CN105239425A - Acid dye leveling agent integrating uniform dyeing, color increasing and color fixing and preparation method thereof - Google Patents
Acid dye leveling agent integrating uniform dyeing, color increasing and color fixing and preparation method thereof Download PDFInfo
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- CN105239425A CN105239425A CN201510683006.8A CN201510683006A CN105239425A CN 105239425 A CN105239425 A CN 105239425A CN 201510683006 A CN201510683006 A CN 201510683006A CN 105239425 A CN105239425 A CN 105239425A
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- hyperchromic
- fixation
- levelling agent
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- attapulgite
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 86
- 238000004043 dyeing Methods 0.000 title claims abstract description 64
- 239000000980 acid dye Substances 0.000 title claims abstract description 56
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 239000000243 solution Substances 0.000 claims abstract description 45
- 229960000892 attapulgite Drugs 0.000 claims abstract description 44
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 44
- 238000003756 stirring Methods 0.000 claims abstract description 37
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 23
- 239000000194 fatty acid Substances 0.000 claims abstract description 23
- 229930195729 fatty acid Natural products 0.000 claims abstract description 23
- -1 fatty acid amine Chemical class 0.000 claims abstract description 23
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 23
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 23
- 239000004359 castor oil Substances 0.000 claims abstract description 22
- 235000019438 castor oil Nutrition 0.000 claims abstract description 22
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims abstract description 22
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 22
- 239000011259 mixed solution Substances 0.000 claims abstract description 19
- 239000002904 solvent Substances 0.000 claims abstract description 14
- 239000002270 dispersing agent Substances 0.000 claims abstract description 11
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 claims description 52
- 230000000215 hyperchromic effect Effects 0.000 claims description 43
- 230000003750 conditioning effect Effects 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000008367 deionised water Substances 0.000 claims description 14
- 229910021641 deionized water Inorganic materials 0.000 claims description 14
- 239000004094 surface-active agent Substances 0.000 claims description 13
- 239000012752 auxiliary agent Substances 0.000 claims description 12
- 150000001768 cations Chemical class 0.000 claims description 9
- 239000006185 dispersion Substances 0.000 claims description 9
- 239000003945 anionic surfactant Substances 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000003607 modifier Substances 0.000 abstract 2
- 238000009775 high-speed stirring Methods 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 41
- 239000000835 fiber Substances 0.000 description 13
- 230000000694 effects Effects 0.000 description 10
- 230000004075 alteration Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 239000002253 acid Substances 0.000 description 5
- 239000004952 Polyamide Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 229920002647 polyamide Polymers 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000002932 luster Substances 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 201000010260 leiomyoma Diseases 0.000 description 2
- 239000000693 micelle Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- BAECOWNUKCLBPZ-HIUWNOOHSA-N Triolein Natural products O([C@H](OCC(=O)CCCCCCC/C=C\CCCCCCCC)COC(=O)CCCCCCC/C=C\CCCCCCCC)C(=O)CCCCCCC/C=C\CCCCCCCC BAECOWNUKCLBPZ-HIUWNOOHSA-N 0.000 description 1
- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 description 1
- 241001463139 Vitta Species 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
Abstract
The invention provides an acid dye leveling agent integrating uniform dyeing, color increasing and color fixing and a preparation method thereof. The acid dye leveling agent comprises, by weight parts, 10-30 parts of sodium lignin sulfonate, 15-30 parts of sulfonated castor oil, 20-40 parts of fatty acid amine polyoxyethylene ether, 5-25 parts of nano-attapulgite and 20-50 parts of addition agents. The preparation method comprises the steps: (1) adding a PH modifier to a solvent, evenly stirring the solvent so that the PH of the solvent is stable, slowing adding sodium lignin sulfonate, sulfonated castor oil and fatty acid amine polyoxyethylene ether, evenly stirring the solvent to fully dissolve the solvent, and performing defoaming to obtain mixed solution; (2) adding dispersing agent and the PH modifier into the solvent, adjusting the PH of the solution, adding nano-attapulgite, performing high-speed stirring until the nano-attapulgite is dispersed fully, and obtaining nano-attapulgite solution; (3) linearly slowing adding the nano-attapulgite solution into the mixed solution, evenly stirring the mixed solution, and obtaining the acid dye leveling agent integrating uniform dyeing, color increasing and color fixing.
Description
Technical field:
The invention belongs to textile material technical field, be specifically related to a kind ofly collect ACID DYES levelling agent of level dyeing hyperchromic fixation one and preparation method thereof.
Background technology:
In dyeing and printing process process, if occur, the uneven meeting of dyeing has a strong impact on quality and the quality of fabric, therefore in order to make dyestuff reach level dyeing on fabric, does not produce the fault such as vitta, color spot, needs to use levelling agent.The effect of levelling agent has slow dye and moves dye two aspect, makes dyestuff comparatively slowly by while fibers adsorption, impels the dyestuff of dark parts to move to light-colored part, finally reach the object of level dyeing.Along with the development of science and technology, there is various novel fiber, in order to comply with the environmental consciousness of people and development capable of circulation, all kinds of levelling agents of environmental protection also in succession studied go out city.
Levelling agent great majority are water miscible surfactants, according to the impact of levelling agent on dye diffusion and concentration class, mainly be divided into close fibroid and parent dye, wherein close fibroid levelling agent only has the effect of slow dye, the dye levelling agent of parent can reduce the diffusion rate of dyestuff and delay the time of dyeing, has the slow effect contaminating and move dye.And close dye levelling agent is also divided into multiple kind according to the difference of the chemical property of dyestuff.
As everyone knows, dyestuff can be divided into DISPERSE DYES, cation dyes, REACTIVE DYES, direct dyes, ACID DYES, reducing dye, azoic dyes and the condensation dye according to the difference of its chemical property.ACID DYES is the water-soluble dye with acidic-group on a class formation, dye in acid medium, mostly containing sulfonate sodium in ACID DYES, can be water-soluble, lovely luster, chromatogram are complete, mainly be mainly used in the dyeing such as wool, silk and polyamide fibre, also can be used for the aspects such as leather, paper, ink, but cannot directly carry out painted to cellulose fibre.
The disclosed a kind of acid levelling agent of Chinese patent CN103243582A (publication date 2013.8.14) and preparation method, this acid levelling agent comprises polyvinylpyrrolidone, empgen BB, aliphatic alcohol polyethenoxy, sodium sulfate of polyethenoxy ether of fatty alcohol and water, this levelling agent by select dissimilar raw material composite go out wide, the effective ACID DYES levelling agent of applicability, especially reduce the look flower, the color spot agent strip defect that easily occur when ACID DYES dyes to polyamide fibre.The disclosed a kind of high temperature levelling agent of Chinese patent CN103290705B (publication date 2013.9.11), this high temperature levelling agent comprises glycerin ether oleate, tartaric acid, aliphatic amine polyoxyethylene ether, lanolin, glycol fatty acid ester and glycerol trioleate.This high temperature levelling agent has excellent dye dispersion, the initial stage delays metachromia, as the High Temperature High Pressure Disperse Leveler of polyster fibre, can maintain dye bath and dye in acid condition, effectively avoids sensitive dye to be hydrolyzed and the cloth cover chromatic light deviation that causes.
From above-mentioned prior art, current ACID DYES levelling agent is seldom both sexes Compositional type levelling agent, and the ACID DYES levelling agent spininess of preparation is to the uniform dyeing property of single fiber, the research of the aberration of fabric and the saturation degree of color is unsatisfactory, is therefore necessary to develop a kind of ACID DYES levelling agent integrating the hyperchromic fixation of level dyeing.
Summary of the invention:
The technical problem to be solved in the present invention is to provide and a kind ofly collects ACID DYES levelling agent of level dyeing hyperchromic fixation one and preparation method thereof, the ACID DYES levelling agent of the hyperchromic fixation one of this collection level dyeing comprises anion surfactant, weak cation surfactant and high molecular polymer, when can make dyeing by the ACID DYES levelling agent of the composite preparation of three, even dyeing effect is good, aberration rate is little, and bright in colour, high to the relevance factor of multiple fiber.
For solving the problems of the technologies described above, technical scheme of the present invention is:
A kind of ACID DYES levelling agent collecting the hyperchromic fixation one of level dyeing, it is characterized in that, the described hyperchromic fixation of the level dyeing ACID DYES levelling agent integrally that integrates is as both sexes compound surfactant, described both sexes compound surfactant comprises anion surfactant, weak cation surfactant and high molecular polymer, described anion surfactant is sodium lignin sulfonate and sulfonated castor oil, described weak cation surfactant is fatty acid amine polyoxyethylene ether, and described high molecular polymer comprises nano-attapulgite.
Preferably, the component in the ACID DYES levelling agent of the hyperchromic fixation one of described collection level dyeing, by weight, comprising:
Sodium lignin sulfonate 10-30 part;
Sulfonated castor oil 15-30 part;
Fatty acid amine polyoxyethylene ether 20-40 part;
Nano-attapulgite 5-25 part;
Auxiliary agent 20-50 part.
Preferably, the component in the ACID DYES levelling agent of the hyperchromic fixation one of described collection level dyeing, by weight, comprising:
Sodium lignin sulfonate 20-30 part;
Sulfonated castor oil 15-25 part;
Fatty acid amine polyoxyethylene ether 25-40 part;
Nano-attapulgite 5-20 part;
Auxiliary agent 25-50 part.
Preferably described auxiliary agent comprises PH conditioning agent, dispersant and solvent.
The present invention also provides a kind of preparation method collecting the ACID DYES levelling agent of the hyperchromic fixation one of level dyeing, it is characterized in that: comprise the following steps:
(1) in solvent, add PH conditioning agent, stir stable to the pH value of solution, slowly add sodium lignin sulfonate, sulfonated castor oil and fatty acid amine polyoxyethylene ether, stir to dissolving completely, froth breaking obtains mixed solution;
(2) in solvent, add dispersant and PH conditioning agent, the pH value of regulator solution, after stirring, add nano-attapulgite, high-speed stirred is complete to dispersion, obtains nano-attapulgite solution;
(3) nano-attapulgite solution step (2) prepared slowly joins in mixed solution prepared by step (1) with wire, stirs, and obtains the ACID DYES levelling agent collecting the hyperchromic fixation one of level dyeing.
Preferred as technique scheme, in described step (1) and step (2), solvent is softening deionized water.
Preferred as technique scheme, in described step (1) and step (2), the pH value of solution is 4.5-6.5.
Preferred as technique scheme, in described step (2), the concentration of nano-attapulgite solution is 2-3mg/L.
Preferred as technique scheme, in described step (2), the rotating speed of high-speed stirred is 1500-2000rpm/min.
Preferred as technique scheme, in described step (3), the rotating speed of stirring is 500-800rpm/min.
Compared with prior art, the present invention has following beneficial effect:
(1) containing macromolecule levelling agent nano-attapulgite in the ACID DYES levelling agent of the hyperchromic fixation one of the collection level dyeing prepared of the present invention, can by forming the micelle of space net structure with dye molecule inclusion, play the slow effect contaminating and move dye, increase the level-dyeing property of dyestuff, and the tinting strength, tinting power of dyestuff can be improved, ensure the gorgeous of color and luster.
(2) containing weak cation surfactant and anion surfactant in the ACID DYES levelling agent of the hyperchromic fixation one of the collection level dyeing prepared of the present invention, under acid bath dye environment, the affinity of weak cation surfactant to dyestuff is strong, the dyestuff of upper dye can be moved, there is the effect moving dye, anion surfactant has certain affinity to fiber, and migration rate is higher than anionic dye, therefore early fiber surface can be attached to one step ahead, then replace by dye anion, play the effect of slow dye, therefore weak cation surfactant is matched with anion surfactant, can act on fiber and dyestuff simultaneously, improve the uniformity that each molecule of dyestuff contaminates, the existence of maximum reduction aberration.
(3) the hyperchromic fixation of the collection level dyeing ACID DYES levelling agent integrally that prepared by the present invention can improve the uniformity of the intermolecular distribution of ACID DYES, reduce the generation of aberration, to the ACID DYES of shades of colour, all there is good even dyeing effect, and can promote that each dye molecule formation micelle is attached to the surface of fiber, improve the degree of staining of dyestuff, ensure the gorgeous of color and luster.
Detailed description of the invention:
Describe the present invention in detail below in conjunction with specific embodiment, be used for explaining the present invention in this illustrative examples of the present invention and explanation, but not as a limitation of the invention.
Embodiment 1:
Collect the component in the ACID DYES levelling agent of the hyperchromic fixation one of level dyeing, by weight, comprising:
Sodium lignin sulfonate 10 parts;
Sulfonated castor oil 15 parts;
Fatty acid amine polyoxyethylene ether 20 parts;
Nano-attapulgite 5 parts;
Auxiliary agent 20 parts.
Concrete preparation method is:
(1) in softening deionized water, PH conditioning agent is added, the pH value of regulator solution is 4.5, stirs stable to the pH value of solution, slowly adds sodium lignin sulfonate, sulfonated castor oil and fatty acid amine polyoxyethylene ether, stir to dissolving completely, froth breaking obtains mixed solution.
(2) in softening deionized water, dispersant and PH conditioning agent is added, the pH value of regulator solution is 4.5, after stirring, and adds nano-attapulgite, complete to dispersion with the speed high-speed stirred of 1500rpm/min, obtain the nano-attapulgite solution of 2mg/L.
(3) nano-attapulgite solution step (2) prepared slowly joins in mixed solution prepared by step (1) with wire, stir with the speed of 500rpm/min, obtain the ACID DYES levelling agent collecting the hyperchromic fixation one of level dyeing.
Embodiment 2:
Collect the component in the ACID DYES levelling agent of the hyperchromic fixation one of level dyeing, by weight, comprising:
Sodium lignin sulfonate 30 parts;
Sulfonated castor oil 30 parts;
Fatty acid amine polyoxyethylene ether 40 parts;
Nano-attapulgite 25 parts;
Auxiliary agent 50 parts.
Concrete preparation method is:
(1) in softening deionized water, PH conditioning agent is added, the pH value of regulator solution is 6.5, stirs stable to the pH value of solution, slowly adds sodium lignin sulfonate, sulfonated castor oil and fatty acid amine polyoxyethylene ether, stir to dissolving completely, froth breaking obtains mixed solution.
(2) in softening deionized water, dispersant and PH conditioning agent is added, the pH value of regulator solution is 6.5, after stirring, and adds nano-attapulgite, complete to dispersion with the speed high-speed stirred of 2000rpm/min, obtain the nano-attapulgite solution of 3mg/L.
(3) nano-attapulgite solution step (2) prepared slowly joins in mixed solution prepared by step (1) with wire, stir with the speed of 800rpm/min, obtain the ACID DYES levelling agent collecting the hyperchromic fixation one of level dyeing.
Embodiment 3:
Collect the component in the ACID DYES levelling agent of the hyperchromic fixation one of level dyeing, by weight, comprising:
Sodium lignin sulfonate 25 parts;
Sulfonated castor oil 20 parts;
Fatty acid amine polyoxyethylene ether 30 parts;
Nano-attapulgite 10 parts;
Auxiliary agent 40 parts.
Concrete preparation method is:
(1) in softening deionized water, PH conditioning agent is added, the pH value of regulator solution is 5, stirs stable to the pH value of solution, slowly adds sodium lignin sulfonate, sulfonated castor oil and fatty acid amine polyoxyethylene ether, stir to dissolving completely, froth breaking obtains mixed solution.
(2) in softening deionized water, dispersant and PH conditioning agent is added, the pH value of regulator solution is 5.5, after stirring, and adds nano-attapulgite, complete to dispersion with the speed high-speed stirred of 1800rpm/min, obtain the nano-attapulgite solution of 2.5mg/L.
(3) nano-attapulgite solution step (2) prepared slowly joins in mixed solution prepared by step (1) with wire, stir with the speed of 600rpm/min, obtain the ACID DYES levelling agent collecting the hyperchromic fixation one of level dyeing.
Embodiment 4:
Collect the component in the ACID DYES levelling agent of the hyperchromic fixation one of level dyeing, by weight, comprising:
Sodium lignin sulfonate 20 parts;
Sulfonated castor oil 15 parts;
Fatty acid amine polyoxyethylene ether 25 parts;
Nano-attapulgite 5 parts;
Auxiliary agent 25 parts.
Concrete preparation method is:
(1) in softening deionized water, PH conditioning agent is added, the pH value of regulator solution is 6, stirs stable to the pH value of solution, slowly adds sodium lignin sulfonate, sulfonated castor oil and fatty acid amine polyoxyethylene ether, stir to dissolving completely, froth breaking obtains mixed solution.
(2) in softening deionized water, dispersant and PH conditioning agent is added, the pH value of regulator solution is 5.5, after stirring, and adds nano-attapulgite, complete to dispersion with the speed high-speed stirred of 1500rpm/min, obtain the nano-attapulgite solution of 3mg/L.
(3) nano-attapulgite solution step (2) prepared slowly joins in mixed solution prepared by step (1) with wire, stir with the speed of 600rpm/min, obtain the ACID DYES levelling agent collecting the hyperchromic fixation one of level dyeing.
Embodiment 5:
Collect the component in the ACID DYES levelling agent of the hyperchromic fixation one of level dyeing, by weight, comprising:
Sodium lignin sulfonate 25 parts;
Sulfonated castor oil 25 parts;
Fatty acid amine polyoxyethylene ether 35 parts;
Nano-attapulgite 20 parts;
Auxiliary agent 30 parts.
Concrete preparation method is:
(1) in softening deionized water, PH conditioning agent is added, the pH value of regulator solution is 6.5, stirs stable to the pH value of solution, slowly adds sodium lignin sulfonate, sulfonated castor oil and fatty acid amine polyoxyethylene ether, stir to dissolving completely, froth breaking obtains mixed solution.
(2) in softening deionized water, dispersant and PH conditioning agent is added, the pH value of regulator solution is 6, after stirring, and adds nano-attapulgite, complete to dispersion with the speed high-speed stirred of 2000rpm/min, obtain the nano-attapulgite solution of 2mg/L.
(3) nano-attapulgite solution step (2) prepared slowly joins in mixed solution prepared by step (1) with wire, stir with the speed of 750rpm/min, obtain the ACID DYES levelling agent collecting the hyperchromic fixation one of level dyeing.
Embodiment 6:
Collect the component in the ACID DYES levelling agent of the hyperchromic fixation one of level dyeing, by weight, comprising:
Sodium lignin sulfonate 30 parts;
Sulfonated castor oil 15 parts;
Fatty acid amine polyoxyethylene ether 30 parts;
Nano-attapulgite 25 parts;
Auxiliary agent 30 parts.
Concrete preparation method is:
(1) in softening deionized water, PH conditioning agent is added, the pH value of regulator solution is 6.5, stirs stable to the pH value of solution, slowly adds sodium lignin sulfonate, sulfonated castor oil and fatty acid amine polyoxyethylene ether, stir to dissolving completely, froth breaking obtains mixed solution.
(2) in softening deionized water, dispersant and PH conditioning agent is added, the pH value of regulator solution is 5.5, after stirring, and adds nano-attapulgite, complete to dispersion with the speed high-speed stirred of 1800rpm/min, obtain the nano-attapulgite solution of 2.4mg/L.
(3) nano-attapulgite solution step (2) prepared slowly joins in mixed solution prepared by step (1) with wire, stir with the speed of 800rpm/min, obtain the ACID DYES levelling agent collecting the hyperchromic fixation one of level dyeing.
The ACID DYES levelling agent of the hyperchromic fixation one of the collection level dyeing prepared by embodiment 1-6 is used in the dyeing of wool, silk and polyamide fibre, and the result obtaining K/S value, aberration, level-dyeing property and colorfastness to rubbing is after testing as follows:
Woolen dyed result:
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | |
| K/S value | 6.3 | 6.0 | 6.1 | 6.1 | 6.2 | 6.3 |
| Aberration | 3.0 | 3.1 | 3.2 | 3.2 | 3.0 | 3.1 |
| Level-dyeing property | 0.02 | 0.015 | 0.02 | 0.016 | 0.019 | 0.017 |
| Colorfastness to rubbing | 5 | 4-5 | 4-5 | 5 | 5 | 4-5 |
Dyeing silk result:
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | |
| K/S value | 6.4 | 6.1 | 6.2 | 6.2 | 6.3 | 6.1 |
| Aberration | 2.9 | 3.3 | 3.1 | 3.0 | 3.2 | 3.0 |
| Level-dyeing property | 0.03 | 0.021 | 0.2.4 | 0.025 | 0.026 | 0.021 |
| Colorfastness to rubbing | 4-5 | 5 | 4-5 | 5 | 4-5 | 4-5 |
Nylon dyeing result:
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | |
| K/S value | 6.2 | 5.7 | 6.0 | 5.8 | 5.9 | 6.2 |
| Aberration | 3.4 | 2.0 | 3.1 | 3.0 | 3.2 | 3.1 |
| Level-dyeing property | 0.03 | 0.02 | 0.03 | 0.02 | 0.03 | 0.03 |
| Colorfastness to rubbing | 4-5 | 4-5 | 5 | 4-5 | 4-5 | 5 |
As seen from the above table, the ACID DYES levelling agent of collection level dyeing hyperchromic fixation one prepared by the present invention is all good to the Color of wool, silk and polyamide fibre, and possess level dyeing, fixation, the hyperchromic effect be integrated, three's effects equalizer, is conducive to marketing.
Above-described embodiment is illustrative principle of the present invention and effect thereof only, but not for limiting the present invention.Any person skilled in the art scholar all without prejudice under spirit of the present invention and category, can modify above-described embodiment or changes.Therefore, such as have in art usually know the knowledgeable do not depart from complete under disclosed spirit and technological thought all equivalence modify or change, must be contained by claim of the present invention.
Claims (10)
1. one kind collects the ACID DYES levelling agent of the hyperchromic fixation one of level dyeing, it is characterized in that, the described hyperchromic fixation of the level dyeing ACID DYES levelling agent integrally that integrates is as both sexes compound surfactant, described both sexes compound surfactant comprises anion surfactant, weak cation surfactant and high molecular polymer, described anion surfactant is sodium lignin sulfonate and sulfonated castor oil, described weak cation surfactant is fatty acid amine polyoxyethylene ether, and described high molecular polymer comprises nano-attapulgite.
2. a kind of ACID DYES levelling agent collecting the hyperchromic fixation one of level dyeing according to claim 1, is characterized in that, the component in the ACID DYES levelling agent of the hyperchromic fixation one of described collection level dyeing, by weight, comprising:
Sodium lignin sulfonate 10-30 part;
Sulfonated castor oil 15-30 part;
Fatty acid amine polyoxyethylene ether 20-40 part;
Nano-attapulgite 5-25 part;
Auxiliary agent 20-50 part.
3. a kind of ACID DYES levelling agent collecting the hyperchromic fixation one of level dyeing according to claim 2, is characterized in that, the component in the ACID DYES levelling agent of the hyperchromic fixation one of described collection level dyeing, by weight, comprising:
Sodium lignin sulfonate 20-30 part;
Sulfonated castor oil 15-25 part;
Fatty acid amine polyoxyethylene ether 25-40 part;
Nano-attapulgite 5-20 part;
Auxiliary agent 25-50 part.
4. a kind of ACID DYES levelling agent collecting the hyperchromic fixation one of level dyeing according to Claims 2 or 3, it is characterized in that, described auxiliary agent comprises PH conditioning agent, dispersant and solvent.
5. collect a preparation method for the ACID DYES levelling agent of the hyperchromic fixation one of level dyeing, it is characterized in that: comprise the following steps:
(1) in solvent, add PH conditioning agent, stir stable to the pH value of solution, slowly add sodium lignin sulfonate, sulfonated castor oil and fatty acid amine polyoxyethylene ether, stir to dissolving completely, froth breaking obtains mixed solution;
(2) in solvent, add dispersant and PH conditioning agent, the pH value of regulator solution, after stirring, add nano-attapulgite, high-speed stirred is complete to dispersion, obtains nano-attapulgite solution;
(3) nano-attapulgite solution step (2) prepared slowly joins in mixed solution prepared by step (1) with wire, stirs, and obtains the ACID DYES levelling agent collecting the hyperchromic fixation one of level dyeing.
6. a kind of preparation method collecting the ACID DYES levelling agent of level dyeing hyperchromic fixation one according to claim 5, is characterized in that: in described step (1) and step (2),
Solvent is softening deionized water.
7. a kind of preparation method collecting the ACID DYES levelling agent of level dyeing hyperchromic fixation one according to claim 5, is characterized in that: in described step (1) and step (2),
The pH value of solution is 4.5-6.5.
8. a kind of preparation method collecting the ACID DYES levelling agent of the hyperchromic fixation one of level dyeing according to claim 5, it is characterized in that: in described step (2), the concentration of nano-attapulgite solution is 2-3mg/L.
9. a kind of preparation method collecting the ACID DYES levelling agent of the hyperchromic fixation one of level dyeing according to claim 5, it is characterized in that: in described step (2), the rotating speed of high-speed stirred is 1500-2000rpm/min.
10. a kind of preparation method collecting the ACID DYES levelling agent of the hyperchromic fixation one of level dyeing according to claim 5, it is characterized in that: in described step (3), the rotating speed of stirring is 500-800rpm/min.
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| CN111136743A (en) * | 2019-12-13 | 2020-05-12 | 阜南佳利工艺品股份有限公司 | Treatment method for improving wood dyeing stability |
| CN111136743B (en) * | 2019-12-13 | 2021-05-25 | 阜南佳利工艺品股份有限公司 | Treatment method for improving wood dyeing stability |
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