CN103388224B - Blended fabric of antiflaming vinylon and antiflaming viscose - Google Patents
Blended fabric of antiflaming vinylon and antiflaming viscose Download PDFInfo
- Publication number
- CN103388224B CN103388224B CN201310338409.XA CN201310338409A CN103388224B CN 103388224 B CN103388224 B CN 103388224B CN 201310338409 A CN201310338409 A CN 201310338409A CN 103388224 B CN103388224 B CN 103388224B
- Authority
- CN
- China
- Prior art keywords
- antiflaming
- vinylon
- viscose
- blended fabric
- flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Artificial Filaments (AREA)
- Woven Fabrics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a blended fabric of antiflaming vinylon and antiflaming viscose. The blended fabric is formed by blending 50-70 parts by weight of antiflaming vinylon fibers and 30-50 parts by weight of antiflaming viscose. The blended fabric of antiflaming vinylon and antiflaming viscose is higher in antiflaming performance, people feel comfortable when wearing the blended fabric, the cost is relatively low, and the blended fabric can be applied to protection series of products.
Description
Technical field
The present invention relates to a kind of fabric, particularly relate to the BLENDED FABRIC of a kind of Flame Vinylon and anti-flaming viscose.
Background technology
In recent years, the fire that countries in the world cause because of textiles constantly increases.China this for over ten years, the Fire response occurred every year on average is 3-4 ten thousand, death toll 2-3 thousand people, fire damage folding money 2-3 hundred million RMB.These accidents are all because textile combustion causes.
As everyone knows, in the face of the situation such as precipitate fire or burn.Adult still can save oneself, escape etc., but minor, particularly infant will be subject to serious or even fatal harm.So, take the lead in children's garment fabric, use fire resistance fibre to be natural thing naturally.In fact, America and Europe etc. are national as far back as the just flame-retardant standard of promulgation to children's garment, sofa fabric, the various textiles filler eighties in last century.The particularly U.S., US Consumer Product Safety Commission issued again the revised edition of sleeping suit for children flame-retardancy standards in 1996.
Flame vinylon fiber, contain the compound of anti-flaming function element (halogen, phosphorus, nitrogen etc.) by grafting on the large molecule of polyvinyl alcohol (PVA), or by add fire retardant blended after, carry out the technical process such as solution-polymerized SBR, stretching, heat treatment and formalizing and obtain Flame Vinylon.Main Flame Vinylon kind has at present: dimension polyvinyl chloride fibre, CY841 fiber (trade name of decabromodiphenyl oxide/antimony Flame Vinylon), high-strength fire-retarding polyvinyl (TDE fire-retardant high-strength polyvinyl), high-strength halogen-free flameproof polyvinyl (fire retardant: DDPS fire resistance fibre).For CY841 fiber, fire retardant made by this fiber utilization decabromodiphenyl oxide and antimonous oxide, adopts normal wet spinning to produce Flame Vinylon; Deca-BDE Flame Vinylon is compared with common polyvinyl, and its core-skin Rotating fields difference is less, and fire retardant is dispersed in fiber with granular form, and its continuous phase is PVA, is the less fire resistance fibre of epidermal area fire retardant.
In all kinds of fire resistance fibre, Flame Vinylon has the excellent properties such as high strength, fire-retardant and good hygroscopicity concurrently because of it, is subject to outer extensive concern in the industry.
Flame Vinylon is roughly applied in three fields: one is for curtain, wall paper, general dress material, Work Clothes, industrial cloth, filter cloth etc.; Two is for carpet, bedding etc.; Three is for nonwoven fabric and papermaking etc.At present, domestic high-strength fire-retarding polyvinyl can carry out pure spinning or blending, and its fabric is mainly used in the field higher to inflaming retarding fabric requirement of strength such as tarpaulin, fire-entry suit, frock, BDU.
But, although the fabric flame retardant effect of pure Flame Vinylon weaving is better, there is expensive and that snugness of fit is poor shortcoming.
Summary of the invention
For the deficiencies in the prior art, technical problem to be solved by this invention is to provide the BLENDED FABRIC of a kind of Flame Vinylon and anti-flaming viscose.
Technical problem to be solved by this invention is achieved by the following technical solution:
A BLENDED FABRIC for Flame Vinylon and anti-flaming viscose, is prepared from by the flame vinylon fiber of 50-70 weight portion and the Fire resistant viscose fiber blending of 30-50 weight portion.
Preferably,
In described Fire resistant viscose fiber, fire retardant accounts for the mass percentage 6-8% of described Fire resistant viscose fiber.
Described fire retardant is made up of following components in mass portion: 10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide 40-60 part; [3-[(methylol) is amino]-3-carbonyl propyl group]-dimethyl phosphonate 20-40 part; Three (2,3-dibromopropyl) fulminuric acid ester 10-30 part.
Concrete, in the present invention:
Described Fire resistant viscose fiber, has good flame retardant effect, has good flexibility, can strengthen dress ornament comfort property.
Described Fire resistant viscose fiber can adopt following method to be prepared from: mixed with viscose solution (also known as rayon spinning liquid) by fire retardant, wet spinning spinning process is shaping routinely, described fire retardant accounts for the mass percentage 6-8% of described Fire resistant viscose fiber, described fire retardant is made up of following components in mass portion: 10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide 40-60 part; [3-[(methylol) is amino]-3-carbonyl propyl group]-dimethyl phosphonate 20-40 part; Three (2,3-dibromopropyl) fulminuric acid ester 10-30 part.
In described fire retardant:
10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, English name: 10-(2,5-Dihydroxyphenyl)-10H-9-oxa-10-phospha-phenantbrene-10-oxide, No. CAS: 99208-50-1.
[3-[(methylol) is amino]-3-carbonyl propyl group]-dimethyl phosphonate, CAS accession number: 20120-33-6, English name: 3-(Dimethylphosphono)-N-methylolpropionamide.
Three (2,3-dibromopropyl) fulminuric acid ester, English name: Flame retardant TBC, Chinese another name: fire retardant TBC, molecular formula: C
12h
15br
6n
3o.
Described viscose solution is the sodium hydrate aqueous solution of cellulose sulfonate.Preferably, in described viscose solution, the weight percent content of first fibre is 8-9%, and the weight percent content of NaOH is 4-6%, falling ball viscosity 50-60 second, degree of ripeness 10-14%.
The BLENDED FABRIC of Flame Vinylon of the present invention and anti-flaming viscose, first can carry out shredding mixing by flame vinylon fiber and Fire resistant viscose fiber, adopts industry universal method to make blended yarn, then adopts conventional method to weave blended yarn to form fabric.
The BLENDED FABRIC of Flame Vinylon of the present invention and anti-flaming viscose has higher fire resistance, and comfortable and easy to wear, relative inexpensiveness.
The BLENDED FABRIC of Flame Vinylon of the present invention and anti-flaming viscose can be applied to protection series of products.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Flame vinylon fiber, the CY841 fiber that SINOPEC Sichuan Vinylon Factory is produced, oxygen index (OI) LOI value 31.4%.
Embodiment 1
Take: 10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide 50 kilograms; [3-[(methylol) is amino]-3-carbonyl propyl group]-dimethyl phosphonate 30 kilograms; Three (2,3-dibromopropyl) fulminuric acid ester 20 kilograms, is uniformly mixed obtained composite flame-retardant agent.
Mixed with viscose solution by above-mentioned composite flame-retardant agent, wet spinning spinning process is shaping routinely, can obtain described Fire resistant viscose fiber, and the length of Fire resistant viscose fiber is 38mm.Wherein, the mass percentage controlling fire retardant in finished product Fire resistant viscose fiber is 7%, and the viscose solution in described raw material, the weight percent content of first fibre is 8.5%, and the weight percent content of NaOH is 5%, falling ball viscosity 55 seconds, degree of ripeness 12%.
Take flame vinylon fiber 60 kilograms, above-mentioned obtained Fire resistant viscose fiber 40 kilograms, mix, shredding preliminary treatment, carding machine is carded to the carded sliver; Also close on drawing frame again and make ripe bar; Speed frames carry out drawing-off and twisting, and finally further draw twisting on fine spining machine, make blended yarn, yarn linear density is 39tex.Adopted by blended yarn large circle machine knitting device making method to weave again, warp count is 200/10cm, warp count is 200/10cm, the BLENDED FABRIC of final obtained Flame Vinylon and anti-flaming viscose.
Embodiment 2
Substantially the same manner as Example 1, unique difference is, fire retardant used is 10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, instead of by 10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, [3-[(methylol) amino]-3-carbonyl propyl group] the mixing fire retardant of-dimethyl phosphonate and three (2,3-dibromopropyl) fulminuric acid ester three compound.
Embodiment 3
Substantially the same manner as Example 1, unique difference is, fire retardant used is [3-[(methylol) is amino]-3-carbonyl propyl group]-dimethyl phosphonate, instead of by 10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, [3-[(methylol) amino]-3-carbonyl propyl group] the mixing fire retardant of-dimethyl phosphonate and three (2,3-dibromopropyl) fulminuric acid ester three compound.
Embodiment 4
Substantially the same manner as Example 1, unique difference is, fire retardant used is three (2,3-dibromopropyl) fulminuric acid ester, instead of by 10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, [3-[(methylol) amino]-3-carbonyl propyl group] the mixing fire retardant of-dimethyl phosphonate and three (2,3-dibromopropyl) fulminuric acid ester three compound.
Embodiment 5
Substantially the same manner as Example 1, unique difference is, fire retardant used is tricresyl phosphate (dimethylbenzene) ester, instead of by 10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, [3-[(methylol) amino]-3-carbonyl propyl group] the mixing fire retardant of-dimethyl phosphonate and three (2,3-dibromopropyl) fulminuric acid ester three compound.Fire retardant tricresyl phosphate (dimethylbenzene) ester is the general fire retardant of the industry, and CAS accession number 25155-23-1, also known as xylenylphosphate.
Test case
The Fire resistant viscose fiber obtained embodiment 1-5 respectively and the BLENDED FABRIC of final finished product Flame Vinylon and anti-flaming viscose carry out fire resistance test.
| Oxygen index (OI) LOI value, % | |
| The Fire resistant viscose fiber that embodiment 1 is obtained | 29.4 |
| The Fire resistant viscose fiber that embodiment 2 is obtained | 28.5 |
| The Fire resistant viscose fiber that embodiment 3 is obtained | 28.4 |
| The Fire resistant viscose fiber that embodiment 4 is obtained | 27.6 |
| The Fire resistant viscose fiber that embodiment 5 is obtained | 28.0 |
| The flame-retarding blended fabric that embodiment 1 is obtained | 30.6 |
| The flame-retarding blended fabric that embodiment 2 is obtained | 30.2 |
| The flame-retarding blended fabric that embodiment 3 is obtained | 30.1 |
| The flame-retarding blended fabric that embodiment 4 is obtained | 29.9 |
| The Fire resistant viscose fiber that embodiment 5 is obtained | 30.0 |
The present invention is by 10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, [3-[(methylol) amino]-3-carbonyl propyl group]-dimethyl phosphonate and three (2,3-dibromopropyl) these the three kinds of composite uses of fire retardant of fulminuric acid ester, flame retardant effect Synergistic, achieves beyond thought excellent technique effect.
Claims (1)
1. a BLENDED FABRIC for Flame Vinylon and anti-flaming viscose, is characterized in that, is prepared from by the flame vinylon fiber of 50-70 weight portion and the Fire resistant viscose fiber blending of 30-50 weight portion; In described Fire resistant viscose fiber, fire retardant accounts for the mass percentage 6-8% of described Fire resistant viscose fiber; Described fire retardant is made up of following components in mass portion: 10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide 40-60 part; [3-[(methylol) is amino]-3-carbonyl propyl group]-dimethyl phosphonate 20-40 part; Three (2,3-dibromopropyl) fulminuric acid ester 10-30 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310338409.XA CN103388224B (en) | 2013-08-05 | 2013-08-05 | Blended fabric of antiflaming vinylon and antiflaming viscose |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310338409.XA CN103388224B (en) | 2013-08-05 | 2013-08-05 | Blended fabric of antiflaming vinylon and antiflaming viscose |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103388224A CN103388224A (en) | 2013-11-13 |
| CN103388224B true CN103388224B (en) | 2015-07-15 |
Family
ID=49532641
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310338409.XA Active CN103388224B (en) | 2013-08-05 | 2013-08-05 | Blended fabric of antiflaming vinylon and antiflaming viscose |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103388224B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104713420A (en) * | 2015-02-11 | 2015-06-17 | 陕西元丰纺织技术研究有限公司 | Police fighting and training fabric and manufacturing method thereof |
| CN106757679A (en) * | 2016-11-17 | 2017-05-31 | 安徽新盾消防设备有限公司 | Flame-retardant textile |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1257948A (en) * | 1998-12-21 | 2000-06-28 | 孙致明 | Labour-protecting appliances of flame-retarding blended fabric |
| CN1793446A (en) * | 2005-12-29 | 2006-06-28 | 中国人民解放军海军医学研究所 | Thermal resistant fire resistant fibric and preparation process thereof |
| CN201864855U (en) * | 2010-09-13 | 2011-06-15 | 无锡华东创新材料研究院 | Flame-retarding fabric capable of expanding by heating |
| CN102561031A (en) * | 2012-02-03 | 2012-07-11 | 上海韬鸿化工科技有限公司 | Flame retardant viscose fiber and preparation method thereof |
| CN103012765A (en) * | 2012-12-08 | 2013-04-03 | 北京服装学院 | Preparation method for moisture-absorbing and flame-retardant polyester fiber |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09324330A (en) * | 1996-06-07 | 1997-12-16 | Kanegafuchi Chem Ind Co Ltd | Flame retardant blended yarn and flame retardant fabric excellent in strength using the same |
-
2013
- 2013-08-05 CN CN201310338409.XA patent/CN103388224B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1257948A (en) * | 1998-12-21 | 2000-06-28 | 孙致明 | Labour-protecting appliances of flame-retarding blended fabric |
| CN1793446A (en) * | 2005-12-29 | 2006-06-28 | 中国人民解放军海军医学研究所 | Thermal resistant fire resistant fibric and preparation process thereof |
| CN201864855U (en) * | 2010-09-13 | 2011-06-15 | 无锡华东创新材料研究院 | Flame-retarding fabric capable of expanding by heating |
| CN102561031A (en) * | 2012-02-03 | 2012-07-11 | 上海韬鸿化工科技有限公司 | Flame retardant viscose fiber and preparation method thereof |
| CN103012765A (en) * | 2012-12-08 | 2013-04-03 | 北京服装学院 | Preparation method for moisture-absorbing and flame-retardant polyester fiber |
Non-Patent Citations (1)
| Title |
|---|
| 同济大学普通化学及无机化学教研室."第九节 阻燃剂及其应用".《普通化学》.同济大学出版社,1993,第319-324页. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103388224A (en) | 2013-11-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103361856B (en) | The BLENDED FABRIC of PSA fiber and anti-flaming viscose | |
| CN102191609B (en) | Arc-protection antiflaming blending fabric | |
| CN104313748B (en) | Processing method of flame-retardant blended yarn | |
| CN106948052A (en) | A kind of flame-proof electrostatic resistance yarn and its fabric | |
| CN106400235A (en) | Blended yarn of organic silicon nitrogen system flame-retardant fiber and organophosphorus system flame-retardant fiber | |
| CN106948073A (en) | Flame-retardant acrylic fibre cotton blended knitted fabric | |
| CN105839255A (en) | Flame-retardant yarn for children's clothing and preparing method of flame-retardant yarn | |
| CN106400266A (en) | Multi-component low-cost permanent inflaming retarding fabric and preparation method for same | |
| CN104630971A (en) | Vinylon modacrylic viscose blended fabric | |
| CN104018278A (en) | High temperature-resistant anti-burning fabric | |
| CN103284368A (en) | Blended flame-retardant fabric and flame-retardant protecting clothes | |
| CN103361994B (en) | Thermal resistant fire resistant fibric | |
| CN103388224B (en) | Blended fabric of antiflaming vinylon and antiflaming viscose | |
| CN108166119A (en) | The fire-retardant blend of comfort arc protection | |
| KR101406500B1 (en) | Process of producing aramid air-jet belnded spun yarn having exellent appearance and friction resistance | |
| CN103361996B (en) | The BLENDED FABRIC of Vinyon N and anti-flaming viscose | |
| CN105220314B (en) | A kind of resistance to 320～340 DEG C of fire- resistance cloths and preparation method thereof | |
| CN103361833B (en) | The BLENDED FABRIC of meta-aramid and anti-flaming viscose | |
| CN103388267B (en) | The BLENDED FABRIC of polyphenylene sulfide and anti-flaming viscose | |
| CN103361870B (en) | The BLENDED FABRIC of Ju Fang oxadiazole and anti-flaming viscose | |
| US20210254278A1 (en) | Flame Retardant Fabric and Method | |
| KR20160010917A (en) | Long staple aramid fiber air-jet yarn having excellent uniformity, stress and strain, friction resistance and process of producing thereof | |
| CN103397534B (en) | The blend fabric of Fanglun l414 and anti-flaming viscose | |
| CN104630979A (en) | Acrylic fiber and spandex blended fabric | |
| CN111020737B (en) | Antibacterial flame-retardant fiber and preparation method of fabric thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: NINGBO GILEKO COMMODITY CO., LTD. Free format text: FORMER OWNER: SHANGHAI WANJING TEXTILE SCIENCE + TECHNOLOGY CO., LTD. Effective date: 20150618 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| C53 | Correction of patent of invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Zhang Zhouyi Inventor before: Yuan Juan |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: YUAN JUAN TO: ZHANG ZHOUYI |
|
| TA01 | Transfer of patent application right |
Effective date of registration: 20150618 Address after: 315615, No. 365 North Garden Road, Taoyuan street, Ninghai County, Ningbo, Zhejiang Applicant after: Ningbo Gelan Household Articles Co., Ltd. Address before: 201107 Shanghai city Minhang District Minhang Road 88 Lane No. 1-30 building twenty-second room T158 Applicant before: Shanghai Wanjing Textile Technology Co., Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |