CN106758158B - A kind of environmental protection weaving refining agent and preparation method thereof for mulberry silk - Google Patents

A kind of environmental protection weaving refining agent and preparation method thereof for mulberry silk Download PDF

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CN106758158B
CN106758158B CN201611166258.4A CN201611166258A CN106758158B CN 106758158 B CN106758158 B CN 106758158B CN 201611166258 A CN201611166258 A CN 201611166258A CN 106758158 B CN106758158 B CN 106758158B
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CN106758158A (en
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钱华
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Mianyang Jialide Textile Technology Co ltd
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WUJIANG BEISHE SHENGYUAN TEXTILE AUXILIARIES FACTORY
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Abstract

The environmental protection weaving refining agent and preparation method thereof that the invention discloses a kind of for mulberry silk, it is made from the following raw materials in parts by weight: 10-20 parts of C16 sodium secondary alkyl sulfonate, 10-15 parts of carboxyethyl thiosuccinic acid, 5-12 parts of nonylphenol polyoxyethylene ether, 5-10 parts of vinyl acetate, 1-3 parts of glucose, 3-7 parts of glycerol, 2-6 parts of sodium para-aminosalicylate, 1-4 parts of sulfosuccinate bisamide salt, 2-5 parts of malic acid, 2-4 parts of potassium sorbate, 1-3 parts of cellulase, 1-4 parts of double palmityl ethylene diamine dipropionic acid sodium, 1-5 parts of trimethylolpropane, 1-2 parts of sodium tripolyphosphate, 1-3 parts of anionic surfactant, 2-4 parts of defoaming agent, 1-4 parts of emulsifier.The refining agent being prepared, it is small to silk fabrics stimulation with good emulsion dispersion property, have the function of submissive silk fabrics.Meanwhile also disclosing corresponding preparation method.

Description

A kind of environmental protection weaving refining agent and preparation method thereof for mulberry silk
Technical field
The present invention relates to weaving refining agent field, be related specifically to it is a kind of for mulberry silk environmental protection weaving refining agent and its Preparation method.
Background technique
In mulberry silk dyeing and printing process, in order to keep the velvet touch and fine quality of mulberry silk, it is necessary to silkworm silk weaving Object carries out the refining processing for the purpose of degumming.The natural impurity on all kinds of textiles is removed with chemically and physically method, is stained with Dirt and the technical process for weaving slurry.And during fabric finishing, often encounter cloth cover greasy dirt, contamination, color stain, color Flower, silicone oil spot etc., cause product quality to reduce, and some can not even repair.Therefore, textile dyeing, require before stamp through Certain scouring process is crossed, to remove the impurity and greasy dirt on cloth cover, and the refining of mulberry silk is mainly scouring processes.Due to passing The scouring agent of system has ignored more consideration is given to the impurity of common fabric and woven finish and weaving process to mulberry silk particular oils The emulsion dispersion of agent needs and degumming demand, so this research is directed primarily to develop a refining for Light of Mulberry Silk Fabrics Agent makes it have good emulsion dispersion property, small to silk fabrics stimulation, has the function of submissive silk fabrics.
Summary of the invention
In order to solve the above technical problems, the present invention provides a kind of environmentally friendly refining agent and its preparation side of weaving for mulberry silk Method is combined by using specified raw material, cooperates corresponding production technology, the obtained environmental protection weaving refining for mulberry silk Agent, it is small to silk fabrics stimulation with good emulsion dispersion property, have the function of submissive silk fabrics, can satisfy industry Requirement, with good application prospect.
The purpose of the present invention can be achieved through the following technical solutions:
For the environmental protection weaving refining agent of mulberry silk, it is made from the following raw materials in parts by weight: C16 sodium secondary alkyl sulfonate 10- 20 parts, 10-15 parts of carboxyethyl thiosuccinic acid, 5-12 parts of nonylphenol polyoxyethylene ether, 5-10 parts of vinyl acetate, glucose 1- 3 parts, 3-7 parts of glycerol, 2-6 parts of sodium para-aminosalicylate, 1-4 parts of sulfosuccinate bisamide salt, 2-5 parts of malic acid, sorbic acid 2-4 parts of potassium, 1-3 parts of cellulase, 1-4 parts of double palmityl ethylene diamine dipropionic acid sodium, 1-5 parts of trimethylolpropane, trimerization phosphorus Sour sodium 1-2 parts, 1-3 parts of anionic surfactant, 2-4 parts of defoaming agent, 1-4 parts of emulsifier.
Preferably, the anionic surfactant is odium stearate, sodium citrate, stearine, alpha-sulfo list One or more of carboxylate.
Preferably, the defoaming agent is benzyl carbinol olein, Laurate alcohol ester phenylacetate, tributyl phosphate, dimethicone In any one.
Preferably, the emulsifier is selected from secondary octyl phenol polyethenoxy ether, aliphatic amine polyoxyethylene ether, rosin acid polyoxy second Any one or a few in enester, sodium butylnaphthalenesulfonate.
The preparation method of the environmental protection weaving refining agent for mulberry silk, comprising the following steps:
(1) each raw material is weighed according to parts by weight；
(2) vinyl acetate, glucose, glycerol, sodium para-aminosalicylate are added in 1L deionized water, with constant temperature magnetic Power blender stirs evenly；
(3) be added in the solution in step (2): C16 sodium secondary alkyl sulfonate, carboxyethyl thiosuccinic acid, nonyl phenol are poly- Ethylene oxide ether, emulsifier are settled to 5L, ultrasonic disperse, and ultrasonic time is 45 minutes, supersonic frequency 220-250KW；
(4) the ultrasonic disperse mixture of step (3) is injected into mixer, adds sulfosuccinate bisamide salt, apple Acid, potassium sorbate, cellulase, double palmityl ethylene diamine dipropionic acid sodium, anionic surfactant, heating stirring to 55 DEG C, mixing speed is 50-100 revs/min, reaction time 10-25 minute；
(5) trimethylolpropane, sodium tripolyphosphate, defoaming agent are added in reaction kettle, are mixed, mixing speed is 200-300 revs/min, the reaction time is 35 minutes, and reaction temperature is 120-160 DEG C；
(6) mixture of step (4) is added in the reaction kettle of step (5), it is isometric to mix, while slowly pressurization heating It is activated to 180 DEG C of heat preservations, is kept stirring 300 revs/min of speed, the reaction time 30 minutes；
(7) toward the mixture cooled to room temperature of step (6), pH value then is adjusted to 7-8, stirring with disodium bicarbonate Uniformly up to semi-finished product；
(8) the semi-finished product mixed liquor in step (7) is crossed into membrane choosing, removes bulky grain, packing.
Preferably, the pressure of the step (6) is 5-10Mpa.
Preferably, the membrane aperture of the step (8) is 100-200 μm.
Compared with prior art, the present invention has the advantages that:
(1) the environmental protection weaving refining agent for mulberry silk of the invention, with vinyl acetate, glucose, glycerol, to amino Sodium salicylate, C16 sodium secondary alkyl sulfonate, carboxyethyl thiosuccinic acid, nonylphenol polyoxyethylene ether are main component, pass through addition Sulfosuccinate bisamide salt, malic acid, potassium sorbate, cellulase, double palmityl ethylene diamine dipropionic acid sodium, trihydroxy methyl Propane, sodium tripolyphosphate, anionic surfactant, defoaming agent, emulsifier are aided with dissolution stirring, ultrasonic disperse, heating instead It answers, the techniques such as pressured activation, cooled film, so that the environmental protection weaving refining agent for mulberry silk being prepared, with good Good emulsion dispersion property, it is small to silk fabrics stimulation, have the function of submissive silk fabrics, can satisfy the requirement of industry, has Preferable application prospect.
(2) the environmental protection weaving refining agent raw material for mulberry silk of the invention is cheap, simple process, is suitable for large-scale industry Change and uses, it is practical.
Specific embodiment
The technical solution of invention is described in detail combined with specific embodiments below.
Embodiment 1
(1) 10 parts of C16 sodium secondary alkyl sulfonate, 10 parts of carboxyethyl thiosuccinic acid, polyoxyethylene nonyl phenyl are weighed according to parts by weight 5 parts of vinethene, 5 parts of vinyl acetate, 1 part of glucose, 3 parts of glycerol, 2 parts of sodium para-aminosalicylate, sulfosuccinate bisamide 1 part of salt, 2 parts of malic acid, 2 parts of potassium sorbate, 1 part of cellulase, double 1 part of palmityl ethylene diamine dipropionic acid sodium, trihydroxy methyl 1 part of propane, 1 part of sodium tripolyphosphate, 1 part of odium stearate, 2 parts of benzyl carbinol olein, 1 part of secondary octyl phenol polyethenoxy ether；
(2) vinyl acetate, glucose, glycerol, sodium para-aminosalicylate are added in 1L deionized water, with constant temperature magnetic Power blender stirs evenly；
(3) be added in the solution in step (2): C16 sodium secondary alkyl sulfonate, carboxyethyl thiosuccinic acid, nonyl phenol are poly- Ethylene oxide ether, secondary octyl phenol polyethenoxy ether are settled to 5L, ultrasonic disperse, and ultrasonic time is 45 minutes, and supersonic frequency is 220KW；
(4) the ultrasonic disperse mixture of step (3) is injected into mixer, adds sulfosuccinate bisamide salt, apple Acid, potassium sorbate, cellulase, double palmityl ethylene diamine dipropionic acid sodium, odium stearate, heating stirring is to 55 DEG C, stirring speed Degree is 50 revs/min, the reaction time 10 minutes；
(5) trimethylolpropane, sodium tripolyphosphate, benzyl carbinol olein are added in reaction kettle, are mixed, stirring speed Degree is 200 revs/min, and the reaction time is 35 minutes, and reaction temperature is 120 DEG C；
(6) mixture of step (4) is added in the reaction kettle of step (5), it is isometric to mix, while slowly pressurization heating It is activated to 180 DEG C of heat preservations, is kept stirring 300 revs/min of speed, the reaction time 30 minutes, pressure 5Mp；
(7) toward the mixture cooled to room temperature of step (6), pH value then is adjusted to 7 with disodium bicarbonate, stirring is equal Even semi-finished product to obtain the final product；
(8) the semi-finished product mixed liquor in step (7) is crossed into membrane choosing, removes bulky grain, packing, membrane aperture is 100 μ m。
The performance test results of environmental protection weaving refining agent obtained for mulberry silk are as shown in table 1.
Embodiment 2
(1) 13 parts of C16 sodium secondary alkyl sulfonate, 12 parts of carboxyethyl thiosuccinic acid, polyoxyethylene nonyl phenyl are weighed according to parts by weight 8 parts of vinethene, 7 parts of vinyl acetate, 2 parts of glucose, 4 parts of glycerol, 3 parts of sodium para-aminosalicylate, sulfosuccinate bisamide 2 parts of salt, 3 parts of malic acid, 3 parts of potassium sorbate, 2 parts of cellulase, double 2 parts of palmityl ethylene diamine dipropionic acid sodium, trihydroxy methyl 2 parts of propane, 1 part of sodium tripolyphosphate, 1 part of sodium citrate, 3 parts of Laurate alcohol ester phenylacetate, 2 parts of aliphatic amine polyoxyethylene ether；
(2) vinyl acetate, glucose, glycerol, sodium para-aminosalicylate are added in 1L deionized water, with constant temperature magnetic Power blender stirs evenly；
(3) be added in the solution in step (2): C16 sodium secondary alkyl sulfonate, carboxyethyl thiosuccinic acid, nonyl phenol are poly- Ethylene oxide ether, aliphatic amine polyoxyethylene ether are settled to 5L, ultrasonic disperse, and ultrasonic time is 45 minutes, supersonic frequency 230KW；
(4) the ultrasonic disperse mixture of step (3) is injected into mixer, adds sulfosuccinate bisamide salt, apple Acid, potassium sorbate, cellulase, double palmityl ethylene diamine dipropionic acid sodium, sodium citrate, heating stirring is to 55 DEG C, stirring speed Degree is 70 revs/min, the reaction time 15 minutes；
(5) trimethylolpropane, sodium tripolyphosphate, Laurate alcohol ester phenylacetate are added in reaction kettle, are mixed, stirring Speed is 240 revs/min, and the reaction time is 35 minutes, and reaction temperature is 130 DEG C；
(6) mixture of step (4) is added in the reaction kettle of step (5), it is isometric to mix, while slowly pressurization heating It is activated to 180 DEG C of heat preservations, is kept stirring 300 revs/min of speed, the reaction time 30 minutes, pressure 7Mp；
(7) toward the mixture cooled to room temperature of step (6), pH value then is adjusted to 7.4 with disodium bicarbonate, is stirred Uniformly up to semi-finished product；
(8) the semi-finished product mixed liquor in step (7) is crossed into membrane choosing, removes bulky grain, packing, membrane aperture is 120 μ m。
The performance test results of environmental protection weaving refining agent obtained for mulberry silk are as shown in table 1.
Embodiment 3
(1) 17 parts of C16 sodium secondary alkyl sulfonate, 14 parts of carboxyethyl thiosuccinic acid, polyoxyethylene nonyl phenyl are weighed according to parts by weight 10 parts of vinethene, 9 parts of vinyl acetate, 2 parts of glucose, 6 parts of glycerol, 5 parts of sodium para-aminosalicylate, sulfosuccinate bisamide 3 parts of salt, 4 parts of malic acid, 3 parts of potassium sorbate, 2 parts of cellulase, double 3 parts of palmityl ethylene diamine dipropionic acid sodium, trihydroxy methyl 4 parts of propane, 2 parts of sodium tripolyphosphate, 2 parts of stearine, 3 parts of tributyl phosphate, 3 parts of polyoxylethylene abietate；
(2) vinyl acetate, glucose, glycerol, sodium para-aminosalicylate are added in 1L deionized water, with constant temperature magnetic Power blender stirs evenly；
(3) be added in the solution in step (2): C16 sodium secondary alkyl sulfonate, carboxyethyl thiosuccinic acid, nonyl phenol are poly- Ethylene oxide ether, polyoxylethylene abietate are settled to 5L, ultrasonic disperse, and ultrasonic time is 45 minutes, supersonic frequency 240KW；
(4) the ultrasonic disperse mixture of step (3) is injected into mixer, adds sulfosuccinate bisamide salt, apple Acid, potassium sorbate, cellulase, double palmityl ethylene diamine dipropionic acid sodium, stearine, heating stirring are stirred to 55 DEG C Mixing speed is 80 revs/min, the reaction time 20 minutes；
(5) trimethylolpropane, sodium tripolyphosphate, tributyl phosphate are added in reaction kettle, are mixed, mixing speed It is 280 revs/min, the reaction time is 35 minutes, and reaction temperature is 150 DEG C；
(6) mixture of step (4) is added in the reaction kettle of step (5), it is isometric to mix, while slowly pressurization heating It is activated to 180 DEG C of heat preservations, is kept stirring 300 revs/min of speed, the reaction time 30 minutes, pressure 9Mp；
(7) toward the mixture cooled to room temperature of step (6), pH value then is adjusted to 7.8 with disodium bicarbonate, is stirred Uniformly up to semi-finished product；
(8) the semi-finished product mixed liquor in step (7) is crossed into membrane choosing, removes bulky grain, packing, membrane aperture is 150 μ m。
The performance test results of environmental protection weaving refining agent obtained for mulberry silk are as shown in table 1.
Embodiment 4
(1) 20 parts of C16 sodium secondary alkyl sulfonate, 15 parts of carboxyethyl thiosuccinic acid, polyoxyethylene nonyl phenyl are weighed according to parts by weight The double acyls of 12 parts of vinethene, 10 parts of vinyl acetate, 3 parts of glucose, 7 parts of glycerol, 6 parts of sodium para-aminosalicylate, sulfosuccinate 4 parts of amine salt, 5 parts of malic acid, 4 parts of potassium sorbate, 3 parts of cellulase, double 4 parts of palmityl ethylene diamine dipropionic acid sodium, three hydroxyl first 5 parts of base propane, 2 parts of sodium tripolyphosphate, 3 parts of α-sulfomonocarboxylic acid ester, 4 parts of dimethicone, 4 parts of sodium butylnaphthalenesulfonate；
(2) vinyl acetate, glucose, glycerol, sodium para-aminosalicylate are added in 1L deionized water, with constant temperature magnetic Power blender stirs evenly；
(3) be added in the solution in step (2): C16 sodium secondary alkyl sulfonate, carboxyethyl thiosuccinic acid, nonyl phenol are poly- Ethylene oxide ether, sodium butylnaphthalenesulfonate are settled to 5L, ultrasonic disperse, and ultrasonic time is 45 minutes, supersonic frequency 250KW；
(4) the ultrasonic disperse mixture of step (3) is injected into mixer, adds sulfosuccinate bisamide salt, apple Acid, potassium sorbate, cellulase, double palmityl ethylene diamine dipropionic acid sodium, α-sulfomonocarboxylic acid ester, heating stirring to 55 DEG C, Mixing speed is 100 revs/min, the reaction time 25 minutes；
(5) trimethylolpropane, sodium tripolyphosphate, dimethicone are added in reaction kettle, are mixed, mixing speed It is 300 revs/min, the reaction time is 35 minutes, and reaction temperature is 160 DEG C；
(6) mixture of step (4) is added in the reaction kettle of step (5), it is isometric to mix, while slowly pressurization heating It is activated to 180 DEG C of heat preservations, is kept stirring 300 revs/min of speed, the reaction time 30 minutes, pressure 10Mp；
(7) toward the mixture cooled to room temperature of step (6), pH value then is adjusted to 8 with disodium bicarbonate, stirring is equal Even semi-finished product to obtain the final product；
(8) the semi-finished product mixed liquor in step (7) is crossed into membrane choosing, removes bulky grain, packing, membrane aperture is 200 μ m。
The performance test results of environmental protection weaving refining agent obtained for mulberry silk are as shown in table 1.
Comparative example 1
(1) 10 parts of C16 sodium secondary alkyl sulfonate, 10 parts of carboxyethyl thiosuccinic acid, polyoxyethylene nonyl phenyl are weighed according to parts by weight 5 parts of vinethene, 5 parts of vinyl acetate, 1 part of glucose, 2 parts of sodium para-aminosalicylate, 1 part of sulfosuccinate bisamide salt, apple 2 parts of tartaric acid, 1 part of cellulase, double 1 part of palmityl ethylene diamine dipropionic acid sodium, 1 part of trimethylolpropane, sodium tripolyphosphate 1 Part, 1 part of odium stearate, 2 parts of benzyl carbinol olein, 1 part of secondary octyl phenol polyethenoxy ether；
(2) vinyl acetate, glucose, sodium para-aminosalicylate are added in 1L deionized water, are stirred with constant temperature magnetic force Device is mixed to stir evenly；
(3) be added in the solution in step (2): C16 sodium secondary alkyl sulfonate, carboxyethyl thiosuccinic acid, nonyl phenol are poly- Ethylene oxide ether, secondary octyl phenol polyethenoxy ether are settled to 5L, ultrasonic disperse, and ultrasonic time is 45 minutes, and supersonic frequency is 220KW；
(4) the ultrasonic disperse mixture of step (3) is injected into mixer, adds sulfosuccinate bisamide salt, apple Acid, cellulase, double palmityl ethylene diamine dipropionic acid sodium, odium stearate, heating stirring to 55 DEG C, mixing speed is 50 turns/ Minute, the reaction time 10 minutes；
(5) trimethylolpropane, sodium tripolyphosphate, benzyl carbinol olein are added in reaction kettle, are mixed, stirring speed Degree is 200 revs/min, and the reaction time is 35 minutes, and reaction temperature is 120 DEG C；
(6) mixture of step (4) is added in the reaction kettle of step (5), it is isometric to mix, while slowly pressurization heating It is activated to 180 DEG C of heat preservations, is kept stirring 300 revs/min of speed, the reaction time 30 minutes, pressure 5Mp；
(7) toward the mixture cooled to room temperature of step (6), pH value then is adjusted to 7 with disodium bicarbonate, stirring is equal Even semi-finished product to obtain the final product；
(8) the semi-finished product mixed liquor in step (7) is crossed into membrane choosing, removes bulky grain, packing, membrane aperture is 100 μ m。
The performance test results of environmental protection weaving refining agent obtained for mulberry silk are as shown in table 1.
Comparative example 2
(1) 20 parts of C16 sodium secondary alkyl sulfonate, 15 parts of carboxyethyl thiosuccinic acid, polyoxyethylene nonyl phenyl are weighed according to parts by weight 12 parts of vinethene, 10 parts of vinyl acetate, 7 parts of glycerol, 6 parts of sodium para-aminosalicylate, 4 parts of sulfosuccinate bisamide salt, mountain 4 parts of potassium sorbate, double 4 parts of palmityl ethylene diamine dipropionic acid sodium, 5 parts of trimethylolpropane, 2 parts of sodium tripolyphosphate, alpha-sulfo list 3 parts of carboxylate, 4 parts of dimethicone, 4 parts of sodium butylnaphthalenesulfonate；
(2) vinyl acetate, glycerol, sodium para-aminosalicylate are added in 1L deionized water, use temperature constant magnetic stirring Device stirs evenly；
(3) be added in the solution in step (2): C16 sodium secondary alkyl sulfonate, carboxyethyl thiosuccinic acid, nonyl phenol are poly- Ethylene oxide ether, sodium butylnaphthalenesulfonate are settled to 5L, ultrasonic disperse, and ultrasonic time is 45 minutes, supersonic frequency 250KW；
(4) the ultrasonic disperse mixture of step (3) is injected into mixer, adds sulfosuccinate bisamide salt, sorb Sour potassium, double palmityl ethylene diamine dipropionic acid sodium, α-sulfomonocarboxylic acid ester, heating stirring to 55 DEG C, mixing speed is 100 turns/ Minute, the reaction time 25 minutes；
(5) trimethylolpropane, sodium tripolyphosphate, dimethicone are added in reaction kettle, are mixed, mixing speed It is 300 revs/min, the reaction time is 35 minutes, and reaction temperature is 160 DEG C；
(6) mixture of step (4) is added in the reaction kettle of step (5), it is isometric to mix, while slowly pressurization heating It is activated to 180 DEG C of heat preservations, is kept stirring 300 revs/min of speed, the reaction time 30 minutes, pressure 10Mp；
(7) toward the mixture cooled to room temperature of step (6), pH value then is adjusted to 8 with disodium bicarbonate, stirring is equal Even semi-finished product to obtain the final product；
(8) the semi-finished product mixed liquor in step (7) is crossed into membrane choosing, removes bulky grain, packing, membrane aperture is 200 μ m。
The performance test results of environmental protection weaving refining agent obtained for mulberry silk are as shown in table 1.
The environmental protection weaving refining agent that mulberry silk is used for made from embodiment 1-4 and comparative example 1-2 is subjected to capillary effect, infiltration Rate, Oil and Fat Content, layering required time, this several dispersion index, mass loss rate degumming rate performance tests.
Table 1
　 Capillary effect Permeability (s, 20 DEG C of canvas sedimentations) Oil and Fat Content % The time required to layering Dispersion index Mass loss rate % Degumming rate %
Embodiment 1 7.85 7 0.06 7 points 35 seconds 12.7 11.2 24.8
Embodiment 2 7.956 6 0.066 7 points 51 seconds 13.4 10.9 25.0
Embodiment 3 7.532 7 0.068 7 points 53 seconds 12.8 11.5 24.9
Embodiment 4 8.274 6 0.063 7 points 58 seconds 13.1 10.8 25.1
Comparative example 1 4.88 10 0.774 5 points 14 seconds 18.7 16.3 21.1
Comparative example 2 5.41 13 0.81 5 points 47 seconds 17.5 17.2 22.7
The environmental protection weaving refining agent for mulberry silk of the invention, with vinyl acetate, glucose, glycerol, to amino water Poplar acid sodium, C16 sodium secondary alkyl sulfonate, carboxyethyl thiosuccinic acid, nonylphenol polyoxyethylene ether are main component, by the way that sulphur is added Change succinic acid bisamide salt, malic acid, potassium sorbate, cellulase, double palmityl ethylene diamine dipropionic acid sodium, trihydroxy methyl third Alkane, sodium tripolyphosphate, anionic surfactant, defoaming agent, emulsifier, be aided with dissolution stirring, ultrasonic disperse, heating react, The techniques such as pressured activation, cooled film, so that the environmental protection weaving refining agent for mulberry silk being prepared, with good Emulsion dispersion property, it is small to silk fabrics stimulation, have the function of submissive silk fabrics, can satisfy the requirement of industry, has preferable Application prospect.The environmental protection weaving refining agent raw material for mulberry silk of the invention is cheap, simple process, is suitable for large-scale industry Change and uses, it is practical.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks Domain is included within the scope of the present invention.

Claims (3)

1. a kind of preparation method of the environmental protection weaving refining agent for mulberry silk, which comprises the following steps:
(1) 10-20 parts of C16 sodium secondary alkyl sulfonate, 10-15 parts of carboxyethyl thiosuccinic acid, nonyl phenol is weighed according to parts by weight to gather 5-12 parts of ethylene oxide ether, 5-10 parts of vinyl acetate, 1-3 parts of glucose, 3-7 parts of glycerol, 2-6 parts of sodium para-aminosalicylate, sulphur Change 1-4 parts of succinic acid bisamide salt, 2-5 parts of malic acid, 2-4 parts of potassium sorbate, 1-3 parts of cellulase, double palmityl second two 1-4 parts of amine dipropionic acid, 1-5 parts of trimethylolpropane, 1-2 parts of sodium tripolyphosphate, 1-3 parts of anionic surfactant, defoaming 2-4 parts of agent, 1-4 parts of emulsifier；
(2) vinyl acetate, glucose, glycerol, sodium para-aminosalicylate are added in 1 L deionized water, with constant temperature magnetic force Blender stirs evenly；
(3) it is added in the solution in step (2): C16 sodium secondary alkyl sulfonate, carboxyethyl thiosuccinic acid, polyoxyethylene nonyl phenyl second Alkene ether, emulsifier are settled to 5 L, ultrasonic disperse, and ultrasonic time is 45 minutes, and supersonic frequency is 220-250 KW；
(4) the ultrasonic disperse mixture of step (3) is injected into mixer, adds sulfosuccinate bisamide salt, malic acid, mountain Potassium sorbate, cellulase, double palmityl ethylene diamine dipropionic acid sodium, anionic surfactant, heating stirring is to 55 DEG C, stirring Speed is 50-100 revs/min, reaction time 10-25 minute；
(5) trimethylolpropane, sodium tripolyphosphate, defoaming agent are added in reaction kettle, are mixed, mixing speed 200- 300 revs/min, the reaction time is 35 minutes, and reaction temperature is 120-160 DEG C；
(6) mixture of step (4) is added in the reaction kettle of step (5), it is isometric to mix, while slowly pressurization is warming up to 180 DEG C of heat preservation activation, are kept stirring 300 revs/min of speed, the reaction time 30 minutes；
(7) toward the mixture cooled to room temperature of step (6), pH value then is adjusted to 7-8 with disodium bicarbonate, is stirred evenly Up to semi-finished product；
(8) the semi-finished product mixed liquor in step (7) is crossed into membrane choosing, removes bulky grain, packing.
2. the preparation method of the environmental protection weaving refining agent according to claim 1 for mulberry silk, it is characterised in that: described The pressure of step (6) is 5-10 Mpa.
3. the preparation method of the environmental protection weaving refining agent according to claim 1 for mulberry silk, it is characterised in that: described The membrane aperture of step (8) is 100-200 μm.
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CN105002734A (en) * 2015-07-01 2015-10-28 广东灵捷制造化工有限公司 Degreasing and blenching auxiliary agent used for medical gauze one-step bath pretreatment, and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN103290688A (en) * 2013-05-16 2013-09-11 任芳芳 Cotton fabric refining agent
CN103666827A (en) * 2013-11-27 2014-03-26 江苏中新资源集团有限公司 Raw wool detergent and preparation method thereof
CN103898734A (en) * 2014-03-24 2014-07-02 苏州润弘贸易有限公司 Preparation method of silk wadding blended fabric scouring agent
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