CN105219253A - A kind of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint and preparation method thereof - Google Patents
A kind of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint and preparation method thereof Download PDFInfo
- Publication number
- CN105219253A CN105219253A CN201510644596.3A CN201510644596A CN105219253A CN 105219253 A CN105219253 A CN 105219253A CN 201510644596 A CN201510644596 A CN 201510644596A CN 105219253 A CN105219253 A CN 105219253A
- Authority
- CN
- China
- Prior art keywords
- parts
- component
- solvent
- priming paint
- asphalt modification
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses a kind of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint and preparation method thereof, described priming paint comprises following component: component A: epoxy resin A, epoxy resin B, zinc phosphate, coal-tar pitch, modified resin, red iron oxide, process white, sericite, compound phosphorus titanium valve, anti-settling slurry, defoamer, dispersion agent, the first mixed solvent; B component: modified by cardanol polyamide resin, salt spray resistance auxiliary agent, the second mixed solvent.Component A, for first preparing component A and B component respectively, in use, then mixes with B component by its preparation method.Priming paint of the present invention has good drying property, sticking power, salt spray resistance, chemical resistance.
Description
Technical field
The invention belongs to technical field of coatings, be specifically related to a kind of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint and preparation method thereof.
Background technology
The zinc phosphate that market occurs is all adopt epoxy resin or modified resin split zinc phosphate to make, and during environment for strong acid and strong base, epoxy resin is more difficult meets its performance requriements, as petroleum pipe line, and oil equipment, petroleum storage tank etc.Patent CN102898928A discloses a kind of moisturecuring epoxy phosphate zinc primer for rusty surface, under normal temperature condition can 5% sulfuric acid and 5% sodium hydroxide in successive soaking 240 hours non-foaming, do not come off, and salt spray resistance can reach 1000 hours non-foaming, do not come off.Require in GB/T50393-2008 " steel petroleum storage tank anticorrosion engineering technical specifications " that the sulfuric acid of paint film resistance to 5% and 5% sodium hydroxide successive soaking 720 hours paint films under 60 DEG C of conditions are non-foaming, do not come off.PetroChina Company Limited. and China Petrochemical Industry now usual way adopt non-solvent epoxy antifouling paste or epoxy novolac antifouling paste to construct, such cost compare is high, how realizing low cost and over-all properties can meet technical requirement, is the important development direction in the heavy antisepsis fields such as petroleum pipe line, petroleum storage tank, oil equipment.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art and provide a kind of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint and preparation method thereof, this priming paint has good drying property, sticking power, salt spray resistance, chemical resistance.
A kind of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint, includes following component by weight: component A: epoxy resin A10 ~ 15 part, epoxy resin B10 ~ 15 part, zinc phosphate 10 ~ 15 parts, coal-tar pitch 5 ~ 10 parts, modified resin 2 ~ 4 parts, red iron oxide 15 ~ 20 parts, process white 10 ~ 20 parts, sericite 2 ~ 5 parts, compound phosphorus titanium valve 10 ~ 15 parts, 0.4 ~ 0.6 part, anti-settling slurry, defoamer 0.2 ~ 0.4 part, dispersion agent 0.2 ~ 0.5 part, the first mixed solvent 6 ~ 11 parts; B component: modified by cardanol polyamide resin 50 ~ 60 parts, salt spray resistance auxiliary agent 1 ~ 2 part, the second mixed solvent 38 ~ 40 parts.
As the further improvement of foregoing invention, in component A, also include N,N-DMAA 2 ~ 8 parts.
As the further improvement of foregoing invention, in B component, also include dimethylamino ethyl acrylate 3 ~ 7 parts.
As the further improvement of foregoing invention, described red iron oxide is that flake ferric oxide is red.
As the further improvement of foregoing invention, described first mixed solvent is mixed according to volume ratio 50 ~ 70:10 ~ 20:10 ~ 20:5 ~ 15 by benzene kind solvent, alcoholic solvent, ketones solvent and ether solvent.
As the further improvement of foregoing invention, described second mixed solvent is mixed according to volume ratio 50 ~ 70:10 ~ 20:10 ~ 20:5 ~ 15 by benzene kind solvent, alcoholic solvent, ketones solvent and ether solvent.
As the further improvement of foregoing invention, described benzene kind solvent is toluene, dimethylbenzene or trimethylbenzene; Alcoholic solvent is methyl alcohol, ethanol, propyl carbinol or phenylcarbinol; Ketones solvent is acetone, butanone or cyclohexanone; Esters solvent is ethylene glycol monobutyl ether.
The preparation method of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint, component A is prepared by following steps: step 1, with mixed solvent, anti-settling slurry is dissolved, add epoxy resin A again, epoxy resin B and coal-tar pitch, dispersion agent is added while stirring under 400 ~ 600rpm condition, defoamer, 400 ~ 600rpm continues stirring 10 ~ 15min, step 2, add red iron oxide, process white, zinc phosphate and sericite, 600 ~ 800rpm stirs 15 ~ 20min, being ground to fineness is 50 μm, step 3, add Special Resin and compound ferrophosphorus powder, 800 ~ 1000rpm stirs 15 ~ 20min, obtain, B component is prepared by following steps: mixed solvent, under 400 ~ 600rpm condition, adds modified by cardanol polyamide resin and salt spray resistance auxiliary agent while stirring, and 400 ~ 600rpm stirs 10 ~ 15min, to obtain final product.
As the further improvement of foregoing invention, also need in step 2 to add N,N-DMAA.
As the further improvement of foregoing invention, also need in the preparation method of B component to add dimethylamino ethyl acrylate in a solvent.
In use, the weight ratio of component A and B component is preferably 3 ~ 7:1.
Asphalt modification epoxy phosphate zinc heavy antisepsis priming paint of the present invention has good drying property, sticking power, salt spray resistance, chemical resistance.
Embodiment
The raw material that following examples adopt is:
Epoxy resin A (6101, three wood)
Epoxy resin B (828, three wood)
Flake ferric oxide red (R01, Chongqing stablizes the country)
Zinc phosphate (NPZA, the triumphant rising sun in Chongqing)
Coal-tar pitch (coal-tar middle oil pitch, straits, Fujian group)
Modified resin (2602, Jiangsu special chemical article)
Anti-settling slurry (SUPER, ring fine jade chemistry)
Dispersion agent (9850, this chemistry of sea inscription)
Defoamer (EFKA2722, EFKA company)
Compound phosphorus titanium valve (X-500, Xiang Tan span new millennium)
Sericite (A4, Chuzhou ten thousand bridge)
Modified by cardanol polyamide resin (5444, Ka Delai chemistry)
Salt spray resistance auxiliary agent (1121, this chemistry of sea inscription)
First mixed solvent and the second mixed solvent are mixed according to volume ratio 60:15:15:10 by benzene kind solvent, alcoholic solvent, ketones solvent and ether solvent; Described benzene kind solvent is toluene, dimethylbenzene or trimethylbenzene; Alcoholic solvent is methyl alcohol, ethanol, propyl carbinol or phenylcarbinol; Ketones solvent is acetone, butanone or cyclohexanone; Esters solvent is ethylene glycol monobutyl ether.
Embodiment 1
A kind of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint, includes following component by weight: component A: epoxy resin A10 part, epoxy resin B15 part, zinc phosphate 10 parts, coal-tar pitch 5 parts, modified resin 2 parts, red iron oxide 20 parts, process white 18 parts, sericite 2 parts, compound phosphorus titanium valve 15 parts, 0.6 part, anti-settling slurry, defoamer 0.2 part, dispersion agent 0.5 part, the first mixed solvent 6.7 parts; B component: modified by cardanol polyamide resin 50 parts, salt spray resistance auxiliary agent 2 parts, the second mixed solvent 38 parts.
Preparation method:
Component A: step 1, dissolves anti-settling slurry with mixed solvent, then adds epoxy resin A, epoxy resin B and coal-tar pitch, dispersion agent, defoamer is added while stirring under 400rpm condition, 600rpm continues to stir 10min, and step 2, adds red iron oxide, process white, zinc phosphate and sericite, 600rpm stirs 15min, being ground to fineness is 50 μm, step 3, adds Special Resin and compound ferrophosphorus powder, 1000rpm stirs 15min, to obtain final product.
B component: mixed solvent, under 400rpm condition, adds modified by cardanol polyamide resin and salt spray resistance auxiliary agent while stirring, and 600rpm stirs 10min, to obtain final product.
Embodiment 2
A kind of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint, includes following component by weight: component A: epoxy resin A15 part, epoxy resin B10 part, zinc phosphate 15 parts, coal-tar pitch 10 parts, modified resin 2 parts, red iron oxide 15 parts, process white 20 parts, sericite 5 parts, compound phosphorus titanium valve 10 parts, 0.5 part, anti-settling slurry, defoamer 0.3 part, dispersion agent 0.3 part, the first mixed solvent 6.9 parts; B component: modified by cardanol polyamide resin 55 parts, salt spray resistance auxiliary agent 2 parts, the second mixed solvent 39 parts.
Preparation method:
Component A: step 1, dissolves anti-settling slurry with mixed solvent, then adds epoxy resin A, epoxy resin B and coal-tar pitch, dispersion agent, defoamer is added while stirring under 600rpm condition, 400rpm continues to stir 15min, and step 2, adds red iron oxide, process white, zinc phosphate and sericite, 800rpm stirs 20min, being ground to fineness is 50 μm, step 3, adds Special Resin and compound ferrophosphorus powder, 800rpm stirs 20min, to obtain final product.
B component: mixed solvent, under 600rpm condition, adds modified by cardanol polyamide resin and salt spray resistance auxiliary agent while stirring, and 400rpm stirs 15min, to obtain final product.
Embodiment 3
A kind of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint, includes following component by weight: component A: epoxy resin A12 part, epoxy resin B14 part, zinc phosphate 11 parts, coal-tar pitch 8 parts, modified resin 4 parts, red iron oxide 17 parts, process white 19 parts, sericite 3 parts, compound phosphorus titanium valve 12 parts, 0.5 part, anti-settling slurry, defoamer 0.3 part, dispersion agent 0.4 part, the first mixed solvent 9 parts; B component: modified by cardanol polyamide resin 54 parts, salt spray resistance auxiliary agent 2 parts, the second mixed solvent 39 parts.
Preparation method:
Component A: step 1, dissolves anti-settling slurry with mixed solvent, then adds epoxy resin A, epoxy resin B and coal-tar pitch, dispersion agent, defoamer is added while stirring under 500rpm condition, 500rpm continues to stir 13min, and step 2, adds red iron oxide, process white, zinc phosphate and sericite, 700rpm stirs 18min, being ground to fineness is 50 μm, step 3, adds Special Resin and compound ferrophosphorus powder, 900rpm stirs 18min, to obtain final product.
B component: mixed solvent, under 500rpm condition, adds modified by cardanol polyamide resin and salt spray resistance auxiliary agent while stirring, and 500rpm stirs 15min, to obtain final product.
Embodiment 4
A kind of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint, includes following component by weight: component A: epoxy resin A11 part, epoxy resin B14 part, zinc phosphate 13 parts, coal-tar pitch 9 parts, modified resin 3 parts, red iron oxide 16 parts, process white 15 parts, sericite 4 parts, compound phosphorus titanium valve 13 parts, 0.5 part, anti-settling slurry, defoamer 0.3 part, dispersion agent 0.4 part, the first mixed solvent 9 parts; B component: modified by cardanol polyamide resin 52 parts, salt spray resistance auxiliary agent 2 parts, the second mixed solvent 40 parts.
Preparation method:
Component A: step 1, dissolves anti-settling slurry with mixed solvent, then adds epoxy resin A, epoxy resin B and coal-tar pitch, dispersion agent, defoamer is added while stirring under 500rpm condition, 500rpm continues to stir 13min, and step 2, adds red iron oxide, process white, zinc phosphate and sericite, 700rpm stirs 18min, being ground to fineness is 50 μm, step 3, adds Special Resin and compound ferrophosphorus powder, 900rpm stirs 18min, to obtain final product.
B component: mixed solvent, under 500rpm condition, adds modified by cardanol polyamide resin and salt spray resistance auxiliary agent while stirring, and 500rpm stirs 15min, to obtain final product.
Embodiment 5
The difference of the present embodiment and embodiment 3 is: also include N,N-DMAA 2 ~ 8 parts in component A.
A kind of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint, include following component by weight: component A: epoxy resin A12 part, epoxy resin B14 part, zinc phosphate 11 parts, coal-tar pitch 8 parts, modified resin 4 parts, red iron oxide 17 parts, process white 19 parts, sericite 3 parts, compound phosphorus titanium valve 12 parts, 0.5 part, anti-settling slurry, defoamer 0.3 part, dispersion agent 0.4 part, N,N-DMAA 7 parts, the first mixed solvent 9 parts; B component: modified by cardanol polyamide resin 54 parts, salt spray resistance auxiliary agent 2 parts, the second mixed solvent 39 parts.
Preparation method:
Component A: step 1, dissolves anti-settling slurry with mixed solvent, then adds epoxy resin A, epoxy resin B and coal-tar pitch, under 500rpm condition, add dispersion agent, defoamer while stirring, 500rpm continues to stir 13min, step 2, add red iron oxide, process white, zinc phosphate, N, N-DMAA and sericite, 700rpm stirs 18min, and being ground to fineness is 50 μm, step 3, add Special Resin and compound ferrophosphorus powder, 900rpm stirs 18min, to obtain final product.
B component: mixed solvent, under 500rpm condition, adds modified by cardanol polyamide resin and salt spray resistance auxiliary agent while stirring, and 500rpm stirs 15min, to obtain final product.
Embodiment 6
The difference of the present embodiment and embodiment 5 is: also include dimethylamino ethyl acrylate 3 ~ 7 parts in B component.
A kind of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint, include following component by weight: component A: epoxy resin A12 part, epoxy resin B14 part, zinc phosphate 11 parts, coal-tar pitch 8 parts, modified resin 4 parts, red iron oxide 17 parts, process white 19 parts, sericite 3 parts, compound phosphorus titanium valve 12 parts, 0.5 part, anti-settling slurry, defoamer 0.3 part, dispersion agent 0.4 part, N,N-DMAA 7 parts, the first mixed solvent 9 parts; B component: modified by cardanol polyamide resin 54 parts, salt spray resistance auxiliary agent 2 parts, dimethylamino ethyl acrylate 5 parts, the second mixed solvent 39 parts.
Preparation method:
Component A: step 1, dissolves anti-settling slurry with mixed solvent, then adds epoxy resin A, epoxy resin B and coal-tar pitch, under 500rpm condition, add dispersion agent, defoamer while stirring, 500rpm continues to stir 13min, step 2, add red iron oxide, process white, zinc phosphate, N, N-DMAA and sericite, 700rpm stirs 18min, and being ground to fineness is 50 μm, step 3, add Special Resin and compound ferrophosphorus powder, 900rpm stirs 18min, to obtain final product.
B component: mixed solvent, under 500rpm condition, adds modified by cardanol polyamide resin, dimethylamino ethyl acrylate and salt spray resistance auxiliary agent while stirring, and 500rpm stirs 15min, to obtain final product.
Performance test
Test method is: by the proportioning paint according to weight ratio 5:1 of the component A in each embodiment and B component, the above-mentioned mixed solvent configured is adopted to carry out being diluted to spray viscosity (20 ~ 30S, NK-2 cup), get salt spray resistance test steel plate and standard-bred mouth iron plate carry out phosphatization or grinding process, by the paint spraying that mixed up on material, salt spray resistance tested steel plate thickness controls at 80 ~ 100 micron thickness, on tinplate sheet, gauge control is at the thickness of 20 ~ 30 microns, after 48 hours do solid work completely, do all-round property testing, slaking tested salt spray resistance after 7 days.Time of drying, sticking power was according to GB/T1720, and impact is according to GB/T1732, and toughness is according to GB/T1731, and viscosity is according to GB/T1723, and resistance to neutral salt spray is according to GB/T1771, and the coating in over-all properties and CN102898928A contrasts according to GB/T1728.Result is as shown in the table.
As can be seen from the table, the priming paint in embodiment 1 ~ 4 has good drying property, sticking power, salt spray resistance, chemical resistance; By adding N,N-DMAA in component A, salt spray resistance and the chemical resistance of priming paint can be improved; In embodiment 6, by adding dimethylamino ethyl acrylate in B component, not only can improve surface drying and doing solid work speed, salt spray resistance and the chemical resistance of priming paint can also be improved.
Claims (10)
1. an asphalt modification epoxy phosphate zinc heavy antisepsis priming paint, is characterized in that: include following component by weight: component A: epoxy resin A10 ~ 15 part, epoxy resin B10 ~ 15 part, zinc phosphate 10 ~ 15 parts, coal-tar pitch 5 ~ 10 parts, modified resin 2 ~ 4 parts, red iron oxide 15 ~ 20 parts, process white 10 ~ 20 parts, sericite 2 ~ 5 parts, compound phosphorus titanium valve 10 ~ 15 parts, 0.4 ~ 0.6 part, anti-settling slurry, defoamer 0.2 ~ 0.4 part, dispersion agent 0.2 ~ 0.5 part, the first mixed solvent 6 ~ 11 parts; B component: modified by cardanol polyamide resin 50 ~ 60 parts, salt spray resistance auxiliary agent 1 ~ 2 part, the second mixed solvent 38 ~ 40 parts.
2. asphalt modification epoxy phosphate zinc heavy antisepsis priming paint according to claim 1, is characterized in that: also include N,N-DMAA 2 ~ 8 parts in component A.
3. asphalt modification epoxy phosphate zinc heavy antisepsis priming paint according to claim 1, is characterized in that: also include dimethylamino ethyl acrylate 3 ~ 7 parts in B component.
4. asphalt modification epoxy phosphate zinc heavy antisepsis priming paint according to claim 1, is characterized in that: described red iron oxide is that flake ferric oxide is red.
5. asphalt modification epoxy phosphate zinc heavy antisepsis priming paint according to claim 1, is characterized in that: described first mixed solvent is mixed according to volume ratio 50 ~ 70:10 ~ 20:10 ~ 20:5 ~ 15 by benzene kind solvent, alcoholic solvent, ketones solvent and ether solvent.
6. asphalt modification epoxy phosphate zinc heavy antisepsis priming paint according to claim 1, is characterized in that: described second mixed solvent is mixed according to volume ratio 50 ~ 70:10 ~ 20:10 ~ 20:5 ~ 15 by benzene kind solvent, alcoholic solvent, ketones solvent and ether solvent.
7. the asphalt modification epoxy phosphate zinc heavy antisepsis priming paint according to claim 5 or 6, is characterized in that: described benzene kind solvent is toluene, dimethylbenzene or trimethylbenzene; Alcoholic solvent is methyl alcohol, ethanol, propyl carbinol or phenylcarbinol; Ketones solvent is acetone, butanone or cyclohexanone; Esters solvent is ethylene glycol monobutyl ether.
8. the preparation method of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint according to claim 1, it is characterized in that: component A is prepared by following steps: step 1, with mixed solvent, anti-settling slurry is dissolved, add epoxy resin A again, epoxy resin B and coal-tar pitch, dispersion agent is added while stirring under 400 ~ 600rpm condition, defoamer, 400 ~ 600rpm continues stirring 10 ~ 15min, step 2, add red iron oxide, process white, zinc phosphate and sericite, 600 ~ 800rpm stirs 15 ~ 20min, being ground to fineness is 50 μm, step 3, add Special Resin and compound ferrophosphorus powder, 800 ~ 1000rpm stirs 15 ~ 20min, obtain, B component is prepared by following steps: mixed solvent, under 400 ~ 600rpm condition, adds modified by cardanol polyamide resin and salt spray resistance auxiliary agent while stirring, and 400 ~ 600rpm stirs 10 ~ 15min, to obtain final product.
9. the preparation method of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint according to claim 8, is characterized in that: also need in step 2 to add N,N-DMAA.
10. the preparation method of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint according to claim 8, is characterized in that: also need in the preparation method of B component to add dimethylamino ethyl acrylate in a solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510644596.3A CN105219253B (en) | 2015-10-08 | 2015-10-08 | A kind of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510644596.3A CN105219253B (en) | 2015-10-08 | 2015-10-08 | A kind of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105219253A true CN105219253A (en) | 2016-01-06 |
| CN105219253B CN105219253B (en) | 2018-03-13 |
Family
ID=54988548
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510644596.3A Active CN105219253B (en) | 2015-10-08 | 2015-10-08 | A kind of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105219253B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106280894A (en) * | 2016-08-26 | 2017-01-04 | 江苏华夏制漆科技有限公司 | A kind of petroleum storage tank water-base epoxy anticorrosive paint and preparation method thereof |
| CN106833266A (en) * | 2017-01-11 | 2017-06-13 | 合肥英索莱特新材料科技有限公司 | Epoxy coal tar anti-corrosive paint |
| CN109825166A (en) * | 2019-01-31 | 2019-05-31 | 连州市格雷特化工有限公司 | A kind of coil coating waste residue recoverying and utilizing method and the priming paint using this method preparation |
| CN111518427A (en) * | 2020-05-19 | 2020-08-11 | 上海锐涵信息技术有限公司 | Faucet with temperature-sensing color-changing coating |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4771088A (en) * | 1987-01-15 | 1988-09-13 | The Glidden Company | Method of stabilizing epoxy-polyamide coatings |
| CN102898928A (en) * | 2012-10-24 | 2013-01-30 | 江苏纽克莱涂料有限公司 | Moisture-curing epoxy zinc phosphate over-rust primer |
| JP2014024976A (en) * | 2012-07-27 | 2014-02-06 | Dic Graphics Corp | Aqueous resin composition |
| CN104073127A (en) * | 2014-07-04 | 2014-10-01 | 天津市津海特种涂料装饰有限公司 | Moisture-cured epoxy asphalt anticorrosive paint and preparation method thereof |
| CN104140735A (en) * | 2014-03-23 | 2014-11-12 | 成都拜迪新材料有限公司 | High-specific-weight high-zinc-content heavy-duty epoxy zinc-rich primer and preparation method thereof |
| CN104140752A (en) * | 2014-05-20 | 2014-11-12 | 成都拜迪新材料有限公司 | Preparation method of waterborne polyurethane anti-rust primer with rust for steel structure |
| CN104212332A (en) * | 2014-08-25 | 2014-12-17 | 江苏华夏制漆科技有限公司 | Epoxy aluminum-rich coating and preparation method thereof |
-
2015
- 2015-10-08 CN CN201510644596.3A patent/CN105219253B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4771088A (en) * | 1987-01-15 | 1988-09-13 | The Glidden Company | Method of stabilizing epoxy-polyamide coatings |
| JP2014024976A (en) * | 2012-07-27 | 2014-02-06 | Dic Graphics Corp | Aqueous resin composition |
| CN102898928A (en) * | 2012-10-24 | 2013-01-30 | 江苏纽克莱涂料有限公司 | Moisture-curing epoxy zinc phosphate over-rust primer |
| CN104140735A (en) * | 2014-03-23 | 2014-11-12 | 成都拜迪新材料有限公司 | High-specific-weight high-zinc-content heavy-duty epoxy zinc-rich primer and preparation method thereof |
| CN104140752A (en) * | 2014-05-20 | 2014-11-12 | 成都拜迪新材料有限公司 | Preparation method of waterborne polyurethane anti-rust primer with rust for steel structure |
| CN104073127A (en) * | 2014-07-04 | 2014-10-01 | 天津市津海特种涂料装饰有限公司 | Moisture-cured epoxy asphalt anticorrosive paint and preparation method thereof |
| CN104212332A (en) * | 2014-08-25 | 2014-12-17 | 江苏华夏制漆科技有限公司 | Epoxy aluminum-rich coating and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 陈卫星等: "《涂料及检测技术》", 31 March 2011, 化学工业出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106280894A (en) * | 2016-08-26 | 2017-01-04 | 江苏华夏制漆科技有限公司 | A kind of petroleum storage tank water-base epoxy anticorrosive paint and preparation method thereof |
| CN106833266A (en) * | 2017-01-11 | 2017-06-13 | 合肥英索莱特新材料科技有限公司 | Epoxy coal tar anti-corrosive paint |
| CN109825166A (en) * | 2019-01-31 | 2019-05-31 | 连州市格雷特化工有限公司 | A kind of coil coating waste residue recoverying and utilizing method and the priming paint using this method preparation |
| CN111518427A (en) * | 2020-05-19 | 2020-08-11 | 上海锐涵信息技术有限公司 | Faucet with temperature-sensing color-changing coating |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105219253B (en) | 2018-03-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105733405A (en) | Graphene-based enhanced high-solid epoxy anticorrosive coating and method for preparing same | |
| CN106221458A (en) | A kind of steel construction special anti-corrosion sealing wax and preparation method thereof | |
| CN103232786B (en) | A kind of Solvent-free nanometer epoxy anticorrosive paint and preparation method thereof | |
| CN101633808A (en) | High chlorinated polyethylene coating containing stainless steel flakes and preparation method thereof | |
| CN103881531A (en) | Epoxy zinc-enriched coating and preparation method thereof | |
| CN106811004A (en) | A kind of heavy antisepsis non-solvent epoxy basalt flake paint and preparation method thereof | |
| CN105219253A (en) | A kind of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint and preparation method thereof | |
| CN102585665B (en) | Methanol-gasoline-resisting static-electricity-conducting anticorrosive paint | |
| CN103483983B (en) | A kind of epoxy zinc rich primer and preparation method thereof | |
| CN101143991A (en) | Polyaniline anticorrosion paint easy to disperse | |
| CN110343455A (en) | Aqueous heavy anti-corrosion paint, preparation method and the purposes of the coupling agent modified graphene of silane-containing | |
| CN106833271A (en) | A kind of graphite ene-type water-thinned epoxy zinc-rich anticorrosive paint and preparation method thereof | |
| CN104403463A (en) | Aqueous low-surface treatment coating for iron power transmission tower surface protection and preparation method for aqueous low-surface treatment coating | |
| CN105219218A (en) | A kind of aqueous phenolic aldehyde epoxy anticorrosive paint and preparation method thereof | |
| CN107556886A (en) | A kind of graphite-epoxy alkene zinc powder coating | |
| CN105907240B (en) | A kind of water corrosion-resistant epoxy paint and preparation method thereof containing anti-flash rusting agent | |
| CN104845499A (en) | Preparation method for waterborne epoxy paste paint | |
| CN105925138B (en) | A kind of anticorrosive paint and preparation method thereof for metal rusty scale | |
| CN105176265A (en) | Steel plate pre-coating quick-drying anti-corrosive primer and preparation method thereof | |
| CN103214655B (en) | Modified epoxy resin and high-solid anticorrosive coating prepared therewith | |
| CN106867357B (en) | A kind of nanometer modified high-solid body divides epoxy primer | |
| CN104356868A (en) | Coating composition directly painted on rust layer | |
| CN106833335B (en) | A kind of anticorrosive paint composite modified using nano graphite flakes and rare earth oxide | |
| CN103773174B (en) | Electrostatic conductive anticorrosion paint composition | |
| CN102408788B (en) | Anticorrosive coating with high bonding strength |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |