion, 6~9 parts of curing agent, 23~27 parts of ceramic nitriding aluminium powder, Neon SiC powder 3.5~4.5 Part, 2.5~3.5 parts of nano grade silica particles, 1.5~2.5 parts of inorganic antiseptic, 2.75~4.25 parts of defoaming agent, levelling agent 1.5~2.5 parts, 72~78 parts of deionized water.
Preferably, in parts by weight, the A composition includes: 12.5 parts of acrylic acid ester emulsion, epoxy resin latex 10 Part, 5 parts of curing agent, 65 parts of zinc powder, B composition includes: 35 parts of acrylic acid ester emulsion, and 15 parts of epoxy resin latex, curing agent 7.5 parts, 25 parts of ceramic nitriding aluminium powder, 4 parts of Neon SiC powder, 3 parts of nano grade silica particles, 2 parts of inorganic antiseptic, 3.5 parts of defoaming agent, 2 parts of levelling agent, 75 parts of deionized water.
Compared with the prior art, the advantages of the present invention are as follows: the coating in the present invention has good anti-microbial property, can The growth of bacterium is reduced, while there is certain wearability, excellent combination property has wide in the use aspect of plasthetics Application prospect.
Specific embodiment
The present invention is described further by the following example: according to following embodiments, the present invention may be better understood. However, as it will be easily appreciated by one skilled in the art that specific material ratio, process conditions and its result described in embodiment are only used In illustrating the present invention, without the present invention described in detail in claims should will not be limited.
The present invention discloses a kind of antibiotic paint formula for plasthetics surface, including weight percent is 20~30% A composition and weight percent be 70~80% B form, wherein in parts by weight, A composition includes: acrylate 10~15 parts of lotion, 8~12 parts of epoxy resin latex, 3~8 parts of curing agent, 60~70 parts of zinc powder, the B composition includes: propylene It 30~40 parts of acid esters lotion, 10~20 parts of epoxy resin latex, 5~10 parts of curing agent, 20~30 parts of ceramic nitriding aluminium powder, receives 3~5 parts of silicon carbide powder of rice, 2~4 parts of nano grade silica particles, 1~3 part of inorganic antiseptic, 2~5 parts of defoaming agent, levelling 1~3 part of agent, 70~80 parts of deionized water.
Wherein, the partial size of the Neon SiC powder and the nano grade silica particles be respectively 50~100nm and 80~120nm, it is preferred that the partial size of the Neon SiC powder and the nano grade silica particles be respectively 80nm and 100nm;The inorganic antiseptic is the mixture of zinc oxide and silver oxide, further, the zinc oxide and the silver oxide Mass ratio be 1.1~2:1, it is preferred that the mass ratio of the zinc oxide and the silver oxide be 1.5:1;Further, described The weight percent of A composition is 25%, and the weight percent of the B composition is 75%.
Following antibiotic paint formulas for plasthetics surface being illustrated with specifically embodiment in the present invention.
Embodiment 1
A kind of antibiotic paint formula for plasthetics surface, including weight percent be 20% A composition and weight The B that percentage is 80% is formed, wherein in parts by weight, the A composition includes: 10 parts of acrylic acid ester emulsion, epoxy resin 8 parts of lotion, 3 parts of curing agent, 60 parts of zinc powder, B composition includes: 30 parts of acrylic acid ester emulsion, and 10 parts of epoxy resin latex, Gu 5 parts of agent, 20 parts of ceramic nitriding aluminium powder, 3 parts of Neon SiC powder, 2 parts of nano grade silica particles, inorganic antiseptic 1 Part, 2 parts of defoaming agent, 1 part of levelling agent, 70 parts of deionized water.
Embodiment 2
A kind of antibiotic paint formula for plasthetics surface, including weight percent be 25% A composition and weight The B that percentage is 75% is formed, wherein in parts by weight, the A composition includes: 11 parts of acrylic acid ester emulsion, epoxy resin 9 parts of lotion, 4 parts of curing agent, 62 parts of zinc powder, B composition includes: 32.5 parts of acrylic acid ester emulsion, and 13 parts of epoxy resin latex, It is 6 parts of curing agent, 23 parts of ceramic nitriding aluminium powder, 3.5 parts of Neon SiC powder, 2.5 parts of nano grade silica particles, inorganic anti- 1.5 parts of microbial inoculum, 2.75 parts of defoaming agent, 1.5 parts of levelling agent, 72 parts of deionized water.
Embodiment 3
A kind of antibiotic paint formula for plasthetics surface, including weight percent be 25% A composition and weight The B that percentage is 75% is formed, wherein in parts by weight, the A composition includes: 12.5 parts of acrylic acid ester emulsion, asphalt mixtures modified by epoxy resin 10 parts of fat liquor, 5 parts of curing agent, 65 parts of zinc powder, the B composition includes: 35 parts of acrylic acid ester emulsion, epoxy resin latex 15 Part, it is 7.5 parts of curing agent, 25 parts of ceramic nitriding aluminium powder, 4 parts of Neon SiC powder, 3 parts of nano grade silica particles, inorganic 2 parts of antibacterial agent, 3.5 parts of defoaming agent, 2 parts of levelling agent, 75 parts of deionized water.
Embodiment 4
A kind of antibiotic paint formula for plasthetics surface, including weight percent be 25% A composition and weight The B that percentage is 75% is formed, wherein in parts by weight, the A composition includes: 14 parts of acrylic acid ester emulsion, epoxy resin 11 parts of lotion, 6 parts of curing agent, 68 parts of zinc powder, the B composition includes: 37.5 parts of acrylic acid ester emulsion, epoxy resin latex 18 Part, 9 parts of curing agent, 27 parts of ceramic nitriding aluminium powder, 4.5 parts of Neon SiC powder, 3.5 parts of nano grade silica particles, nothing 2.5 parts of machine antibacterial agent, 4.25 parts of defoaming agent, 2.5 parts of levelling agent, 78 parts of deionized water.
Embodiment 5
A kind of antibiotic paint formula for plasthetics surface, including weight percent be 30% A composition and weight The B that percentage is 70% is formed, wherein in parts by weight, the A composition includes: 15 parts of acrylic acid ester emulsion, epoxy resin 12 parts of lotion, 8 parts of curing agent, 70 parts of zinc powder, B composition includes: 40 parts of acrylic acid ester emulsion, and 20 parts of epoxy resin latex, 10 parts of curing agent, 30 parts of ceramic nitriding aluminium powder, 5 parts of Neon SiC powder, 4 parts of nano grade silica particles, inorganic antibacterial 3 parts of agent, 5 parts of defoaming agent, 3 parts of levelling agent, 80 parts of deionized water.
By in the present invention be used for plasthetics surface antibiotic paint formula antibiotic property and wearability test, The result shows that good anti-microbial property is had according to the wear-resistant antibacterial plastic coating that the formula in above-described embodiment 1~5 obtains, The growth of bacterium can be reduced, while there is certain wearability, excellent combination property has in the use aspect of plasthetics Wide application prospect.
Finally, it is to be noted that, the terms "include", "comprise" or its any other variant be intended to it is non-exclusive Property include so that include a series of elements process, method, article or equipment not only include those elements, but also Further include other elements that are not explicitly listed, or further include for this process, method, article or equipment it is intrinsic Element.

Claims (7)

1. a kind of antibiotic paint formula for plasthetics surface, which is characterized in that including weight percent be 20~30% A composition and weight percent be 70~80% B form, wherein in parts by weight, A composition includes: acrylate 10~15 parts of lotion, 8~12 parts of epoxy resin latex, 3~8 parts of curing agent, 60~70 parts of zinc powder, the B composition includes: propylene It 30~40 parts of acid esters lotion, 10~20 parts of epoxy resin latex, 5~10 parts of curing agent, 20~30 parts of ceramic nitriding aluminium powder, receives 3~5 parts of silicon carbide powder of rice, 2~4 parts of nano grade silica particles, 1~3 part of inorganic antiseptic, 2~5 parts of defoaming agent, levelling 1~3 part of agent, 70~80 parts of deionized water.
2. the antibiotic paint formula according to claim 1 for plasthetics surface, which is characterized in that the nano-sized carbon The partial size of SiClx powder and the nano grade silica particles is respectively 50~100nm and 80~120nm.
3. the antibiotic paint formula according to claim 1 for plasthetics surface, which is characterized in that described inorganic anti- Microbial inoculum is the mixture of zinc oxide and silver oxide.
4. the antibiotic paint formula according to claim 3 for plasthetics surface, which is characterized in that the zinc oxide Mass ratio with the silver oxide is 1.1~2:1.
5. the antibiotic paint formula according to claim 1 for plasthetics surface, which is characterized in that the A composition Weight percent be 25%, the weight percent of B composition is 75%.
6. the antibiotic paint formula according to claim 1 for plasthetics surface, which is characterized in that according to parts by weight Meter, A composition include: 11~14 parts of acrylic acid ester emulsion, and 9~11 parts of epoxy resin latex, 4~6 parts of curing agent, zinc powder 62 ~68 parts, B composition includes: 32.5~37.5 parts of acrylic acid ester emulsion, and 13~18 parts of epoxy resin latex, curing agent 6~9 Part, 23~27 parts of ceramic nitriding aluminium powder, 3.5~4.5 parts of Neon SiC powder, nano grade silica particles 2.5~3.5 Part, 1.5~2.5 parts of inorganic antiseptic, 2.75~4.25 parts of defoaming agent, 1.5~2.5 parts of levelling agent, 72~78 parts of deionized water.
7. the antibiotic paint formula according to claim 1 for plasthetics surface, which is characterized in that according to parts by weight Meter, A composition include: 12.5 parts of acrylic acid ester emulsion, and 10 parts of epoxy resin latex, 5 parts of curing agent, 65 parts of zinc powder, the B Composition includes: 35 parts of acrylic acid ester emulsion, 15 parts of epoxy resin latex, 7.5 parts of curing agent, 25 parts of ceramic nitriding aluminium powder, is received Rice 4 parts of silicon carbide powder, 3 parts of nano grade silica particles, 2 parts of inorganic antiseptic, 3.5 parts of defoaming agent, 2 parts of levelling agent, go from 75 parts of sub- water.
CN201910276290.5A 2018-10-12 2019-04-08 A kind of antibiotic paint formula for plasthetics surface Pending CN109971279A (en)

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CN201811186301 2018-10-12
CN2018111863012 2018-10-12

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112358783A (en) * 2020-11-23 2021-02-12 海信(广东)空调有限公司 Dual-ion composite antibacterial coating, antibacterial mildew-proof coating, cross-flow fan of air conditioner indoor unit and preparation method of cross-flow fan

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001035713A2 (en) * 1999-11-18 2001-05-25 Essential Coatings Pty Ltd Anti-fouling composition
CN102964956A (en) * 2012-12-20 2013-03-13 上海滋普环保科技有限公司 Environment-friendly antimicrobial odorless latex paint
CN104403504A (en) * 2014-11-28 2015-03-11 安徽省金盾涂料有限责任公司 Wear-resisting corrosion-resistant antibacterial aqueous coating
CN107868499A (en) * 2017-12-16 2018-04-03 苏州赛斯德工程设备有限公司 A kind of finishing antibiotic fungus-resisting paint

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001035713A2 (en) * 1999-11-18 2001-05-25 Essential Coatings Pty Ltd Anti-fouling composition
CN102964956A (en) * 2012-12-20 2013-03-13 上海滋普环保科技有限公司 Environment-friendly antimicrobial odorless latex paint
CN104403504A (en) * 2014-11-28 2015-03-11 安徽省金盾涂料有限责任公司 Wear-resisting corrosion-resistant antibacterial aqueous coating
CN107868499A (en) * 2017-12-16 2018-04-03 苏州赛斯德工程设备有限公司 A kind of finishing antibiotic fungus-resisting paint

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王进美: "《健康纺织品开发与应用》", 30 November 2005, 中国纺织出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112358783A (en) * 2020-11-23 2021-02-12 海信(广东)空调有限公司 Dual-ion composite antibacterial coating, antibacterial mildew-proof coating, cross-flow fan of air conditioner indoor unit and preparation method of cross-flow fan

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