CN106752179A - A kind of fire resistant anticorrosive tubing and preparation method thereof - Google Patents
A kind of fire resistant anticorrosive tubing and preparation method thereof Download PDFInfo
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- CN106752179A CN106752179A CN201611146354.2A CN201611146354A CN106752179A CN 106752179 A CN106752179 A CN 106752179A CN 201611146354 A CN201611146354 A CN 201611146354A CN 106752179 A CN106752179 A CN 106752179A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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Abstract
The invention discloses a kind of fire resistant anticorrosive tubing, include following components in the first component according to the mass fraction：Modifying epoxy resin by organosilicon：22 28 parts, pigment：18 20 parts, filler：11 14 parts, plasticizer：79 parts, Masterbatch：38 parts, butylene：13 18 parts, stabilizer：9 11 parts, antioxidant：6 11 parts, silicon carbide micro-powder：7 12 parts, fluorographite：46 parts, methyl methacrylate：38 42 parts；Include following components in the second component according to the mass fraction：1 butanol：37 parts, polypropylene carbonate fat：8 12 parts, 3 butanediols：25 parts, epoxy resin：12 17 parts, activated carbon：79 parts, dispersant：9 12 parts, coalescents：18 22 parts, defoamer：47 parts, butadiene-styrene rubber：12 17 parts, toluene：8 11 parts, water：30 35 parts, the present invention not only increases operating efficiency, reduces scrappage, and simplify production stage.
Description
Technical field
The present invention relates to tubing technical field, a kind of fire resistant anticorrosive tubing and its preparation side are particularly related to
Method.
Background technology
During goods transportation, tubing is the important component of goods transportation, prior art to warehouse logisticses industry
In, tubing is particularly easy to be damaged in an environment of high temperature, and the learies of device are improved, and pollute environment, and long-term use is held
The corrosion and breaking-up of tubing are easily caused, to improve operating efficiency, reduces cost, the present invention proposes a kind of fire resistant anticorrosive
Tubing and preparation method thereof.
The content of the invention
The technical problems to be solved by the invention are the shortcomings for overcoming prior art, there is provided a kind of fire resistant anticorrosive pipe
Material, including metal pipe material, metal pipe material outer surface are coated with one layer of fire resistant anticorrosive paint, and coating is pressed by first and second liang of components
First：Second=4:3 ratio is composited, first and second in terms of mass fraction comprising following components：
Include following components in first component according to the mass fraction：Modifying epoxy resin by organosilicon：22-28 parts, pigment：18-20 parts,
Filler：11-14 parts, plasticizer：7-9 parts, Masterbatch：3-8 parts, butylene：13-18 parts, stabilizer：9-11 parts, antioxidant：6-11
Part, silicon carbide micro-powder：7-12 parts, fluorographite：4-6 parts, methyl methacrylate：38-42 parts；
Include following components in second component according to the mass fraction：N-butyl alcohol：3-7 parts, polypropylene carbonate fat：8-12 parts, 3- fourths two
Alcohol：2-5 parts, epoxy resin：12-17 parts, activated carbon：7-9 parts, dispersant：9-12 parts, coalescents：18-22 parts, defoamer：
4-7 parts, butadiene-styrene rubber：12-17 parts, toluene：8-11 parts, water：30-35 parts；
Pigment is the one kind in titanium dioxide, iron oxide red, carbon black, barium sulfate or chrome oxide green；Filler is glass flake；Plasticizer
It is one or more in di-sec-octyl phthalate, dibutyl phthalate or diisononyl phthalate；Stabilization
Agent is the one kind in CH4O2 calcium zinc stabilizers, Dythal or barium stearate；Antioxidant be antioxidant 1076 and
The mixture of antioxidant 1010；Dispersant is the one kind in sodium tripolyphosphate, sodium tetrapolyphosphate or calgon；Coalescents
It is the one kind in ethylene glycol ethyl ether, butyl glycol ether, ethylene glycol or propane diols；Defoamer is in organosilicon, polyethers or acid amides
One or more.
The technical scheme that further limits of the invention is：
Foregoing fire resistant anticorrosive tubing, metal pipe material outer surface is coated with one layer of fire resistant anticorrosive paint, and coating is by first
The component of second two presses first：Second=4:3 ratio is composited, first and second in terms of mass fraction comprising following components：
Include following components in first component according to the mass fraction：Modifying epoxy resin by organosilicon：22 parts, pigment：18 parts, filler：
11 parts, plasticizer：7 parts, Masterbatch：3 parts, butylene：13 parts, stabilizer：9 parts, antioxidant：6 parts, silicon carbide micro-powder：7 parts, fluorine
Graphite：4 parts, methyl methacrylate：38 parts；
Include following components in second component according to the mass fraction：N-butyl alcohol：3 parts, polypropylene carbonate fat：8 parts, 3- butanediols：2 parts,
Epoxy resin：12 parts, activated carbon：7 parts, dispersant：9 parts, coalescents：18 parts, defoamer：4 parts, butadiene-styrene rubber：12 parts, first
Benzene：8 parts, water：30 parts；
Pigment is the one kind in titanium dioxide, iron oxide red, carbon black, barium sulfate or chrome oxide green；Filler is glass flake；Plasticizer
It is one or more in di-sec-octyl phthalate, dibutyl phthalate or diisononyl phthalate；Stabilization
Agent is the one kind in CH4O2 calcium zinc stabilizers, Dythal or barium stearate；Antioxidant be antioxidant 1076 and
The mixture of antioxidant 1010；Dispersant is the one kind in sodium tripolyphosphate, sodium tetrapolyphosphate or calgon；Coalescents
It is the one kind in ethylene glycol ethyl ether, butyl glycol ether, ethylene glycol or propane diols；Defoamer is in organosilicon, polyethers or acid amides
One or more.
Foregoing fire resistant anticorrosive tubing, metal pipe material outer surface is coated with one layer of fire resistant anticorrosive paint, coating
First is pressed by first and second liang of components：Second=4:3 ratio is composited, first and second in terms of mass fraction comprising following components：
Include following components in first component according to the mass fraction：Modifying epoxy resin by organosilicon：28 parts, pigment：20 parts, filler：
14 parts, plasticizer：9 parts, Masterbatch：8 parts, butylene：18 parts, stabilizer：11 parts, antioxidant：11 parts, silicon carbide micro-powder：12 parts,
Fluorographite：6 parts, methyl methacrylate：42 parts；
Include following components in second component according to the mass fraction：N-butyl alcohol：7 parts, polypropylene carbonate fat：12 parts, 3- butanediols：5 parts,
Epoxy resin：17 parts, activated carbon：9 parts, dispersant：12 parts, coalescents：22 parts, defoamer：7 parts, butadiene-styrene rubber：17 parts,
Toluene：11 parts, water：35 parts；
Pigment is the one kind in titanium dioxide, iron oxide red, carbon black, barium sulfate or chrome oxide green；Filler is glass flake；Plasticizer
It is one or more in di-sec-octyl phthalate, dibutyl phthalate or diisononyl phthalate；Stabilization
Agent is the one kind in CH4O2 calcium zinc stabilizers, Dythal or barium stearate；Antioxidant be antioxidant 1076 and
The mixture of antioxidant 1010；Dispersant is the one kind in sodium tripolyphosphate, sodium tetrapolyphosphate or calgon；Coalescents
It is the one kind in ethylene glycol ethyl ether, butyl glycol ether, ethylene glycol or propane diols；Defoamer is in organosilicon, polyethers or acid amides
One or more.
Foregoing fire resistant anticorrosive tubing and preparation method thereof, the method is comprised the following steps that：
（One）Carried out during modifying epoxy resin by organosilicon, pigment, filler and Masterbatch are added into the reactor with agitator
Stirring, the temperature of reactor is 50-60 DEG C, and mixing speed is 130-145r/min, and butylene, carbonization are sequentially added in whipping process
Silicon powder, fluorographite and methyl methacrylate, continuous heating, when temperature reaches 80-85 DEG C, add stabilizer to stir
Mix, mixing speed is 120-125r/min, is then lowered the temperature, be to add appropriate plasticizer and anti-when temperature drops to 20-25 DEG C
Oxygen agent adjusts its stickiness, and the first component being filtrated to get in fire resistant anticorrosive paint is stand-by；
（Two）It is stirred during n-butyl alcohol, polypropylene carbonate fat, 3- butanediols and epoxy resin are added into mixer, stirs 25-
30min, mixing speed is 135-145r/min, adds epoxy resin, activated carbon, butadiene-styrene rubber and toluene, stirs 20-
25min, waits and is sufficiently mixed uniform rear addition dispersant and defoamer, and high-speed stirred 15-20min, mixing speed is 300-
320r/min, finally adds appropriate coalescents and water to suitable viscosity, is filtrated to get in fire resistant anticorrosive paint
Component B is stand-by；
（Three）First component is put into reactor and is stirred, component B is slowly added to during stirring, until the first and second components are stirred
Mix uniform, you can obtain fire resistant anticorrosive paint, coating is coated on into tube surfaces can obtain fire resistant anticorrosive tubing.
It is using technical scheme beneficial effect：The fire resistant anticorrosive tubing coating applicability of present invention design
By force, small and low cost is polluted, not only with excellent temperature rise effect, and with stronger heat-resisting quantity, tubing can be made to exist
It is unaffected in the environment of high temperature, the life-span of tubing is increased, scrappage is reduced, and the preparation technology of tubing protective layer is simple
It is single, production cost is reduced as solvent using water in technique, environment is protected, improve operating efficiency.
Specific embodiment
Embodiment 1
The present embodiment provides a kind of fire resistant anticorrosive tubing, including metal pipe material, metal pipe material outer surface be coated with one layer it is resistance to
High-temp anti-corrosion coating, coating presses first by first and second liang of components：Second=4:3 ratio is composited, and first and second are included in terms of mass fraction
Following components：
Include following components in first component according to the mass fraction：Modifying epoxy resin by organosilicon：22 parts, pigment：18 parts, filler：
11 parts, plasticizer：7 parts, Masterbatch：3 parts, butylene：13 parts, stabilizer：9 parts, antioxidant：6 parts, silicon carbide micro-powder：7 parts, fluorine
Graphite：4 parts, methyl methacrylate：38 parts；
Include following components in second component according to the mass fraction：N-butyl alcohol：3 parts, polypropylene carbonate fat：8 parts, 3- butanediols：2 parts,
Epoxy resin：12 parts, activated carbon：7 parts, dispersant：9 parts, coalescents：18 parts, defoamer：4 parts, butadiene-styrene rubber：12 parts, first
Benzene：8 parts, water：30 parts；
Pigment is the one kind in titanium dioxide, iron oxide red, carbon black, barium sulfate or chrome oxide green；Filler is glass flake；Plasticizer
It is one or more in di-sec-octyl phthalate, dibutyl phthalate or diisononyl phthalate；Stabilization
Agent is the one kind in CH4O2 calcium zinc stabilizers, Dythal or barium stearate；Antioxidant be antioxidant 1076 and
The mixture of antioxidant 1010；Dispersant is the one kind in sodium tripolyphosphate, sodium tetrapolyphosphate or calgon；Coalescents
It is the one kind in ethylene glycol ethyl ether, butyl glycol ether, ethylene glycol or propane diols；Defoamer is in organosilicon, polyethers or acid amides
One or more；
Above-mentioned fire resistant anticorrosive tubing and preparation method thereof, comprises the following steps：
（One）Carried out during modifying epoxy resin by organosilicon, pigment, filler and Masterbatch are added into the reactor with agitator
Stirring, the temperature of reactor is 50 DEG C, and mixing speed is 130r/min, sequentially added in whipping process butylene, silicon carbide micro-powder,
Fluorographite and methyl methacrylate, continuous heating, when temperature reaches 80 DEG C, add stabilizer stirring, mixing speed
It is 120r/min, then lowers the temperature, is that the appropriate plasticizer of addition and antioxidant adjust its stickiness, mistake when temperature drops to 20 DEG C
The first component that filter is obtained in fire resistant anticorrosive paint is stand-by；
（Two）It is stirred during n-butyl alcohol, polypropylene carbonate fat, 3- butanediols and epoxy resin are added into mixer, is stirred
25min, mixing speed is 135r/min, adds epoxy resin, activated carbon, butadiene-styrene rubber and toluene, stirs 20min, waits and fills
Divide and dispersant and defoamer are added after being well mixed, high-speed stirred 15min, mixing speed is 300r/min, finally add suitable
The coalescents and water of amount are to suitable viscosity, and the component B being filtrated to get in fire resistant anticorrosive paint is stand-by；
（Three）First component is put into reactor and is stirred, component B is slowly added to during stirring, until the first and second components are stirred
Mix uniform, you can obtain fire resistant anticorrosive paint, coating is coated on into tube surfaces can obtain fire resistant anticorrosive tubing.
Embodiment 2
The present embodiment provides a kind of fire resistant anticorrosive tubing, including metal pipe material, and the metal pipe material outer surface is coated with one
Layer fire resistant anticorrosive paint, the coating presses first by first and second liang of components：Second=4:3 ratio is composited, and described first and second with matter
Amount number meter includes following components：
Include following components in first component according to the mass fraction：Modifying epoxy resin by organosilicon：28 parts, pigment：20 parts, filler：
14 parts, plasticizer：9 parts, Masterbatch：8 parts, butylene：18 parts, stabilizer：11 parts, antioxidant：11 parts, silicon carbide micro-powder：12 parts,
Fluorographite：6 parts, methyl methacrylate：42 parts；
Include following components in second component according to the mass fraction：N-butyl alcohol：7 parts, polypropylene carbonate fat：12 parts, 3- butanediols：5 parts,
Epoxy resin：17 parts, activated carbon：9 parts, dispersant：12 parts, coalescents：22 parts, defoamer：7 parts, butadiene-styrene rubber：17 parts,
Toluene：11 parts, water：35 parts；
Pigment is the one kind in titanium dioxide, iron oxide red, carbon black, barium sulfate or chrome oxide green；Filler is glass flake；Plasticizer
It is one or more in di-sec-octyl phthalate, dibutyl phthalate or diisononyl phthalate；Stabilization
Agent is the one kind in CH4O2 calcium zinc stabilizers, Dythal or barium stearate；Antioxidant be antioxidant 1076 and
The mixture of antioxidant 1010；Dispersant is the one kind in sodium tripolyphosphate, sodium tetrapolyphosphate or calgon；Coalescents
It is the one kind in ethylene glycol ethyl ether, butyl glycol ether, ethylene glycol or propane diols；Defoamer is in organosilicon, polyethers or acid amides
One or more；
Above-mentioned fire resistant anticorrosive tubing and preparation method thereof, comprises the following steps：
（One）Carried out during modifying epoxy resin by organosilicon, pigment, filler and Masterbatch are added into the reactor with agitator
Stirring, the temperature of reactor is 60 DEG C, and mixing speed is 145r/min, sequentially added in whipping process butylene, silicon carbide micro-powder,
Fluorographite and methyl methacrylate, continuous heating, when temperature reaches 85 DEG C, add stabilizer stirring, mixing speed
It is 125r/min, then lowers the temperature, is that the appropriate plasticizer of addition and antioxidant adjust its stickiness, mistake when temperature drops to 25 DEG C
The first component that filter is obtained in fire resistant anticorrosive paint is stand-by；
（Two）It is stirred during n-butyl alcohol, polypropylene carbonate fat, 3- butanediols and epoxy resin are added into mixer, is stirred
30min, mixing speed is 145r/min, adds epoxy resin, activated carbon, butadiene-styrene rubber and toluene, stirs 25min, waits and fills
Divide and dispersant and defoamer are added after being well mixed, high-speed stirred 20min, mixing speed is 320r/min, finally add suitable
The coalescents and water of amount are to suitable viscosity, and the component B being filtrated to get in fire resistant anticorrosive paint is stand-by；
（Three）First component is put into reactor and is stirred, component B is slowly added to during stirring, until the first and second components are stirred
Mix uniform, you can obtain fire resistant anticorrosive paint, coating is coated on into tube surfaces can obtain fire resistant anticorrosive tubing.
Embodiment 3
The present embodiment provides a kind of fire resistant anticorrosive tubing, including metal pipe material, metal pipe material outer surface be coated with one layer it is resistance to
High-temp anti-corrosion coating, coating presses first by first and second liang of components：Second=4:3 ratio is composited, and first and second are included in terms of mass fraction
Following components：
Include following components in first component according to the mass fraction：Modifying epoxy resin by organosilicon：25 parts, pigment：19 parts, filler：
12 parts, plasticizer：8 parts, Masterbatch：5 parts, butylene：15 parts, stabilizer：10 parts, antioxidant：8 parts, silicon carbide micro-powder：10 parts,
Fluorographite：5 parts, methyl methacrylate：40 parts；
Include following components in second component according to the mass fraction：N-butyl alcohol：5 parts, polypropylene carbonate fat：10 parts, 3- butanediols：3 parts,
Epoxy resin：15 parts, activated carbon：8 parts, dispersant：10 parts, coalescents：20 parts, defoamer：5 parts, butadiene-styrene rubber：15 parts,
Toluene：9 parts, water：32 parts；
Pigment is the one kind in titanium dioxide, iron oxide red, carbon black, barium sulfate or chrome oxide green；Filler is glass flake；Plasticizer
It is one or more in di-sec-octyl phthalate, dibutyl phthalate or diisononyl phthalate；Stabilization
Agent is the one kind in CH4O2 calcium zinc stabilizers, Dythal or barium stearate；Antioxidant be antioxidant 1076 and
The mixture of antioxidant 1010；Dispersant is the one kind in sodium tripolyphosphate, sodium tetrapolyphosphate or calgon；Coalescents
It is the one kind in ethylene glycol ethyl ether, butyl glycol ether, ethylene glycol or propane diols；Defoamer is in organosilicon, polyethers or acid amides
One or more；
Above-mentioned fire resistant anticorrosive tubing and preparation method thereof, comprises the following steps：
（One）Carried out during modifying epoxy resin by organosilicon, pigment, filler and Masterbatch are added into the reactor with agitator
Stirring, the temperature of reactor is 55 DEG C, and mixing speed is 140r/min, sequentially added in whipping process butylene, silicon carbide micro-powder,
Fluorographite and methyl methacrylate, continuous heating, when temperature reaches 83 DEG C, add stabilizer stirring, mixing speed
It is 123r/min, then lowers the temperature, is that the appropriate plasticizer of addition and antioxidant adjust its stickiness, mistake when temperature drops to 23 DEG C
The first component that filter is obtained in fire resistant anticorrosive paint is stand-by；
（Two）It is stirred during n-butyl alcohol, polypropylene carbonate fat, 3- butanediols and epoxy resin are added into mixer, is stirred
28min, mixing speed is 140r/min, adds epoxy resin, activated carbon, butadiene-styrene rubber and toluene, stirs 23min, waits and fills
Divide and dispersant and defoamer are added after being well mixed, high-speed stirred 18min, mixing speed is 310r/min, finally add suitable
The coalescents and water of amount are to suitable viscosity, and the component B being filtrated to get in fire resistant anticorrosive paint is stand-by；
（Three）First component is put into reactor and is stirred, component B is slowly added to during stirring, until the first and second components are stirred
Mix uniform, you can obtain fire resistant anticorrosive paint, coating is coated on into tube surfaces can obtain fire resistant anticorrosive tubing.
In addition to the implementation, the present invention can also have other embodiment.All use equivalents or equivalent transformation shape
Into technical scheme, all fall within the protection domain of application claims.
Claims (4)
1. a kind of fire resistant anticorrosive tubing, including metal pipe material, it is characterised in that：The metal pipe material outer surface is coated with one
Layer fire resistant anticorrosive paint, the coating presses first by first and second liang of components：Second=4:3 ratio is composited, and described first and second with matter
Amount number meter includes following components：
Include following components in the first component according to the mass fraction：Modifying epoxy resin by organosilicon：22-28 parts, pigment：18-
20 parts, filler：11-14 parts, plasticizer：7-9 parts, Masterbatch：3-8 parts, butylene：13-18 parts, stabilizer：9-11 parts, antioxygen
Agent：6-11 parts, silicon carbide micro-powder：7-12 parts, fluorographite：4-6 parts, methyl methacrylate：38-42 parts；
Include following components in the second component according to the mass fraction：N-butyl alcohol：3-7 parts, polypropylene carbonate fat：8-12 parts, 3- fourths
Glycol：2-5 parts, epoxy resin：12-17 parts, activated carbon：7-9 parts, dispersant：9-12 parts, coalescents：18-22 parts, froth breaking
Agent：4-7 parts, butadiene-styrene rubber：12-17 parts, toluene：8-11 parts, water：30-35 parts；
Described pigment is the one kind in titanium dioxide, iron oxide red, carbon black, barium sulfate or chrome oxide green；Described filler is glass
Glass scale；Described plasticizer is di-sec-octyl phthalate, dibutyl phthalate or diisononyl phthalate
In one or more；Described stabilizer is in CH4O2 calcium zinc stabilizers, Dythal or barium stearate
It is a kind of；Described antioxidant is the mixture of antioxidant 1076 and antioxidant 1010；Described dispersant is sodium tripolyphosphate, four
One kind in polyphosphate sodium or calgon；Described coalescents are ethylene glycol ethyl ether, butyl glycol ether, ethylene glycol or third
One kind in glycol；Described defoamer is one or more in organosilicon, polyethers or acid amides.
2. fire resistant anticorrosive tubing according to claim 1, it is characterised in that：The metal pipe material outer surface is coated with
One layer of fire resistant anticorrosive paint, the coating presses first by first and second liang of components：Second=4:3 ratio is composited, described first and second with
Mass fraction meter includes following components：
Include following components in the first component according to the mass fraction：Modifying epoxy resin by organosilicon：22 parts, pigment：18 parts, fill out
Material：11 parts, plasticizer：7 parts, Masterbatch：3 parts, butylene：13 parts, stabilizer：9 parts, antioxidant：6 parts, silicon carbide micro-powder：7 parts,
Fluorographite：4 parts, methyl methacrylate：38 parts；
Include following components in the second component according to the mass fraction：N-butyl alcohol：3 parts, polypropylene carbonate fat：8 parts, 3- butanediols：2
Part, epoxy resin：12 parts, activated carbon：7 parts, dispersant：9 parts, coalescents：18 parts, defoamer：4 parts, butadiene-styrene rubber：12
Part, toluene：8 parts, water：30 parts；
Described pigment is the one kind in titanium dioxide, iron oxide red, carbon black, barium sulfate or chrome oxide green；Described filler is glass
Glass scale；Described plasticizer is di-sec-octyl phthalate, dibutyl phthalate or diisononyl phthalate
In one or more；Described stabilizer is in CH4O2 calcium zinc stabilizers, Dythal or barium stearate
It is a kind of；Described antioxidant is the mixture of antioxidant 1076 and antioxidant 1010；Described dispersant is sodium tripolyphosphate, four
One kind in polyphosphate sodium or calgon；Described coalescents are ethylene glycol ethyl ether, butyl glycol ether, ethylene glycol or third
One kind in glycol；Described defoamer is one or more in organosilicon, polyethers or acid amides.
3. fire resistant anticorrosive tubing according to claim 1, it is characterised in that：The metal pipe material outer surface is coated with
One layer of fire resistant anticorrosive paint, the coating presses first by first and second liang of components：Second=4:3 ratio is composited, described first and second with
Mass fraction meter includes following components：
Include following components in the first component according to the mass fraction：Modifying epoxy resin by organosilicon：28 parts, pigment：20 parts, fill out
Material：14 parts, plasticizer：9 parts, Masterbatch：8 parts, butylene：18 parts, stabilizer：11 parts, antioxidant：11 parts, silicon carbide micro-powder：12
Part, fluorographite：6 parts, methyl methacrylate：42 parts；
Include following components in the second component according to the mass fraction：N-butyl alcohol：7 parts, polypropylene carbonate fat：12 parts, 3- butanediols：
5 parts, epoxy resin：17 parts, activated carbon：9 parts, dispersant：12 parts, coalescents：22 parts, defoamer：7 parts, butadiene-styrene rubber：17
Part, toluene：11 parts, water：35 parts；
Described pigment is the one kind in titanium dioxide, iron oxide red, carbon black, barium sulfate or chrome oxide green；Described filler is glass
Glass scale；Described plasticizer is di-sec-octyl phthalate, dibutyl phthalate or diisononyl phthalate
In one or more；Described stabilizer is in CH4O2 calcium zinc stabilizers, Dythal or barium stearate
It is a kind of；Described antioxidant is the mixture of antioxidant 1076 and antioxidant 1010；Described dispersant is sodium tripolyphosphate, four
One kind in polyphosphate sodium or calgon；Described coalescents are ethylene glycol ethyl ether, butyl glycol ether, ethylene glycol or third
One kind in glycol；Described defoamer is one or more in organosilicon, polyethers or acid amides.
4. a kind of preparation method of fire resistant anticorrosive tubing, the preparation method is provided with any claim in claim 1-3
Described fire resistant anticorrosive tubing, it is characterised in that the preparation method is comprised the following steps：
（One）Carried out during modifying epoxy resin by organosilicon, pigment, filler and Masterbatch are added into the reactor with agitator
Stirring, the temperature of reactor is 50-60 DEG C, and mixing speed is 130-145r/min, and butylene, carbonization are sequentially added in whipping process
Silicon powder, fluorographite and methyl methacrylate, continuous heating, when temperature reaches 80-85 DEG C, add stabilizer to stir
Mix, mixing speed is 120-125r/min, is then lowered the temperature, be to add appropriate plasticizer and anti-when temperature drops to 20-25 DEG C
Oxygen agent adjusts its stickiness, and the first component being filtrated to get in fire resistant anticorrosive paint is stand-by；
（Two）It is stirred during n-butyl alcohol, polypropylene carbonate fat, 3- butanediols and epoxy resin are added into mixer, stirs 25-
30min, mixing speed is 135-145r/min, adds epoxy resin, activated carbon, butadiene-styrene rubber and toluene, stirs 20-
25min, waits and is sufficiently mixed uniform rear addition dispersant and defoamer, and high-speed stirred 15-20min, mixing speed is 300-
320r/min, finally adds appropriate coalescents and water to suitable viscosity, is filtrated to get in fire resistant anticorrosive paint
Component B is stand-by；
（Three）First component is put into reactor and is stirred, component B is slowly added to during stirring, until the first and second components are stirred
Mix uniform, you can obtain fire resistant anticorrosive paint, coating is coated on into tube surfaces can obtain fire resistant anticorrosive tubing.
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| CN201611146354.2A CN106752179A (en) | 2016-12-13 | 2016-12-13 | A kind of fire resistant anticorrosive tubing and preparation method thereof |
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| CN201611146354.2A CN106752179A (en) | 2016-12-13 | 2016-12-13 | A kind of fire resistant anticorrosive tubing and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109203527A (en) * | 2018-10-22 | 2019-01-15 | 安徽青润精密科技有限公司 | A kind of preparation method of corrosion-resistant water pipe |
| WO2019109380A1 (en) * | 2017-12-06 | 2019-06-13 | 唐建明 | Compressor for refrigeration system |
| CN111995068A (en) * | 2020-08-28 | 2020-11-27 | 南京传业环保科技有限公司 | Environment-friendly nontoxic sewage treatment agent and preparation method thereof |
| CN112354305A (en) * | 2020-10-30 | 2021-02-12 | 南京捷立德环保科技有限公司 | Spraying device for dust removal |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104231857A (en) * | 2014-09-18 | 2014-12-24 | 江苏海晟涂料有限公司 | Composite epoxy anticorrosive paint and preparation method thereof |
| CN104479488A (en) * | 2014-12-27 | 2015-04-01 | 李康 | Preparation method of corrosion-resistant latex paint |
| CN105838188A (en) * | 2016-04-28 | 2016-08-10 | 江苏金源腾峰换热设备有限公司 | Treating process of high-temperature-resistant tubular product for waste-heat utilization device |
-
2016
- 2016-12-13 CN CN201611146354.2A patent/CN106752179A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104231857A (en) * | 2014-09-18 | 2014-12-24 | 江苏海晟涂料有限公司 | Composite epoxy anticorrosive paint and preparation method thereof |
| CN104479488A (en) * | 2014-12-27 | 2015-04-01 | 李康 | Preparation method of corrosion-resistant latex paint |
| CN105838188A (en) * | 2016-04-28 | 2016-08-10 | 江苏金源腾峰换热设备有限公司 | Treating process of high-temperature-resistant tubular product for waste-heat utilization device |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019109380A1 (en) * | 2017-12-06 | 2019-06-13 | 唐建明 | Compressor for refrigeration system |
| CN109203527A (en) * | 2018-10-22 | 2019-01-15 | 安徽青润精密科技有限公司 | A kind of preparation method of corrosion-resistant water pipe |
| CN111995068A (en) * | 2020-08-28 | 2020-11-27 | 南京传业环保科技有限公司 | Environment-friendly nontoxic sewage treatment agent and preparation method thereof |
| WO2022041418A1 (en) * | 2020-08-28 | 2022-03-03 | 南京传业环保科技有限公司 | Environment-friendly non-toxic wastewater treatment agent and preparation method therefor |
| CN112354305A (en) * | 2020-10-30 | 2021-02-12 | 南京捷立德环保科技有限公司 | Spraying device for dust removal |
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Application publication date: 20170531 |