CN103388224A - Blended fabric of antiflaming vinylon and antiflaming viscose - Google Patents
Blended fabric of antiflaming vinylon and antiflaming viscose Download PDFInfo
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- CN103388224A CN103388224A CN201310338409XA CN201310338409A CN103388224A CN 103388224 A CN103388224 A CN 103388224A CN 201310338409X A CN201310338409X A CN 201310338409XA CN 201310338409 A CN201310338409 A CN 201310338409A CN 103388224 A CN103388224 A CN 103388224A
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Abstract
The invention discloses a blended fabric of antiflaming vinylon and antiflaming viscose. The blended fabric is formed by blending 50-70 parts by weight of antiflaming vinylon fibers and 30-50 parts by weight of antiflaming viscose. The blended fabric of antiflaming vinylon and antiflaming viscose is higher in antiflaming performance, people feel comfortable when wearing the blended fabric, the cost is relatively low, and the blended fabric can be applied to protection series of products.
Description
Technical field
The present invention relates to a kind of fabric, relate in particular to the BLENDED FABRIC of a kind of Flame Vinylon and anti-flaming viscose.
Background technology
In recent years, countries in the world constantly increase because of the fire that textiles causes.China this for over ten years, the fire number of times that occurs every year on average is ten thousand of 3-4, death toll 2-3 thousand people, fire damage folding money 2-3 hundred million RMB.These accidents all cause because of textile combustion.
As everyone knows, in the face of situations such as precipitate fire or burns.The adult still can save oneself, escape etc., but minor, particularly infant will be subject to serious or even fatal harm.So taking the lead in using fire resistance fibre in the children's garment fabric is natural thing naturally.In fact, the country such as American-European just promulgates flame-retardant standard to children's garment, sofa fabric, various textiles fillers as far back as the eighties in last century.U.S. particularly, US Consumer Product Safety Commission issued again the revised edition of sleeping suit for children flame-retardancy standards in 1996.
Flame vinylon fiber, to contain the compound of anti-flaming function element (halogen, phosphorus, nitrogen etc.) by grafting on the large molecule of polyvinyl alcohol (PVA), or, by after adding the fire retardant blend, carry out the technical process such as solution spinning, stretching, heat treatment and formalizing and make Flame Vinylon.At present main Flame Vinylon kind has: dimension polyvinyl chloride fibre, CY841 fiber (trade name of decabromodiphenyl oxide/antimony Flame Vinylon), high-strength fire-retarding polyvinyl (TDE fire-retardant high-strength polyvinyl), high-strength halogen-free flameproof polyvinyl (fire retardant: the DDPS fire resistance fibre).Take the CY841 fiber as example, this fiber utilization decabromodiphenyl oxide and antimonous oxide are made fire retardant, adopt common wet spinning to produce Flame Vinylon; The deca-BDE Flame Vinylon is compared with common polyvinyl, and its core-skin layer architectural difference is less, and fire retardant is dispersed in fiber with granular form, and its continuous phase is PVA, is the less fire resistance fibre of epidermal area fire retardant.
In all kinds of fire resistance fibres, Flame Vinylon, because it has the excellent properties such as high strength, fire-retardant and good hygroscopicity concurrently, is subject to outer extensive concern in the industry.
Flame Vinylon roughly is applied in three fields: the one, for curtain, wall paper, general dress material, Work Clothes, industrial cloth, filter cloth etc.; The 2nd, for carpet, bedding etc.; The 3rd, for nonwoven fabric and papermaking etc.At present, domestic high-strength fire-retarding polyvinyl can carry out pure spinning or blending, and its fabric is mainly used in the fields higher to the inflaming retarding fabric requirement of strength such as tarpaulin, fire-entry suit, frock, BDU.
Yet,, although the fabric flame retardant effect of pure Flame Vinylon weaving is better, exist shortcoming expensive and that snugness of fit is poor.
Summary of the invention
For the deficiencies in the prior art, technical problem to be solved by this invention is to provide the BLENDED FABRIC of a kind of Flame Vinylon and anti-flaming viscose.
Technical problem to be solved by this invention is achieved by the following technical solution:
The BLENDED FABRIC of a kind of Flame Vinylon and anti-flaming viscose, be prepared from by the flame vinylon fiber of 50-70 weight portion and the Fire resistant viscose fiber blending of 30-50 weight portion.
Preferably,
In described Fire resistant viscose fiber, fire retardant accounts for the quality percentage composition 6-8% of described Fire resistant viscose fiber.
Described fire retardant is comprised of following components in mass portion: 10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide 40-60 part; [the 3-[(methylol) amino]-3-carbonyl propyl group]-dimethyl phosphonate 20-40 part; Three (2,3-dibromopropyl) fulminuric acid ester 10-30 part.
Concrete, in the present invention:
Described Fire resistant viscose fiber, have good flame retardant effect, has good flexibility, can strengthen the dress ornament comfort property.
Described Fire resistant viscose fiber can adopt following method to be prepared from: fire retardant is mixed with viscose solution (claiming again rayon spinning liquid), wet spinning sprays the silk technological forming routinely, described fire retardant accounts for the quality percentage composition 6-8% of described Fire resistant viscose fiber, described fire retardant is comprised of following components in mass portion: 10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide 40-60 part; [the 3-[(methylol) amino]-3-carbonyl propyl group]-dimethyl phosphonate 20-40 part; Three (2,3-dibromopropyl) fulminuric acid ester 10-30 part.
In described fire retardant:
10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, and English name: 10-(2,5-Dihydroxyphenyl)-10H-9-oxa-10-phospha-phenantbrene-10-oxide, No. CAS: 99208-50-1.
[the 3-[(methylol) amino]-3-carbonyl propyl group]-dimethyl phosphonate, CAS accession number: 20120-33-6, English name: 3-(Dimethylphosphono)-N-methylolpropionamide.
Three (2,3-dibromopropyl) fulminuric acid ester, English name: Flame retardant TBC, Chinese another name: fire retardant TBC, molecular formula: C
12H
15Br
6N
3O。
Described viscose solution is the sodium hydrate aqueous solution of cellulose sulfonate.Preferably, in described viscose solution, the weight percent content of first fibre is 8-9%, and the weight percent content of NaOH is 4-6%, falling ball viscosity 50-60 second, degree of ripeness 10-14%.
The BLENDED FABRIC of Flame Vinylon of the present invention and anti-flaming viscose, can be first carry out shredding with flame vinylon fiber and Fire resistant viscose fiber and mix, and adopts industry universal method to make blended yarn, then adopt conventional method to weave blended yarn to form fabric.
The BLENDED FABRIC of Flame Vinylon of the present invention and anti-flaming viscose has higher fire resistance, and comfortable and easy to wear, and cost is relatively cheap.
The BLENDED FABRIC of Flame Vinylon of the present invention and anti-flaming viscose can be applied to protect series of products.
The specific embodiment
The invention will be further described below in conjunction with embodiment.
Flame vinylon fiber, the CY841 fiber that SINOPEC Sichuan Vinylon Factory is produced, oxygen index (OI) LOI value 31.4%.
Embodiment 1
Take: 10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-50 kilograms of 10-oxides; [3-[(methylol) amino]-3-carbonyl propyl group]-30 kilograms of dimethyl phosphonates; 20 kilograms of three (2,3-dibromopropyl) fulminuric acid esters, be uniformly mixed and make composite flame-retardant agent.
Above-mentioned composite flame-retardant agent is mixed with viscose solution, and wet spinning spray silk technological forming, can make described Fire resistant viscose fiber routinely, and the length of Fire resistant viscose fiber is 38mm.Wherein, the quality percentage composition of controlling fire retardant in the finished product Fire resistant viscose fiber is 7%, and the viscose solution in described raw material, the weight percent content of first fibre are 8.5%, and the weight percent content of NaOH is 5%, falling ball viscosity 55 seconds, degree of ripeness 12%.
Take 60 kilograms of flame vinylon fibers, 40 kilograms of the above-mentioned Fire resistant viscose fiber that makes, mix, and the shredding preliminary treatment is carded to the carded sliver on carding machine; Again on drawing frame and close and make ripe; Carry out drawing-off and twisting on Speed frames, further draw twisting on fine spining machine finally, make blended yarn, and yarn linear density is 39tex.Blended yarn is adopted large circle machine knitting device making method to weave, warp count is that 200/10cm, warp count are 200/10cm, finally makes the BLENDED FABRIC of Flame Vinylon and anti-flaming viscose again.
Embodiment 2
Substantially the same manner as Example 1, unique difference is, fire retardant used is 10-(2, the 5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, rather than by 10-(2, the 5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, [the 3-[(methylol) amino]-3-carbonyl propyl group]-the compound mixing fire retardant of dimethyl phosphonate and three (2,3-dibromopropyl) fulminuric acid ester three.
Embodiment 3
Substantially the same manner as Example 1, unique difference is, fire retardant used is [3-[(methylol) amino]-3-carbonyl propyl group]-dimethyl phosphonate, rather than by 10-(2, the 5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, [the 3-[(methylol) amino]-3-carbonyl propyl group]-the compound mixing fire retardant of dimethyl phosphonate and three (2,3-dibromopropyl) fulminuric acid ester three.
Embodiment 4
Substantially the same manner as Example 1, unique difference is, fire retardant used is three (2, the 3-dibromopropyl) fulminuric acid ester, rather than by 10-(2, the 5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, [the 3-[(methylol) amino]-3-carbonyl propyl group]-the compound mixing fire retardant of dimethyl phosphonate and three (2,3-dibromopropyl) fulminuric acid ester three.
Embodiment 5
Substantially the same manner as Example 1, unique difference is, fire retardant used is tricresyl phosphate (dimethylbenzene) ester, rather than by 10-(2, the 5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, [the 3-[(methylol) amino]-3-carbonyl propyl group]-the compound mixing fire retardant of dimethyl phosphonate and three (2,3-dibromopropyl) fulminuric acid ester three.Fire retardant tricresyl phosphate (dimethylbenzene) ester is the general fire retardant of the industry, and CAS accession number 25155-23-1, claim again xylenylphosphate.
Test case
The BLENDED FABRIC of the Fire resistant viscose fiber that respectively embodiment 1-5 is made and final finished product Flame Vinylon and anti-flaming viscose is carried out the fire resistance test.
| ? | Oxygen index (OI) LOI value, % |
| The Fire resistant viscose fiber that embodiment 1 makes | 29.4 |
| The Fire resistant viscose fiber that embodiment 2 makes | 28.5 |
| The Fire resistant viscose fiber that embodiment 3 makes | 28.4 |
| The Fire resistant viscose fiber that embodiment 4 makes | 27.6 |
| The Fire resistant viscose fiber that embodiment 5 makes | 28.0 |
| The flame-retarding blended fabric that embodiment 1 makes | 30.6 |
| The flame-retarding blended fabric that embodiment 2 makes | 30.2 |
| The flame-retarding blended fabric that embodiment 3 makes | 30.1 |
| The flame-retarding blended fabric that embodiment 4 makes | 29.9 |
| The Fire resistant viscose fiber that embodiment 5 makes | 30.0 |
The present invention is with 10-(2, the 5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, [the 3-[(methylol) amino]-3-carbonyl propyl group]-dimethyl phosphonate and three (2, the 3-dibromopropyl) these three kinds of composite uses of fire retardant of fulminuric acid ester, the flame retardant effect Synergistic, obtained beyond thought excellent technique effect.
Claims (3)
1. the BLENDED FABRIC of a Flame Vinylon and anti-flaming viscose, is characterized in that, by the flame vinylon fiber of 50-70 weight portion and the Fire resistant viscose fiber blending of 30-50 weight portion, is prepared from.
2. the BLENDED FABRIC of Flame Vinylon as claimed in claim 1 and anti-flaming viscose, is characterized in that, in described Fire resistant viscose fiber, fire retardant accounts for the quality percentage composition 6-8% of described Fire resistant viscose fiber.
3. the BLENDED FABRIC of Flame Vinylon as claimed in claim 2 and anti-flaming viscose, is characterized in that, described fire retardant is comprised of following components in mass portion: 10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide 40-60 part; [the 3-[(methylol) amino]-3-carbonyl propyl group]-dimethyl phosphonate 20-40 part; Three (2,3-dibromopropyl) fulminuric acid ester 10-30 part.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310338409.XA CN103388224B (en) | 2013-08-05 | 2013-08-05 | Blended fabric of antiflaming vinylon and antiflaming viscose |
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| CN201310338409.XA CN103388224B (en) | 2013-08-05 | 2013-08-05 | Blended fabric of antiflaming vinylon and antiflaming viscose |
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| CN103388224A true CN103388224A (en) | 2013-11-13 |
| CN103388224B CN103388224B (en) | 2015-07-15 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104713420A (en) * | 2015-02-11 | 2015-06-17 | 陕西元丰纺织技术研究有限公司 | Police fighting and training fabric and manufacturing method thereof |
| CN106757679A (en) * | 2016-11-17 | 2017-05-31 | 安徽新盾消防设备有限公司 | Flame-retardant textile |
Citations (6)
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|---|---|---|---|---|
| JPH09324330A (en) * | 1996-06-07 | 1997-12-16 | Kanegafuchi Chem Ind Co Ltd | Flame retardant blended yarn and flame retardant fabric excellent in strength using the same |
| CN1257948A (en) * | 1998-12-21 | 2000-06-28 | 孙致明 | Labour-protecting appliances of flame-retarding blended fabric |
| CN1793446A (en) * | 2005-12-29 | 2006-06-28 | 中国人民解放军海军医学研究所 | Thermal resistant fire resistant fibric and preparation process thereof |
| CN201864855U (en) * | 2010-09-13 | 2011-06-15 | 无锡华东创新材料研究院 | Flame-retarding fabric capable of expanding by heating |
| CN102561031A (en) * | 2012-02-03 | 2012-07-11 | 上海韬鸿化工科技有限公司 | Flame retardant viscose fiber and preparation method thereof |
| CN103012765A (en) * | 2012-12-08 | 2013-04-03 | 北京服装学院 | Preparation method for moisture-absorbing and flame-retardant polyester fiber |
-
2013
- 2013-08-05 CN CN201310338409.XA patent/CN103388224B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09324330A (en) * | 1996-06-07 | 1997-12-16 | Kanegafuchi Chem Ind Co Ltd | Flame retardant blended yarn and flame retardant fabric excellent in strength using the same |
| CN1257948A (en) * | 1998-12-21 | 2000-06-28 | 孙致明 | Labour-protecting appliances of flame-retarding blended fabric |
| CN1793446A (en) * | 2005-12-29 | 2006-06-28 | 中国人民解放军海军医学研究所 | Thermal resistant fire resistant fibric and preparation process thereof |
| CN201864855U (en) * | 2010-09-13 | 2011-06-15 | 无锡华东创新材料研究院 | Flame-retarding fabric capable of expanding by heating |
| CN102561031A (en) * | 2012-02-03 | 2012-07-11 | 上海韬鸿化工科技有限公司 | Flame retardant viscose fiber and preparation method thereof |
| CN103012765A (en) * | 2012-12-08 | 2013-04-03 | 北京服装学院 | Preparation method for moisture-absorbing and flame-retardant polyester fiber |
Non-Patent Citations (1)
| Title |
|---|
| 同济大学普通化学及无机化学教研室: "《普通化学》", 31 August 1993, article ""第九节 阻燃剂及其应用"", pages: 319-324 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104713420A (en) * | 2015-02-11 | 2015-06-17 | 陕西元丰纺织技术研究有限公司 | Police fighting and training fabric and manufacturing method thereof |
| CN106757679A (en) * | 2016-11-17 | 2017-05-31 | 安徽新盾消防设备有限公司 | Flame-retardant textile |
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| CN103388224B (en) | 2015-07-15 |
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Owner name: NINGBO GILEKO COMMODITY CO., LTD. Free format text: FORMER OWNER: SHANGHAI WANJING TEXTILE SCIENCE + TECHNOLOGY CO., LTD. Effective date: 20150618 |
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Effective date of registration: 20150618 Address after: 315615, No. 365 North Garden Road, Taoyuan street, Ninghai County, Ningbo, Zhejiang Applicant after: Ningbo Gelan Household Articles Co., Ltd. Address before: 201107 Shanghai city Minhang District Minhang Road 88 Lane No. 1-30 building twenty-second room T158 Applicant before: Shanghai Wanjing Textile Technology Co., Ltd. |
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