CN106757679A - Flame-retardant textile - Google Patents

Flame-retardant textile Download PDF

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Publication number
CN106757679A
CN106757679A CN201611011913.9A CN201611011913A CN106757679A CN 106757679 A CN106757679 A CN 106757679A CN 201611011913 A CN201611011913 A CN 201611011913A CN 106757679 A CN106757679 A CN 106757679A
Authority
CN
China
Prior art keywords
retardant
flame
fire
percentage
raw material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611011913.9A
Other languages
Chinese (zh)
Inventor
桂永林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Xin Dun Fire-Fighting Equipment Co Ltd
Original Assignee
Anhui Xin Dun Fire-Fighting Equipment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Xin Dun Fire-Fighting Equipment Co Ltd filed Critical Anhui Xin Dun Fire-Fighting Equipment Co Ltd
Priority to CN201611011913.9A priority Critical patent/CN106757679A/en
Publication of CN106757679A publication Critical patent/CN106757679A/en
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
    • D01F2/08—Composition of the spinning solution or the bath
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/16—Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00—Inorganic fibres
    • D10B2101/10—Inorganic fibres based on non-oxides other than metals
    • D10B2101/12—Carbon; Pitch
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20—Cellulose-derived artificial fibres
    • D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24—Viscose
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/06—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated alcohols, e.g. polyvinyl alcohol, or of their acetals or ketals
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/10—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
    • D10B2321/101—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide modacrylic
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides

Abstract

The present invention relates to kind of a flame-retardant textile, include according to the raw material of percentage by weight：Vinyon N 20 ~ 40%, carbon fiber 6 ~ 10%, inherent flame retardant polyamide fibre 3 ~ 8%, high-strength fire-retarding polyvinyl 3 ~ 8%, meta-aramid 15 ~ 25%, PSA fiber 15 ~ 25%, FRC 5 ~ 12%, polyhedral silsesquioxane 1 ~ 2%.Its water proof fire retardant ability is strong, and quality is solid, wear-resisting, ageing-resistant, and environmental protection.

Description

Flame-retardant textile
Technical field
The present invention relates to fire-fighting quipment field, and in particular to a kind of flame-retardant textile.
Background technology
Fire-retardant requirement is all placed on major position by current countries in the world in the exploitation of textile raw material and product, Especially to Europe, the household textiles of U.S. export, it is necessary to there is the fire-retardant function could to enter market；As our people lives The raising of level and the requirement more and more higher to textile, flame-retardant textile also turn into the developing direction of textile.Flame-retardant textile is just Refer to just that after contact flame or red-hot object, can prevent the labor protection that be ignited or can slow down and terminate burning in itself from knitting Thing, suitable near naked light, spark or motlten metal operate, or have it is inflammable, have the environment of fire hazard in operation.Especially It is that household textiles there are strict requirements to anti-flammability, has clearly to 7 major class Household ornament fabrics flame resistance performance characteristics Regulation, particularly has strict flame-retardancy requirements for the decorative product in hotel, restaurant, household room, and this 7 products are：Mattress, Sheet lid quilt, curtain, wall paper, sofa fabric, towel bath towel, carpet, the requirement of its fire retardant characteristics reaches nonflammable, and burning is not yet Easily distribute pernicious gas.Wherein curtain, mattress, bed clothes also have security higher, the fabric such as with chemical fibre as raw material its resistance Firing requirement is：There is no extremely toxic cyano group gas, poisonous halogen gas；Carbon monoxide is not susceptible to, it is nonflammable, even if combustion Burn, will not also spread；Repeatedly washing does not also change.So design with excellent fire resistance, and environmentally friendly, quality is good Flame-retardant textile be present flame-retardant textile general orientation.
The content of the invention
It is an object of the present invention to provide a kind of flame-retardant textile, water proof fire retardant ability is strong, and quality is solid, wear-resisting, ageing-resistant, and ring Protect.
In order to realize the above object the technical solution adopted by the present invention is：A kind of flame-retardant textile, according to percentage by weight Raw material includes：Vinyon N 20 ~ 40%, carbon fiber 6 ~ 10%, inherent flame retardant polyamide fibre 3 ~ 8%, high-strength fire-retarding polyvinyl 3 ~ 8%, meta-aramid 15 ~ 25%, PSA fiber 15 ~ 25%, FRC 5 ~ 12%, polyhedral silsesquioxane 1 ~ 2%.
Preferably, described flame-retardant textile, includes according to the raw material of percentage by weight：Vinyon N 30%, carbon fiber 8%, this Matter fire-retardant polyamide fibre 5%, high-strength fire-retarding polyvinyl 5%, meta-aramid 20%, PSA fiber 20%, FRC 10%, polyhedron sesquialter Siloxanes 2%.
Further, it is 8 ~ 10% that fire retardant accounts for its weight/mass percentage composition in described FRC.
Further, the raw material of the fire retardant percentage by weight includes：10- (2,5- dihydroxy phenyl)- 10- hydrogen -9- oxa- -10- phospho hetero phenanthrene -10- oxides 35%；[3- [(methylol) amino] -3- carbonyls propyl group]-dimethyl phosphonate 30%；Three (2,3- dibromopropyl) fulminuric acid esters 35%.
The technical effects of the invention are that：Vinyon N, carbon fiber, inherent flame retardant polyamide fibre, high-strength fire-retarding polyvinyl, meta virtue Synthetic fibre, PSA fiber, FRC these materials inherently have excellent fire resistance, and FRC has waterproof Fire retardancy has certain cementability simultaneously；And polyhedral silsesquioxane (POSS) is the distinctive organosilicon resistance of a class Combustion agent, can just show excellent fire-retardant, mechanics and thermal property under extremely low addition.It is obtained according to above-mentioned percentage Flame-retardant textile water proof fire retardant ability it is strong, quality is solid, wear-resisting, ageing-resistant, and environmental protection.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all Belong to the scope of protection of the invention.
Embodiment 1：A kind of flame-retardant textile, includes according to the raw material of percentage by weight：Vinyon N 30%, carbon fiber 8%, essence Fire-retardant polyamide fibre 5%, high-strength fire-retarding polyvinyl 5%, meta-aramid 20%, PSA fiber 20%, FRC 10%, polyhedron sesquialter silicon Oxygen alkane 2%.
Further, it is 8 ~ 10% that fire retardant accounts for its weight/mass percentage composition in described FRC.
It is further preferred that the raw material of the fire retardant percentage by weight includes：10- (2,5- dihydroxy benzenes Base) -10- hydrogen -9- oxa- -10- phospho hetero phenanthrene -10- oxides 35%；[3- [(methylol) amino] -3- carbonyls propyl group]-phosphonic acids two Methyl esters 30%；Three (2,3- dibromopropyl) fulminuric acid esters 35%.
Vinyon N, carbon fiber, inherent flame retardant polyamide fibre, high-strength fire-retarding polyvinyl, meta-aramid, PSA fiber, FRC These materials inherently have excellent fire resistance, and FRC has water proof fire retardant ability while having certain Cementability；And polyhedral silsesquioxane (POSS) is the distinctive organic silicon fibre retardant of a class, under extremely low addition Excellent fire-retardant, mechanics and thermal property can just be shown.According to flame-retardant textile water proof fire retardant energy obtained in above-mentioned percentage Power is strong, and quality is solid, wear-resisting, ageing-resistant, and environmental protection.
Embodiment 2：A kind of flame-retardant textile, includes according to the raw material of percentage by weight：Vinyon N 20%, carbon fiber 10%, this Matter fire-retardant polyamide fibre 3%, high-strength fire-retarding polyvinyl 8%, meta-aramid 23%, PSA fiber 23%, FRC 12%, polyhedron sesquialter Siloxanes 1%.
Further, it is 8 ~ 10% that fire retardant accounts for its weight/mass percentage composition in described FRC.
It is further preferred that the raw material of the fire retardant percentage by weight includes：10- (2,5- dihydroxy benzenes Base) -10- hydrogen -9- oxa- -10- phospho hetero phenanthrene -10- oxides 35%；[3- [(methylol) amino] -3- carbonyls propyl group]-phosphonic acids two Methyl esters 30%；Three (2,3- dibromopropyl) fulminuric acid esters 35%.
Strong according to flame-retardant textile water proof fire retardant ability obtained in above-mentioned percentage, quality is solid, wear-resisting, ageing-resistant, and ring Protect.
Embodiment 3：A kind of flame-retardant textile, includes according to the raw material of percentage by weight：Vinyon N 40%, carbon fiber 6%, essence Fire-retardant polyamide fibre 8%, high-strength fire-retarding polyvinyl 3%, meta-aramid 15%, PSA fiber 20%, FRC 7%, polyhedron silsesquioxane Alkane 1%.
Further, it is 8 ~ 10% that fire retardant accounts for its weight/mass percentage composition in described FRC.
It is further preferred that the raw material of the fire retardant percentage by weight includes：10- (2,5- dihydroxy benzenes Base) -10- hydrogen -9- oxa- -10- phospho hetero phenanthrene -10- oxides 35%；[3- [(methylol) amino] -3- carbonyls propyl group]-phosphonic acids two Methyl esters 30%；Three (2,3- dibromopropyl) fulminuric acid esters 35%.
Strong according to flame-retardant textile water proof fire retardant ability obtained in above-mentioned percentage, quality is solid, wear-resisting, ageing-resistant, and ring Protect.
The same elasticity of the thermal insulation layer scrim material that obtains is good by being matched in the present embodiment for above-mentioned material, and bonding force is strong, matter is tight, Ageing-resistant, fire-retardant and heat-proof quality has good, and use time more than 2 years is still elastic good, mould proof, not aging, and with good Fire-retardant and heat-insulating capability.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be in other specific forms realized.

Claims (4)

1. a kind of flame-retardant textile, it is characterised in that the raw material according to percentage by weight includes：Vinyon N 20 ~ 40%, carbon fiber 6 ~ 10%, inherent flame retardant polyamide fibre 3 ~ 8%, high-strength fire-retarding polyvinyl 3 ~ 8%, meta-aramid 15 ~ 25%, PSA fiber 15 ~ 25%, anti-flaming viscose is fine Dimension 5 ~ 12%, polyhedral silsesquioxane 1 ~ 2%.
2. flame-retardant textile according to claim 1, it is characterised in that the raw material according to percentage by weight includes：Vinyon N 30%, carbon fiber 8%, inherent flame retardant polyamide fibre 5%, high-strength fire-retarding polyvinyl 5%, meta-aramid 20%, PSA fiber 20%, FRC 10%, polyhedral silsesquioxane 2%.
3. flame-retardant textile according to claim 1 and 2, it is characterised in that fire retardant is accounted in described FRC Its weight/mass percentage composition is 8 ~ 10%.
4. flame-retardant textile according to claim 3, it is characterised in that the raw material bag of the fire retardant percentage by weight Include：10- (2,5- dihydroxy phenyl) -10- hydrogen -9- oxa- -10- phospho hetero phenanthrene -10- oxides 35%；[3- [(methylol) ammonia Base] -3- carbonyls propyl group]-dimethyl phosphonate 30%；Three (2,3- dibromopropyl) fulminuric acid esters 35%.
CN201611011913.9A 2016-11-17 2016-11-17 Flame-retardant textile Pending CN106757679A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611011913.9A CN106757679A (en) 2016-11-17 2016-11-17 Flame-retardant textile

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611011913.9A CN106757679A (en) 2016-11-17 2016-11-17 Flame-retardant textile

Publications (1)

Publication Number Publication Date
CN106757679A true CN106757679A (en) 2017-05-31

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Country Status (1)

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CN (1) CN106757679A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107663696A (en) * 2017-10-16 2018-02-06 天津工业大学 One kind is permanently from fire-retardant household textiles fabric
CN108179496A (en) * 2017-12-28 2018-06-19 宁波三同编织有限公司 A kind of easy dye, the preparation method of flame retardant cationic polyester fiber fabric
CN108703424A (en) * 2018-05-23 2018-10-26 苏州凤霓绣叶文化艺术有限公司 A kind of flame-retardant garment plus material

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101181661A (en) * 2007-12-13 2008-05-21 中国人民解放军总后勤部军需装备研究所 Multifunctional ventilating type protection material and preparation method thereof
CA2812453A1 (en) * 2010-09-23 2012-03-29 Invista Technologies S.A.R.L. Flame retardant fibers, yarns, and fabrics made therefrom
CN103388224A (en) * 2013-08-05 2013-11-13 上海婉静纺织科技有限公司 Blended fabric of antiflaming vinylon and antiflaming viscose
CN103622185A (en) * 2012-08-28 2014-03-12 上海特安纶纤维有限公司 Breathable flame-retardant fabric and breathable flame-retardant protective suit
CN103741250A (en) * 2013-12-04 2014-04-23 太仓荣文合成纤维有限公司 Inorganic/organic hybrid composite fire retardation agent and application of the same in PET fibers
CN104228273A (en) * 2014-09-19 2014-12-24 上海特安纶纤维有限公司 Inflaming retarding cushion for bus chair
CN104328582A (en) * 2014-10-31 2015-02-04 上海特安纶纤维有限公司 Regenerated flame-retardant heat-insulating yarn fabric and making method thereof
CN104829831A (en) * 2015-02-11 2015-08-12 杭州师范大学 Halogen-free flame-retarding nylon-6 preparation method

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101181661A (en) * 2007-12-13 2008-05-21 中国人民解放军总后勤部军需装备研究所 Multifunctional ventilating type protection material and preparation method thereof
CA2812453A1 (en) * 2010-09-23 2012-03-29 Invista Technologies S.A.R.L. Flame retardant fibers, yarns, and fabrics made therefrom
CN103622185A (en) * 2012-08-28 2014-03-12 上海特安纶纤维有限公司 Breathable flame-retardant fabric and breathable flame-retardant protective suit
CN103388224A (en) * 2013-08-05 2013-11-13 上海婉静纺织科技有限公司 Blended fabric of antiflaming vinylon and antiflaming viscose
CN103741250A (en) * 2013-12-04 2014-04-23 太仓荣文合成纤维有限公司 Inorganic/organic hybrid composite fire retardation agent and application of the same in PET fibers
CN104228273A (en) * 2014-09-19 2014-12-24 上海特安纶纤维有限公司 Inflaming retarding cushion for bus chair
CN104328582A (en) * 2014-10-31 2015-02-04 上海特安纶纤维有限公司 Regenerated flame-retardant heat-insulating yarn fabric and making method thereof
CN104829831A (en) * 2015-02-11 2015-08-12 杭州师范大学 Halogen-free flame-retarding nylon-6 preparation method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107663696A (en) * 2017-10-16 2018-02-06 天津工业大学 One kind is permanently from fire-retardant household textiles fabric
CN108179496A (en) * 2017-12-28 2018-06-19 宁波三同编织有限公司 A kind of easy dye, the preparation method of flame retardant cationic polyester fiber fabric
CN108703424A (en) * 2018-05-23 2018-10-26 苏州凤霓绣叶文化艺术有限公司 A kind of flame-retardant garment plus material

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Application publication date: 20170531