CN105603779A - Multifunctional high-temperature environmentally-friendly levelling agent and preparation method thereof - Google Patents
Multifunctional high-temperature environmentally-friendly levelling agent and preparation method thereof Download PDFInfo
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- CN105603779A CN105603779A CN201610104942.3A CN201610104942A CN105603779A CN 105603779 A CN105603779 A CN 105603779A CN 201610104942 A CN201610104942 A CN 201610104942A CN 105603779 A CN105603779 A CN 105603779A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
- D06P1/50—Derivatives of cellulose
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
- D06P1/621—Compounds without nitrogen
- D06P1/622—Sulfonic acids or their salts
- D06P1/623—Aliphatic, aralophatic or cycloaliphatic
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/655—Compounds containing ammonium groups
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67383—Inorganic compounds containing silicon
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Abstract
The invention discloses a multifunctional high-temperature environmentally-friendly levelling agent. The multifunctional high-temperature environmentally-friendly levelling agent is prepared from, by weight, 20-30 parts of polyethylene glycol mono stearate, 1-3 parts of amino-terminated double-head-sealing agent organic silicone, 5-10 parts of calcium lignosulphonate, 6-8 parts of ethylene glycol double succinic acid octyl alcohol ester sulfonate, 1.5-3 parts of hydroxypropyl methyl cellulose, 1-1.5 parts of hydrophilic gas phase white carbon black, 10-15 parts of sodium gluconate, 4-8 parts of sodium methallyl sulfonate, 2-5 parts of epoxymethacrylate, 0.2-0.5 part of a dispersing agent and 30-40 parts of deionized water. The invention further discloses a preparation method of the multifunctional high-temperature environmentally-friendly levelling agent, the multifunctional high-temperature environmentally-friendly levelling agent has excellent dyeing retarding, dyeing transfer and dispersing performance and is applicable to the dyeing process under multiple situations, so that a dyed object is pure in coloured light and soft in hand feeling, the tinctorial yield is not affected, raw materials such as styrenated phenol and phenol which are not environmentally friendly are not contained, and no harm is caused to the environment.
Description
Technical field:
The present invention relates to textile auxiliary technical field, be specifically related to a kind of multifunctional high-temperature environmental protection level dyeingAgent.
Background technology:
In the time using dyestuff to dye to fiber, after not only should accomplishing to dye, fiber color is dark dense and firmGu, and more to reach the uniform requirement of color, must make dye molecule be evenly distributed in fiberSurperficial and inner, make the whole fabric face color depth, form and aspect consistent with vividness, realize fabricUniformity dyeing. But in reality dyes particularly colorant match and resisdye process, fibrous physics form andThe inhomogeneities of chemical constitution and the difference to aspects such as Dye Adsorption performances and fabric pretreatment and dyeThe restriction of look process conditions, often can cause textile dyeing non-uniform phenomenon as barriness and specking etc. To the greatest extentPipe can adopt selection, the control overflow dyeing machine programming rate of dyestuff and increase staining solution flow and bath raio etc.Way solves, however there will be again that efficiency is low, energy consumption and water consumption high and control the problems such as difficulty.Conventional solution city adds high temperature resistant levelling agent to improve dyeing quality in dye bath.
High-temperature dyeing agent is generally the compound of nonionic and anion surfactant. Non-ionic surfaceIn activating agent, contain a large amount of polyoxyethylene segments disperse dyes are had to stronger peptizaiton, canSolve the problem that causes dyestuff cohesion to occur specking because Cloud Points of Nonionic Surfactants is low. Non-fromIn sub-surface active agent molecule structure, introduce sulfonic group, can improve to disperse dyes dispersion force in,Overcome non-ionic surface active agent to the coherent adverse effect of dyestuff, finally greatly improve level dyeing andDispersion effect.
Chinese patent (201310225731.1) discloses a kind of high temperature levelling agent, by polyester polyethers siliconOil block copolymer 0.1-1%, polyethylene glycol mono stearate 9-10% and excess water composition, polyesterThe composition of raw materials of polyether silicone oil block copolymer is: polyethylene glycol 120-160 part, ethylene glycol 18-30Part, polyether diols 15-25 part, dimethyl terephthalate (DMT) 20-28 part, hold amino double-seal head agentOrganosilicon 10-30 part, 3-gamma-piperazinepropyl methyldimethoxysilane 5-10 part and acetic acid slaine0.2-2 part. The high temperature levelling agent that this invention provides can not only improve the dyeing of polyester fiber or its fabricQuality, but also make polyester fiber or its fabric after dyeing obtain excellent fluffy softness, goodGood antistatic property and hydrophilicity. But it has impact to the color fastness that dyes thing, delay and dye and move and dyeProperty is poor.
Summary of the invention:
The object of this invention is to provide a kind of multifunctional high-temperature environmental protection levelling agent, its have excellent slowly dye,Move and dye and dispersive property, be applicable to the dyeing course under multiple situation, make to dye and look for light pure, handSense is soft, does not affect tinctorial yield, not containing the raw material of the not environmental protection such as styrenated phenol, phenol, to environment withoutEvil.
Another object of the present invention is to provide the preparation method of this multifunctional high-temperature environmental protection levelling agent.
For achieving the above object, the present invention is by the following technical solutions:
A kind of multifunctional high-temperature environmental protection levelling agent, in weight portion, comprises following component:
Polyethylene glycol mono stearate 20-30 part,
Hold amino double-seal head agent organosilicon 1-3 part,
Calcium lignosulfonate 5-10 part,
Ethylene glycol bis butanedioic acid n-octyl alcohol dibasic acid esters sodium sulfonate 6-8 part,
Hydroxypropyl methylcellulose 1.5-3 part,
Hydrophily gas-phase silica 1-1.5 part,
Gluconic acid sodium salt 10-15 part,
Methylpropene sodium sulfonate 4-8 part,
Epoxymethacrylate 2-5 part,
Dispersant 0.2-0.5 part,
Deionized water 30-40 part.
As technique scheme preferably, a kind of multifunctional high-temperature environmental protection levelling agent, in weight portion,Comprise following component:
23 parts of polyethylene glycol mono stearates,
Hold 1.5 parts of amino double-seal head agent organosilicons,
7 parts of calcium lignosulfonates,
7.5 parts of ethylene glycol bis butanedioic acid n-octyl alcohol dibasic acid esters sodium sulfonates,
2 parts of hydroxypropyl methylcelluloses,
1 part of hydrophily gas-phase silica,
13 parts of gluconic acid sodium salts,
6 parts of methylpropene sodium sulfonates,
2.5 parts of epoxymethacrylates,
0.2 part of dispersant,
40 parts of deionized waters.
As technique scheme preferably, the polyethylene glycol in described polyethylene glycol mono stearate isPEG200 or PEG600.
As technique scheme preferably, the particle size of described hydrophily gas-phase silica is1-2μm。
As technique scheme preferably, described dispersant is organo-silicon coupling agent, detergent alkylateThe mixture of sodium sulfonate, lauryl sodium sulfate, three's mass ratio is 0.1-0.3:1:1-1.5.
A preparation method for multifunctional high-temperature environmental protection levelling agent, comprises the following steps:
(1) hydrophily gas-phase silica, dispersant and deionized water are joined in homogenizer,Under the state of 5000-8000 rev/min, stir 20-40min, continue to add gluconic acid sodium salt, stirObtain mixed liquor A;
(2) by polyethylene glycol mono stearate, hold amino double-seal head agent organosilicon, hydroxypropyl methyl fibreDimension element, epoxymethacrylate, ethylene glycol bis butanedioic acid n-octyl alcohol dibasic acid esters sodium sulfonate, sulfomethylated ligninAcid calcium, methylpropene sodium sulfonate and deionized water are mixed, and are warming up to 40-50 DEG C, and constant temperature stirs 1-2h,Obtain mixed liquid B;
(3) the mixed liquid B mixing that mixed liquor A step (1) being obtained and step (2) obtain is stirredMix evenly, obtain multifunctional high-temperature environmental protection levelling agent.
As technique scheme preferably, in step (1), the condition of described stirring be 6000 turn/Point, 30min.
As technique scheme preferably, in step (2), the condition that described constant temperature stirs is 40 DEG C,1.5h。
The present invention has following beneficial effect:
The present invention adds hydrophily white carbon in levelling agent, can effectively improve the high temperature resistant of levelling agentPerformance, it has and excellent slowly dye, moves and dye and dispersive property, is applicable to the dyeing under multiple situationJourney, makes to dye and looks for light pure, soft, does not affect tinctorial yield, not containing styrenated phenol, phenolDeng the raw material of not environmental protection, environmental sound.
Detailed description of the invention:
For a better understanding of the present invention, below by embodiment, the present invention is further described, implementsExample, only for explaining the present invention, can not form any restriction to the present invention.
Embodiment 1
A kind of multifunctional high-temperature environmental protection levelling agent, in weight portion, comprises following component:
20 parts of polyethylene glycol mono stearates,
Hold 1 part of amino double-seal head agent organosilicon,
5 parts of calcium lignosulfonates,
6 parts of ethylene glycol bis butanedioic acid n-octyl alcohol dibasic acid esters sodium sulfonates,
1.5 parts of hydroxypropyl methylcelluloses,
1 part of hydrophily gas-phase silica,
10 parts of gluconic acid sodium salts,
4 parts of methylpropene sodium sulfonates,
2 parts of epoxymethacrylates,
0.2 part of dispersant, 30 parts of deionized waters.
Its preparation method comprises the following steps:
(1) hydrophily gas-phase silica, dispersant and deionized water are joined in homogenizer,Under the state of 5000 revs/min, stir 20min, continue to add gluconic acid sodium salt, stir and mixedLiquid A;
(2) by polyethylene glycol mono stearate, hold amino double-seal head agent organosilicon, hydroxypropyl methyl fibreDimension element, epoxymethacrylate, ethylene glycol bis butanedioic acid n-octyl alcohol dibasic acid esters sodium sulfonate, sulfomethylated ligninAcid calcium, methylpropene sodium sulfonate and deionized water are mixed, and are warming up to 40-50 DEG C, and constant temperature stirs 1h,Obtain mixed liquid B;
(3) the mixed liquid B mixing that mixed liquor A step (1) being obtained and step (2) obtain is stirredMix evenly, obtain multifunctional high-temperature environmental protection levelling agent.
Embodiment 2
A kind of multifunctional high-temperature environmental protection levelling agent, in weight portion, comprises following component:
30 parts of polyethylene glycol mono stearates,
Hold 3 parts of amino double-seal head agent organosilicons,
10 parts of calcium lignosulfonates,
8 parts of ethylene glycol bis butanedioic acid n-octyl alcohol dibasic acid esters sodium sulfonates,
3 parts of hydroxypropyl methylcelluloses,
1.5 parts of hydrophily gas-phase silicas,
15 parts of gluconic acid sodium salts,
8 parts of methylpropene sodium sulfonates,
5 parts of epoxymethacrylates,
0.5 part of dispersant, 40 parts of deionized waters.
Its preparation method comprises the following steps:
(1) hydrophily gas-phase silica, dispersant and deionized water are joined in homogenizer,Under the state of 8000 revs/min, stir 40min, continue to add gluconic acid sodium salt, stir and mixedLiquid A;
(2) by polyethylene glycol mono stearate, hold amino double-seal head agent organosilicon, hydroxypropyl methyl fibreDimension element, epoxymethacrylate, ethylene glycol bis butanedioic acid n-octyl alcohol dibasic acid esters sodium sulfonate, sulfomethylated ligninAcid calcium, methylpropene sodium sulfonate and deionized water are mixed, and are warming up to 40-50 DEG C, and constant temperature stirs 2h,Obtain mixed liquid B;
(3) the mixed liquid B mixing that mixed liquor A step (1) being obtained and step (2) obtain is stirredMix evenly, obtain multifunctional high-temperature environmental protection levelling agent.
Embodiment 3
A kind of multifunctional high-temperature environmental protection levelling agent, in weight portion, comprises following component:
23 parts of polyethylene glycol mono stearates,
Hold 1.5 parts of amino double-seal head agent organosilicons,
7 parts of calcium lignosulfonates,
7.5 parts of ethylene glycol bis butanedioic acid n-octyl alcohol dibasic acid esters sodium sulfonates,
2 parts of hydroxypropyl methylcelluloses,
1 part of hydrophily gas-phase silica,
13 parts of gluconic acid sodium salts,
6 parts of methylpropene sodium sulfonates,
2.5 parts of epoxymethacrylates,
0.2 part of dispersant, 40 parts of deionized waters.
Its preparation method comprises the following steps:
(1) hydrophily gas-phase silica, dispersant and deionized water are joined in homogenizer,Under the state of 6000 revs/min, stir 25min, continue to add gluconic acid sodium salt, stir and mixedLiquid A;
(2) by polyethylene glycol mono stearate, hold amino double-seal head agent organosilicon, hydroxypropyl methyl fibreDimension element, epoxymethacrylate, ethylene glycol bis butanedioic acid n-octyl alcohol dibasic acid esters sodium sulfonate, sulfomethylated ligninAcid calcium, methylpropene sodium sulfonate and deionized water are mixed, and are warming up to 40-50 DEG C, and constant temperature stirs 1.2h,Obtain mixed liquid B;
(3) the mixed liquid B mixing that mixed liquor A step (1) being obtained and step (2) obtain is stirredMix evenly, obtain multifunctional high-temperature environmental protection levelling agent.
Embodiment 4
A kind of multifunctional high-temperature environmental protection levelling agent, in weight portion, comprises following component:
22 parts of polyethylene glycol mono stearates,
Hold 1.5 parts of amino double-seal head agent organosilicons,
6 parts of calcium lignosulfonates,
6.5 parts of ethylene glycol bis butanedioic acid n-octyl alcohol dibasic acid esters sodium sulfonates,
2 parts of hydroxypropyl methylcelluloses,
1.1 parts of hydrophily gas-phase silicas,
11 parts of gluconic acid sodium salts,
5 parts of methylpropene sodium sulfonates,
3 parts of epoxymethacrylates,
0.3 part of dispersant, 32 parts of deionized waters.
Its preparation method comprises the following steps:
(1) hydrophily gas-phase silica, dispersant and deionized water are joined in homogenizer,Under the state of 7000 revs/min, stir 30min, continue to add gluconic acid sodium salt, stir and mixedLiquid A;
(2) by polyethylene glycol mono stearate, hold amino double-seal head agent organosilicon, hydroxypropyl methyl fibreDimension element, epoxymethacrylate, ethylene glycol bis butanedioic acid n-octyl alcohol dibasic acid esters sodium sulfonate, sulfomethylated ligninAcid calcium, methylpropene sodium sulfonate and deionized water are mixed, and are warming up to 40-50 DEG C, and constant temperature stirs 1.4h,Obtain mixed liquid B;
(3) the mixed liquid B mixing that mixed liquor A step (1) being obtained and step (2) obtain is stirredMix evenly, obtain multifunctional high-temperature environmental protection levelling agent.
Embodiment 5
A kind of multifunctional high-temperature environmental protection levelling agent, in weight portion, comprises following component:
24 parts of polyethylene glycol mono stearates,
Hold 2 parts of amino double-seal head agent organosilicons,
7 parts of calcium lignosulfonates,
7 parts of ethylene glycol bis butanedioic acid n-octyl alcohol dibasic acid esters sodium sulfonates,
2.5 parts of hydroxypropyl methylcelluloses,
1.3 parts of hydrophily gas-phase silicas,
12 parts of gluconic acid sodium salts,
6 parts of methylpropene sodium sulfonates,
4 parts of epoxymethacrylates,
0.4 part of dispersant, 36 parts of deionized waters.
Its preparation method comprises the following steps:
(1) hydrophily gas-phase silica, dispersant and deionized water are joined in homogenizer,Under the state of 6000 revs/min, stir 35min, continue to add gluconic acid sodium salt, stir and mixedLiquid A;
(2) by polyethylene glycol mono stearate, hold amino double-seal head agent organosilicon, hydroxypropyl methyl fibreDimension element, epoxymethacrylate, ethylene glycol bis butanedioic acid n-octyl alcohol dibasic acid esters sodium sulfonate, sulfomethylated ligninAcid calcium, methylpropene sodium sulfonate and deionized water are mixed, and are warming up to 40-50 DEG C, and constant temperature stirs 1.6h,Obtain mixed liquid B;
(3) the mixed liquid B mixing that mixed liquor A step (1) being obtained and step (2) obtain is stirredMix evenly, obtain multifunctional high-temperature environmental protection levelling agent.
Embodiment 6
A kind of multifunctional high-temperature environmental protection levelling agent, in weight portion, comprises following component:
26 parts of polyethylene glycol mono stearates,
Hold 2.5 parts of amino double-seal head agent organosilicons,
8 parts of calcium lignosulfonates,
7.5 parts of ethylene glycol bis butanedioic acid n-octyl alcohol dibasic acid esters sodium sulfonates,
3 parts of hydroxypropyl methylcelluloses,
1.4 parts of hydrophily gas-phase silicas,
13 parts of gluconic acid sodium salts,
7 parts of methylpropene sodium sulfonates,
4.5 parts of epoxymethacrylates,
0.45 part of dispersant, 38 parts of deionized waters.
Its preparation method comprises the following steps:
(1) hydrophily gas-phase silica, dispersant and deionized water are joined in homogenizer,Under the state of 8000 revs/min, stir 40min, continue to add gluconic acid sodium salt, stir and mixedLiquid A;
(2) by polyethylene glycol mono stearate, hold amino double-seal head agent organosilicon, hydroxypropyl methyl fibreDimension element, epoxymethacrylate, ethylene glycol bis butanedioic acid n-octyl alcohol dibasic acid esters sodium sulfonate, sulfomethylated ligninAcid calcium, methylpropene sodium sulfonate and deionized water are mixed, and are warming up to 40-50 DEG C, and constant temperature stirs 1.8h,Obtain mixed liquid B;
(3) the mixed liquid B mixing that mixed liquor A step (1) being obtained and step (2) obtain is stirredMix evenly, obtain multifunctional high-temperature environmental protection levelling agent.
The multifunctional high-temperature environmental protection levelling agent of below being prepared by the present invention carries out performance test, and it is rightPET polyester fiber dyes.
(1) colouring method: the dyeing of taking high-temperature pressure dyeing and conventional PET polyester fiberTo a collection of PET polyester fiber dye (at 40 DEG C, add the auxiliary agent such as levelling agent, anti wrinkling agent, dyestuff,Insulation 10min, is warming up to 80 DEG C with the speed of 2 DEG C/min, continues the speed liter with 1.5 DEG C/minTemperature is to 130 DEG C, and insulation 30min, is cooled to 60 DEG C with the speed of 1.5 DEG C/min, discharge opeing), wherein,Levelling agent uses respectively the prepared high temperature levelling agent of embodiment 1-6 and traditional levelling agent (levelling agent1227 dodecyl benzyl dimethyl ammonium chloride).
(2) method of testing:
1) fluffy flexibility feel: professional person divides into groups to touch scoring, is divided into into five grades, wherein:1-is without feel; The slight fluffy softness of 2-; 3-has some fluffy softnesses; The more fluffy softness of 4-; 5-is superFluffy softness.
2) washability: test according to AATCC-135 standard;
3) test of other indexs is carried out with reference to relevant criterion. Test result is as shown in table 1:
Table 1
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Comparative example | |
| Fluffy flexibility feel | 5 | 5 | 5 | 5 | 5 | 5 | 2 |
| Washability, level | 5 | 5 | 4 | 5 | 4 | 5 | 2 |
| Move the rate of dying, % | 70 | 65 | 66 | 60 | 69 | 65 | 3.2 |
From table 1, multifunctional high-temperature environmental protection levelling agent prepared by the present invention has the excellent rate of dying of moving,The fabric feeling of processing is good, washing fastness excellence.
Claims (8)
1. a multifunctional high-temperature environmental protection levelling agent, is characterized in that, in weight portion, comprises following component:
Polyethylene glycol mono stearate 20-30 part,
Hold amino double-seal head agent organosilicon 1-3 part,
Calcium lignosulfonate 5-10 part,
Ethylene glycol bis butanedioic acid n-octyl alcohol dibasic acid esters sodium sulfonate 6-8 part,
Hydroxypropyl methylcellulose 1.5-3 part,
Hydrophily gas-phase silica 1-1.5 part,
Gluconic acid sodium salt 10-15 part,
Methylpropene sodium sulfonate 4-8 part,
Epoxymethacrylate 2-5 part,
Dispersant 0.2-0.5 part,
Deionized water 30-40 part.
2. a kind of multifunctional high-temperature environmental protection levelling agent as claimed in claim 1, is characterized in that, in weight portion,Comprise following component:
23 parts of polyethylene glycol mono stearates,
Hold 1.5 parts of amino double-seal head agent organosilicons,
7 parts of calcium lignosulfonates,
7.5 parts of ethylene glycol bis butanedioic acid n-octyl alcohol dibasic acid esters sodium sulfonates,
2 parts of hydroxypropyl methylcelluloses,
1 part of hydrophily gas-phase silica,
13 parts of gluconic acid sodium salts,
6 parts of methylpropene sodium sulfonates,
2.5 parts of epoxymethacrylates,
0.2 part of dispersant,
40 parts of deionized waters.
3. a kind of multifunctional high-temperature environmental protection levelling agent as claimed in claim 1, is characterized in that described polyethylene glycolPolyethylene glycol in monostearate is PEG200 or PEG600.
4. a kind of multifunctional high-temperature environmental protection levelling agent as claimed in claim 1, is characterized in that described hydrophily gasThe particle size of phase white carbon is 1-2 μ m.
5. a kind of multifunctional high-temperature environmental protection levelling agent as claimed in claim 1, is characterized in that, described dispersant isThe mixture of organo-silicon coupling agent, neopelex, lauryl sodium sulfate, three's mass ratio is0.1-0.3:1:1-1.5。
6. the preparation method of a kind of multifunctional high-temperature environmental protection levelling agent as described in as arbitrary in claim 1 to 5, its featureBe, comprise the following steps:
(1) hydrophily gas-phase silica, dispersant and deionized water are joined in homogenizer, at 5000-8000Rev/min state under stir 20-40min, continue to add gluconic acid sodium salt, stir and obtain mixed liquor A;
(2) by polyethylene glycol mono stearate, hold amino double-seal head agent organosilicon, hydroxypropyl methylcellulose, methylAcrylic acid epoxy ester, ethylene glycol bis butanedioic acid n-octyl alcohol dibasic acid esters sodium sulfonate, calcium lignosulfonate, methylpropene sodium sulfonateMix with deionized water, be warming up to 40-50 DEG C, constant temperature stirs 1-2h, obtains mixed liquid B;
(3) the mixed liquid B mixing and stirring that mixed liquor A step (1) being obtained and step (2) obtain,Obtain multifunctional high-temperature environmental protection levelling agent.
7. the preparation method of a kind of multifunctional high-temperature environmental protection levelling agent as claimed in claim 6, is characterized in that, stepSuddenly in (1), the condition of described stirring is 6000 revs/min, 30min.
8. the preparation method of a kind of multifunctional high-temperature environmental protection levelling agent as claimed in claim 6, is characterized in that, stepSuddenly in (2), the condition that described constant temperature stirs is 40 DEG C, 1.5h.
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| CN107401069A (en) * | 2017-06-23 | 2017-11-28 | 太仓大唐化纤厂 | A kind of acid dyes levelling agent |
| CN107687102A (en) * | 2017-09-29 | 2018-02-13 | 界首市恒吉服饰有限责任公司 | A kind of method of wool fiber dyeing |
| CN110983826A (en) * | 2019-12-17 | 2020-04-10 | 上海雅运新材料有限公司 | Rayon reactive printing leveling agent composition and preparation method thereof |
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| CN112012020A (en) * | 2020-09-01 | 2020-12-01 | 浙江汉邦新材料股份有限公司 | Woolen dustproof softening agent |
| CN112012020B (en) * | 2020-09-01 | 2023-08-08 | 浙江汉邦新材料股份有限公司 | Dustproof woolen softener |
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| CN114892430A (en) * | 2022-06-17 | 2022-08-12 | 晋江市盛星新材料科技有限公司 | Multifunctional leveling agent for polyester fabric and preparation method and use method thereof |
| CN114892430B (en) * | 2022-06-17 | 2023-11-24 | 晋江市盛星新材料科技有限公司 | Multifunctional leveling agent for polyester fabric and preparation method and application method thereof |
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