CN106700777A - Nano silver ion antibacterial anti-theft door special paint and preparation method thereof - Google Patents
Nano silver ion antibacterial anti-theft door special paint and preparation method thereof Download PDFInfo
- Publication number
- CN106700777A CN106700777A CN201611141310.0A CN201611141310A CN106700777A CN 106700777 A CN106700777 A CN 106700777A CN 201611141310 A CN201611141310 A CN 201611141310A CN 106700777 A CN106700777 A CN 106700777A
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- China
- Prior art keywords
- nano silver
- agent
- silver ion
- ion antibiotic
- antibiotic
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A nano silver ion antibacterial anti-theft door special paint is prepared from the following raw materials by the weight percentage: 15%-31.7% of an amino resin emulsion, 60%-77.6% of an acrylic resin emulsion, 0.2%-0.4% of cellulose acetate butyrate, 0.2%-0.4% of a broad-spectrum antibiotic, 0.2%-0.4% of a nano silver ion antibacterial agent, 0.2%-0.6% of a weathering enhancer, 0.5%-1.2% of an adhesion promoter, 0.1%-0.3% of a dispersant, 0.1%-0.3% of a levelling agent, 0.2%-0.4% of a filler and 4%-6% of an anti-mildew auxiliary agent. The nano silver ion antibacterial anti-theft door special paint has good antibacterial effect, can avoid contact infection, and also can play a key role in weather resistance of a door. The process is simple to operate and facilitates industrialized application.
Description
Technical field
Present invention relates particularly to a kind of nano silver ion antibiotic antitheft door paint special and preparation method thereof.
Background technology
With the raising of quality of life, almost every household can all install antitheft door, and antitheft door seems clean attractive in appearance, in fact,
Because it can frequently be contacted with the hand of many people, and extraneous other environment influence, can all be remained on antitheft door or grown greatly
Amount bacterium, can be easy to cross-infection occur each other so between user.And use time is more long, bacterium can then grow
It is more.U.S.'s disease control science personnel once carried out the result of random inspection and also indicated that to subscriber household door, door handle and often contact
The bacterium exceeding standard rate in face is 81.3%, and mould recall rate is 60.2%, and total coli group recall rate is up to 100% unexpectedly, it is seen then that closed
Can not ignore in the bacterium on door, however, at present in door industry, people are then substantially recognized not the antibacterial knowledge for being related to door
Foot, is on the one hand not in place due to publicizing, and another aspect Shi Men producers are in process of production at all without reference to antimicrobial technology.It is existing
Although the report on antimicrobial paint is many in having technology, really it is suitable for the paint of antitheft door and has no relevant report, because
This, developing a kind of paint special of suitable antitheft door can then seem very necessary.
The content of the invention
The purpose of the present invention is to provide a kind of nano silver ion antibiotic antitheft door paint special, while providing its preparation method
It is another goal of the invention of the invention.
Based on above-mentioned purpose, this invention takes following technical scheme:Nano silver ion antibiotic antitheft door paint special, by with
The raw material of lower percentage by weight is made:Amino resin emulsion 15%~31.7%, emulsion acrylic resin 60%~77.6%, acetic acid fourth
Acid cellulose 0.2%~0.4%, broad-spectrum antibiotic 0.2%~0.4%, nano silver ion antibiotic agent 0.2%~0.4%, weather-proof reinforcing agent
0.2%~0.6%, adhesion promoter 0.5%~1.2%, dispersant 0.1%~0.3%, levelling agent 0.1%~0.3%, filler 0.2%
~0.4%, anti-mildew auxiliary agent 4%~6%.
Preferably, described nano silver ion antibiotic antitheft door paint special, is made up of the raw material of following percentage by weight:Ammonia
Base resin emulsion 18%, emulsion acrylic resin 74%, acetylbutyrylcellulose 0.3%, broad-spectrum antibiotic 0.3%, nano-silver ionic
It is antiseptic 0.3%, weather-proof reinforcing agent 0.4%, adhesion promoter 1%, dispersant 0.2%, levelling agent 0.1%, filler 0.4%, mould proof
Become auxiliary agent 5%.
Preferably, the broad-spectrum antibiotic is high efficiency composition bactericide DK-23;Nano silver ion antibiotic agent is oiliness nanometer
Silver antibacterial agent JL-119;Weather-proof reinforcing agent is ultraviolet absorbent UV-531;Adhesion promoter is adhesion promoter EDL-
6026F;Dispersant is dispersant 4171;Levelling agent is levelling agent 380 or 390;Filler is titanium white;Anti-mildew auxiliary agent is anti-for antibacterial
Mould anti-corrosive aids TH22-27.
The preparation method of described nano silver ion antibiotic antitheft door paint special, grinds after directly mixing dispersion by each raw material
Obtain final product.
Compared with prior art, the beneficial effects of the present invention are:
1st, using nano silver ion antibiotic antitheft door paint special of the invention, good anti-bacterial effect, avoiding contact with property is infected, while
Can the weatherability of opposite house play a key effect.
2nd, each raw material that the antitheft door paint special is used in the preparation can by after directly buying on the market through letter
Single processing, processing cost is low, and technological operation is simple, is easy to industrial applications.
3rd, while the various pigment that paint special of the invention can according to demand add on the market for antitheft door are compounded
Toning, reach it is attractive in appearance under conditions of also do not influence its antibacterial effect, compounding effect is preferable.
Specific embodiment
Hereinafter the present invention will be illustrated by embodiment, but these specific embodiments limit this hair never in any form
Bright protection domain.
Embodiment 1
Nano silver ion antibiotic antitheft door paint special, is made up of the raw material of following percentage by weight:Amino resin emulsion 18%, third
Olefin(e) acid resin emulsion 74%, acetylbutyrylcellulose 0.3%, broad-spectrum antibiotic 0.3%, nano silver ion antibiotic agent(Oiliness Nano Silver
Antiseptic JL-119)0.3%th, weather-proof reinforcing agent 0.4%, adhesion promoter(Adhesion promoter EDL-6026F)1%th, disperse
Agent 0.2%, levelling agent 0.1%, filler 0.4%, anti-mildew auxiliary agent(Antibacterial and mouldproof anti-corrosive aids TH22-27)5%.
Embodiment 2
Nano silver ion antibiotic antitheft door paint special, is made up of the raw material of following percentage by weight:Amino resin emulsion 15%, third
Olefin(e) acid resin emulsion 77.6%, acetylbutyrylcellulose 0.2%, broad-spectrum antibiotic 0.2%, nano silver ion antibiotic agent(Oiliness nanometer
Silver antibacterial agent JL-119)0.2%th, weather-proof reinforcing agent 0.6%, adhesion promoter(Adhesion promoter EDL-6026F)1.2%、
Dispersant 0.3%, levelling agent 0.3%, filler titanium white 0.4%, anti-mildew auxiliary agent(Antibacterial and mouldproof anti-corrosive aids TH22-27)4%.
Embodiment 3
Nano silver ion antibiotic antitheft door paint special, is made up of the raw material of following percentage by weight:Amino resin emulsion 31.7%,
Emulsion acrylic resin 60%, acetylbutyrylcellulose 0.4%, broad-spectrum antibiotic 0.4%, nano silver ion antibiotic agent(Oiliness nanometer
Silver antibacterial agent JL-119)0.4%th, weather-proof reinforcing agent(Ultraviolet absorbent UV-531)0.2%th, adhesion promoter(Attachment is made every effort to promote
Enter agent EDL-6026F)0.5%th, dispersant 0.1%, levelling agent 0.1%, filler titanium white 0.2%, anti-mildew auxiliary agent(Antibacterial and mouldproof is prevented
Rotten auxiliary agent TH22-27)6%.
In the various embodiments described above,
Amino resins used is amino resins 303, supply company:Grand titanium group Shanghai trade Co., Ltd;
The model TAR-6678-60 of acrylic resin, business men:TONJ;
The model high efficiency composition bactericide DK-23 of broad-spectrum antibiotic, producer produces for Li Yuan Chemical Co., Ltd.s of Foshan City;
Dispersant is BCK-4171 dispersants, producer:Guangdong Zhi Hui Chemical Co., Ltd.s;
Levelling agent is levelling agent 380 or 390, producer:Guangdong Zhi Hui Chemical Co., Ltd.s;
Effect experiment
To verify invention effect of the invention, respectively to using antitheft door paint special obtained in formula of the invention(Embodiment 1-
3)Contrasted with obtained paint is not formulated according to this.
Comparative example is the formula of the preparation paint of row industry routine:Alkyd resin 3,880 10.00%, acrylic resin BS/
965 49%, amino resins 5,860 26.5%, the % of secondary butyl ester 3.00, the % of butyl ether 3.00, the % of butanol 2.00, anti-settling slurry 260L 4.1%
, levelling agent BYK333 0.2%, oil resistance agent 47v,500 0.02%, adhesion promoter ADP 2%.
Result shows, normally descends the fungus resistance to reach more than 60% using the paint of formula production now, can kill life
In often contact germ, ultraviolet weatherability index reaches 700 more than hour, and especially during the formula of embodiment 1, its is resistance to
Bacterium property reaches 80%, and ultraviolet weatherability index reaches 800 hours;And according to the conventional paint contact surface for being formulated preparation then
Grow a large amount of cross-infection bacteriums, only 350 hours of ultraviolet weathering index.
Claims (4)
1. nano silver ion antibiotic antitheft door paint special, it is characterised in that be made up of the raw material of following percentage by weight:Amino tree
Fat liquor 15%~31.7%, emulsion acrylic resin 60%~77.6%, acetylbutyrylcellulose 0.2%~0.4%, broad-spectrum antibiotic
0.2%~0.4%, nano silver ion antibiotic agent 0.2%~0.4%, weather-proof reinforcing agent 0.2%~0.6%, adhesion promoter 0.5%~
1.2%th, dispersant 0.1%~0.3%, levelling agent 0.1%~0.3%, filler 0.2%~0.4%, anti-mildew auxiliary agent 4%~6%.
2. nano silver ion antibiotic antitheft door paint special as claimed in claim 1, it is characterised in that by following percentage by weight
Raw material be made:Amino resin emulsion 18%, emulsion acrylic resin 74%, acetylbutyrylcellulose 0.3%, broad-spectrum antibiotic
0.3%th, nano silver ion antibiotic agent 0.3%, weather-proof reinforcing agent 0.4%, adhesion promoter 1%, dispersant 0.2%, levelling agent
0.1%th, filler 0.4%, anti-mildew auxiliary agent 5%.
3. nano silver ion antibiotic antitheft door paint special as claimed in claim 1 or 2, it is characterised in that the broad-spectrum antibacterial
Element is high efficiency composition bactericide DK-23;Nano silver ion antibiotic agent is oiliness nano silver antimicrobials JL-119;Weather-proof reinforcing agent is
Ultraviolet absorbent UV-531;Adhesion promoter is adhesion promoter EDL-6026F;Dispersant is dispersant 4171;Stream
Flat agent is levelling agent 380 or 390;Filler is titanium white;Anti-mildew auxiliary agent is antibacterial and mouldproof anti-corrosive aids TH22-27.
4. the preparation method of the nano silver ion antibiotic antitheft door paint special described in claim 3, it is characterised in that by each raw material
Directly ground after mixing dispersion and obtained final product.
Priority Applications (1)
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CN201611141310.0A CN106700777A (en) | 2016-12-12 | 2016-12-12 | Nano silver ion antibacterial anti-theft door special paint and preparation method thereof |
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CN201611141310.0A CN106700777A (en) | 2016-12-12 | 2016-12-12 | Nano silver ion antibacterial anti-theft door special paint and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113652093A (en) * | 2021-06-17 | 2021-11-16 | 苏州市晨煊纺织科技有限公司 | Preparation method of nano-silver antibacterial regenerated silk fibroin material |
Citations (5)
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CN102977746A (en) * | 2012-12-25 | 2013-03-20 | 广州慧谷工程材料有限公司 | Nanometer oil-strain resistant and antibacterial self-cleaning coating and preparation method and application thereof |
CN104419279A (en) * | 2013-08-29 | 2015-03-18 | 晟通科技集团有限公司 | Antibacterial hydrophilic coating |
CN106010018A (en) * | 2016-08-01 | 2016-10-12 | 安庆瑞泰化工有限公司 | Antibacterial water-based coating and preparation method thereof |
CN106085044A (en) * | 2016-06-06 | 2016-11-09 | 马鞍山博诺环保科技有限公司 | A kind of antimicrobial nano coating, preparation method and antimicrobial nano coatings |
CN106147457A (en) * | 2016-08-12 | 2016-11-23 | 安庆市七仙女电器制造有限公司 | A kind of hair dryer antibiotic paint and preparation method thereof |
-
2016
- 2016-12-12 CN CN201611141310.0A patent/CN106700777A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102977746A (en) * | 2012-12-25 | 2013-03-20 | 广州慧谷工程材料有限公司 | Nanometer oil-strain resistant and antibacterial self-cleaning coating and preparation method and application thereof |
CN104419279A (en) * | 2013-08-29 | 2015-03-18 | 晟通科技集团有限公司 | Antibacterial hydrophilic coating |
CN106085044A (en) * | 2016-06-06 | 2016-11-09 | 马鞍山博诺环保科技有限公司 | A kind of antimicrobial nano coating, preparation method and antimicrobial nano coatings |
CN106010018A (en) * | 2016-08-01 | 2016-10-12 | 安庆瑞泰化工有限公司 | Antibacterial water-based coating and preparation method thereof |
CN106147457A (en) * | 2016-08-12 | 2016-11-23 | 安庆市七仙女电器制造有限公司 | A kind of hair dryer antibiotic paint and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113652093A (en) * | 2021-06-17 | 2021-11-16 | 苏州市晨煊纺织科技有限公司 | Preparation method of nano-silver antibacterial regenerated silk fibroin material |
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Application publication date: 20170524 |
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