CN103214655B - Modified epoxy resin and high-solid anticorrosive coating prepared therewith - Google Patents
Modified epoxy resin and high-solid anticorrosive coating prepared therewith Download PDFInfo
- Publication number
- CN103214655B CN103214655B CN201310100908.5A CN201310100908A CN103214655B CN 103214655 B CN103214655 B CN 103214655B CN 201310100908 A CN201310100908 A CN 201310100908A CN 103214655 B CN103214655 B CN 103214655B
- Authority
- CN
- China
- Prior art keywords
- component
- modified epoxy
- parts
- epoxy resin
- solid anticorrosive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention discloses modified epoxy resin and high-solid anticorrosive coating prepared therewith. The modified epoxy resin is prepared through a reaction of E-44 epoxy resin and a fluorinated acrylic acid mixed monomer, and styrene. The fluorinated acrylic acid mixed monomer is prepared from the raw materials of methyl methacrylate, butyl acrylate and hexafluoro butyl methacrylate. According to the invention, with the novel components and ratio, the prepared modified epoxy resin reaches the technical indicators that: the modified epoxy resin is light-yellow transparent viscose liquid with acid value of 4.6mgKOH/g, epoxy value of 0.03 equivalents/l00g, and viscosity (25 DEG C) of 0.245Pa.s; the resin has excellent performances in the respects such as water resistance, acid and alkali resistance, high and low temperature resistance, corrosion resistance, adhesion strength, and the like. The invention also provides a high-solid anticorrosive coating prepared with the modified epoxy resin and a novel ratio. As a result, the coating has excellent performances in the respects such as water resistance, acid and alkali resistance, high and low temperature resistance, corrosion resistance, adhesion strength, and the like. The coating can be used on different low-altitude aircraft substrates of aluminum alloy, titanium alloy, magnesium alloy, composite materials, and the like.
Description
Technical field
The High-solid anticorrosive paint that the present invention relates to a kind of modified epoxy and prepare with it.
Background technology
Epoxy resin application is very extensive, and due to himself structure, it is corrosion-resistant, thermostability etc. is subject to certain restrictions, and therefore needs to carry out modification to epoxy resin.There are reports to utilize polyester to carry out modification to epoxy resin, such as Chinese invention patent CN101864236 and CN101885831 etc.; Utilizing Acrylic Acid Monomer to carry out graft modification epoxy resin also has some to report, such as Lee is published in " coatings industry " " the protection against corrosion iron oxide red primer preparation and property based on acrylic acid-grafted epoxy resin is studied " of the 42nd volume the 6th phase 1-5 page in 2012 for vertical etc.Existing low flyer ground protective system has the defect that can not be applicable to different low flyer grounds.
Summary of the invention
The object of the invention is to, the High-solid anticorrosive paint a kind of modified epoxy being provided and preparing with it.The modified epoxy that the present invention obtains is superior performance in water-fast, high-low temperature resistant, antiseptic property and sticking power etc.; The High-solid anticorrosive paint of what the present invention utilized above-mentioned modified epoxy to prepare be applicable to different low flyer ground, overcomes existing low flyer ground protective system and there is the defect that can not be applicable to different low flyer grounds.
Technical scheme of the present invention: modified epoxy, the weight proportion of feed composition is as follows, and consumption is weight part;
Epoxy resin 60 ~ 75 parts, perfluoroalkyl acrylate mix monomer 18 ~ 25 parts,
Vinylbenzene 12 ~ 20 parts;
Described perfluoroalkyl acrylate mix monomer comprises following component, in massfraction:
Methacrylic acid 25 ~ 40%, butyl acrylate 25 ~ 40%,
Hexafluorobutyl mathacrylate 25 ~ 40%.
In aforesaid modified epoxy, the weight proportion of feed composition is as follows:
Epoxy resin 65 ~ 70 parts, perfluoroalkyl acrylate mix monomer 20 ~ 22 parts,
Vinylbenzene 15 ~ 18 parts;
Described perfluoroalkyl acrylate mix monomer comprises following component, in massfraction:
Methacrylic acid 30 ~ 36%, butyl acrylate 30 ~ 36%,
Hexafluorobutyl mathacrylate 30 ~ 36%.
In aforesaid modified epoxy, described epoxy resin is E-44 epoxy resin; Described perfluoroalkyl acrylate mix monomer by mass ratio be the methacrylic acid of 1:1:1, butyl acrylate and Hexafluorobutyl mathacrylate form.
Prepare the method for aforesaid modified epoxy, it is: heating E-44 epoxy resin is to 105 ~ 115 DEG C, under agitation drip perfluoroalkyl acrylate mix monomer, after insulation reaction 3 ~ 4h, survey acid number, when acid number is less than 5mgKOH/g, be cooled to about 7O DEG C, add vinylbenzene to dilute, stir evenly rear cooling discharge, obtain modified epoxy.
By High-solid anticorrosive paint prepared by aforesaid modified epoxy, it is made up of component A and B component, and the quality proportioning of component A and B component is 100:20 ~ 40;
Component A presses the raw material preparation of row weight proportion:
Modified epoxy 16 ~ 20 parts, 601-75 epoxy resin 10 ~ 13 parts,
Pigment 24 ~ 30 parts, anti-settling agent 0.1 ~ 0.3 part,
Flow agent 0.05 ~ 0.15 part, filler 8 ~ 10 parts,
Matting agent 3 ~ 4 parts, rust-preventive agent 4 ~ 6 parts,
Defoamer 0.1 ~ 0.2 part, butyl glycol ether 1 ~ 1.5 part,
Toluene 3 ~ 4 parts, dimethylbenzene 18 ~ 21 parts;
B component presses the raw material preparation of row weight proportion:
60 ~ 66 parts, solidifying agent, toluene 19 ~ 22 parts,
Propyl carbinol 4 ~ 6 parts, butyl glycol ether 0.5 ~ 1.5 part,
Dimethylbenzene 4 ~ 6 parts, siccative 2 ~ 4 parts.
In aforesaid High-solid anticorrosive paint, the quality proportioning of component A and B component is 100:25 ~ 35.
In aforesaid High-solid anticorrosive paint, the quality proportioning of component A and B component is 100:33.
In aforesaid High-solid anticorrosive paint, described pigment is made up of titanium dioxide; Described anti-settling agent is wilkinite; Described filler is made up of talcum powder and barium sulfate; Described matting agent is flatting silica.
In aforesaid High-solid anticorrosive paint, described pigment is made up of by the mass ratio of 1:0.8 ~ 1.2 titanium dioxide TR-33 and R902+ titanium dioxide; Described anti-settling agent is wilkinite 938; Described flow agent is MAA flow agent; Described filler is made up of 1:0.8 ~ 1.2 in mass ratio superfine talcum powder CMS-666 and barium sulfate; Described matting agent is C906 flatting silica; Described rust-preventive agent is phosphorus zinc chromate; Described defoamer is 5400 defoamers; Described solidifying agent is solidifying agent 2015; Described siccative is siccative T-30.
Prepare the method for aforesaid High-solid anticorrosive paint, it is characterized in that, it comprises following three steps:
A, first modified epoxy, 601-75 epoxy resin and dimethylbenzene to be mixed, under agitation slowly add anti-settling agent, high speed dispersion is about 5min to homogeneous, under agitation adds pigment and defoamer, stir 15min, then add filler, stir 15min, more under agitation add matting agent, flow agent, rust-preventive agent, butyl glycol ether and toluene, stir 20min, grind with sand milling after being uniformly dispersed and be less than 40 μm to fineness, cross and filter abrasive sand, filter and package and obtain component A;
B, by solidifying agent, toluene, propyl carbinol, butyl glycol ether, dimethylbenzene and siccative mix, stir 20min, be uniformly dispersed, filter and package and obtain B component;
C, by component A and B component mixing, after stirring, namely obtain High-solid anticorrosive paint.
Compared with prior art, the present invention is by adopting new component and proportioning, obtained modified epoxy reaches following technical indicator: pale yellow transparent thick liquid, acid number 4.6mgKOH/g, oxirane value 0.03 equivalent/l00g, viscosity (when 25 ° of C) is 0.245Pas, superior performance in water-fast, resistance to acids and bases, high-low temperature resistant, antiseptic property and sticking power etc.The High-solid anticorrosive paint that the present invention adopts above-mentioned modified epoxy and new proportioning to make, test-results shows, superior performance in water-fast, resistance to acids and bases, high-low temperature resistant, antiseptic property and sticking power etc., can be used for the low flyer ground that aluminium alloy, titanium alloy, magnesium alloy and matrix material etc. are different.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated, but not as the foundation limited the present invention.
Embodiment.
Prepare modified epoxy in the steps below:
A, methacrylic acid, butyl acrylate and the Hexafluorobutyl mathacrylate mass ratio by 1:1:1 to be mixed, obtained perfluoroalkyl acrylate mix monomer.
B, get 67.65 parts of E-44 epoxy resin, heat to 110 DEG C, under agitation drip 21.18 parts of perfluoroalkyl acrylate mix monomers, after insulation reaction 4h, survey acid number, when acid number is less than 5mgKOH/g, be cooled to 7O DEG C, add 16.47 parts of vinylbenzene to dilute, stir evenly rear cooling discharge, obtained modified epoxy.
The performance index of obtained modified epoxy are as follows: outward appearance pale yellow transparent thick liquid, acid number is 4.6mgKOH/g, and oxirane value is 0.03 equivalent/l00g, and viscosity (when 25 ° of C) is 0.245Pas.
Follow these steps to prepare High-solid anticorrosive paint:
A, first get 18.2 parts of modified epoxies, the 601-75 epoxy resin of 11.29 parts and 19.45 parts of dimethylbenzene, after mixing, under agitation slowly add 0.2 part of wilkinite 938, high speed dispersion is about 5min to homogeneous, under agitation adds 14.88 parts of TR-33 titanium dioxides, 14.88 parts of R902
+titanium dioxide and 0.13 part of 5400 defoamer, stir 15min, then 4.92 parts of talcum powder 666 and 4.99 parts of barium sulfate are added, stir 15min, under agitation add 3.46 parts of C906 flatting silicas, 0.09 part of MAA flow agent, 4.99 parts of phosphorus zinc chromates, 1.32 parts of butyl glycol ethers and 3.29 parts of toluene again, stir 20min, grind to fineness with sand milling after being uniformly dispersed and be less than 40 μm, cross and filter abrasive sand, filter and package and obtain component A.
B, get 64.09 parts of solidifying agent, 2015,21.12 parts of toluene, 5.92 parts of propyl carbinols, 0.99 part of butyl glycol ether, 4.93 parts of dimethylbenzene and 2.96 parts of siccative T-30, after mixing, stir 20min, be uniformly dispersed, filter and package and obtain B component.
C, get component A and B component that mass ratio is 100:33, after mixing, stir, obtained High-solid anticorrosive paint.
Above-mentioned 601-75 epoxy resin and E-44 epoxy resin are that Sanmu Group Co., Ltd., Jiangsu produces.
Above-mentioned titanium dioxide TR-33 is that Dongguan City Shuan Li titanium dioxide company limited produces.
Above-mentioned R902+ titanium dioxide Shanghai Xiang Tai Chemical Co., Ltd. produces.
Above-mentioned wilkinite 938 is that Xiamen Ai Kema industrial chemicals company limited produces.
Above-mentioned MAA flow agent is that prosperous titanium digests (China) production.
Above-mentioned superfine talcum powder CMS-666 is that Heshan chemical industry (Liaoning) company limited produces.
Above-mentioned barium sulfate be Shanghai jump river titanium white heavy chemicals company limited produce.
Above-mentioned C906 flatting silica is that Shanghai Xin Xin Industry Co., Ltd produces.
Above-mentioned phosphorus zinc chromate is that Lanxi City Xin Rong chemical metallization company limited produces.
Above-mentioned 5400 defoamers are that upper sea cowry reaches the production of wrapping material company limited.
Above-mentioned 2015 solidifying agent are that Shanghai Yao Shan Chemical Co., Ltd. produces.
Above-mentioned siccative T-30 is that Shanghai hundred mattress Chemical Co., Ltd. produces.
Above-mentioned obtained High-solid anticorrosive paint is carried out on aluminium alloy, titanium alloy, magnesium alloy and matrix material examination to be coated with, coating performance is as shown in the table.
Above-mentioned testing data shows: the High-solid anticorrosive paint that the present invention obtains is superior performance in water-fast, high-low temperature resistant, antiseptic property and sticking power etc., can be used for different low flyer grounds.
The generality of the above-mentioned invention to relating in the application describes and the description of its embodiment be should not be understood as to the restriction formed this invention technical scheme.Those skilled in the art's disclosing according to the application, can under the prerequisite without prejudice to involved invention integrant, above-mentioned generality is described or/and the public technology feature in embodiment (comprising embodiment) increases, reduces or combines, forms other the technical scheme belonging to described invention.
Claims (9)
1. the High-solid anticorrosive paint prepared of modified epoxy, it is characterized in that: it is made up of component A and B component, the quality proportioning of component A and B component is 100:20 ~ 40;
Component A presses the raw material preparation of row weight proportion:
B component presses the raw material preparation of row weight proportion:
60 ~ 66 parts, solidifying agent, toluene 19 ~ 22 parts,
Propyl carbinol 4 ~ 6 parts, butyl glycol ether 0.5 ~ 1.5 part,
Dimethylbenzene 4 ~ 6 parts, siccative 2 ~ 4 parts;
The weight proportion of the feed composition of described modified epoxy is as follows, and consumption is weight part;
Epoxy resin 60 ~ 75 parts, perfluoroalkyl acrylate mix monomer 18 ~ 25 parts,
Vinylbenzene 12 ~ 20 parts;
Described perfluoroalkyl acrylate mix monomer comprises following component, in massfraction:
Methacrylic acid 25 ~ 40%, butyl acrylate 25 ~ 40%,
Hexafluorobutyl mathacrylate 25 ~ 40%.
2. the High-solid anticorrosive paint prepared of modified epoxy according to claim 1, it is characterized in that, the weight proportion of the feed composition of described modified epoxy is as follows:
Epoxy resin 65 ~ 70 parts, perfluoroalkyl acrylate mix monomer 20 ~ 22 parts,
Vinylbenzene 15 ~ 18 parts;
Described perfluoroalkyl acrylate mix monomer comprises following component, in massfraction:
Methacrylic acid 30 ~ 36%, butyl acrylate 30 ~ 36%,
Hexafluorobutyl mathacrylate 30 ~ 36%.
3. the High-solid anticorrosive paint prepared of modified epoxy according to claim 1 and 2, is characterized in that: described epoxy resin is E-44 epoxy resin; Described perfluoroalkyl acrylate mix monomer by mass ratio be the methacrylic acid of 1:1:1, butyl acrylate and Hexafluorobutyl mathacrylate form.
4. prepare High-solid anticorrosive paint prepared by the modified epoxy described in claim 1,2 or 3, it is characterized in that, the method of described modified epoxy is: heating ring epoxy resins, to 105 ~ 115 DEG C, under agitation drips perfluoroalkyl acrylate mix monomer, after insulation reaction 3 ~ 4h, survey acid number, when acid number is less than 5mgKOH/g, be cooled to about 7O DEG C, add vinylbenzene and dilute, stir evenly rear cooling discharge, obtain modified epoxy.
5. High-solid anticorrosive paint according to claim 1, is characterized in that: the quality proportioning of component A and B component is 100:25 ~ 35.
6. High-solid anticorrosive paint according to claim 5, is characterized in that: the quality proportioning of component A and B component is 100:33.
7. the High-solid anticorrosive paint according to claim 1,5 or 6, is characterized in that: described pigment is made up of titanium dioxide; Described anti-settling agent is wilkinite; Described filler is made up of talcum powder and barium sulfate; Described matting agent is flatting silica.
8. High-solid anticorrosive paint according to claim 7, is characterized in that: described pigment is made up of by the mass ratio of 1:0.8 ~ 1.2 titanium dioxide TR-33 and R902+ titanium dioxide; Described anti-settling agent is wilkinite 938; Described flow agent is MAA flow agent; Described filler is made up of 1:0.8 ~ 1.2 in mass ratio superfine talcum powder CMS-666 and barium sulfate; Described matting agent is C906 flatting silica; Described rust-preventive agent is phosphorus zinc chromate; Described defoamer is 5400 defoamers; Described solidifying agent is solidifying agent 2015; Described siccative is siccative T-30.
9. prepare the method for High-solid anticorrosive paint as claimed in claim 7, it is characterized in that, it comprises following three steps:
A, first modified epoxy, 601-75 epoxy resin and dimethylbenzene to be mixed, under agitation slowly add anti-settling agent, high speed dispersion 5min, to homogeneous, under agitation adds pigment and defoamer, stir 15min, then add filler, stir 15min, more under agitation add matting agent, flow agent, rust-preventive agent, butyl glycol ether and toluene, stir 20min, grind with sand milling after being uniformly dispersed and be less than 40 μm to fineness, cross and filter abrasive sand, filter and package and obtain component A;
B, by solidifying agent, toluene, propyl carbinol, butyl glycol ether, dimethylbenzene and siccative mix, stir 20min, be uniformly dispersed, filter and package and obtain B component;
C, by component A and B component mixing, after stirring, namely obtain High-solid anticorrosive paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310100908.5A CN103214655B (en) | 2013-03-27 | 2013-03-27 | Modified epoxy resin and high-solid anticorrosive coating prepared therewith |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310100908.5A CN103214655B (en) | 2013-03-27 | 2013-03-27 | Modified epoxy resin and high-solid anticorrosive coating prepared therewith |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103214655A CN103214655A (en) | 2013-07-24 |
| CN103214655B true CN103214655B (en) | 2015-01-07 |
Family
ID=48812850
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310100908.5A Active CN103214655B (en) | 2013-03-27 | 2013-03-27 | Modified epoxy resin and high-solid anticorrosive coating prepared therewith |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103214655B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104327674B (en) * | 2014-11-18 | 2016-06-08 | 江苏科技大学 | The epoxy-resin coating composite of a kind of directly application on rust layer |
| CN104513588A (en) * | 2014-12-18 | 2015-04-15 | 河北科莱冷暖工程有限公司 | Nitrogen-containing flame retardant epoxy resin abrasion proof and water proof coating |
| CN107163645A (en) * | 2017-06-14 | 2017-09-15 | 合肥市旺友门窗有限公司 | A kind of aluminum alloy doors and windows wear-resistant paint and preparation method thereof |
| CN108031404A (en) * | 2017-11-25 | 2018-05-15 | 赖邦德 | surfactant and its preparation method and application |
| CN109749054B (en) * | 2018-12-13 | 2021-07-16 | 珠海宏昌电子材料有限公司 | Epoxy resin for extinction powder coating and preparation method and application thereof |
| CN112341905A (en) * | 2020-11-26 | 2021-02-09 | 沈阳化工研究院有限公司 | High-solid-content rust-conversion acid-resistant anticorrosive paint and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1380370A (en) * | 2002-03-25 | 2002-11-20 | 葛明槽 | Fire-resistant powder coating material and its production process |
| CN101125995A (en) * | 2007-09-28 | 2008-02-20 | 王新虎 | Screw thread adhesion abrasion resisting self-lubricating coating and preparation method thereof |
| CN102732124A (en) * | 2012-06-04 | 2012-10-17 | 上海大学 | Fluorine-containing heavy-duty anticorrosive coating and its application |
-
2013
- 2013-03-27 CN CN201310100908.5A patent/CN103214655B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN103214655A (en) | 2013-07-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103214655B (en) | Modified epoxy resin and high-solid anticorrosive coating prepared therewith | |
| CN103059304B (en) | Preparation and application of long-acting anticorrosion temperature-resistant coating | |
| CN104140732B (en) | A kind of water paint of high salt fog high durable and preparation method thereof | |
| CN104231857B (en) | A kind of composite epoxy anticorrosive paint and preparation method thereof | |
| CN102898926B (en) | Coating of a kind of high temperature resistant, wear-resisting, heavy antisepsis and preparation method thereof | |
| CN105838192B (en) | A kind of epoxy polysiloxane coating and preparation method | |
| CN104109450A (en) | Graphene anticorrosive powder paint and preparation method thereof | |
| CN102702899B (en) | Water-based modified pure acrylic acid anticorrosive paint | |
| CN104371541A (en) | High-temperature primer for metro wheels and preparation method of high-temperature primer | |
| CN105713481A (en) | Graphene-modified epoxy zinc-rich primer and preparation method thereof | |
| CN103865380B (en) | A kind of insulation compound and electrical sheet material and preparation method thereof | |
| CN107603472A (en) | A kind of fire resistant anticorrosive hood and preparation method thereof | |
| CN105237693B (en) | Hybrid inorganic-organic silicon dioxide modified acrylic resin and its coating | |
| CN106085076A (en) | A kind of low temperature resistant cracking resistance city copper casted sculpture coating and preparation method thereof | |
| CN103131290A (en) | Water-based metal baking paint and preparation method thereof | |
| CN105385311A (en) | Environmentally friendly high temperature resistant anticorrosion paint and preparation method thereof | |
| CN104530913A (en) | Environment-friendly solvent-free epoxy ultrathin marking paint and preparing method thereof | |
| CN103342939A (en) | Water-soluble epoxy ester antirust paint | |
| CN103214917B (en) | Marine corrosion-resistant epoxy aluminum-magnesium-nickel rear earth rich nanometer material and preparation method thereof | |
| CN105219253A (en) | A kind of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint and preparation method thereof | |
| CN108219622A (en) | It is a kind of based on the aluminium alloy of graphene low-density anticorrosive paint and preparation method thereof | |
| CN104327667B (en) | A kind of preparation method for dry and wet transformator solvent-free Self-leveling iron core coating varnish | |
| CN109777248A (en) | A kind of water-base epoxy anti-corrosion primer | |
| CN103589329A (en) | Novel insulating paint for ballast and preparation method of insulating paint | |
| CN103254725A (en) | Ocean heavy anti-corrosion epoxy aluminum-nickel-rich nano-coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210421 Address after: No.11, Shengyang Road, Shangma Industrial Park, Wenling Economic Development Zone, Wenzhou, Zhejiang, 317500 Patentee after: ZHEJIANG YUTONG NEW MATERIAL Co.,Ltd. Address before: Room 633, C building, No. 525 Xixi Road, Xihu District, Zhejiang, Hangzhou 310013, China Patentee before: HANGZHOU RIYAO TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| CP02 | Change in the address of a patent holder |
Address after: No.11, Shengyang Road, Shangma Industrial Park, Wenling Economic Development Zone, Wenling City, Taizhou City, Zhejiang Province, 317500 Patentee after: ZHEJIANG YUTONG NEW MATERIAL Co.,Ltd. Address before: No.11, Shengyang Road, Shangma Industrial Park, Wenling Economic Development Zone, Wenzhou, Zhejiang, 317500 Patentee before: ZHEJIANG YUTONG NEW MATERIAL Co.,Ltd. |
|
| CP02 | Change in the address of a patent holder |