CN105969540A - Novel environment-friendly closestool detergent - Google Patents

Novel environment-friendly closestool detergent Download PDF

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Publication number
CN105969540A
CN105969540A CN201610313936.9A CN201610313936A CN105969540A CN 105969540 A CN105969540 A CN 105969540A CN 201610313936 A CN201610313936 A CN 201610313936A CN 105969540 A CN105969540 A CN 105969540A
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CN
China
Prior art keywords
parts
acid
novel environment
detergent
friendly closestool
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610313936.9A
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Chinese (zh)
Inventor
王晓娜
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Maanshan Numen Intellectual Property Management Services Co Ltd
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Maanshan Numen Intellectual Property Management Services Co Ltd
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Priority to CN201610313936.9A priority Critical patent/CN105969540A/en
Publication of CN105969540A publication Critical patent/CN105969540A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0068Deodorant compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0073Anticorrosion compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2082Polycarboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/34Organic compounds containing sulfur
    • C11D3/3409Alkyl -, alkenyl -, cycloalkyl - or terpene sulfates or sulfonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3753Polyvinylalcohol; Ethers or esters thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3942Inorganic per-compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • C11D1/721End blocked ethers

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention relates to a novel environment-friendly closestool detergent, which is mainly prepared from the following raw materials in parts by weight: 5 to 10 parts of anionic surfactants, 4 to 6 parts of nonionic surfactants, 6 to 12 parts of sodium dodecyl benzene sulfonate, 5 to 10 parts of sulfonic acid, 1 to 2 parts of ethylenediamine tetracetic acid, 5 to 7 parts of propanediol butyl ether, 5 to 10 parts of tuberose, 5 to 10 parts of mint, 2 to 8 parts of jasmines, 1 to 4 parts of clove, 5 to 10 parts of honeysuckle flowers, 5 to 10 parts of morning glories, 6 to 10 parts of hydrogen peroxide, 1 to 2 parts of sodium percarbonate, 6 to 10 parts of methanesulfonic acid, 2 to 4 parts of oxalic acid, 3 to 6 parts of citric acid, 3 to 6 parts of sodium citrate, 1 to 3 parts of polyvinyl alcohol, 1 to 3 parts of plasticizing agents and 1 to 2 parts of ABS (acrylonitrile butadiene styrene) antisticking agents. The novel environment-friendly closestool detergent has the advantages that the environment pollution is little; the corrosivity is low; the water pollution is little; through fragrant odor, the air quality of a toilet can be improved, and mosquitoes and insects can be repelled; the novel environment-friendly closestool detergent is suitable for being popularized.

Description

A kind of novel environment friendly Closestool cleanser
Technical field
The present invention relates to a kind of novel environment friendly Closestool cleanser.
Background technology
Toilet must accomplish routine cleaning, not so can leave dirt.Dirt of long duration is difficult to clean.There is a lot of toilet cleaner, be placed in the water storage cylinder of toilet, rushed toilet every time and all toilet sufficiently can be cleaned.The most this cleaning is the most inadequate, because once cleanout fluid spills, it will the facility of surrounding is caused corrosion and injury.Meanwhile, the abnormal smells from the patient of toilet and the wet environment of toilet are easy to cause mosquito.So, this is accomplished by toilet bowl cleaning agent the most also can possess the effect of mosquito dispersing.
Summary of the invention
The invention aims to overcome above deficiency and provide that a kind of environmental pollution is little, corrosivity is little, fragrant odour little to water pollution can improve the air quality of toilet, mosquito dispersing, the suitable a kind of novel environment friendly Closestool cleanser promoted.
The present invention is achieved through the following technical solutions: a kind of novel environment friendly Closestool cleanser, mainly it is composed of the following raw materials by weight: anion surfactant 5-10 part, nonionic surfactant 4-6 part, dodecylbenzene sodium sulfonate 6-12 part, sulfonic acid 5-10 part, ethylenediaminetetraacetic acid 1-2 part, propandiol butyl ether 5-7 part, Polianthes tuberosa L. 5-10 part, Herba Menthae 5-10 part, jasmine 2-8 part, Flos Caryophylli 1-4 part, Flos Lonicerae 5-10 part, morning glory 5-10 part, hydrogen peroxide 6-10 part, SODIUM PERCARBONATE 1-2 part, pyrovinic acid 6-10 part, oxalic acid 2-4 part, citric acid 3-6 part, sodium citrate 3-6 part, polyvinyl alcohol 1-3 part, plasticizer 1-3 part, ABS antitack agent 1-2 part.
Further improvement of the present invention is: nonionic surfactant is polyoxyethylene ether, cocoanut fatty acid diethanolamide, NPE.
Further improvement of the present invention is: described anion surfactant is fatty alcohol-polyoxyethylene ether.
Beneficial effects of the present invention:
The present invention to little to water pollution, environmental pollution is little, corrosivity is little, the facility of periphery will not be produced corrosivity, especially will not corrode the parts in the water storage cylinder of toilet, fragrant odour of the present invention, natural fragrance will not make people be poisoned, the air quality of toilet, mosquito dispersing can be improved, suitably promote.
Detailed description of the invention:
In order to deepen the understanding of the present invention, below in conjunction with embodiment, the invention will be further described, and this embodiment is only used for explaining the present invention, is not intended that limiting the scope of the present invention.
Embodiment 1
Raw material: anion surfactant 5 parts, nonionic surfactant 4 parts, dodecylbenzene sodium sulfonate 6 parts, sulfonic acid 5 parts; ethylenediaminetetraacetic acid 1 part, propandiol butyl ether 5 parts, Polianthes tuberosa L. 5 parts, Herba Menthae 5 parts; jasmine 2 parts, Flos Caryophylli 1 part, Flos Lonicerae 5 parts, 5 parts of morning glory; hydrogen peroxide 6 parts, SODIUM PERCARBONATE 1 part, pyrovinic acid 6 parts; oxalic acid 2 parts, citric acid 3 parts, sodium citrate 3 parts; polyvinyl alcohol 1 part, plasticizer 1 part, ABS antitack agent 1 part.
Embodiment 2
Raw material: anion surfactant 5 parts, nonionic surfactant 6 parts, dodecylbenzene sodium sulfonate 12 parts, sulfonic acid 10 parts; ethylenediaminetetraacetic acid 2 parts, propandiol butyl ether 7 parts, Polianthes tuberosa L. 10 parts, Herba Menthae 10 parts; jasmine 8 parts, Flos Caryophylli 4 parts, Flos Lonicerae 10 parts, 10 parts of morning glory; hydrogen peroxide 10 parts, SODIUM PERCARBONATE 2 parts, pyrovinic acid 10 parts; oxalic acid 4 parts, citric acid 6 parts, sodium citrate 6 parts; polyvinyl alcohol 3 parts, plasticizer 3 parts, ABS antitack agent 2 parts.
Embodiment 3
Raw material: anion surfactant 5 parts, nonionic surfactant 5 parts, dodecylbenzene sodium sulfonate 9 parts, sulfonic acid 7 parts; ethylenediaminetetraacetic acid 1.5 parts, propandiol butyl ether 6 parts, Polianthes tuberosa L. 8 parts, Herba Menthae 7 parts; jasmine 5 parts, Flos Caryophylli 3 parts, Flos Lonicerae 7.5 parts, 8 parts of morning glory; hydrogen peroxide 8 parts, SODIUM PERCARBONATE 1.5 parts, pyrovinic acid 8 parts; oxalic acid 3 parts, citric acid 4 parts, sodium citrate 4.5 parts; polyvinyl alcohol 2 parts, plasticizer 2 parts, ABS antitack agent 1.5 parts.
Embodiment 4
Raw material: anion surfactant 10 parts, nonionic surfactant 4 parts, dodecylbenzene sodium sulfonate 6 parts, sulfonic acid 5 parts; ethylenediaminetetraacetic acid 1 part, propandiol butyl ether 5 parts, Polianthes tuberosa L. 5 parts, Herba Menthae 5 parts; jasmine 2 parts, Flos Caryophylli 1 part, Flos Lonicerae 5 parts, 5 parts of morning glory; hydrogen peroxide 6 parts, SODIUM PERCARBONATE 1 part, pyrovinic acid 6 parts; oxalic acid 2 parts, citric acid 3 parts, sodium citrate 3 parts; polyvinyl alcohol 1 part, plasticizer 1 part, ABS antitack agent 1 part.
Embodiment 5
Raw material: anion surfactant 10 parts, nonionic surfactant 5 parts, dodecylbenzene sodium sulfonate 9 parts, sulfonic acid 7 parts; ethylenediaminetetraacetic acid 1.5 parts, propandiol butyl ether 6 parts, Polianthes tuberosa L. 8 parts, Herba Menthae 7 parts; jasmine 5 parts, Flos Caryophylli 3 parts, Flos Lonicerae 7.5 parts, 8 parts of morning glory; hydrogen peroxide 8 parts, SODIUM PERCARBONATE 1.5 parts, pyrovinic acid 8 parts; oxalic acid 3 parts, citric acid 4 parts, sodium citrate 4.5 parts; polyvinyl alcohol 2 parts, plasticizer 2 parts, ABS antitack agent 1.5 parts.
Embodiment 6
Raw material: anion surfactant 7 parts, nonionic surfactant 4 parts, dodecylbenzene sodium sulfonate 12 parts, sulfonic acid 5 parts; ethylenediaminetetraacetic acid 2 parts, propandiol butyl ether 5 parts, Polianthes tuberosa L. 10 parts, Herba Menthae 5 parts; jasmine 8 parts, Flos Caryophylli 1 part, Flos Lonicerae 10 parts, 5 parts of morning glory; hydrogen peroxide 10 parts, SODIUM PERCARBONATE 1 part, pyrovinic acid 10 parts; oxalic acid 2 parts, citric acid 6 parts, sodium citrate 3 parts; polyvinyl alcohol 3 parts, plasticizer 1 part, ABS antitack agent 2 parts.
The Closestool cleanser made by above example 1-6, is given using other hardly of same community respectively, carries out Comparative result after the week, the user using the present invention shows, after using, the air of toilet is the most pure and fresh, simultaneously mosquito is not had to occur yet, flush toilets the cleanest.In summary, environmental pollution of the present invention is little, corrosivity is little, fragrant odour little to water pollution can improve the air quality of toilet, mosquito dispersing, be suitable for promoting.
The foregoing is only explanation embodiments of the present invention; be not limited to the present invention, for a person skilled in the art, all within the spirit and principles in the present invention; the any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.

Claims (3)

1. a novel environment friendly Closestool cleanser, it is characterized in that: it is mainly composed of the following raw materials by weight: anion surfactant 5-10 part, nonionic surfactant 4-6 part, dodecylbenzene sodium sulfonate 6-12 part, sulfonic acid 5-10 part, ethylenediaminetetraacetic acid 1-2 part, propandiol butyl ether 5-7 part, Polianthes tuberosa L. 5-10 part, Herba Menthae 5-10 part, jasmine 2-8 part, Flos Caryophylli 1-4 part, Flos Lonicerae 5-10 part, morning glory 5-10 part, hydrogen peroxide 6-10 part, SODIUM PERCARBONATE 1-2 part, pyrovinic acid 6-10 part, oxalic acid 2-4 part, citric acid 3-6 part, sodium citrate 3-6 part, polyvinyl alcohol 1-3 part, plasticizer 1-3 part, ABS antitack agent 1-2 part.
A kind of novel environment friendly Closestool cleanser, it is characterised in that: nonionic surfactant is polyoxyethylene ether, cocoanut fatty acid diethanolamide, NPE.
A kind of novel environment friendly Closestool cleanser, it is characterised in that: described anion surfactant is aliphatic alcohol polyethenoxy.
CN201610313936.9A 2016-05-13 2016-05-13 Novel environment-friendly closestool detergent Pending CN105969540A (en)

Priority Applications (1)

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CN201610313936.9A CN105969540A (en) 2016-05-13 2016-05-13 Novel environment-friendly closestool detergent

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106753863A (en) * 2016-11-24 2017-05-31 新时代健康产业(集团)有限公司 A kind of cleaning agent suitable for toilet and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101372649A (en) * 2008-09-24 2009-02-25 北京洛娃日化有限公司 Acidic bathroom detergent
CN102559399A (en) * 2011-12-16 2012-07-11 张家港市仁达化工有限公司 Acidic cleaning composition
CN105542998A (en) * 2015-12-15 2016-05-04 青岛拓联信息技术有限公司 Highly-efficient toilet cleaning agent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101372649A (en) * 2008-09-24 2009-02-25 北京洛娃日化有限公司 Acidic bathroom detergent
CN102559399A (en) * 2011-12-16 2012-07-11 张家港市仁达化工有限公司 Acidic cleaning composition
CN105542998A (en) * 2015-12-15 2016-05-04 青岛拓联信息技术有限公司 Highly-efficient toilet cleaning agent

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
崔璐娟、雷洪、何自强: "《精细化学品化学及应用研究》", 31 July 2015, 中国水利水电出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106753863A (en) * 2016-11-24 2017-05-31 新时代健康产业(集团)有限公司 A kind of cleaning agent suitable for toilet and preparation method thereof

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Application publication date: 20160928