CN105735006A - Multifunctional environment-friendly dyeing deepening agent and preparation method thereof - Google Patents
Multifunctional environment-friendly dyeing deepening agent and preparation method thereof Download PDFInfo
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5292—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds containing Si-atoms
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
- D06P1/621—Compounds without nitrogen
- D06P1/622—Sulfonic acids or their salts
- D06P1/623—Aliphatic, aralophatic or cycloaliphatic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67383—Inorganic compounds containing silicon
Abstract
The invention discloses a multifunctional environment-friendly dyeing deepening agent. The agent is prepared from, by weight, 2-5 parts of lignin, 6-10 parts of chitosan oligosaccharide, 3-8 parts of nano-silicon sol, 2-6 parts of transglutaminase, 4-8 parts of seconary alkane sulphonate sodium, 7-12 parts of fluoride acrylic emulsion, 2-4 parts of calcium sulfate, 1-3 parts of modified cyclodextrin, 1-1.5 parts of polyoxypropylene and polyoxyethylene segmented copolymer, 2-3 parts of alpha-hyclroxy acetic acid, 1-3 parts of fluoro alkyl polyether modified polysiloxane and 20-30 parts of deionized water. The invention further discloses a preparation method of the multifunctional environment-friendly dyeing deepening agent. The deepening agent is good in deepening effect, the consumption of dyes can be effectively lowered, the dyeing efficiency of dyes is greatly improved, the compatibility of the agent and dyes is good, and fabric processed by the deepening agent is soft, comfortable, bright in color and luster and good in mechanical property.
Description
Technical field:
The present invention relates to textile auxiliary field, be specifically related to a kind of multi-functional environment-protection deep dyeing promoter.
Background technology:
In recent years, energy-saving and cost-reducing top priority and the breakthrough being to adjust China's economic structure.Dyeing water consumption is relatively big,
Occupying second in the manufacturing industry of the whole nation, wastewater discharge is the biggest, but the recycling of water is less, recycling
Rate is only 7%.Power consumption, water consumption and sewage discharge cost in the whole dyeing and finishing course of processing are bigger.As cotton
And cocoon fiber uses reactive dyeing, adding washing, move back techniques such as boiling drift, water consumption and wastewater flow rate are more.
Main matter in the dyeing waste-water of printing and dyeing mill is dyestuff and auxiliary agent, in the premise keeping dyeing and printing products dye level
Under, the effective way reducing dyeing waste water discharge is to reduce the injected volume of dyestuff in dyeing course, because any dye
The dye-uptake that material does not all have very, some product needed contaminates dark, then with greater need for dye bath has the dyestuff of high concentration,
After contaminating fiber on major part dyestuff, the colourity of dyeing waste-water is the highest, adds the intractability of dyeing waste-water.
It addition, a lot of fabrics all exist the problem of depth difference, especially painting to fabric, dark color is not deep, and black is the most black,
Some black fabric, to the visual effect of a kind of vast expanse of whiteness of people, has people once dyestuff to be brought up to above the most of no avail, phase
It is counter that bring is the dye decline of every fastness and the raising of cost, to this end, it is contemplated that rear whole at dyed fabric
Add deep-dyeing agent during reason, be so possible not only to reduce the consumption of dyestuff, it is thus achieved that preferably color depth, and reduce useless
The processing cost of water, has certain environment protection significance, and this has become as a study hotspot.Increase deep approach to have a lot
Kind, in terms of big for, amount of dye that a kind of method is attached on fabric increases, color burn；Another kind side
Method is increased without the amount of dye on fabric, starts with from optical angle, improves the optical characteristics of fabric face, increases fabric
Apparent Depth.
Chinese patent (201110009352.X) discloses a kind of printing deepening agent, and its recipe ratio is: benzoate
80-90%, benzyl alcohol 4.5-7.5%, fatty alcohol 2.5-5.0%, this deep-dyeing agent can effectively penetrate into the interior of polyster fibre
Portion, increases the intermolecular gap of polyster fibre, makes disperse dyes be more prone to colouring, reaches to increase deep purpose.But
This deep-dyeing agent has infringement to fabric fibre, can affect its mechanical property, and this deep-dyeing agent has certain harm to environment.
Chinese patent (201010288531.7) discloses a kind of dyed cotton fabric and increases the gorgeous finishing agent of deep increasing, and it is had by poly-
Organic siloxane emulsion forms by weight 100:5-10 with Methyl Hydrogen Polysiloxane Fluid emulsion.Dyed cotton is knitted by the gorgeous deep-dyeing agent of this increasing
Thing has and well increases deep and brightening effect, and fabrics feel soft is smooth after processing, but its compatibility ratio with dyestuff
Poor, stability is bad.
Summary of the invention:
It is an object of the invention to provide a kind of multi-functional environment-protection deep dyeing promoter, its increasing is the most effective, can effectively reduce
The consumption of dyestuff, is greatly improved the dye-uptake of dyestuff, and the compatibility with dyestuff is good, and the fabric after this deep-dyeing agent processes is soft
Soft comfortable, bright, mechanical property is good.
It is a further object to provide the preparation method of this multi-functional environment-protection deep dyeing promoter.
For achieving the above object, the present invention is by the following technical solutions:
A kind of multi-functional environment-protection deep dyeing promoter, in parts by weight, including following components:
Lignin 2-5 part,
Oligochitosan 6-10 part,
Nano silica sol 3-8 part,
T-5398 2-6 part,
SAS 4-8 part,
Fluorine acrylic emulsion 7-12 part,
Calcium sulfate 2-4 part,
Modified cyclodextrin 1-3 part,
Polyoxyethylene polyoxypropylene block copolymer 1-1.5 part,
α-carboxyl acetic acid 2-3 part,
Fluorine-based alkyl, polyether modified polyorganosiloxane 1-3 part,
Deionized water 20-30 part.
Preferred as technique scheme, a kind of multi-functional environment-protection deep dyeing promoter, in parts by weight, including following
Component:
Lignin 3.5 parts,
Oligochitosan 7 parts,
Nano silica sol 5 parts,
T-5398 4 parts,
SAS 4 parts,
Fluorine acrylic emulsion 10 parts,
2.2 parts of calcium sulfate,
Modified cyclodextrin 2 parts,
Polyoxyethylene polyoxypropylene block copolymer 1 part,
α-carboxyl acetic acid 2 parts,
Fluorine-based alkyl, polyether modified polyorganosiloxane 1.5 parts,
Deionized water 30 parts.
Preferred as technique scheme, described T-5398 is microbial transglutaminase.
Preferred as technique scheme, the size of described Nano silica sol is 15-20nm.
Preferred as technique scheme, described fluorine acrylic emulsion is for using the synthesis of pre-emulsification semi-continuous emulsion polymerizing technology
Trifluoroethyl methacrylate and the polymer of n-butyl acrylate.
Preferred as technique scheme, the preparation method of described modified cyclodextrin is particularly as follows: by mass fraction 90%
Concentrated sulphuric acid be placed in 100mL round-bottomed flask, be slowly added to cyclodextrin and in 0-2 DEG C of ice-water bath stir 1h；Will be anti-
Answering liquid to be poured into water, add calcium carbonate, leach the calcium sulfate precipitation of generation, washing, filtrate merges.Filtrate adds
Entering ethanol, place 24h, remove precipitation at 0-3 DEG C, filtrate regulates pH to 8-10 with sodium carbonate, filters, uses vinegar
Acid regulation filtrate pH to 6-7, decompression, vacuum filtration, concentrate, add dehydrated alcohol, produce white precipitate, filter,
Washing, vacuum drying obtains modified cyclodextrin.
The preparation method of a kind of multi-functional environment-protection deep dyeing promoter, comprises the following steps:
(1) lignin, oligochitosan, fluorine acrylic emulsion, polyoxyethylene polyoxypropylene block copolymer and deionized water are mixed
Conjunction stirs, and is warming up to 50-70 DEG C, under the state of 5000 revs/min, and constant temperature stirring 1.5-2h, obtain mixed emulsion；
(2) by Nano silica sol, SAS, calcium sulfate, modified cyclodextrin, α-carboxyl acetic acid, fluorine-based
Alkyl, polyether modified polyorganosiloxane and deionized water mixing, at 40-50 DEG C, under the power of 500-1000W, ultrasonic 2-5h,
Obtain mixed dispersion liquid；
(3) the mixed dispersion liquid mixing that the mixed emulsion that step (1) obtained, step (2) obtain, adds and turns paddy
Transglutaminase, stirs, and obtains multi-functional environment-protection deep dyeing promoter.
Preferred as technique scheme, described in step (1), the condition of stirring is at 60 DEG C, constant temperature stirring 2h.
Preferred as technique scheme, condition ultrasonic described in step (2) is: 40 DEG C, under 800W, ultrasonic
3.5h。
The method have the advantages that
The present invention adds calcium sulfate, oligochitosan, modified cyclodextrin in deep-dyeing agent, can the knot of effective relaxed fibre
Structure, thus expose and more contaminate seat so that dyestuff is easier to enter fibrous inside, thus improves the upper dye of dyestuff
Rate；The addition of lignin, Nano silica sol, α-carboxyl acetic acid etc. makes fiber surface add many cations, and
This dye seat of dye on anionic dye such as acid stain, acid mordant dyes just, thus improve the dye-uptake of dyestuff,
Reach to increase deep effect；
This deep-dyeing agent is to fabric fibre without damaging, and the fiber softening after process is comfortable, excellent in mechanical performance, and it is stable
Property is good, and the compatibility with dyestuff is good, and this deep-dyeing agent is nontoxic, to human body and environmentally friendly.
Detailed description of the invention:
In order to be better understood from the present invention, below by embodiment, the present invention is further described, and embodiment is served only for solving
Release the present invention, the present invention will not be constituted any restriction.
Embodiment 1
A kind of multi-functional environment-protection deep dyeing promoter, in parts by weight, including following components:
Lignin 2 parts, oligochitosan 6 parts,
Nano silica sol 3 parts, T-5398 2 parts,
SAS 4 parts, fluorine acrylic emulsion 7 parts,
2 parts of calcium sulfate, modified cyclodextrin 1 part,
Polyoxyethylene polyoxypropylene block copolymer 1 part,
α-carboxyl acetic acid 2 parts,
Fluorine-based alkyl, polyether modified polyorganosiloxane 1 part,
Deionized water 20 parts.
Its preparation method comprises the following steps:
(1) lignin, oligochitosan, fluorine acrylic emulsion, polyoxyethylene polyoxypropylene block copolymer and deionized water are mixed
Conjunction stirs, and is warming up to 50 DEG C, under the state of 5000 revs/min, and constant temperature stirring 1.5h, obtain mixed emulsion；
(2) by Nano silica sol, SAS, calcium sulfate, modified cyclodextrin, α-carboxyl acetic acid, fluorine-based
Alkyl, polyether modified polyorganosiloxane and deionized water mixing, at 40-50 DEG C, under the power of 500W, ultrasonic 2h, obtain
Mixed dispersion liquid；
(3) the mixed dispersion liquid mixing that the mixed emulsion that step (1) obtained, step (2) obtain, adds and turns paddy
Transglutaminase, stirs, and obtains multi-functional environment-protection deep dyeing promoter.
Embodiment 2
A kind of multi-functional environment-protection deep dyeing promoter, in parts by weight, including following components:
Lignin 5 parts, oligochitosan 10 parts,
Nano silica sol 8 parts, T-5398 6 parts,
SAS 8 parts, fluorine acrylic emulsion 12 parts,
4 parts of calcium sulfate, modified cyclodextrin 3 parts,
Polyoxyethylene polyoxypropylene block copolymer 1.5 parts,
α-carboxyl acetic acid 3 parts,
Fluorine-based alkyl, polyether modified polyorganosiloxane 3 parts,
Deionized water 30 parts.
Its preparation method comprises the following steps:
(1) lignin, oligochitosan, fluorine acrylic emulsion, polyoxyethylene polyoxypropylene block copolymer and deionized water are mixed
Conjunction stirs, and is warming up to 70 DEG C, under the state of 5000 revs/min, and constant temperature stirring 2h, obtain mixed emulsion；
(2) by Nano silica sol, SAS, calcium sulfate, modified cyclodextrin, α-carboxyl acetic acid, fluorine-based
Alkyl, polyether modified polyorganosiloxane and deionized water mixing, at 40-50 DEG C, under the power of 1000W, ultrasonic 5h, obtain
Mixed dispersion liquid；
(3) the mixed dispersion liquid mixing that the mixed emulsion that step (1) obtained, step (2) obtain, adds and turns paddy
Transglutaminase, stirs, and obtains multi-functional environment-protection deep dyeing promoter.
Embodiment 3
A kind of multi-functional environment-protection deep dyeing promoter, in parts by weight, including following components:
Lignin 3.5 parts, oligochitosan 7 parts,
Nano silica sol 5 parts, T-5398 4 parts,
SAS 4 parts, fluorine acrylic emulsion 10 parts,
2.2 parts of calcium sulfate, modified cyclodextrin 2 parts,
Polyoxyethylene polyoxypropylene block copolymer 1 part,
α-carboxyl acetic acid 2 parts,
Fluorine-based alkyl, polyether modified polyorganosiloxane 1.5 parts,
Deionized water 30 parts.
Its preparation method comprises the following steps:
(1) lignin, oligochitosan, fluorine acrylic emulsion, polyoxyethylene polyoxypropylene block copolymer and deionized water are mixed
Conjunction stirs, and is warming up to 55 DEG C, under the state of 5000 revs/min, and constant temperature stirring 1.6h, obtain mixed emulsion；
(2) by Nano silica sol, SAS, calcium sulfate, modified cyclodextrin, α-carboxyl acetic acid, fluorine-based
Alkyl, polyether modified polyorganosiloxane and deionized water mixing, at 40-50 DEG C, under the power of 600W, ultrasonic 3h, obtain
Mixed dispersion liquid；
(3) the mixed dispersion liquid mixing that the mixed emulsion that step (1) obtained, step (2) obtain, adds and turns paddy
Transglutaminase, stirs, and obtains multi-functional environment-protection deep dyeing promoter.
Embodiment 4
A kind of multi-functional environment-protection deep dyeing promoter, in parts by weight, including following components:
Lignin 3 parts, oligochitosan 7 parts,
Nano silica sol 4 parts, T-5398 3 parts,
SAS 5 parts, fluorine acrylic emulsion 8 parts,
3 parts of calcium sulfate, modified cyclodextrin 1.5 parts,
Polyoxyethylene polyoxypropylene block copolymer 1.1 parts,
α-carboxyl acetic acid 2.2 parts,
Fluorine-based alkyl, polyether modified polyorganosiloxane 1.5 parts,
Deionized water 22 parts.
Its preparation method comprises the following steps:
(1) lignin, oligochitosan, fluorine acrylic emulsion, polyoxyethylene polyoxypropylene block copolymer and deionized water are mixed
Conjunction stirs, and is warming up to 60 DEG C, under the state of 5000 revs/min, and constant temperature stirring 1.7h, obtain mixed emulsion；
(2) by Nano silica sol, SAS, calcium sulfate, modified cyclodextrin, α-carboxyl acetic acid, fluorine-based
Alkyl, polyether modified polyorganosiloxane and deionized water mixing, at 40-50 DEG C, under the power of 700W, ultrasonic 3.5h,
To mixed dispersion liquid；
(3) the mixed dispersion liquid mixing that the mixed emulsion that step (1) obtained, step (2) obtain, adds and turns paddy
Transglutaminase, stirs, and obtains multi-functional environment-protection deep dyeing promoter.
Embodiment 5
A kind of multi-functional environment-protection deep dyeing promoter, in parts by weight, including following components:
Lignin 4 parts, oligochitosan 8 parts,
Nano silica sol 5 parts, T-5398 4 parts,
SAS 6 parts, fluorine acrylic emulsion 9 parts,
3 parts of calcium sulfate, modified cyclodextrin 2 parts,
Polyoxyethylene polyoxypropylene block copolymer 1.2 parts,
α-carboxyl acetic acid 2.4 parts,
Fluorine-based alkyl, polyether modified polyorganosiloxane 2 parts,
Deionized water 24 parts.
Its preparation method comprises the following steps:
(1) lignin, oligochitosan, fluorine acrylic emulsion, polyoxyethylene polyoxypropylene block copolymer and deionized water are mixed
Conjunction stirs, and is warming up to 65 DEG C, under the state of 5000 revs/min, and constant temperature stirring 1.8h, obtain mixed emulsion；
(2) by Nano silica sol, SAS, calcium sulfate, modified cyclodextrin, α-carboxyl acetic acid, fluorine-based
Alkyl, polyether modified polyorganosiloxane and deionized water mixing, at 40-50 DEG C, under the power of 800W, ultrasonic 4h, obtain
Mixed dispersion liquid；
(3) the mixed dispersion liquid mixing that the mixed emulsion that step (1) obtained, step (2) obtain, adds and turns paddy
Transglutaminase, stirs, and obtains multi-functional environment-protection deep dyeing promoter.
Embodiment 6
A kind of multi-functional environment-protection deep dyeing promoter, in parts by weight, including following components:
Lignin 4.5 parts, oligochitosan 9 parts,
Nano silica sol 7 parts, T-5398 5 parts,
SAS 7 parts, fluorine acrylic emulsion 10 parts,
3.5 parts of calcium sulfate, modified cyclodextrin 2.5 parts,
Polyoxyethylene polyoxypropylene block copolymer 1.4 parts,
α-carboxyl acetic acid 2.8 parts,
Fluorine-based alkyl, polyether modified polyorganosiloxane 2.5 parts,
Deionized water 28 parts.
Its preparation method comprises the following steps:
(1) lignin, oligochitosan, fluorine acrylic emulsion, polyoxyethylene polyoxypropylene block copolymer and deionized water are mixed
Conjunction stirs, and is warming up to 70 DEG C, under the state of 5000 revs/min, and constant temperature stirring 1.9h, obtain mixed emulsion；
(2) by Nano silica sol, SAS, calcium sulfate, modified cyclodextrin, α-carboxyl acetic acid, fluorine-based
Alkyl, polyether modified polyorganosiloxane and deionized water mixing, at 40-50 DEG C, under the power of 900W, ultrasonic 4.5h,
To mixed dispersion liquid；
(3) the mixed dispersion liquid mixing that the mixed emulsion that step (1) obtained, step (2) obtain, adds and turns paddy
Transglutaminase, stirs, and obtains multi-functional environment-protection deep dyeing promoter.
The multi-functional environment-protection deep dyeing promoter prepared the present invention below carries out performance test.
1, deep-dyeing process, uses bafta, particularly as follows:
Technological process: the amount calculated by prescription weighs deep-dyeing agent, is placed in beaker, adds distilled water by bath raio, will
Bafta soaks two according to different pick-ups two and rolls, and then preliminary drying bakes further according to experimental program.
2, method of testing
(1) fabric strength test
Fabric is cut into 30 × 6cm, removes the long limit yarn of galley proof, make the bar limit of galley proof not contain broken yarn line, and minor face
Effective length is 5cm.It is in 65% exsiccator that the fabric having torn burr open is put into relative humidity, equilibrium at room temperature 12h with
On, measuring according to standard GB/T/T3923-1997, every piece of sample testing is averaged for three times, pulling force 100N.
(2) color fastness to washing test
The reagent that the water-fastness color fastness of textile uses is soap flakes, and the concentration of soap flakes is 5g/L, and the testing time is 30min,
Test temperature is 40 DEG C.Use adjacent fabric be two pieces, every piece of a size of 10cm × 4cm, first piece with sample
Identical fabric is made, and during test bafta, second piece of stickers lining cloth is wool fabric, and real silk fabric is bafta.To knit
The cloth of thing sample clip 10cm × 4cm, places it between two pieces of stickers lining cloth fabrics, and sews up along surrounding, makes
One group of test sample.Test is to carry out in equipped with the SW-12 type A color fastness to washing testing machine of two rotary shafts,
After test terminates, variable color and the staining of every kind of stickers lining cloth to sample, the variable color sum of series of sample is chosen with gray scale
Adjacent fabric and sample contacts staining progression simultaneously.
(3) fabric face depth test
By fabric with on the Ultra Scan XE type colour photometer of Htmterlab company of the U.S. read fabric sample K/S
Value.Colour examining light source is D65Light source, 10 ° of visual angles, every piece of sample four fold, reads and averages for ten times.
Test result is as shown in table 1, and wherein comparative example is common commercially available deep-dyeing agent:
Table 1
| Comparative example | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | |
| Ultimate strength, N | 220.0 | 721.3 | 712.5 | 697.6 | 682.9 | 742.3 | 686.7 |
| Soaping fastness, level 5 | 4 | 5 | 5 | 5 | 4-5 | 4-5 | 5 |
| K/S value | 21.47 | 39.99 | 45.17 | 46.32 | 50.60 | 45.89 | 49.95 |
From the point of view of table 1, deep-dyeing agent prepared by the present invention increases deep excellent effect, and the fabric mechanics after process is good, resistance to
Washing property is good.
Claims (9)
1. a multi-functional environment-protection deep dyeing promoter, it is characterised in that in parts by weight, including following
Component:
Lignin 2-5 part,
Oligochitosan 6-10 part,
Nano silica sol 3-8 part,
T-5398 2-6 part,
SAS 4-8 part,
Fluorine acrylic emulsion 7-12 part,
Calcium sulfate 2-4 part,
Modified cyclodextrin 1-3 part,
Polyoxyethylene polyoxypropylene block copolymer 1-1.5 part,
α-carboxyl acetic acid 2-3 part,
Fluorine-based alkyl, polyether modified polyorganosiloxane 1-3 part,
Deionized water 20-30 part.
2. a kind of multi-functional environment-protection deep dyeing promoter as claimed in claim 1, it is characterised in that with
Weight portion meter, including following components:
Lignin 3.5 parts,
Oligochitosan 7 parts,
Nano silica sol 5 parts,
T-5398 4 parts,
SAS 4 parts,
Fluorine acrylic emulsion 10 parts,
2.2 parts of calcium sulfate,
Modified cyclodextrin 2 parts,
Polyoxyethylene polyoxypropylene block copolymer 1 part,
α-carboxyl acetic acid 2 parts,
Fluorine-based alkyl, polyether modified polyorganosiloxane 1.5 parts,
Deionized water 30 parts.
3. a kind of multi-functional environment-protection deep dyeing promoter as claimed in claim 1, it is characterised in that institute
Stating T-5398 is microbial transglutaminase.
4. a kind of multi-functional environment-protection deep dyeing promoter as claimed in claim 1, it is characterised in that institute
The size stating Nano silica sol is 15-20nm.
5. a kind of multi-functional environment-protection deep dyeing promoter as claimed in claim 1, it is characterised in that institute
Stating fluorine acrylic emulsion is the trifluoroethyl methacrylate using the synthesis of pre-emulsification semi-continuous emulsion polymerizing technology
Polymer with n-butyl acrylate.
6. a kind of multi-functional environment-protection deep dyeing promoter as claimed in claim 1, it is characterised in that institute
State the preparation method of modified cyclodextrin particularly as follows: the concentrated sulphuric acid of mass fraction 90% is placed in 100mL round bottom
In flask, it is slowly added to cyclodextrin and in 0-2 DEG C of ice-water bath, stirs 1h；Reactant liquor is poured into water,
Adding calcium carbonate, leach the calcium sulfate precipitation of generation, washing, filtrate merges.Second is added in filtrate
Alcohol, places 24h at 0-3 DEG C, removes precipitation, and filtrate regulates pH to 8-10 with sodium carbonate, filters,
Regulate filtrate pH to 6-7, decompression, vacuum filtration with acetic acid, concentrate, add dehydrated alcohol, produce
White precipitate, filters, washing, and vacuum drying obtains modified cyclodextrin.
7. the preparation side of a kind of multi-functional environment-protection deep dyeing promoter as described in claim 1 to 6 is arbitrary
Method, it is characterised in that comprise the following steps:
(1) by lignin, oligochitosan, fluorine acrylic emulsion, polyoxyethylene polyoxypropylene block copolymer and
Deionized water mixing and stirring, is warming up to 50-70 DEG C, and under the state of 5000 revs/min, constant temperature stirs
1.5-2h, obtain mixed emulsion；
(2) by Nano silica sol, SAS, calcium sulfate, modified cyclodextrin, α-carboxyl
Acetic acid, fluorine-based alkyl, polyether modified polyorganosiloxane and deionized water mixing, at 40-50 DEG C, 500-1000W
Power under, ultrasonic 2-5h, obtain mixed dispersion liquid；
(3) the mixed dispersion liquid mixing that the mixed emulsion that step (1) obtained, step (2) obtain,
Add T-5398, stir, obtain multi-functional environment-protection deep dyeing promoter.
The preparation method of a kind of multi-functional environment-protection deep dyeing promoter the most as claimed in claim 7, it is special
Levying and be, described in step (1), the condition of stirring is at 60 DEG C, constant temperature stirring 2h.
The preparation method of a kind of multi-functional environment-protection deep dyeing promoter the most as claimed in claim 7, it is special
Levying and be, condition ultrasonic described in step (2) is: 40 DEG C, under 800W, and ultrasonic 3.5h.
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Application publication date: 20160706 |