CN102935277B - Fire extinguishing composition - Google Patents
Fire extinguishing composition Download PDFInfo
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- CN102935277B CN102935277B CN201110232195.9A CN201110232195A CN102935277B CN 102935277 B CN102935277 B CN 102935277B CN 201110232195 A CN201110232195 A CN 201110232195A CN 102935277 B CN102935277 B CN 102935277B
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- fire
- extinguishing
- quality
- extinguishing composite
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- 239000000203 mixture Substances 0.000 title abstract description 16
- 239000000654 additive Substances 0.000 claims abstract description 9
- 230000000996 additive effect Effects 0.000 claims abstract description 9
- 239000004254 Ammonium phosphate Substances 0.000 claims abstract description 8
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims abstract description 8
- 235000019289 ammonium phosphates Nutrition 0.000 claims abstract description 8
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims abstract description 8
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 claims abstract description 6
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002131 composite material Substances 0.000 claims description 38
- 239000003814 drug Substances 0.000 claims description 15
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 10
- 235000019270 ammonium chloride Nutrition 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 5
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 claims description 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 3
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 3
- 150000001241 acetals Chemical class 0.000 claims description 3
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 3
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 3
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 3
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 3
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 3
- 239000005011 phenolic resin Substances 0.000 claims description 3
- 229920001568 phenolic resin Polymers 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 11
- 239000000126 substance Substances 0.000 abstract description 10
- 239000000443 aerosol Substances 0.000 abstract description 7
- 238000002485 combustion reaction Methods 0.000 abstract description 4
- 239000007789 gas Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229920004449 Halon® Polymers 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000001413 cellular effect Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 2
- 238000006253 efflorescence Methods 0.000 description 2
- 238000009740 moulding (composite fabrication) Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000006187 pill Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 206010037844 rash Diseases 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical group [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/06—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires containing gas-producing, chemically-reactive components
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Fire-Extinguishing Compositions (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention relates to a novel fire extinguishing composition, which includes: 30 mass%-70 mass% of ferrocene, 30 mass%-70 mass% of ammonium phosphate, 0 mass%-10 mass% of tetrabromobisphenol A or 0 mass%-10 mass% of decabromodiphenyl ether and a performance additive. In use, a pyrotechnic agent is taken as the thermal source and power source. The pyrotechnic agent is first ignited, and the high temperature of pyrotechnic agent combustion is utilized to heat the fire extinguishing composition to decomposing volatilization or reaction, and a large number of fire extinguishing substances can be generated. The substances can be ejected together with the pyrotechnic agent so as to reach the fire extinguishing purpose. The invention provides the aerosol fire extinguishing composition which can be stored without pressure, and is safer, more environment-friendly and efficient.
Description
Technical field
The invention belongs to fire-fighting domain, relate to fire-extinguishing composite, the use of inhibition material.Relate to a kind of high-effect fire-extinguishing composition of phosphoric acid ammonium compounds more specifically.
Background technology
Since Montreal, CAN pact in 1987 to propose to replace the objectives of halon fire agent to various countries, each state all in the research being devoted to new fire-fighting technique, should fire-fighting efficiency high, the fire-fighting technique of environmentally safe is the direction that people make great efforts again.
Gas extinguishing system, powder extinguishing system and water system fire extinguishing system etc. are widely applied by the substitute as halon extinguisher due to environmental sound.Carbon dioxide, the extinguishing mechanism of the inert gas fire-fighting systems such as IG541 is mainly physics fire extinguishing, by reducing oxygen concentration two fire smothering of ignition zone, this fire-fighting mode easily threatens to the personal safety of personnel, powder extinguishing system is powder by spraying under gas-pressurized effect and flame contact, there is physical chemistry inhibitory action and put out a fire, water fog sprinkler is the cooling by water mists, suffocate and completely cut off thermal-radiating triple role and be issued to control fire, the object suppressing fire and stamp out a fire.
But, these fire extinguishing systems all need hig pressure storage, not only volume is larger, the danger of physical explosion is also there is in storage process, document " safety analysis of gas extinguishing system " analyzes the danger existing for gas extinguishing system, and lists in use the caused security incident of reservoir pressure gas extinguishing system.
Existing aerosol extinguishing agent mainly contains S type and K type extinguishing chemical, by comprehensively analyzing its performance characteristics, its weak point is mainly: aerosol extinguishing agent is all the chain-breaking reactions utilizing extinguishing chemical generation redox reaction to discharge a large amount of gas, active particle, the covering of a large amount of gas suffocates, and realizes the fire extinguishing object that chemistry combines with physics.Redox reaction is generally exothermic reaction, discharging aerocolloidal while, discharge a large amount of heat, for effectively reducing device and aerocolloidal temperature, avoid spot fire occurs, need increase cooling system, cause apparatus structure complicated heavy, technological process is complicated, cost is high, simultaneously due to the existence of cooling system, make a large amount of active ion lose activity or deposit, cause extinguishing property greatly to reduce.And the little density of extinguishing material release particle concentration is low, not easily penetrates fire plume and directly arrives burning things which may cause a fire disaster root, reaches the object effectively suppressing rapidly burning things which may cause a fire disaster.
Summary of the invention
For the inherent shortcoming of the present situation of existing extinguishing chemical, particularly aerosol extinguishing agent, the invention provides a kind of without the need to pressure storage, aerosol class fire-extinguishing composite that is safer, more environment-friendly high-efficiency.
The present invention relates to a kind of high-effect fire-extinguishing composition, it is characterized in that: this fire-extinguishing composite comprises: ferrocene 30 quality % ~ 70 quality %, preferably 40 quality % ~ 60 quality %, ammonium phosphate 30 quality % ~ 70 quality %, preferably 35 quality % ~ 55 quality %; Described fire-extinguishing composite is for heating power source and power source with pyrotechnics class medicament, first light pyrotechnics class medicament, utilize the high temperature that pyrotechnics class medicament burns to make fire-extinguishing composite decomposes or reaction, produce a large amount of extinguishing materials, spray together with pyrotechnics class medicament and reach fire extinguishing object.
Fire-extinguishing composite involved in the present invention also comprises tetrabromobisphenol A or deca-BDE, and its content, for being greater than 0 quality % to being less than or equal to 10 quality %, is good with 3 quality % ~ 8 quality % scopes.
Fire-extinguishing composite involved in the present invention also can contain performance additive, its content is that 0 quality % is to being less than or equal to 30 quality %, preferably 2 quality % ~ 20 quality %, performance additive can be selected from ammonium chloride, dolomol, zinc stearate, acetal glue, hydroxypropyl methylcellulose, sodium cellulose glycolate, phenolic resins one or more, suitably can adjust according to proportioning.
Fire-extinguishing composite of the present invention can adopt the technological formings such as pill, mold pressing, extruding to be spherical, sheet, and strip is packaged, cellular, and can be passed through Surface coating process.CMC or hydroxyethylcellulose is preferably added when carrying out Surface coating process.This surface capping agents can improve the surface smoothness of composition system, and improves its intensity, wearability and shock resistance, prevents fire-extinguishing composite generation efflorescence in transportation, falls slag and overflows the appearance of extinguishing device phenomenon.
High-effect fire-extinguishing composition of the present invention can reach following effect simultaneously: one, in high-temperature heating situation, can to be heated generation endothermic decomposition, reduce the temperature that aerosol extinguishing agent spurts material effectively fast, two, abrupt release goes out mass efficient extinguishing material, and extinguishing material is based on solid particle, also have a little liquid particles, by the synergy of multiple particulate, substantially reduce attack time; Three, decomposed substance is based on solid particle, and relative density is comparatively large, is easier to penetrate fire plume, effectively controls burning things which may cause a fire disaster; Four, solia particle falls to combustible substance surface and is easy to formation diaphragm, has effectively blocked looping combustion reaction, has further increased the fire extinguishing effectiveness of extinguishing chemical; Five, fire-extinguishing composite abundant raw material, is easy to machine-shaping, and can be used alone or support the use with physics cooling agent; Six, stable performance, long term storage is easy to, seven, hypotoxicity or nontoxicity, environmentally friendly function admirable.
The suppression mechanism of high-effect fire-extinguishing composition of the present invention is as follows: during use, with pyrotechnics class medicament for heating power source and power source, by lighting pyrotechnics class medicament burning liberated heat, fire-extinguishing composite at high temperature dewaters cooling, further decomposition discharges extinguishing material, this extinguishing material reacts necessary O by free radical and looping combustion, OH, one or more in H free radical are reacted, thus cut off looping combustion reaction, also reduce oxygen partial pressure by physical action and suppress flame, or there is physics and the fire extinguishing of organoselenocyanate functional realiey simultaneously, meanwhile, synergistic function is produced with firework medicament, further increase the fire extinguishing effectiveness of extinguishing chemical, substantially reduce effective attack time.Compared with traditional fire-extinguishing composite, the present invention can provide a kind of more efficient, safer fire-extinguishing composite.
Below by specific embodiment more specific description fire-extinguishing composite of the present invention.
Detailed description of the invention
Below by specific embodiment more specific description fire-extinguishing composite of the present invention.
A kind of high-effect fire-extinguishing composition of the present invention, it mainly comprises: ferrocene 30 quality % ~ 70 quality %, preferably 40 quality % ~ 60 quality %, ammonium phosphate 30 quality % ~ 70 quality %, preferably 35 quality % ~ 55 quality %, tetrabromobisphenol A or deca-BDE, its content, for being less than or equal to 10 quality %, being good with 3 quality % ~ 8 quality % scopes, can also adding performance additive, its content be 0 quality % to being less than or equal to 30 quality %, preferably 2 quality % ~ 20 quality %; This fire-extinguishing composite is for heating power source and power source with pyrotechnics class medicament, first light pyrotechnics class medicament, utilize the high temperature that pyrotechnics class medicament burns to make fire-extinguishing composite decomposes or reaction, produce a large amount of extinguishing materials, spray together with pyrotechnics class medicament and reach fire extinguishing object.
Performance additive of the present invention can be selected from ammonium chloride, dolomol, zinc stearate, acetal glue, hydroxypropyl methylcellulose, sodium cellulose glycolate, phenolic resins one or more, suitably can adjust according to proportioning; Also include adhesive in performance additive of the present invention, but the application of adhesive in fire-extinguishing composite belongs to ordinary skill in the art means, and its content controls usually below 15%.
Fire-extinguishing composite of the present invention can adopt the technological formings such as pill, mold pressing, extruding to be spherical, sheet, and strip is packaged, cellular, and can be passed through Surface coating process.CMC or hydroxyethylcellulose is preferably added when carrying out Surface coating process.This surface capping agents can improve the surface smoothness of composition system, and improves its intensity, wearability and shock resistance, prevents fire-extinguishing composite generation efflorescence in transportation, falls slag and overflows the appearance of extinguishing device phenomenon.
Above-mentioned fire-extinguishing composite, the 4 assembly ratios that first have chosen wherein are tested, with the extinguishing chemical under equal conditions Experimental Comparison of prior art, according to BS6165:2002 " Specification for small disposablefire extinguishers of the aerosol type ", specific as follows:
Embodiment 1
Obtained sheet ferrocene, ammonium phosphate, tetrabromobisphenol A and ammonium chloride composition sample 50g are added in the hand-held fire extinguisher that 50gK type hot aerosol propellant is housed, enforcement area is 0.1m
2the gasoline fire-extinguishing test of food tray; Experimental test the results are shown in Table 1.
Embodiment 2
Obtained sheet ferrocene, ammonium phosphate, deca-BDE, ammonium chloride and zinc stearate composition are tested according to embodiment 1, test result is in table 1.
Embodiment 3
Obtained sheet ferrocene, ammonium phosphate, deca-BDE and ammonium chloride composition are tested according to embodiment 1, test result is in table 1.
Embodiment 4
Obtained sheet ferrocene, ammonium phosphate, tetrabromobisphenol A and zinc stearate composition are tested according to embodiment 1, test result is in table 1.
The various composition component of table 1 compares and comparison of test results
Can draw from above-mentioned comparing result: under same experimental conditions, the fire-extinguishing composite two of embodiment 1-4 even three entirely go out, and all not the knocking out of comparative example 1-2; The injecting time of embodiment 1-4 all shortens nearly about 28s at about 11s than the injecting time of comparative example 1, compared with comparative example 2, also shortens.Therefore, fire-extinguishing composite of the present invention is obviously better than the extinguishing medium of prior art in fire extinguishing effectiveness, and fire-extinguishing composite injecting time of the present invention is short, and it belongs to the endothermic reaction, can also reduce nozzle temperature.
Above-mentioned specific embodiment is only exemplary, and under above-mentioned instruction of the present invention, those skilled in the art can carry out various improvement and distortion on the basis of above-described embodiment, and these improve or distortion drops in protection scope of the present invention.It will be understood by those skilled in the art that specific descriptions are above to explain object of the present invention, not for limiting invention.
Claims (6)
1. a fire-extinguishing composite, is characterized in that: described fire-extinguishing composite comprises:
Ferrocene 30 quality % ~ 70 quality %,
Ammonium phosphate 30 quality % ~ 70 quality %;
Described fire-extinguishing composite is for heating power source and power source with pyrotechnics class medicament, first light pyrotechnics class medicament, utilize the high temperature that pyrotechnics class medicament burns to make fire-extinguishing composite decomposes or reaction, produce a large amount of extinguishing materials, spray together with pyrotechnics class medicament and reach fire extinguishing object.
2. fire-extinguishing composite according to claim 1, is characterized in that: described fire-extinguishing composite also comprises tetrabromobisphenol A or deca-BDE, and its content is for being greater than 0 quality % to being less than or equal to 10 quality %.
3. fire-extinguishing composite according to claim 1 and 2, is characterized in that: described fire-extinguishing composite also comprises performance additive, and described performance additive content is for being greater than 0 quality % to being less than or equal to 30 quality %.
4. fire-extinguishing composite according to claim 3, is characterized in that: described performance additive is one or more in ammonium chloride, dolomol, zinc stearate, acetal glue, hydroxypropyl methylcellulose, sodium cellulose glycolate, phenolic resins.
5. fire-extinguishing composite according to claim 4, is characterized in that: each component of described fire-extinguishing composite and mass percentage thereof are:
6. fire-extinguishing composite according to claim 5, is characterized in that: described fire-extinguishing composite selects CMC or hydroxyethylcellulose to be covering.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110232195.9A CN102935277B (en) | 2011-08-16 | 2011-08-16 | Fire extinguishing composition |
| PCT/CN2012/080071 WO2013023571A1 (en) | 2011-08-16 | 2012-08-14 | Fire-extinguishing composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110232195.9A CN102935277B (en) | 2011-08-16 | 2011-08-16 | Fire extinguishing composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102935277A CN102935277A (en) | 2013-02-20 |
| CN102935277B true CN102935277B (en) | 2015-07-22 |
Family
ID=47694220
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110232195.9A Active CN102935277B (en) | 2011-08-16 | 2011-08-16 | Fire extinguishing composition |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN102935277B (en) |
| WO (1) | WO2013023571A1 (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1380370A (en) * | 2002-03-25 | 2002-11-20 | 葛明槽 | Fire-resistant powder coating material and its production process |
| CN1695752A (en) * | 2004-05-13 | 2005-11-16 | 景中兴 | New type fire agent recipe for forest fire and technique |
| US20070007019A1 (en) * | 2005-06-17 | 2007-01-11 | Aerojet-General Corporation | Hybrid fire extinguisher for extended suppression times |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1083281C (en) * | 1999-06-03 | 2002-04-24 | 北京理工大学 | Fire extinguishing agent of aerosol |
| CN100544796C (en) * | 2002-08-09 | 2009-09-30 | 法纳瓦南·凯玛特 | Fire extinguishing ball |
-
2011
- 2011-08-16 CN CN201110232195.9A patent/CN102935277B/en active Active
-
2012
- 2012-08-14 WO PCT/CN2012/080071 patent/WO2013023571A1/en active Application Filing
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1380370A (en) * | 2002-03-25 | 2002-11-20 | 葛明槽 | Fire-resistant powder coating material and its production process |
| CN1695752A (en) * | 2004-05-13 | 2005-11-16 | 景中兴 | New type fire agent recipe for forest fire and technique |
| US20070007019A1 (en) * | 2005-06-17 | 2007-01-11 | Aerojet-General Corporation | Hybrid fire extinguisher for extended suppression times |
Non-Patent Citations (2)
| Title |
|---|
| "塑料阻燃剂的研究开发进展";李玉芳 等;《四川化工》;20060430;第9卷(第2期);第30-33页 * |
| "阻燃剂的发展及在塑料中的应用";史翎 等;《塑料》;20020630;第31卷(第3期);第11-14页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102935277A (en) | 2013-02-20 |
| WO2013023571A1 (en) | 2013-02-21 |
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Owner name: XIAN JIANRUI SAFETY EMERGENCY EQUIPMENT LIMITED LI Free format text: FORMER OWNER: SHAANXI J+R FIRE FIGHTING CO., LTD. Effective date: 20140404 |
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Application publication date: 20130220 Assignee: YICHANG AND ANN SHIELD FIRE CONTROL TECHNOLOGY CO., LTD. Assignor: XI'AN JIAN RUI SAFETY EMERGENCY EQUIPMENT LIMITED LIABILITY COMPANY Contract record no.: 2017610000011 Denomination of invention: Fire-extinguishing composition and preparing method thereof Granted publication date: 20150722 License type: Exclusive License Record date: 20170427 |
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Effective date of registration: 20170619 Address after: 443005, No. 28, development road, hi tech Zone, Hubei, Yichang Patentee after: YICHANG AND ANN SHIELD FIRE CONTROL TECHNOLOGY CO., LTD. Address before: High tech Zone technology two road 710075 Shaanxi city of Xi'an Province, No. 65 building 7 layer Qingyang Patentee before: XI'AN JIAN RUI SAFETY EMERGENCY EQUIPMENT LIMITED LIABILITY COMPANY |