CN106753863A - A kind of cleaning agent suitable for toilet and preparation method thereof - Google Patents

A kind of cleaning agent suitable for toilet and preparation method thereof Download PDF

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Publication number
CN106753863A
CN106753863A CN201611056397.1A CN201611056397A CN106753863A CN 106753863 A CN106753863 A CN 106753863A CN 201611056397 A CN201611056397 A CN 201611056397A CN 106753863 A CN106753863 A CN 106753863A
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CN
China
Prior art keywords
parts
cleaning agent
methyl
aeo
toilet
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Pending
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CN201611056397.1A
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Chinese (zh)
Inventor
张京
李永强
李颖
温霖
李文成
李婧
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NEW AGE HEALTH INDUSTRY(GROUP) CO Ltd
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NEW AGE HEALTH INDUSTRY(GROUP) CO Ltd
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Priority to CN201611056397.1A priority Critical patent/CN106753863A/en
Publication of CN106753863A publication Critical patent/CN106753863A/en
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0031—Carpet, upholstery, fur or leather cleansers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3409—Alkyl -, alkenyl -, cycloalkyl - or terpene sulfates or sulfonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers

Abstract

The present invention relates to a kind of cleaning agent for toilet, its active component includes the component of following weight portion：0.5 10 parts of citric acid, 1 20 parts of sodium citrate, 28 parts of APG, 4~8 parts of AEO, 1~5 part of perfluorooctane sulfonate can also further add preservative and aid antibacteria agent.Bathroom cleaner dosage stable performance of the present invention, with the lasting period more long, to all facilities in toilet, such as toilet, hand washing sink, toilet wall all have good clean effect and bacteriostasis, and cleaning agent of the present invention is in faintly acid, excitant is smaller, and the corrosivity to metallic facility is smaller, and the nocuity to skin is smaller.

Description

A kind of cleaning agent suitable for toilet and preparation method thereof
Technical field
The invention belongs to daily chemicals technical field, and in particular to a kind of cleaning agent suitable for toilet.
Background technology
Toilet is that each family and public place must not lack, to ensure toilet wall surface in long-term use During do not damage, ceramic tile is often posted on wall.In addition, toilet, bathroom, hand basin are also typically provided with toilet Etc. various facilities.It is different due to bringing dirt to toilet, hand basin and ceramic tile surface, health is directed in the prior art Between in different facilities, generally have using different cleaning agents, be such as specially adapted for the cleaning agent of toilet or hand basin, this just makes The raising of the cumbersome and cleaning cost operated during being cleaned into toilet.
The content of the invention
It is an object of the invention to provide a kind of cleaning agent of facilities various suitable for toilet, its active component is included such as The component of lower weight portion：Citric acid 0.5-10 parts, sodium citrate 1-20 parts, APG 2-8 parts, AEO Or 4~8 parts of NPE, 1~5 part, pyrovinic acid 1-10 parts of perfluorooctane sulfonate.
Citric acid of the invention and buffered sodium citrate system, can make the acid-base value of system reach faintly acid, ensure to compare Under pH value higher, it is efficiently cleaning scale removal to remain to, and sodium citrate can chelate Ca as chelating agent2+, Mg2+Ion, The purpose of scale removal is reached, the two plays a part of Synergistic.Further, it is non-oxidizable strong using to surface low-corrosiveness Acid methyl sulfonic acid, is preferably minimized excitant.And by adding APG, AEO and octyl sulphur Three kinds of surfactants of compounding of sour sodium, further improve scale removal performance.
Preferably, also including Herba Lophatheri extract 0.001-1 parts, tea tree ethereal oil 0.001-1 parts.Both materials can be played Auxiliary scale removal and the effect of antibacterial.
Preferably, 0.1~0.5 part of the compound also including methyl-isothiazol phosphorus ketone and methylchloroisothiazandnone, iodine third 0.1~0.5 part of alkynol butyl mephenesin Carbamate；Both material bases primarily serve the effect of stabilization scale removal system, extend holding effect Phase.
Methyl-isothiazol phosphorus ketone and methyl chloride in the compound of the methyl-isothiazol phosphorus ketone and methylchloroisothiazandnone The amount ratio of OIT is 9:1.
Preferably, the APG is APG0810, APG0814, APG0816, APG1214 or APG1216.
Preferably, the AEO is AEO-9 or AEO-7.
Preferably, the flavones content in the Herba Lophatheri extract is 40%wt-65%wt.
Preferably, the extracting method of the Herba Lophatheri extract is：
1) leaf of bamboo kind of the flavones content more than 1.5%wt is filtered out as raw materials for production using HPLC methods；
2) leaf of bamboo low-temperature dark that will be filtered out dry, pulverize into the leaf of bamboo fine powder of 0.1~1.0cm；
3) by the leaf of bamboo fine powder C1~C3Alcohol extracting obtain leachate；
4) leachate is filtered, vacuum concentration obtains leaf of bamboo crude extract；
5) after the leaf of bamboo crude extract is diluted with water, centrifugation takes clear liquid by ceramic membrane separation；
6) by ceramic membrane permeate by milipore filter, nanofiltration UF membrane, leaf of bamboo treatment fluid is obtained；
7) leaf of bamboo treatment fluid is isolated and purified by polymeric adsorbent, the treatment fluid volume ratio of polymeric adsorbent and above-mentioned film It is 1:(5~20), then polymeric adsorbent is carried out to afford eluent, the eluent of wash-out is water-soluble aliphatic lower alcohol Liquid；
8) it is 1.03~1.14 above-mentioned eluent to be concentrated in vacuo into proportion, then carries out vacuum freeze drying or spray dry It is dry, obtain bamboo leaf flavone.
Preferably, toilet cleaner amount of the present invention includes the component of following weight portion：1~5 part of citric acid, lemon 4~8 parts of lemon 2~20 parts of sodium of acid, 4~8 parts of APG, AEO or NPE, octane 1~5 part of sodium sulfonate, 2~8 parts of pyrovinic acid, Herba Lophatheri extract 0.001-0.5 parts, tea tree ethereal oil 0.001-0.5 parts, base is different 0.1~0.5 part of the compound of lythidathion ketone and methylchloroisothiazandnone, 0.1~0.5 part of iodine propilolic alcohol butyl mephenesin Carbamate；
Methyl-isothiazol phosphorus ketone and methyl chloride in the compound of the methyl-isothiazol phosphorus ketone and methylchloroisothiazandnone The amount ratio of OIT is 9:1.
It is further preferred that toilet cleaner amount of the present invention includes the component of following weight portion：Citric acid 2.5 Part, 10 parts of sodium citrate, 4 parts of APG0810,5 parts of pyrovinic acid, 0.002 part of Herba Lophatheri extract, 0.002 part of tea tree ethereal oil The compound (9 of 6 parts of AEO-9, methyl-isothiazol phosphorus ketone and methylchloroisothiazandnone:1) 0.15 part, iodine propilolic alcohol butyl ammonia 0.15 part of formic acid esters, 2 parts of perfluorooctane sulfonate.
Preferably, toilet cleaner of the present invention also includes 0.1~0.2 part of spices.
During practical application, above-mentioned cleaning agent is a kind of aqueous solution, it is preferred that with the total weight parts of cleaning agent 100 parts of meters, on the basis of said components, surplus are supplied with water.
The preparation method of cleaning dosage of the present invention comprises the following steps：
1) deionized water is added into reactor, and starts stirring；
2) citric acid and sodium citrate are added into reactor, stirring and dissolving；
3) pyrovinic acid is added into reactor, stirring and dissolving
4) by APG, AEO and perfluorooctane sulfonate add reactor, stirring and dissolving；
5) preservative is added into reactor, stirring and dissolving.
If desired spices is added, also further spices can be added after preservative is added.
Cleaning agent of the present invention has the advantages that：
All in toilet with the lasting period more long, are set by bathroom cleaner dosage stable performance of the present invention Apply, such as toilet, hand washing sink, toilet wall all have good clean effect and bacteriostasis, and of the present invention clear Clean dose is in faintly acid, and excitant is smaller, and the corrosivity to metallic facility is smaller, and the nocuity to skin is smaller.
Specific embodiment
Following examples are used to illustrate the present invention, but are not limited to the scope of the present invention.
The raw material being related in the present invention is purchased from：
Embodiment 1
The present embodiment is related to a kind of cleaning agent suitable for toilet, is prepared from by the raw material including following weight portion：
Embodiment 2
The present embodiment is related to a kind of cleaning agent suitable for toilet, is prepared from by the raw material including following weight portion：
Raw material Content (g)
Herba Lophatheri extract 0.002
Tea tree ethereal oil 0.002
Citric Acid Mono 2
Sodium Citrate, usp, Dihydrate Powder 8
Pyrovinic acid 4
APG-CH100 4
AEO-9 6
Pas-8S 2
CM10 0.15
FL10 0.15
MK95431 0.15
Deionized water 73.55
Embodiment 3
The present embodiment is related to a kind of cleaning agent suitable for toilet, by the raw material preparation including following weight portion Into：
Raw material Content (%)
Herba Lophatheri extract 0.002
Tea tree ethereal oil 0.002
Citric Acid Mono 2.5
Sodium Citrate, usp, Dihydrate Powder 10
Pyrovinic acid 5
APG-CH100 5
AEO-9 6
Pas-8S 2
CM10 0.15
FL10 0.15
MK95431 0.15
Deionized water 69.046
Embodiment 4
The present embodiment is related to a kind of cleaning agent suitable for toilet, by the raw material preparation including following weight portion Into：
Embodiment 5
The present embodiment is related to a kind of cleaning agent suitable for toilet, is prepared from by the raw material including following weight portion：
Raw material Content (%)
Herba Lophatheri extract 0.002
Tea tree ethereal oil 0.002
Citric Acid Mono 0.5
Sodium Citrate, usp, Dihydrate Powder 1
Pyrovinic acid 1
APG-CH100 2
AEO-9 4
Pas-8S 1
CM10 0.1
FL10 0.1
MK95431 0.15
Deionized water 90.15
Embodiment 6
The present embodiment is related to a kind of cleaning agent suitable for toilet, is prepared from by the raw material including following weight portion：
Embodiment 7
The preparation method of cleaning agent, comprises the following steps described in any one of embodiment 1~7：
(1) load weighted deionized water is added into reactor, starts stirring.
(2) load weighted citric acid and sodium citrate are added into reactor, stirring and dissolving.
(3) pyrovinic acid is added to add stirring and dissolving.
(4) by load weighted surfactant A PG, AEO-9, PaS-8S, reactor stirring and dissolving is added.
(5) by preservative, essence adds stirring and dissolving.
Comparative example 1
Compared with Example 4, its difference is not add sodium citrate in the feed
If not adding sodium citrate in the product, it is impossible to form buffer system, cause system pH value too low, influence human body Security, causes excessive to skin damage, additionally, sodium citrate or a kind of chelating agent, can aid in removing metal ion, if not Addition, can also have a certain impact to clean effect.
Comparative example 2
Compared with row 4 are implemented, its difference is to substitute pyrovinic acid using hydrochloric acid.
Raw material Content (%)
Herba Lophatheri extract 0.002
Tea tree ethereal oil 0.002
Citric Acid Mono 2.5
Hydrochloric acid 5
Sodium citrate 10
APG-CH100 4
AEO-9 6
Pas-8S 2
CM10 0.15
FL10 0.15
MK95431 0.15
Deionized water 80.05
Replace pyrovinic acid using strong acid, corrosivity is big, very harmful to human body strong stimulation.
Comparative example 3
Cleaning agent described in the present embodiment, does not add perfluorooctane sulfonate wherein.
Raw material Content (g)
Herba Lophatheri extract 0.002
Tea tree ethereal oil 0.002
Citric Acid Mono 2
Sodium Citrate, usp, Dihydrate Powder 8
Pyrovinic acid 4
APG-CH100 4
AEO-9 6
CM10 0.15
FL10 0.15
MK95431 0.15
Deionized water 72.55
APG APG-CH100, octyl sodium sulfonate, although AEO is all surfactant, Emphasis is different, and APG reduces the excitant of other surfaces activating agent and other raw materials, perfluorooctane sulfonate in system With osmosis, increase decontamination detergent power, the conventional cost performance of AEO decontamination de-sludging nonionic high Surfactant, thus three plays synergistic function, it is indispensable.When in formula without perfluorooctane sulfonate, product Scale removal performance reduction.
Experimental example 1
Cleaning agent described in embodiment 1 is applied to the cleaning of toilet, effectively the peculiar smell on removal toilet, urine can be removed Alkalinuria dirt and human body other secretion etc..
Experimental example 2
Cleaning agent described in embodiment 2 is applied to the soap scum between the sanitation and hygiene of tiles in toilet on ceramic tile, can be made Ceramic tile cleaning light.
Experimental example 3
Cleaning agent described in embodiment 3 is applied to the cleaning of hand basin, can go to degrease, soap scum makes hand basin clear Clean light.
Experimental example 4
Cleaning agent described in embodiment 4 is applied to the cleaning of bathroom glass, the spot for being insoluble in water can be removed, make glass Glass is sparkling clean.
Experimental example 5
Embodiment 1~6 and the product of comparative example 1~3, and three kinds of commercially available products are carried out into the test of descaling rate：Claim Take Ca2CO30.800 gram, 40 grams of distilled water, each 10 grams of the product of embodiment 1~6 and comparative example 1~3 reacts 24 hours, calculates Dissolving Ca2CO3Amount, and calculate descaling rate, acquired results such as table 1.
Table 1
Product category Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Descaling rate (%) 28.50 30.28 29.36 31.50
Product category Embodiment 5 Embodiment 6 Comparative example 1 Comparative example 2
Descaling rate (%) 29.56 29.56 10.50 25.68
Product category Comparative example 3 Product 1 Product 2 Product 3
Descaling rate (%) 15.26 5.27 6.00 13.24
From result above, cleaning agent described herein has stronger scale removal ability, can obtain preferable effect.
Although above having used general explanation, specific embodiment and experiment, the present invention is made to retouch in detail State, but on the basis of the present invention, it can be made some modifications or improvements, this is to those skilled in the art apparent 's.Therefore, these modifications or improvements without departing from theon the basis of the spirit of the present invention, belong to claimed Scope.

Claims (10)

1. a kind of cleaning agent suitable for toilet, it is characterised in that its active component includes the component of following weight portion：Lemon It is sour 0.5-10 parts, sodium citrate 1-20 parts, APG 2-8 parts, AEO or NPE 4 ~8 parts, 1~5 part, pyrovinic acid 1-10 parts of perfluorooctane sulfonate.
2. toilet cleaner according to claim 1, it is characterised in that also including Herba Lophatheri extract 0.001-1 parts, Tea tree ethereal oil 0.001-1 parts.
3. cleaning agent according to claim 1 and 2, it is characterised in that also different including methyl-isothiazol phosphorus ketone and methyl chloride 0.1~0.5 part of the compound of thiazolinone, 0.1~0.5 part of iodine propilolic alcohol butyl mephenesin Carbamate；
Methyl-isothiazol phosphorus ketone and the different thiophene of methyl chloride in the compound of the methyl-isothiazol phosphorus ketone and methylchloroisothiazandnone The amount ratio of oxazoline ketone is 9:1.
4. the cleaning agent according to claim 1 or 3, it is characterised in that the APG be APG0810, APG0814, APG0816, APG1214 or APG1216.
5. the cleaning agent according to claim 1 or 3, it is characterised in that the AEO be AEO-9 or AEO-7。
6. the cleaning agent according to Claims 2 or 3, it is characterised in that the flavones content in the Herba Lophatheri extract is 40%wt-65%wt.
7. the cleaning agent according to any one of claim 1~6, it is characterised in that the component including following weight portion：Lemon 1~5 part of acid, 2~20 parts of sodium citrate, 4~8 parts of APG, AEO or NPE 4 ~8 parts, 1~5 part of perfluorooctane sulfonate, 2~8 parts of pyrovinic acid, Herba Lophatheri extract 0.001-0.5 parts, tea tree ethereal oil 0.001- 0.5 part, 0.1~0.5 part of the compound of base isothiazole phosphorus ketone and methylchloroisothiazandnone, iodine propilolic alcohol butyl mephenesin Carbamate 0.1~0.5 part；
Methyl-isothiazol phosphorus ketone and the different thiophene of methyl chloride in the compound of the methyl-isothiazol phosphorus ketone and methylchloroisothiazandnone The amount ratio of oxazoline ketone is 9:1.
8. cleaning agent according to claim 7, it is characterised in that be prepared from by the raw material including following weight portion：Lemon 2.5 parts of lemon acid, 10 parts of sodium citrate, 4 parts of APG0810,5 parts of pyrovinic acid, 0.002 part of Herba Lophatheri extract, tea tree ethereal oil 0.002 part AEO-96 parts, 0.15 part of the compound of methyl-isothiazol phosphorus ketone and methylchloroisothiazandnone, iodine propilolic alcohol butyl ammonia Methyl in the compound of 0.15 part of formic acid esters, 2 parts of perfluorooctane sulfonate, the methyl-isothiazol phosphorus ketone and methylchloroisothiazandnone The amount ratio of isothiazole phosphorus ketone and methylchloroisothiazandnone is 9:1.
9. the cleaning agent according to claim 1~8 times item, it is characterised in that also including 0.1~0.2 part of spices.
10. the preparation method of cleaning agent described in any one of claim 1~8, it is characterised in that comprise the following steps：
1) deionized water is added into reactor, and starts stirring；
2) citric acid and sodium citrate are added into reactor, stirring and dissolving；
3) pyrovinic acid is added into reactor, stirring and dissolving；
4) by APG, AEO and perfluorooctane sulfonate add reactor, stirring and dissolving；
5) preservative is added into reactor, stirring and dissolving.
CN201611056397.1A 2016-11-24 2016-11-24 A kind of cleaning agent suitable for toilet and preparation method thereof Pending CN106753863A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108659974A (en) * 2018-06-21 2018-10-16 枣庄九星生物科技有限公司 A kind of bathroom peculiar-smell-removal detergent of -5- of methyl containing 4- Acetoxyethyls-thiazole
CN110129138A (en) * 2019-04-28 2019-08-16 永联印刷耗材（深圳）有限公司 Printing machine damping fluid circulation cleaning liquid composition
CN111003821A (en) * 2019-12-26 2020-04-14 大庆鉴升科技开发有限公司 Neutral detergent for efficiently removing carbonate and iron oxide scales and preparation method thereof
CN112143568A (en) * 2020-10-27 2020-12-29 北京同禧科技有限公司 Cleaning agent capable of changing color when meeting dirt and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1441840A (en) * 2000-07-14 2003-09-10 雷克特本克斯尔有限公司 Carpet cleaners
CN101239194A (en) * 2008-03-17 2008-08-13 张博 Deodorizing sterilizing foamed liquid for water closet
CN102703230A (en) * 2011-05-25 2012-10-03 王国松 Spray-proof, olid-resistant, anti-sticking automatic foaming powder when wets for toilets
CN104073370A (en) * 2014-07-03 2014-10-01 谢伟杰 Toilet antibacterial cleaning agent
CN105462699A (en) * 2014-09-06 2016-04-06 天津市天亨洗涤剂有限公司 Dishwashing liquid
CN105542998A (en) * 2015-12-15 2016-05-04 青岛拓联信息技术有限公司 Highly-efficient toilet cleaning agent
CN105969540A (en) * 2016-05-13 2016-09-28 马鞍山纽盟知识产权管理服务有限公司 Novel environment-friendly closestool detergent

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1441840A (en) * 2000-07-14 2003-09-10 雷克特本克斯尔有限公司 Carpet cleaners
CN101239194A (en) * 2008-03-17 2008-08-13 张博 Deodorizing sterilizing foamed liquid for water closet
CN102703230A (en) * 2011-05-25 2012-10-03 王国松 Spray-proof, olid-resistant, anti-sticking automatic foaming powder when wets for toilets
CN104073370A (en) * 2014-07-03 2014-10-01 谢伟杰 Toilet antibacterial cleaning agent
CN105462699A (en) * 2014-09-06 2016-04-06 天津市天亨洗涤剂有限公司 Dishwashing liquid
CN105542998A (en) * 2015-12-15 2016-05-04 青岛拓联信息技术有限公司 Highly-efficient toilet cleaning agent
CN105969540A (en) * 2016-05-13 2016-09-28 马鞍山纽盟知识产权管理服务有限公司 Novel environment-friendly closestool detergent

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108659974A (en) * 2018-06-21 2018-10-16 枣庄九星生物科技有限公司 A kind of bathroom peculiar-smell-removal detergent of -5- of methyl containing 4- Acetoxyethyls-thiazole
CN110129138A (en) * 2019-04-28 2019-08-16 永联印刷耗材（深圳）有限公司 Printing machine damping fluid circulation cleaning liquid composition
CN110129138B (en) * 2019-04-28 2021-03-30 永联印刷耗材（深圳）有限公司 Cleaning liquid composition for fountain solution circulating system of printing machine
CN111003821A (en) * 2019-12-26 2020-04-14 大庆鉴升科技开发有限公司 Neutral detergent for efficiently removing carbonate and iron oxide scales and preparation method thereof
CN112143568A (en) * 2020-10-27 2020-12-29 北京同禧科技有限公司 Cleaning agent capable of changing color when meeting dirt and preparation method thereof

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