CN106637947A - Phosphorus-free and low-foam textile refining agent and preparation method thereof - Google Patents
Phosphorus-free and low-foam textile refining agent and preparation method thereof Download PDFInfo
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- CN106637947A CN106637947A CN201611166674.4A CN201611166674A CN106637947A CN 106637947 A CN106637947 A CN 106637947A CN 201611166674 A CN201611166674 A CN 201611166674A CN 106637947 A CN106637947 A CN 106637947A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
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- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
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- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
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- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2246—Esters of unsaturated carboxylic acids
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- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/418—Cyclic amides, e.g. lactams; Amides of oxalic acid
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Abstract
The invention discloses a phosphorus-free and low-foam textile refining agent and a preparation method thereof. The phosphorus-free and low-foam textile refining agent is prepared from the following raw materials in parts by weight: 12 to 18 parts of fatty alcohol ether, 10 to 15 parts of isotridecyl alcohol, 4 to 8 parts of sodium dodecylbenzene sulfonate, 3 to 7 parts of alkyl glucoside, 2 to 5 parts of anhydrous sodium metasilicate, 2 to 4 parts of cetanol sodium sulfate, 3 to 6 parts of sucrose sodium aliphatate, 1 to 3 parts of sodium lignosulphonate, 2 to 3 parts of hydrogenated polyisobutene, 1 to 2 parts of methylisothiazolinone, 1 to 3 parts of an anionic surfactant, 2 to 4 parts of a de-foaming agent and 1 to 4 parts of an emulsifier. The phosphorus-free and low-foam textile refining agent prepared by the invention has good permeability, excellent wettability, low foaming ratio and small damages to textiles. Meanwhile, the invention further discloses the preparation method of the phosphorus-free and low-foam textile refining agent.
Description
Technical field
The present invention relates to refining agent field of weaving, is related specifically to one kind and adds without phosphorus low foam yarn fabric refining agent and its system
Preparation Method.
Background technology
The natural crossing on all kinds of textiles such as cotton, hair, fiber crops, silk and synthetic fibers is removed with chemically and physically method
The technical process of matter, pollutant and weaving slurry is called concise.Scouring agent, is the indispensable auxiliary agent of textile printing and dyeing industry.
Usually by each anionoid, nonionic surfactant and appropriate additive, obtain through the method for certain proportioning
It is a kind of it is based on cleaning function, have the synergistic compound such as infiltration, emulsification, dispersion, complexing concurrently.In existing textile
It is to improve refining effect and operating efficiency in refining process, operates in the environment of high alkalinity typically all more than 100 DEG C.At present
Scouring agent be mostly the compounding synthetic of kinds of surface activating agent, but current scouring agent solubility much in highly basic is very
It is little, and when hardness of water is higher or containing impurity and during fiber fragment, can to a certain extent form flocculent deposit, affect
The scouring result of scouring agent, limits to a certain extent its application in fabric processing.And existing alkaliproof refining agent
Rely primarily on alcohol ether phosphate component to improve alkali resistance, containing a large amount of phosphorus substances, there is serious impact to water quality.Also do not have now
There is a kind of alkaline-resisting environmental protection, biological degradability is good, environmentally-friendly alkali resistant scouring agent of not phosphorous and heavy metal and preparation method thereof.So this
Research is devoted to developing demand of a without phosphorus low foam yarn fabric refining agent to meet market and industry.
The content of the invention
To solve above-mentioned technical problem, the present invention provides a kind of without phosphorus low foam yarn fabric refining agent and preparation method thereof,
By being combined using specified raw material, the corresponding production technology of cooperation, the without phosphorus low foam yarn fabric refining agent for obtaining, it oozes
Permeability can be good, and wetting property is excellent, and foaming ratio is low, little to fabric damage, disclosure satisfy that the requirement of industry, with preferably application
Prospect.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of without phosphorus low foam yarn fabric refining agent, is prepared by the raw materials in：Fatty alcohol ether 12-18 parts, isomery alcohol
10-15 parts, neopelex 4-8 parts, APG 3-7 parts, anhydrous sodium metasilicate 2-5 parts, spermaceti alcohol radical sodium sulphate
2-4 parts, sucrose-fatty sodium 3-6 parts, sodium lignin sulfonate 1-3 parts, Parleam 2-3 parts, methylisothiazolinone 1-2
Part, anion surfactant 1-3 parts, defoamer 2-4 parts, emulsifying agent 1-4 parts.
Preferably, the anion surfactant is odium stearate, sodium citrate, stearine, alpha-sulfo list
One or more in carboxylate.
Preferably, the defoamer is benzyl carbinol olein, Laurate alcohol ester phenylacetate, tributyl phosphate, dimethicone
In any one.
Preferably, the emulsifying agent is selected from secondary octyl phenol polyethenoxy ether, aliphatic amine polyoxyethylene ether, rosin acid polyoxy second
Any one or a few in alkene ester, sodium butylnaphthalenesulfonate.
The preparation method of described without phosphorus low foam yarn fabric refining agent, comprises the following steps：
（1）Each raw material is weighed according to weight portion；
（2）Neopelex, APG are added in 1L deionized waters, it is equal with constant temperature blender with magnetic force stirring
It is even；
（3）To step（2）In solution in add fatty alcohol ether, isomery alcohol, anhydrous sodium metasilicate, emulsifying agent, be settled to 5L, surpass
Sound disperses, and ultrasonic time is 30 minutes, and supersonic frequency is 220-250KW；
（4）By step（3）Ultrasonic disperse mixture injection banbury, add spermaceti alcohol radical sodium sulphate, sucrose-fatty sodium,
Sodium lignin sulfonate, anion surfactant, to 60 DEG C, mixing speed is 50-100 rev/min to heating stirring, the reaction time
15-30 minutes；
（5）Parleam, methylisothiazolinone, defoamer are added in reactor, is mixed, mixing speed is
200-300 rev/min, the reaction time is 20 minutes, and reaction temperature is 120-160 DEG C；
（6）By step（4）Mixture add step（5）Reactor in, equal-volume mixing, while slow pressurization is warming up to
180 DEG C of insulation activation, are kept stirring for 300 revs/min of speed, 15 minutes reaction time；
（7）Toward step（6）Mixture naturally cool to room temperature, then with vinegar acid for adjusting pH value to 7-8, stir and obtain final product half
Finished product；
（8）By step（7）In semi-finished product mixed liquor cross membrane choosing, remove bulky grain, packing.
Preferably, the step（6）Pressure be 5-10Mpa.
Preferably, the step（8）Membrane aperture be 100-200 μm.
Compared with prior art, its advantage is the present invention：
（1）The without phosphorus low foam yarn fabric refining agent of the present invention, with neopelex, APG, fatty alcohol ether, different
Structure alcohol be main component, by add anhydrous sodium metasilicate, spermaceti alcohol radical sodium sulphate, sucrose-fatty sodium, sodium lignin sulfonate,
Parleam, methylisothiazolinone, anion surfactant, defoamer, emulsifying agent, are aided with dissolving stirring, ultrasound
The techniques such as dispersion, heating response, pressured activation, cooled film so that the without phosphorus low foam yarn fabric refining agent being prepared from, its
Permeance property is good, and wetting property is excellent, and foaming ratio is low, little to fabric damage, disclosure satisfy that the requirement of industry, answers with preferable
Use prospect.
（2）The without phosphorus low foam yarn fabric refining agent raw material of the present invention is cheap, process is simple, is suitable to heavy industrialization fortune
With practical.
Specific embodiment
The technical scheme invented is described in detail with reference to specific embodiment.
Embodiment 1
（1）According to weight portion weigh 12 parts of fatty alcohol ether, 10 parts of isomery alcohol, 4 parts of neopelex, 3 parts of APG,
2 parts of anhydrous sodium metasilicate, 2 parts of spermaceti alcohol radical sodium sulphate, 3 parts of sucrose-fatty sodium, 1 part of sodium lignin sulfonate, the poly- isobutyl of hydrogenation
2 parts of alkene, 1 part of methylisothiazolinone, 1 part of odium stearate, 2 parts of benzyl carbinol olein, 1 part of secondary octyl phenol polyethenoxy ether；
（2）Neopelex, APG are added in 1L deionized waters, it is equal with constant temperature blender with magnetic force stirring
It is even；
（3）To step（2）In solution in add fatty alcohol ether, isomery alcohol, anhydrous sodium metasilicate, secondary octyl phenol polyethenoxy
Ether, is settled to 5L, and ultrasonic disperse, ultrasonic time is 30 minutes, and supersonic frequency is 220KW；
（4）By step（3）Ultrasonic disperse mixture injection banbury, add spermaceti alcohol radical sodium sulphate, sucrose-fatty sodium,
Sodium lignin sulfonate, odium stearate, to 60 DEG C, mixing speed is 50 revs/min to heating stirring, 15 minutes reaction time；
（5）Parleam, methylisothiazolinone, benzyl carbinol olein are added in reactor, is mixed, stirring speed
Spend for 200 revs/min, the reaction time is 20 minutes, reaction temperature is 120 DEG C；
（6）By step（4）Mixture add step（5）Reactor in, equal-volume mixing, while slow pressurization is warming up to
180 DEG C of insulation activation, are kept stirring for 300 revs/min of speed, and in 15 minutes reaction time, pressure is 5Mpa；
（7）Toward step（6）Mixture naturally cool to room temperature, then with vinegar acid for adjusting pH value to 7, stir obtain final product half into
Product；
（8）By step（7）In semi-finished product mixed liquor cross membrane choosing, remove bulky grain, packing, membrane aperture is 100 μm.
The performance test results of obtained without phosphorus low foam yarn fabric refining agent are as shown in table 1.
Embodiment 2
（1）According to weight portion weigh 14 parts of fatty alcohol ether, 12 parts of isomery alcohol, 5 parts of neopelex, 4 parts of APG,
3 parts of anhydrous sodium metasilicate, 2 parts of spermaceti alcohol radical sodium sulphate, 4 parts of sucrose-fatty sodium, 2 parts of sodium lignin sulfonate, the poly- isobutyl of hydrogenation
2 parts of alkene, 1 part of methylisothiazolinone, 1 part of sodium citrate, 2 parts of Laurate alcohol ester phenylacetate, 1 part of aliphatic amine polyoxyethylene ether；
（2）Neopelex, APG are added in 1L deionized waters, it is equal with constant temperature blender with magnetic force stirring
It is even；
（3）To step（2）In solution in add fatty alcohol ether, isomery alcohol, anhydrous sodium metasilicate, aliphatic amine polyoxyethylene ether,
5L is settled to, ultrasonic disperse, ultrasonic time is 30 minutes, and supersonic frequency is 230KW；
（4）By step（3）Ultrasonic disperse mixture injection banbury, add spermaceti alcohol radical sodium sulphate, sucrose-fatty sodium,
Sodium lignin sulfonate, sodium citrate, to 60 DEG C, mixing speed is 70 revs/min to heating stirring, 20 minutes reaction time；
（5）Parleam, methylisothiazolinone, Laurate alcohol ester phenylacetate are added in reactor, is mixed, stirring
Speed is 220 revs/min, and the reaction time is 20 minutes, and reaction temperature is 130 DEG C；
（6）By step（4）Mixture add step（5）Reactor in, equal-volume mixing, while slow pressurization is warming up to
180 DEG C of insulation activation, are kept stirring for 300 revs/min of speed, and in 15 minutes reaction time, pressure is 7Mpa；
（7）Toward step（6）Mixture naturally cool to room temperature, then with vinegar acid for adjusting pH value to 7.3, stir and obtain final product half
Finished product；
（8）By step（7）In semi-finished product mixed liquor cross membrane choosing, remove bulky grain, packing, membrane aperture is 120 μm.
The performance test results of obtained without phosphorus low foam yarn fabric refining agent are as shown in table 1.
Embodiment 3
（1）According to weight portion weigh 16 parts of fatty alcohol ether, 14 parts of isomery alcohol, 7 parts of neopelex, 5 parts of APG,
4 parts of anhydrous sodium metasilicate, 3 parts of spermaceti alcohol radical sodium sulphate, 5 parts of sucrose-fatty sodium, 2 parts of sodium lignin sulfonate, the poly- isobutyl of hydrogenation
3 parts of alkene, 2 parts of methylisothiazolinone, 2 parts of stearine, 3 parts of tributyl phosphate, 3 parts of polyoxylethylene abietate；
（2）Neopelex, APG are added in 1L deionized waters, it is equal with constant temperature blender with magnetic force stirring
It is even；
（3）To step（2）In solution in add fatty alcohol ether, isomery alcohol, anhydrous sodium metasilicate, polyoxylethylene abietate,
5L is settled to, ultrasonic disperse, ultrasonic time is 30 minutes, and supersonic frequency is 240KW；
（4）By step（3）Ultrasonic disperse mixture injection banbury, add spermaceti alcohol radical sodium sulphate, sucrose-fatty sodium,
Sodium lignin sulfonate, stearine, to 60 DEG C, mixing speed is 90 revs/min to heating stirring, 25 minutes reaction time；
（5）Parleam, methylisothiazolinone, tributyl phosphate are added in reactor, is mixed, mixing speed
For 280 revs/min, the reaction time is 20 minutes, and reaction temperature is 150 DEG C；
（6）By step（4）Mixture add step（5）Reactor in, equal-volume mixing, while slow pressurization is warming up to
180 DEG C of insulation activation, are kept stirring for 300 revs/min of speed, and in 15 minutes reaction time, pressure is 9Mpa；
（7）Toward step（6）Mixture naturally cool to room temperature, then with vinegar acid for adjusting pH value to 7.7, stir and obtain final product half
Finished product；
（8）By step（7）In semi-finished product mixed liquor cross membrane choosing, remove bulky grain, packing, membrane aperture is 150 μm.
The performance test results of obtained without phosphorus low foam yarn fabric refining agent are as shown in table 1.
Embodiment 4
（1）According to weight portion weigh 18 parts of fatty alcohol ether, 15 parts of isomery alcohol, 8 parts of neopelex, 7 parts of APG,
5 parts of anhydrous sodium metasilicate, 4 parts of spermaceti alcohol radical sodium sulphate, 6 parts of sucrose-fatty sodium, 3 parts of sodium lignin sulfonate, the poly- isobutyl of hydrogenation
3 parts of alkene, 2 parts of methylisothiazolinone, 3 parts of alpha-sulfo monocarboxylate, 4 parts of dimethicone, 4 parts of sodium butylnaphthalenesulfonate；
（2）Neopelex, APG are added in 1L deionized waters, it is equal with constant temperature blender with magnetic force stirring
It is even；
（3）To step（2）In solution in add fatty alcohol ether, isomery alcohol, anhydrous sodium metasilicate, sodium butylnaphthalenesulfonate, constant volume
To 5L, ultrasonic disperse, ultrasonic time is 30 minutes, and supersonic frequency is 250KW；
（4）By step（3）Ultrasonic disperse mixture injection banbury, add spermaceti alcohol radical sodium sulphate, sucrose-fatty sodium,
Sodium lignin sulfonate, alpha-sulfo monocarboxylate, to 60 DEG C, mixing speed is 100 revs/min to heating stirring, 30 points of reaction time
Clock；
（5）Parleam, methylisothiazolinone, dimethicone are added in reactor, is mixed, mixing speed
For 300 revs/min, the reaction time is 20 minutes, and reaction temperature is 160 DEG C；
（6）By step（4）Mixture add step（5）Reactor in, equal-volume mixing, while slow pressurization is warming up to
180 DEG C of insulation activation, are kept stirring for 300 revs/min of speed, and in 15 minutes reaction time, pressure is 10Mpa；
（7）Toward step（6）Mixture naturally cool to room temperature, then with vinegar acid for adjusting pH value to 8, stir obtain final product half into
Product；
（8）By step（7）In semi-finished product mixed liquor cross membrane choosing, remove bulky grain, packing, membrane aperture is 200 μm.
The performance test results of obtained without phosphorus low foam yarn fabric refining agent are as shown in table 1.
Comparative example 1
（1）According to weight portion weigh 12 parts of fatty alcohol ether, 10 parts of isomery alcohol, 4 parts of neopelex, 3 parts of APG,
2 parts of spermaceti alcohol radical sodium sulphate, 1 part of sodium lignin sulfonate, 2 parts of Parleam, 1 part of methylisothiazolinone, odium stearate 1
Part, 2 parts of benzyl carbinol olein, 1 part of secondary octyl phenol polyethenoxy ether；
（2）Neopelex, APG are added in 1L deionized waters, it is equal with constant temperature blender with magnetic force stirring
It is even；
（3）To step（2）In solution in add fatty alcohol ether, isomery alcohol, secondary octyl phenol polyethenoxy ether, be settled to 5L, surpass
Sound disperses, and ultrasonic time is 30 minutes, and supersonic frequency is 220KW；
（4）By step（3）Ultrasonic disperse mixture injection banbury, add spermaceti alcohol radical sodium sulphate, sodium lignin sulfonate,
Odium stearate, to 60 DEG C, mixing speed is 50 revs/min to heating stirring, 15 minutes reaction time；
（5）Parleam, methylisothiazolinone, benzyl carbinol olein are added in reactor, is mixed, stirring speed
Spend for 200 revs/min, the reaction time is 20 minutes, reaction temperature is 120 DEG C；
（6）By step（4）Mixture add step（5）Reactor in, equal-volume mixing, while slow pressurization is warming up to
180 DEG C of insulation activation, are kept stirring for 300 revs/min of speed, and in 15 minutes reaction time, pressure is 5Mpa；
（7）Toward step（6）Mixture naturally cool to room temperature, then with vinegar acid for adjusting pH value to 7, stir obtain final product half into
Product；
（8）By step（7）In semi-finished product mixed liquor cross membrane choosing, remove bulky grain, packing, membrane aperture is 100 μm.
The performance test results of obtained without phosphorus low foam yarn fabric refining agent are as shown in table 1.
Comparative example 2
（1）18 parts of fatty alcohol ether, 15 parts of isomery alcohol, 8 parts of neopelex, anhydrous sodium metasilicate are weighed according to weight portion
5 parts, 4 parts of spermaceti alcohol radical sodium sulphate, 6 parts of sucrose-fatty sodium, 3 parts of Parleam, 2 parts of methylisothiazolinone, α-sulphur
3 parts of base monocarboxylate, 4 parts of dimethicone, 4 parts of sodium butylnaphthalenesulfonate；
（2）Neopelex is added in 1L deionized waters, is stirred with constant temperature blender with magnetic force；
（3）To step（2）In solution in add fatty alcohol ether, isomery alcohol, anhydrous sodium metasilicate, sodium butylnaphthalenesulfonate, constant volume
To 5L, ultrasonic disperse, ultrasonic time is 30 minutes, and supersonic frequency is 250KW；
（4）By step（3）Ultrasonic disperse mixture injection banbury, add spermaceti alcohol radical sodium sulphate, sucrose-fatty sodium,
Alpha-sulfo monocarboxylate, to 60 DEG C, mixing speed is 100 revs/min to heating stirring, 30 minutes reaction time；
（5）Parleam, methylisothiazolinone, dimethicone are added in reactor, is mixed, mixing speed
For 300 revs/min, the reaction time is 20 minutes, and reaction temperature is 160 DEG C；
（6）By step（4）Mixture add step（5）Reactor in, equal-volume mixing, while slow pressurization is warming up to
180 DEG C of insulation activation, are kept stirring for 300 revs/min of speed, and in 15 minutes reaction time, pressure is 10Mpa；
（7）Toward step（6）Mixture naturally cool to room temperature, then with vinegar acid for adjusting pH value to 8, stir obtain final product half into
Product；
（8）By step（7）In semi-finished product mixed liquor cross membrane choosing, remove bulky grain, packing, membrane aperture is 200 μm.
The performance test results of obtained without phosphorus low foam yarn fabric refining agent are as shown in table 1.
Without phosphorus low foam yarn fabric refining agent obtained in embodiment 1-4 and comparative example 1-2 is carried out into permeability, residual fat
Rate, foaming characteristic, this several performance tests of dispersion index and strength loss rate.
Table 1
| Permeability（S, 20 DEG C of canvas sedimentations） | Oil and Fat Content % | Foaming characteristic（Graduated cylinder succusion） | Dispersion index | Strength loss rate % | |
| Embodiment 1 | 7 | 0.063 | 25cm | 13.0 | 11.3 |
| Embodiment 2 | 8 | 0.069 | 23cm | 13.7 | 11.6 |
| Embodiment 3 | 7 | 0.071 | 24cm | 13.1 | 12.1 |
| Embodiment 4 | 7 | 0.066 | 25cm | 13.4 | 11.9 |
| Comparative example 1 | 13 | 0.806 | 34cm | 19.1 | 21.1 |
| Comparative example 2 | 12 | 0.844 | 41cm | 17.9 | 22.7 |
The without phosphorus low foam yarn fabric refining agent of the present invention, with neopelex, APG, fatty alcohol ether, isomery
Alcohol is main component, by adding anhydrous sodium metasilicate, spermaceti alcohol radical sodium sulphate, sucrose-fatty sodium, sodium lignin sulfonate, hydrogen
Change polyisobutene, methylisothiazolinone, anion surfactant, defoamer, emulsifying agent, be aided with dissolving stirring, ultrasound point
The technique such as scattered, heating response, pressured activation, cooled film so that the without phosphorus low foam yarn fabric refining agent being prepared from, it oozes
Permeability can be good, and wetting property is excellent, and foaming ratio is low, little to fabric damage, disclosure satisfy that the requirement of industry, with preferably application
Prospect.The without phosphorus low foam yarn fabric refining agent raw material of the present invention is cheap, process is simple, is suitable to heavy industrialization utilization, real
It is strong with property.
Embodiments of the invention are the foregoing is only, the scope of the claims of the present invention is not thereby limited, it is every using this
Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks
Domain, is included within the scope of the present invention.
Claims (7)
1. a kind of without phosphorus low foam yarn fabric refining agent, it is characterised in that：It is prepared by the raw materials in：Fatty alcohol ether
12-18 parts, isomery alcohol 10-15 parts, neopelex 4-8 parts, APG 3-7 parts, anhydrous sodium metasilicate 2-5 parts,
Spermaceti alcohol radical sodium sulphate 2-4 parts, sucrose-fatty sodium 3-6 parts, sodium lignin sulfonate 1-3 parts, Parleam 2-3 parts, first
Base OIT 1-2 parts, anion surfactant 1-3 parts, defoamer 2-4 parts, emulsifying agent 1-4 parts.
2. without phosphorus low foam yarn fabric refining agent according to claim 1, it is characterised in that：The anion surface active
Agent is one or more in odium stearate, sodium citrate, stearine, alpha-sulfo monocarboxylate.
3. without phosphorus low foam yarn fabric refining agent according to claim 1, it is characterised in that：The defoamer is benzyl carbinol
Any one in olein, Laurate alcohol ester phenylacetate, tributyl phosphate, dimethicone.
4. without phosphorus low foam yarn fabric refining agent according to claim 1, it is characterised in that：The emulsifying agent is selected from Zhong Xin
In base phenol polyethenoxy ether, aliphatic amine polyoxyethylene ether, polyoxylethylene abietate, sodium butylnaphthalenesulfonate any one or it is several
Kind.
5. according to the preparation method of the arbitrary described without phosphorus low foam yarn fabric refining agent of Claims 1 to 4, it is characterised in that
Comprise the following steps：
（1）Each raw material is weighed according to weight portion；
（2）Neopelex, APG are added in 1L deionized waters, it is equal with constant temperature blender with magnetic force stirring
It is even；
（3）To step（2）In solution in add fatty alcohol ether, isomery alcohol, anhydrous sodium metasilicate, emulsifying agent, be settled to 5L, surpass
Sound disperses, and ultrasonic time is 30 minutes, and supersonic frequency is 220-250KW；
（4）By step（3）Ultrasonic disperse mixture injection banbury, add spermaceti alcohol radical sodium sulphate, sucrose-fatty sodium,
Sodium lignin sulfonate, anion surfactant, to 60 DEG C, mixing speed is 50-100 rev/min to heating stirring, the reaction time
15-30 minutes；
（5）Parleam, methylisothiazolinone, defoamer are added in reactor, is mixed, mixing speed is
200-300 rev/min, the reaction time is 20 minutes, and reaction temperature is 120-160 DEG C；
（6）By step（4）Mixture add step（5）Reactor in, equal-volume mixing, while slow pressurization is warming up to
180 DEG C of insulation activation, are kept stirring for 300 revs/min of speed, 15 minutes reaction time；
（7）Toward step（6）Mixture naturally cool to room temperature, then with vinegar acid for adjusting pH value to 7-8, stir and obtain final product half
Finished product；
（8）By step（7）In semi-finished product mixed liquor cross membrane choosing, remove bulky grain, packing.
6. the preparation method of without phosphorus low foam yarn fabric refining agent according to claim 5, it is characterised in that：The step
（6）Pressure be 5-10Mpa.
7. the preparation method of without phosphorus low foam yarn fabric refining agent according to claim 5, it is characterised in that：The step
（8）Membrane aperture be 100-200 μm.
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| CN108708164A (en) * | 2018-06-13 | 2018-10-26 | 广东传化富联精细化工有限公司 | A kind of fabric scouring multi-functional low bubble alkali-resistant penetrant and preparation method thereof |
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