CN1380370A - Fire-resistant powder coating material and its production process - Google Patents
Fire-resistant powder coating material and its production process Download PDFInfo
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- CN1380370A CN1380370A CN 02112798 CN02112798A CN1380370A CN 1380370 A CN1380370 A CN 1380370A CN 02112798 CN02112798 CN 02112798 CN 02112798 A CN02112798 A CN 02112798A CN 1380370 A CN1380370 A CN 1380370A
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Abstract
The present invention relates to a decorative powder coating. It can be divided into two kinds of non-expansive fire-resisting powder coating and expansive fire-resisting powder coating. Its production process includes the following steps: heating proper quantity of polyester resin and/or epoxy resin to glass state temp., adding fire-resisting agent and/or carbon-forming agent, catalyst and foaming agent, stirring, cooling and pulverizing, mixing them with residual polyester resin and/or epoxy resin and other materials, stirring them, extruding, cooling, tabletting, pulverizing and sieving so as to obtain the invented products.
Description
Technical field
The appearance that the present invention relates to products such as a kind of refrigerator, air-conditioning, file cabinet, crane span structure, bus duct, ventilator trunk applies the decorative powder coatings of usefulness.
Background technology
At present, the appearance at products such as refrigerator, air-conditioning, file cabinet, crane span structure, bus duct, ventilator trunks all will apply the decorative powder coatings coating.Existing powder coating mainly contains three kinds, and the one, epoxy polyester mixed type powder paint, it is to be made through mixing, extrude, pulverize, sieving by Resins, epoxy and vibrin and filler; Second kind is polyester type powder paint, and it is made through technology same as described above by vibrin and solidifying agent and filler; The third is the epoxy type powder coating, and it is to be made through above-mentioned same process by Resins, epoxy and solidifying agent and filler.But existing powder coating does not all have fire resistance, and meeting fire can burn, and makes that the fire resistance of these products is relatively poor.
Summary of the invention
Purpose of the present invention is exactly in order to address the above problem, and proposes good fire-proof powdery paint of a kind of fire resistance and production technique thereof.
Technical solution of the present invention:
A kind of unexpansive epoxy polyester mixed type fire-proof powdery paint is characterized in that it is made through heating, mix, extrude, pulverize, sieving by Resins, epoxy, vibrin, auxiliary agent and filler, pigment, fire retardant, and the weight percent of its each composition is:
Resins, epoxy 25-40%
Vibrin 25-40%
Auxiliary agent and filler 10-30%
Pigment 0.5-10%
Fire retardant 0.5-10%.
A kind of unexpansive epoxy type fire-proof powdery paint is characterized in that it is made through heating, mix, extrude, pulverize, sieving by Resins, epoxy, solidifying agent, pigment, auxiliary agent and filler, fire retardant, and the weight percent of its each composition is:
Resins, epoxy 40-60%
Solidifying agent 10-20%
Pigment 0.5-10%
Auxiliary agent and filler 10-30%
Fire retardant 0.5-10%
A kind of unexpansive polyester type fire-proof powdery paint is characterized in that it is made through heating, mix, extrude, pulverize, sieving by vibrin, solidifying agent, pigment, auxiliary agent and filler, fire retardant, and the weight percent of its each composition is:
Vibrin 40-60%
Solidifying agent 10-20%
Pigment 0.5-10%
Auxiliary agent and filler 10-30%
Fire retardant 0.5-10%
A kind of expansion fire-proof powder coating, it is characterized in that it is to increase swelling agent and make expansion epoxy polyester mixed type fire-proof powdery paint, expansion epoxy type fire-proof powdery paint, expansion polyester type fire-proof powdery paint on the basis of unexpansive epoxy polyester mixed type fire-proof powdery paint, unexpansive epoxy type fire-proof powdery paint, unexpansive polyester type fire-proof powdery paint, the weight percent of its composition is:
Non-expansion type fire-proof powdery paint 70-90%
The swelling agent surplus
Wherein swelling agent is made up of carbon forming agent, catalyzer, whipping agent, and the weight percent of its composition is:
Carbon forming agent 30-50%
Catalyzer 20-40%
Whipping agent 10-30%
A kind of production technique of non-expansion type fire-proof powdery paint is characterized in that:
Get an amount of vibrin and/or Resins, epoxy earlier and be heated to second-order transition temperature, its consumption is:
An amount of vibrin and/or Resins, epoxy: fire retardant=1-4: 1, the best is 2: 1, and then the fire retardant of adding formula ratio, after insulation and abundant the stirring, be cooled to bulk, pulverizing, again with other material of remaining vibrin and/or Resins, epoxy and powder coating through mixes stirring, extrude, cool off pulverizing behind the compressing tablet, sieving promptly obtains non-expansion type fire-proof powdery paint of the present invention.
A kind of production technique of expansion fire-proof powder coating is characterized in that:
Get an amount of vibrin and/or Resins, epoxy earlier and be heated to second-order transition temperature, its consumption is:
An amount of vibrin and/or Resins, epoxy: fire retardant=1-4: 1, the best is 2: 1, and then fire retardant, carbon forming agent, catalyzer, the whipping agent of adding formula ratio, after insulation and abundant the stirring, be cooled to bulk, pulverizing, again with other material of remaining vibrin and/or Resins, epoxy and powder coating through mixes stirring, extrude, cool off pulverizing behind the compressing tablet, sieving promptly obtains expansion fire-proof powder coating of the present invention.
The present invention is except that the advantage that keeps existing powder coating, its biggest advantage is to have fire resistance, it is ornamental that product is not only had, its fire resistance improves greatly simultaneously, and powder coating of the present invention has overcome the defective that may occur dust explosion in coating process, can guarantee quality product, improve effect.
Embodiment
Fire-proof powdery paint of the present invention can be divided into two kinds of non-expansion type fire-proof powdery paint and expansion fire-proof powder coating.
The non-expansion type fire-proof powdery paint comprises three kinds of unexpansive epoxy polyester mixed type fire-proof powdery paints, unexpansive epoxy type fire-proof powdery paint, unexpansive polyester type fire-proof powdery paint.
The expansion fire-proof powder coating comprises three kinds of expansion epoxy polyester mixed type fire-proof powdery paints, expansion epoxy type fire-proof powdery paint, expansion polyester type fire-proof powdery paint.
The composition and the weight percent of its various fire-proof powdery paints are as follows:
1, unexpansive epoxy polyester mixed type fire-proof powdery paint, it is made through heating, mix, extrude, pulverize, sieving by Resins, epoxy, vibrin, auxiliary agent and filler, pigment, fire retardant, and the weight percent of its each composition is:
Resins, epoxy 25-40%
Vibrin 25-40%
Auxiliary agent and filler 10-30%
Pigment 0.5-10%
Fire retardant 0.5-10%.
Above-mentioned fire retardant can be selected organophosphorus compound, chlorine class organic compound, bromine class organic compound and antimony compounds etc. for use, (dichloro propyl diester, tricresyl phosphate (chloroethyl) ester, Tritolyl Phosphate, clorafin, tricresyl phosphate (dibromopropyl) ester, perchloro-penta cyclodecane, hexabromobenzene, chlorodiphenyl, tetrachlorophthalic tetrachlorophthalic anhydrid, tetrabromophthalic anhydride, hexachloro endoethylene tetrahydrophthalic acid and acid anhydride, tetrachlorobisphenol A ring, dibromoneopentyl glycol, dibromo butyleneglycol, aluminium hydroxide, weisspiessglanz, zinc borate, barium metaborate are preferably selected tricresyl phosphate (two chloropropyls) ester for use as tricresyl phosphate.The optimum amount of fire retardant is 1-3%.
Auxiliary agent among the present invention and filler comprise brightening agent (or matting agent), flow agent (or wrinkle agent, mallear stria agent, sand streak agent etc.), ultra-fine barium sulfate, light calcium carbonate.
2, unexpansive epoxy type fire-proof powdery paint, it is made through heating, mix, extrude, pulverize, sieving by Resins, epoxy, solidifying agent, pigment, auxiliary agent and filler, fire retardant, and the weight percent of its each composition is:
Resins, epoxy 40-60%
Solidifying agent 10-20%
Pigment 0.5-10%
Auxiliary agent and filler 10-30%
Fire retardant 0.5-10%
Above-mentioned fire retardant can be selected the fire retardant of unexpansive epoxy polyester mixed type fire-proof powdery paint for use, also can comprise tetrachlorobisphenol A, tetrabromo-bisphenol, dibromophenol, tricresyl phosphate biphenol, preferably selects tetrachlorobisphenol A for use.
3, unexpansive polyester type fire-proof powdery paint, it is made through heating, mix, extrude, pulverize, sieving by vibrin, solidifying agent, pigment, auxiliary agent and filler, fire retardant, and the weight percent of its each composition is:
Vibrin 40-60%
Solidifying agent 10-20%
Pigment 0.5-10%
Auxiliary agent and filler 10-30%
Fire retardant 0.5-10%
Above-mentioned fire retardant can be selected the fire retardant of unexpansive epoxy polyester mixed type fire-proof powdery paint for use, also can comprise triphenylphosphate, phosphorus phenol three (dibromopropyl) ester, octabromo-diphenyl, decabromodiphynly oxide, preferably selects decabromodiphynly oxide for use.
Expansion fire-proof powder coating of the present invention is to increase swelling agent and make expansion epoxy polyester mixed type fire-proof powdery paint, expansion epoxy type fire-proof powdery paint, expansion polyester type fire-proof powdery paint on the basis of unexpansive epoxy polyester mixed type fire-proof powdery paint, unexpansive epoxy type fire-proof powdery paint, unexpansive polyester type fire-proof powdery paint, and the weight percent of its composition is:
Non-expansion type fire-proof powdery paint 70-90%
The swelling agent surplus
Wherein swelling agent is made up of carbon forming agent, catalyzer, whipping agent, and the weight percent of its composition is:
Carbon forming agent 30-50%
Catalyzer 20-40%
Whipping agent 10-30%
Above-mentioned carbon forming agent can select for use starch, tetramethylolmethane etc. to contain the high-carbon polyol, preferably selects tetramethylolmethane for use.Catalyzer can be selected primary ammonium phosphate, organophosphate and ammonium polyphosphate for use, preferably selects ammonium polyphosphate for use.Whipping agent can be selected ammonium polyphosphate, ammonium borate and trimeric cyanamide for use, preferably selects ammonium polyphosphate for use.
The production technique of non-expansion type fire-proof powdery paint of the present invention is:
Get an amount of vibrin and/or Resins, epoxy earlier and be heated to second-order transition temperature, its consumption is:
An amount of vibrin and/or Resins, epoxy: fire retardant=1-4: 1, the best is 2: 1, and then the fire retardant of adding formula ratio, after insulation and abundant the stirring, be cooled to bulk, pulverizing, again with other material of remaining vibrin and/or Resins, epoxy and powder coating through mixes stirring, extrude, cool off pulverizing behind the compressing tablet, sieving promptly obtains non-expansion type fire-proof powdery paint of the present invention.
The production technique of expansion fire-proof powder coating of the present invention is:
Get an amount of vibrin and/or Resins, epoxy earlier and be heated to second-order transition temperature, its consumption is:
An amount of vibrin and/or Resins, epoxy: fire retardant=1-4: 1, the best is 2: 1, and then fire retardant, carbon forming agent, catalyzer, the whipping agent of adding formula ratio, after insulation and abundant the stirring, be cooled to bulk, pulverizing, again with other material of remaining vibrin and/or Resins, epoxy and powder coating through mixes stirring, extrude, cool off pulverizing behind the compressing tablet, sieving promptly obtains expansion fire-proof powder coating of the present invention.
Non-expansion type fire-proof powdery paint of the present invention is applicable to ventilator trunk, Anti-theft door and window, steel house and venue etc.The expansion fire-proof powder coating is applicable to crane span structure and bus duct, file cabinet, switch box etc.
Embodiment 1 (unexpansive epoxy polyester mixed type fire-proof powdery paint):
Get 5 kilograms of vibrin earlier and 5 kilograms of Resins, epoxy are heated to second-order transition temperature, and then add 5 kilograms of tricresyl phosphates (two chloropropyls) ester fire retardant, after insulation and abundant the stirring, be cooled to bulk, pulverizing, again with remaining 30 kilograms of vibrin and 30 kilograms of Resins, epoxy and 10 kilograms of brightening agents, 5 kilograms of flow agents, 5 kilograms of light calcium carbonates and 5 kilograms of pigment through mixes stirring, extrude, cool off pulverizing behind the compressing tablet, sieving promptly obtains about 100 kilograms of unexpansive epoxy polyester mixed type fire-proof powdery paints of the present invention.
Embodiment 2 (expansion epoxy polyester mixed type fire-proof powdery paint):
Get 3 kilograms of vibrin earlier and 4 kilograms of Resins, epoxy are heated to second-order transition temperature, and then add 2 kilograms of dibromoneopentyl glycol fire retardants, 10 kilograms of tetramethylolmethane carbon forming agents, 6 kilograms of ammonium polyphosphate catalyzer and 4 kilograms of ammonium polyphosphate whipping agents, after insulation and abundant the stirring, be cooled to bulk, pulverize, again with remaining 25 kilograms of vibrin and 25 kilograms of Resins, epoxy and 9 kilograms of matting agents, 4 kilograms of wrinkle agent, 4 kilograms of ultra-fine barium sulfates and 4 kilograms of pigment stir through mixing, extrude, pulverize behind the cooling compressing tablet, sieve and promptly obtain about 100 kilograms of expansion epoxy polyester mixed type fire-proof powdery paints of the present invention.
Embodiment 3 (unexpansive epoxy type fire-proof powdery paint):
Get 10 kilograms of Resins, epoxy earlier and be heated to second-order transition temperature, and then add 8 kilograms of tetrachlorobisphenol A fire retardants, after insulation and abundant the stirring, be cooled to bulk, pulverizing, again with remaining 40 kilograms of Resins, epoxy, 20 kilograms of solidifying agent and 7 kilograms of brightening agents, 7 kilograms of mallear stria agent, 7 kilograms of light calcium carbonates and 1 kilogram of pigment through mixes stirring, extrude, cool off pulverizing behind the compressing tablet, sieving promptly obtains about 100 kilograms of unexpansive epoxy type fire-proof powdery paints of the present invention.
Embodiment 4 (expansion epoxy type fire-proof powdery paint):
Get 8 kilograms of Resins, epoxy earlier and be heated to second-order transition temperature, and then add 2 kilograms of antimony oxide flame retardants, 4 kilograms of starch carbon forming agents, 4 kilograms of primary ammonium phosphate catalyzer and 2 kilograms of trimeric cyanamide whipping agents, after insulation and abundant the stirring, be cooled to bulk, pulverizing, again with remaining 37 kilograms of Resins, epoxy and 18 kilograms of solidifying agent, 8 kilograms of pigment, 4 kilograms of matting agents, 6 kilograms of wrinkle agent, 7 kilograms of ultra-fine barium sulfates and through mixes stirring, extrude, cool off pulverizing behind the compressing tablet, sieving promptly obtains about 100 kilograms of expansion epoxy type fire-proof powdery paints of the present invention.
Embodiment 5 (unexpansive polyester type fire-proof powdery paint):
Get 1 kilogram of vibrin earlier and be heated to second-order transition temperature, and then add 1 kilogram of decabromodiphynly oxide fire retardant, after insulation and abundant the stirring, be cooled to bulk, pulverizing, again with remaining 54 kilograms of vibrin, 15 kilograms of solidifying agent and 12 kilograms of brightening agents, 8 kilograms of sand streak agent, 6 kilograms of light calcium carbonates and 3 kilograms of pigment through mixes stirring, extrude, cool off pulverizing behind the compressing tablet, sieving promptly obtains about 100 kilograms of unexpansive polyester type fire-proof powdery paints of the present invention.
Embodiment 6 (expansion polyester type fire-proof powdery paint):
Get 15 kilograms of vibrin earlier and be heated to second-order transition temperature, and then add 9 kilograms of phosphorus phenol three (dibromopropyl) ester fire retardant, 15 kilograms of tetramethylolmethane carbon forming agents, 9 kilograms of organic phosphoric acid ester catalysts and 6 kilograms of ammonium borate whipping agents, after insulation and abundant the stirring, be cooled to bulk, pulverize, again with remaining 20 kilograms of vibrin and 10 kilograms of solidifying agent, 2 kilograms of pigment, 3 kilograms of matting agents, 6 kilograms of wrinkle agent, 5 kilograms of ultra-fine barium sulfates and stir through mixing, extrude, pulverize behind the cooling compressing tablet, sieve and promptly obtain about 100 kilograms of expansion polyester type fire-proof powdery paints of the present invention.
The various embodiments described above are non-limiting example, can select according to aforementioned amount ranges and Item Title arbitrary combination.
Claims (10)
1, a kind of unexpansive epoxy polyester mixed type fire-proof powdery paint is characterized in that it is made through heating, mix, extrude, pulverize, sieving by Resins, epoxy, vibrin, auxiliary agent and filler, pigment, fire retardant, and the weight percent of its each composition is:
Resins, epoxy 25-40%
Vibrin 25-40%
Auxiliary agent and filler 10-30%
Pigment 0.5-10%
Fire retardant 0.5-10%.
2, by the described unexpansive epoxy polyester mixed type fire-proof powdery paint of claim 1, it is characterized in that described fire retardant selects organophosphorus compound for use, chlorine class organic compound, bromine class organic compound or antimony compounds, as tricresyl phosphate (dichloro propyl diester, tricresyl phosphate (chloroethyl) ester, Tritolyl Phosphate, clorafin, tricresyl phosphate (dibromopropyl) ester, perchloro-penta cyclodecane, hexabromobenzene, chlorodiphenyl, tetrachlorophthalic tetrachlorophthalic anhydrid, tetrabromophthalic anhydride, hexachloro endoethylene tetrahydrophthalic acid and acid anhydride, the tetrachlorobisphenol A ring, dibromoneopentyl glycol, the dibromo butyleneglycol, aluminium hydroxide, weisspiessglanz, zinc borate, barium metaborate, its preferably phosphoric acid three (two chloropropyls) ester; Described auxiliary agent and filler comprise brightening agent or matting agent, flow agent or wrinkle agent, mallear stria agent, sand streak agent, ultra-fine barium sulfate, light calcium carbonate; The preferable amount of fire retardant is 1-3%.
3, a kind of unexpansive epoxy type fire-proof powdery paint is characterized in that it is made through heating, mix, extrude, pulverize, sieving by Resins, epoxy, solidifying agent, pigment, auxiliary agent and filler, fire retardant, and the weight percent of its each composition is:
Resins, epoxy 40-60%
Solidifying agent 10-20%
Pigment 0.5-10%
Auxiliary agent and filler 10-30%
Fire retardant 0.5-10%
4, by the described unexpansive epoxy type fire-proof powdery paint of claim 3, it is characterized in that described fire retardant selects the fire retardant of unexpansive epoxy polyester mixed type fire-proof powdery paint for use, also select tetrachlorobisphenol A, tetrabromo-bisphenol, dibromophenol, tricresyl phosphate biphenol for use, its preferred tetrachlorobisphenol A.
5, a kind of unexpansive polyester type fire-proof powdery paint is characterized in that it is made through heating, mix, extrude, pulverize, sieving by vibrin, solidifying agent, pigment, auxiliary agent and filler, fire retardant, and the weight percent of its each composition is:
Vibrin 40-60%
Solidifying agent 10-20%
Pigment 0.5-10%
Auxiliary agent and filler 10-30%
Fire retardant 0.5-10%
6, by the described unexpansive polyester type fire-proof powdery paint of claim 5, it is characterized in that described fire retardant selects the fire retardant of unexpansive epoxy polyester mixed type fire-proof powdery paint for use, also select triphenylphosphate, phosphorus phenol three (dibromopropyl) ester, octabromo-diphenyl, decabromodiphynly oxide for use, its preferred decabromodiphynly oxide.
7, a kind of expansion fire-proof powder coating, it is characterized in that it is to increase swelling agent and make expansion epoxy polyester mixed type fire-proof powdery paint, expansion epoxy type fire-proof powdery paint, expansion polyester type fire-proof powdery paint on the basis of unexpansive epoxy polyester mixed type fire-proof powdery paint, unexpansive epoxy type fire-proof powdery paint, unexpansive polyester type fire-proof powdery paint, the weight percent of its composition is:
Non-expansion type fire-proof powdery paint 70-90%
The swelling agent surplus
Wherein swelling agent is made up of carbon forming agent, catalyzer, whipping agent, and the weight percent of its composition is:
Carbon forming agent 30-50%
Catalyzer 20-40%
Whipping agent 10-30%
8, by the described expansion fire-proof powder coating of claim 7, it is characterized in that described carbon forming agent selects for use starch, tetramethylolmethane etc. to contain the high-carbon polyol, select excellent tetramethylolmethane; Catalyzer is selected primary ammonium phosphate, organophosphate and ammonium polyphosphate for use, preferred ammonium polyphosphate; Whipping agent is selected ammonium polyphosphate, ammonium borate and trimeric cyanamide for use, preferred ammonium polyphosphate.
9, a kind of production technique of non-expansion type fire-proof powdery paint is characterized in that:
Get an amount of vibrin and/or Resins, epoxy earlier and be heated to second-order transition temperature, its consumption is:
An amount of vibrin and/or Resins, epoxy: fire retardant=1-4: 1, the best is 2: 1, and then the fire retardant of adding formula ratio, after insulation and abundant the stirring, be cooled to bulk, pulverizing, again with other material of remaining vibrin and/or Resins, epoxy and powder coating through mixes stirring, extrude, cool off pulverizing behind the compressing tablet, sieving promptly obtains non-expansion type fire-proof powdery paint of the present invention.
10, a kind of production technique of expansion fire-proof powder coating is characterized in that:
Get an amount of vibrin and/or Resins, epoxy earlier and be heated to second-order transition temperature, its consumption is:
An amount of vibrin and/or Resins, epoxy: fire retardant=1-4: 1, the best is 2: 1, and then fire retardant, carbon forming agent, catalyzer, the whipping agent of adding formula ratio, after insulation and abundant the stirring, be cooled to bulk, pulverizing, again with other material of remaining vibrin and/or Resins, epoxy and powder coating through mixes stirring, extrude, cool off pulverizing behind the compressing tablet, sieving promptly obtains expansion fire-proof powder coating of the present invention.
Priority Applications (1)
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|---|---|---|---|
| CN 02112798 CN1380370A (en) | 2002-03-25 | 2002-03-25 | Fire-resistant powder coating material and its production process |
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| CN 02112798 CN1380370A (en) | 2002-03-25 | 2002-03-25 | Fire-resistant powder coating material and its production process |
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Cited By (24)
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| WO2007140676A1 (en) * | 2006-06-09 | 2007-12-13 | Xuzhou Zenith Coating Co., Ltd | Fireproofing powder coating for steel structures and the preparing method thereof |
| CN101760114A (en) * | 2010-01-27 | 2010-06-30 | 海洋王照明科技股份有限公司 | Antiseptic powder coating, manufacturing method and applying method thereof |
| CN101205425B (en) * | 2006-12-22 | 2011-10-12 | 徐州正菱涂装有限公司 | Foaming powder coating |
| CN102329570A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Liquid rubber spray paint containing antimony oxide compounds |
| CN102391764A (en) * | 2011-09-30 | 2012-03-28 | 广州擎天实业有限公司 | Low-temperature curing flame-retardant finishing powder paint and preparation method thereof |
| CN102898930A (en) * | 2012-09-21 | 2013-01-30 | 信和新材料股份有限公司 | Hydrocarbon flame resistant intumescent coating and preparation method thereof |
| CN102935277A (en) * | 2011-08-16 | 2013-02-20 | 陕西坚瑞消防股份有限公司 | Fire extinguishing composition |
| CN103131298A (en) * | 2013-02-03 | 2013-06-05 | 倪进培 | Flame retardant powder coating with hydrated zinc borate |
| CN103205178A (en) * | 2013-02-03 | 2013-07-17 | 倪进培 | Preparation method for powder coating containing ethyl acetate |
| CN103214655A (en) * | 2013-03-27 | 2013-07-24 | 杭州日耀科技有限公司 | Modified epoxy resin and high-solid anticorrosive coating prepared therewith |
| CN103497626A (en) * | 2013-09-03 | 2014-01-08 | 蚌埠德美过滤技术有限公司 | Intumescent steel structure fireproof powdery paint |
| CN103965737A (en) * | 2014-05-09 | 2014-08-06 | 福建万安实业有限公司 | Flame retardant powder coating |
| CN104004225A (en) * | 2014-04-29 | 2014-08-27 | 江汉大学 | Application of tetrabromo bisphenol A as antibacterial agent and antibacterial material |
| CN103999857A (en) * | 2014-04-29 | 2014-08-27 | 江汉大学 | Application of tetrachloro bisphenol A as antibacterial agent and antibacterial material |
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- 2002-03-25 CN CN 02112798 patent/CN1380370A/en active Pending
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2007140676A1 (en) * | 2006-06-09 | 2007-12-13 | Xuzhou Zenith Coating Co., Ltd | Fireproofing powder coating for steel structures and the preparing method thereof |
| CN101205425B (en) * | 2006-12-22 | 2011-10-12 | 徐州正菱涂装有限公司 | Foaming powder coating |
| CN101760114B (en) * | 2010-01-27 | 2013-08-07 | 海洋王照明科技股份有限公司 | Antiseptic powder coating, manufacturing method and applying method thereof |
| CN101760114A (en) * | 2010-01-27 | 2010-06-30 | 海洋王照明科技股份有限公司 | Antiseptic powder coating, manufacturing method and applying method thereof |
| CN102329570A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Liquid rubber spray paint containing antimony oxide compounds |
| CN102935277B (en) * | 2011-08-16 | 2015-07-22 | 西安坚瑞安全应急设备有限责任公司 | Fire extinguishing composition |
| CN102935277A (en) * | 2011-08-16 | 2013-02-20 | 陕西坚瑞消防股份有限公司 | Fire extinguishing composition |
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