WO2022041418A1 - Environment-friendly non-toxic wastewater treatment agent and preparation method therefor - Google Patents
Environment-friendly non-toxic wastewater treatment agent and preparation method therefor Download PDFInfo
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- WO2022041418A1 WO2022041418A1 PCT/CN2020/121927 CN2020121927W WO2022041418A1 WO 2022041418 A1 WO2022041418 A1 WO 2022041418A1 CN 2020121927 W CN2020121927 W CN 2020121927W WO 2022041418 A1 WO2022041418 A1 WO 2022041418A1
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
Definitions
- the invention relates to the technical field of sewage treatment, in particular to an environment-friendly non-toxic sewage treatment agent and a preparation method thereof.
- the sewage treatment agent of the prior art has an unsatisfactory effect in treating the above-mentioned sewage.
- polyacrylamide is used as the flocculant for land-source sewage, which has a certain treatment effect, but secondary pollution occurs; the flocculant used in the treatment of coastal waters contains some biological toxicity and will cause secondary pollution; marine aquaculture wastewater is generally
- the adopted physical and chemical methods to control water quality have drawbacks.
- the present invention provides an environment-friendly non-toxic sewage treatment agent and a preparation method thereof.
- the technical problem to be solved by the present invention is to propose an environmentally friendly and non-toxic sewage treatment agent and a preparation method thereof in view of the above shortcomings of the prior art, which efficiently and reasonably treats sewage, improves the work efficiency of workers, saves time and effort, and saves energy.
- Environmental friendly is to propose an environmentally friendly and non-toxic sewage treatment agent and a preparation method thereof in view of the above shortcomings of the prior art, which efficiently and reasonably treats sewage, improves the work efficiency of workers, saves time and effort, and saves energy.
- Component A includes the following components in parts by mass: silicone modified epoxy resin: 8-12 parts, dispersant: 2-8 parts, graphite powder: 10-16 parts, potassium hydrogen phthalate: 2-7 parts, nano silica: 4-9 parts, activated carbon: 22-28 parts, potassium dihydrogen phosphate: 11-17 parts, iron sulfate: 3-8 parts, bentonite: 12-18 parts, aluminum sulfate: 3-8 parts, calcium hydroxide: 19-22 parts;
- Component B includes the following components in parts by mass: citric acid: 9-16 parts, plant fiber: 11-18 parts, microbial inoculum: 9-13 parts, organic acid: 6-9 parts, coagulation agent : 12-18 parts, propylene carbonate: 10-15 parts, 3-butanediol: 2-6 parts, defoamer: 19-22 parts, solvent: 20-27 parts, polychloride salt: 13- 19 parts, synergistic additives: 10-16 parts;
- the C component includes the following components in parts by mass: PVC foaming regulator LP-40: 3-8 parts, 3-methylphenol: 6-10 parts, antioxidant: 12-18 parts, wood fiber Powder: 29-31 parts, carbon fiber powder: 17-20 parts, water glass: 18-22 parts, flame retardant: 3-8 parts, leveling agent: 12-18 parts, stabilizer: 13-18 parts, accessories : 16-20 servings.
- Aforesaid environmentally friendly non-toxic sewage treatment agent, dispersant is a kind of in stearamide, barium stearate or zinc stearate; vegetable fiber is sisal fiber, castor fiber, coconut palm fiber or elm bark fiber.
- the microbial inoculum is a mixture of one or more of Bacillus subtilis, Bacillus megaterium, Bacillus peptone, and rhizobia;
- the organic acid is one of tartaric acid or maleic acid;
- the coagulation agent is One of iron polysilicate or polyacrylamide;
- defoamer is propylene oxide or a mixture of ethylene oxide and propylene oxide;
- solvent is water;
- synergistic additive is methyl isothiazolinone, lignin sulfonic acid The mixture of sodium and chitosan according to the weight ratio of 2:1:1.5;
- the antioxidant is the mixture of antioxidant 1076 and antioxidant 1010;
- the flame retardant is phosphate triester;
- the stabilizer is CH4O2 calcium zinc stabilizer , one of dibasic lead phthalate or barium stearate;
- the auxiliary material is composite rare earth, and the composite rare earth includes the following components by mass percentage: dysprosium: 9
- Component A includes the following components in parts by mass: silicone modified epoxy resin: 8 parts, dispersant: 2 parts, graphite powder: 10 parts, potassium hydrogen phthalate: 2 parts, nanometer dioxide Silicon: 4 parts, activated carbon: 22 parts, potassium dihydrogen phosphate: 11 parts, iron sulfate: 3 parts, bentonite: 12 parts, aluminum sulfate: 3 parts, calcium hydroxide: 19 parts;
- Component B includes the following components in parts by mass: citric acid: 9 parts, plant fiber: 11 parts, microbial inoculum: 9 parts, organic acid: 6 parts, coagulation agent: 12 parts, propylene carbonate : 10 parts, 3-butanediol: 2 parts, defoamer: 19 parts, solvent: 20 parts, polychloride salt: 13 parts, synergistic additive: 10 parts;
- Component C includes the following components in parts by mass: PVC foaming regulator LP-40: 3 parts, 3-methylphenol: 6 parts, antioxidant: 12 parts, wood fiber powder: 29 parts, carbon fiber Powder: 17 parts, water glass: 18 parts, flame retardant: 3 parts, leveling agent: 12 parts, stabilizer: 13 parts, auxiliary materials: 16 parts.
- Component A includes the following components in parts by mass: silicone modified epoxy resin: 12 parts, dispersant: 8 parts, graphite powder: 16 parts, potassium hydrogen phthalate: 7 parts, nano-dioxide Silicon: 9 parts, activated carbon: 28 parts, potassium dihydrogen phosphate: 17 parts, iron sulfate: 8 parts, bentonite: 18 parts, aluminum sulfate: 8 parts, calcium hydroxide: 22 parts;
- Component B includes the following components in parts by mass: citric acid: 16 parts, plant fiber: 18 parts, microbial inoculum: 13 parts, organic acid: 9 parts, coagulation agent: 18 parts, propylene carbonate : 15 parts, 3-butanediol: 6 parts, defoamer: 22 parts, solvent: 27 parts, polychloride salt: 19 parts, synergistic additive: 16 parts;
- Component C includes the following components in parts by mass: PVC foaming regulator LP-40: 8 parts, 3-methylphenol: 10 parts, antioxidant: 18 parts, wood fiber powder: 31 parts, carbon fiber Powder: 20 parts, water glass: 22 parts, flame retardant: 8 parts, leveling agent: 18 parts, stabilizer: 18 parts, auxiliary materials: 20 parts.
- Component A includes the following components in parts by mass: silicone modified epoxy resin: 11 parts, dispersant: 6 parts, graphite powder: 12 parts, potassium hydrogen phthalate: 5 parts, nano-dioxide Silicon: 6 parts, activated carbon: 25 parts, potassium dihydrogen phosphate: 16 parts, iron sulfate: 5 parts, bentonite: 15 parts, aluminum sulfate: 6 parts, calcium hydroxide: 20 parts;
- Component B includes the following components in parts by mass: citric acid: 12 parts, plant fiber: 15 parts, microbial inoculum: 12 parts, organic acid: 8 parts, coagulation agent: 14 parts, propylene carbonate : 12 parts, 3-butanediol: 4 parts, defoamer: 20 parts, solvent: 24 parts, polychloride salt: 17 parts, synergistic additive: 12 parts;
- Component C includes the following components in parts by mass: PVC foaming regulator LP-40: 5 parts, 3-methylphenol: 8 parts, antioxidant: 14 parts, wood fiber powder: 30 parts, carbon fiber Powder: 18 parts, water glass: 20 parts, flame retardant: 5 parts, leveling agent: 14 parts, stabilizer: 15 parts, auxiliary materials: 18 parts.
- the preparation method of the aforementioned environmentally friendly non-toxic sewage treatment agent comprises the following steps:
- step (1) adding ferric sulfate, bentonite, aluminum sulfate and calcium hydroxide to step (1) again, stirring at normal temperature to obtain component A for later use;
- the PVC foaming regulator LP-40, 3-methylphenol and antioxidant are added to the mixer for stirring, the stirring time is 30-40min, the stirring speed is 300-350r/min, and the wood fiber powder is added while stirring , carbon fiber powder, water glass and flame retardant continue to stir for 30-35min, stirring speed is 200-250r/min, finally add leveling agent, stabilizer and auxiliary materials and stir to appropriate viscosity, filter to obtain C component.
- a microbial inoculant added in the present invention has a better inhibitory and killing effect on fungi and pathogenic bacteria in sewage, and on the other hand, it avoids chemical bactericides on water bodies.
- Secondary pollution which is non-toxic and harmless to the human body, greatly improves the environmental protection performance of the sewage treatment agent; activated carbon is also added in the present invention, which has better adsorption capacity for heavy metal ions contained in sewage, and the cost of bamboo charcoal is lower. , can effectively reduce the cost of sewage treatment.
- the sewage treatment agent of the invention can effectively remove pollutants in domestic sewage, improve water quality, and has no additional impact on water quality, long-term improvement of water quality, low production cost, reasonable component design, green environmental protection, and good economic benefits.
- the present embodiment provides an environmentally friendly and non-toxic sewage treatment agent.
- Component A includes the following components in parts by mass: silicone modified epoxy resin: 8 parts, dispersant: 2 parts, graphite powder: 10 parts, potassium hydrogen phthalate: 2 parts, nanometer dioxide Silicon: 4 parts, activated carbon: 22 parts, potassium dihydrogen phosphate: 11 parts, iron sulfate: 3 parts, bentonite: 12 parts, aluminum sulfate: 3 parts, calcium hydroxide: 19 parts;
- Component B includes the following components in parts by mass: citric acid: 9 parts, plant fiber: 11 parts, microbial inoculum: 9 parts, organic acid: 6 parts, coagulation agent: 12 parts, propylene carbonate : 10 parts, 3-butanediol: 2 parts, defoamer: 19 parts, solvent: 20 parts, polychloride salt: 13 parts, synergistic additive: 10 parts;
- Component C includes the following components in parts by mass: PVC foaming regulator LP-40: 3 parts, 3-methylphenol: 6 parts, antioxidant: 12 parts, wood fiber powder: 29 parts, carbon fiber Powder: 17 parts, water glass: 18 parts, flame retardant: 3 parts, leveling agent: 12 parts, stabilizer: 13 parts, accessories: 16 parts;
- the dispersant is one of stearamide, barium stearate or zinc stearate;
- the plant fiber is one of sisal fiber, castor fiber, coconut palm fiber or elm bark fiber;
- the microbial agent is Bacillus subtilis Mixture of one or more of Bacillus megaterium, Bacillus megaterium, Bacillus peptone, and Rhizobium;
- the organic acid is one of tartaric acid or maleic acid;
- the coagulation agent is polyiron silicate or polyacrylamide
- the antifoaming agent is propylene oxide or the mixture of ethylene oxide and propylene oxide;
- the solvent is water;
- the synergistic additive is methylisothiazolinone, sodium lignosulfonate, chitosan according to weight A mixture of 2:1:1.5;
- antioxidant is a mixture of antioxidant 1076 and antioxidant 1010; flame retardant is phosphate triester; stabilizer is CH4O2 calcium zinc stabilizer, dibasic lead
- the preparation method of the above-mentioned environmentally friendly non-toxic sewage treatment agent comprises the following steps:
- step (1) adding ferric sulfate, bentonite, aluminum sulfate and calcium hydroxide to step (1) again, stirring at normal temperature to obtain component A for later use;
- the PVC foaming regulator LP-40, 3-methylphenol and antioxidant are added into the mixer for stirring, the stirring time is 30min, the stirring speed is 300r/min, and the wood fiber powder, carbon fiber powder, The water glass and the flame retardant were continuously stirred for 30 minutes, and the stirring speed was 200 r/min. Finally, the leveling agent, stabilizer and auxiliary materials were added and stirred to a suitable viscosity, and the C component was obtained by filtration.
- the present embodiment provides an environmentally friendly and non-toxic sewage treatment agent.
- Component A includes the following components in parts by mass: silicone modified epoxy resin: 12 parts, dispersant: 8 parts, graphite powder: 16 parts, potassium hydrogen phthalate: 7 parts, nano-dioxide Silicon: 9 parts, activated carbon: 28 parts, potassium dihydrogen phosphate: 17 parts, iron sulfate: 8 parts, bentonite: 18 parts, aluminum sulfate: 8 parts, calcium hydroxide: 22 parts;
- Component B includes the following components in parts by mass: citric acid: 16 parts, plant fiber: 18 parts, microbial inoculum: 13 parts, organic acid: 9 parts, coagulation agent: 18 parts, propylene carbonate : 15 parts, 3-butanediol: 6 parts, defoamer: 22 parts, solvent: 27 parts, polychloride salt: 19 parts, synergistic additive: 16 parts;
- Component C includes the following components in parts by mass: PVC foaming regulator LP-40: 8 parts, 3-methylphenol: 10 parts, antioxidant: 18 parts, wood fiber powder: 31 parts, carbon fiber Powder: 20 parts, water glass: 22 parts, flame retardant: 8 parts, leveling agent: 18 parts, stabilizer: 18 parts, accessories: 20 parts;
- Dispersant is a kind of in stearamide, barium stearate or zinc stearate;
- Plant fiber is a kind of in sisal fiber, castor fiber, coconut palm fiber or elm bark fiber;
- Microbial agent is Bacillus subtilis Mixture of one or more of Bacillus megaterium, Bacillus megaterium, Bacillus peptone, and Rhizobium;
- the organic acid is one of tartaric acid or maleic acid;
- the coagulation agent is polyiron silicate or polyacrylamide
- the antifoaming agent is propylene oxide or the mixture of ethylene oxide and propylene oxide;
- the solvent is water;
- the synergistic additive is methylisothiazolinone, sodium lignosulfonate, chitosan according to weight A mixture of 2:1:1.5;
- antioxidant is a mixture of antioxidant 1076 and antioxidant 1010;
- flame retardant is phosphate triester;
- stabilizer is CH4O2 calcium zinc stabilizer
- the preparation method of the above-mentioned environmentally friendly non-toxic sewage treatment agent comprises the following steps:
- step (1) adding ferric sulfate, bentonite, aluminum sulfate and calcium hydroxide to step (1) again, stirring at normal temperature to obtain component A for later use;
- the present embodiment provides an environmentally friendly and non-toxic sewage treatment agent.
- Component A includes the following components in parts by mass: silicone modified epoxy resin: 11 parts, dispersant: 6 parts, graphite powder: 12 parts, potassium hydrogen phthalate: 5 parts, nano-dioxide Silicon: 6 parts, activated carbon: 25 parts, potassium dihydrogen phosphate: 16 parts, iron sulfate: 5 parts, bentonite: 15 parts, aluminum sulfate: 6 parts, calcium hydroxide: 20 parts;
- Component B includes the following components in parts by mass: citric acid: 12 parts, plant fiber: 15 parts, microbial inoculum: 12 parts, organic acid: 8 parts, coagulation agent: 14 parts, propylene carbonate : 12 parts, 3-butanediol: 4 parts, defoamer: 20 parts, solvent: 24 parts, polychloride salt: 17 parts, synergistic additive: 12 parts;
- Component C includes the following components in parts by mass: PVC foaming regulator LP-40: 5 parts, 3-methylphenol: 8 parts, antioxidant: 14 parts, wood fiber powder: 30 parts, carbon fiber Powder: 18 parts, water glass: 20 parts, flame retardant: 5 parts, leveling agent: 14 parts, stabilizer: 15 parts, accessories: 18 parts;
- the dispersant is one of stearamide, barium stearate or zinc stearate;
- the plant fiber is one of sisal fiber, castor fiber, coconut palm fiber or elm bark fiber;
- the microbial agent is Bacillus subtilis Mixture of one or more of Bacillus megaterium, Bacillus megaterium, Bacillus peptone, and Rhizobium;
- the organic acid is one of tartaric acid or maleic acid;
- the coagulation agent is polyiron silicate or polyacrylamide
- the antifoaming agent is propylene oxide or the mixture of ethylene oxide and propylene oxide;
- the solvent is water;
- the synergistic additive is methylisothiazolinone, sodium lignosulfonate, chitosan according to weight A mixture of 2:1:1.5;
- antioxidant is a mixture of antioxidant 1076 and antioxidant 1010; flame retardant is phosphate triester; stabilizer is CH4O2 calcium zinc stabilizer, dibasic lead
- the preparation method of the above-mentioned environmentally friendly non-toxic sewage treatment agent comprises the following steps:
- step (1) adding ferric sulfate, bentonite, aluminum sulfate and calcium hydroxide to step (1) again, stirring at normal temperature to obtain component A for later use;
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Abstract
Disclosed in the present invention is an environment-friendly non-toxic wastewater treatment agent. The environment-friendly non-toxic wastewater treatment agent is formed by compounding three components A, B, and C according to the ratio of A:B:C=3:1:2, and A, B, and C contains the following components in parts by mass: 8-12 parts of an organic silicone-modified epoxy resin, 2-8 parts of a dispersant, 10-16 parts of graphite powder, 2-7 parts of potassium hydrogen phthalate, 4-9 parts of nano-silica, 22-28 parts of activated carbon, 11-17 parts of potassium dihydrogen phosphate, 3-8 parts of ferric sulfate, 12-18 parts of bentonite, 3-8 parts of aluminum sulfate, 19-22 parts of calcium hydroxide; 9-16 parts of citric acid, 11-18 parts of plant fibers, 9-13 parts of a microbial agent, 6-9 parts of an organic acid, 12-18 parts of a coagulating agent, 10-15 parts of propylene carbonate, 2-6 parts of 3-butanediol, 19-22 parts of a defoaming agent, 20-27 parts of a solvent, 13-19 parts of a polychlorate, 10-16 parts of a synergistic additive; 3-8 parts of a PVC foaming regulator LP-40, 6-10 parts of 3-methylphenol, 12-18 parts of an antioxidant, 29-31 parts of wood fiber powder, 17-20 parts of carbon fiber powder, 18-22 parts of sodium silicate, 3-8 parts of a flame retardant, 12-18 parts of a leveling agent, 13-18 parts of a stabilizer, and 16-20 parts of an auxiliary material.
Description
本发明涉及污水处理技术领域,具体的说是涉及一种环保无毒污水处理剂及其制备方法。The invention relates to the technical field of sewage treatment, in particular to an environment-friendly non-toxic sewage treatment agent and a preparation method thereof.
当前,环境保护已成为世界关注的问题,工业污水的排放要求严格,国家采取了相应的强制措施,寻求一种有效的污水处理剂,能够使污水处理后能达到污水排放要求,是众多企业急需解决的难题。At present, environmental protection has become a concern of the world. The discharge requirements of industrial sewage are strict. The state has taken corresponding compulsory measures to seek an effective sewage treatment agent, which can make sewage treatment meet the sewage discharge requirements, which is urgently needed by many enterprises. problem solved.
现有技术的污水处理剂处理上述污水效果并不理想。如陆源污水絮凝剂多采用聚丙烯酰胺等,有一定的处理效果,但是出现二次污染;近岸海域污水处理采用的絮凝剂含有一些生物毒性及且会造成二次污染;海水养殖废水由于一般所采用的理化方法控制水质的技术存有弊端。为改善这一现状,开发多功能环保型污水处理药剂,高效合理的处理污水,本发明提出了一种环保无毒污水处理剂及其制备方法。The sewage treatment agent of the prior art has an unsatisfactory effect in treating the above-mentioned sewage. For example, polyacrylamide is used as the flocculant for land-source sewage, which has a certain treatment effect, but secondary pollution occurs; the flocculant used in the treatment of coastal waters contains some biological toxicity and will cause secondary pollution; marine aquaculture wastewater is generally The adopted physical and chemical methods to control water quality have drawbacks. In order to improve the current situation, develop multifunctional environment-friendly sewage treatment agents, and treat sewage efficiently and reasonably, the present invention provides an environment-friendly non-toxic sewage treatment agent and a preparation method thereof.
发明内容SUMMARY OF THE INVENTION
本发明所要解决的技术问题是,针对以上现有技术存在的缺点提出一种环保无毒污水处理剂及其制备方法,高效合理的处理了污水,提高了工人的工作效率,省时省力,节能环保。The technical problem to be solved by the present invention is to propose an environmentally friendly and non-toxic sewage treatment agent and a preparation method thereof in view of the above shortcomings of the prior art, which efficiently and reasonably treats sewage, improves the work efficiency of workers, saves time and effort, and saves energy. Environmental friendly.
本发明解决以上技术问题的技术方案是:The technical scheme that the present invention solves the above technical problems is:
一种环保无毒污水处理剂,环保无毒污水处理剂由甲乙丙三组分按甲∶乙∶丙=3∶1∶2的比例复合而成,甲乙丙以质量份数计包含以下组分:An environmentally friendly and non-toxic sewage treatment agent, the environmentally friendly and non-toxic sewage treatment agent is composed of three components of methyl ethyl propylene in the ratio of A:B:C=3:1:2, and methyl ethyl propylene The following components are included in parts by mass :
甲组分中按质量份数计包括以下组分:有机硅改性环氧树脂:8-12份,分散剂:2-8份,石墨粉:10-16份,领苯二甲酸氢钾:2-7份,纳米二氧化硅:4-9份,活性炭:22-28份,磷酸二氢钾:11-17份,硫酸铁:3-8份,膨润土:12-18份,硫酸铝:3-8份,氢氧化钙:19-22份;Component A includes the following components in parts by mass: silicone modified epoxy resin: 8-12 parts, dispersant: 2-8 parts, graphite powder: 10-16 parts, potassium hydrogen phthalate: 2-7 parts, nano silica: 4-9 parts, activated carbon: 22-28 parts, potassium dihydrogen phosphate: 11-17 parts, iron sulfate: 3-8 parts, bentonite: 12-18 parts, aluminum sulfate: 3-8 parts, calcium hydroxide: 19-22 parts;
乙组分中按质量份数计包括以下组分:柠檬酸:9-16份,植物纤维:11-18份,微生物菌剂:9-13份,有机酸:6-9份,聚沉剂:12-18份,碳酸亚丙脂:10-15份,3-丁二醇:2-6份,消泡剂:19-22份,溶剂:20-27份,聚合氯化盐:13-19份,增效添加物:10-16份;Component B includes the following components in parts by mass: citric acid: 9-16 parts, plant fiber: 11-18 parts, microbial inoculum: 9-13 parts, organic acid: 6-9 parts, coagulation agent : 12-18 parts, propylene carbonate: 10-15 parts, 3-butanediol: 2-6 parts, defoamer: 19-22 parts, solvent: 20-27 parts, polychloride salt: 13- 19 parts, synergistic additives: 10-16 parts;
丙组分中按质量份数计包括以下组分:PVC发泡调节剂LP-40:3-8份,3-甲基苯酚:6-10份,抗氧剂:12-18份,木质纤维粉:29-31份,碳纤维粉:17-20份,水玻璃:18-22份,阻燃剂:3-8份,流平剂:12-18份,稳定剂:13-18份,辅料:16-20份。The C component includes the following components in parts by mass: PVC foaming regulator LP-40: 3-8 parts, 3-methylphenol: 6-10 parts, antioxidant: 12-18 parts, wood fiber Powder: 29-31 parts, carbon fiber powder: 17-20 parts, water glass: 18-22 parts, flame retardant: 3-8 parts, leveling agent: 12-18 parts, stabilizer: 13-18 parts, accessories : 16-20 servings.
本发明进一步限定的技术方案是:The technical scheme that the present invention is further limited is:
前述的环保无毒污水处理剂,分散剂为硬脂酰胺、硬脂酸钡或硬脂酸锌中的一种;植物纤维为剑麻纤维、蓖麻纤维、椰棕纤维或榆树皮纤维中的一种;微生物菌剂为枯草芽孢杆菌、巨大芽孢杆菌、胶胨样芽孢杆菌、根瘤菌中的一种或多种的混合;有机酸为酒石酸或马来酸中的一种;聚沉剂为聚硅酸铁或聚丙烯酰胺中的一种;消泡剂为环氧丙烷或环氧乙烷与环氧丙烷的混合物;溶剂为水;增效添加剂为甲基异噻唑啉酮、木质素磺酸钠、壳聚糖按照重量比2:1:1.5组成的混合物;抗氧剂为抗氧剂1076和抗氧剂1010的混合物;阻燃剂为磷酸三酯;稳定剂为CH4O2钙锌稳定剂、二盐基邻苯二甲酸铅或硬脂酸钡中的一种;辅料为复合稀土,复合稀土按质量百分比计包括以下组分:镝:9-12%,铈:15-19%,镨:19-22%,钕:1-5%,其余为镧系元素,以上镧系稀土各组分之和为100%。Aforesaid environmentally friendly non-toxic sewage treatment agent, dispersant is a kind of in stearamide, barium stearate or zinc stearate; vegetable fiber is sisal fiber, castor fiber, coconut palm fiber or elm bark fiber. One; the microbial inoculum is a mixture of one or more of Bacillus subtilis, Bacillus megaterium, Bacillus peptone, and rhizobia; the organic acid is one of tartaric acid or maleic acid; the coagulation agent is One of iron polysilicate or polyacrylamide; defoamer is propylene oxide or a mixture of ethylene oxide and propylene oxide; solvent is water; synergistic additive is methyl isothiazolinone, lignin sulfonic acid The mixture of sodium and chitosan according to the weight ratio of 2:1:1.5; the antioxidant is the mixture of antioxidant 1076 and antioxidant 1010; the flame retardant is phosphate triester; the stabilizer is CH4O2 calcium zinc stabilizer , one of dibasic lead phthalate or barium stearate; the auxiliary material is composite rare earth, and the composite rare earth includes the following components by mass percentage: dysprosium: 9-12%, cerium: 15-19%, praseodymium : 19-22%, neodymium: 1-5%, the rest are lanthanide elements, and the sum of the above lanthanide rare earth components is 100%.
前述的环保无毒污水处理剂,环保无毒污水处理剂由甲乙丙三组分按甲∶乙∶丙=3∶1∶2的比例复合而成,甲乙丙以质量份数计包含以下组分:The aforementioned environmentally friendly non-toxic sewage treatment agent, the environmentally friendly non-toxic sewage treatment agent is compounded by the three components of A, B: C = 3: 1: 2, and the A, B, and C comprise the following components in parts by mass :
甲组分中按质量份数计包括以下组分:有机硅改性环氧树脂:8份,分散剂:2份,石墨粉:10份,领苯二甲酸氢钾:2份,纳米二氧化硅:4份,活性炭:22份,磷酸二氢钾:11份,硫酸铁:3份,膨润土:12份,硫酸铝:3份,氢氧化钙:19份;Component A includes the following components in parts by mass: silicone modified epoxy resin: 8 parts, dispersant: 2 parts, graphite powder: 10 parts, potassium hydrogen phthalate: 2 parts, nanometer dioxide Silicon: 4 parts, activated carbon: 22 parts, potassium dihydrogen phosphate: 11 parts, iron sulfate: 3 parts, bentonite: 12 parts, aluminum sulfate: 3 parts, calcium hydroxide: 19 parts;
乙组分中按质量份数计包括以下组分:柠檬酸:9份,植物纤维:11份,微生物菌剂:9份,有机酸:6份,聚沉剂:12份,碳酸亚丙脂:10份,3-丁二醇:2份,消泡剂:19份,溶剂:20份,聚合氯化盐:13份,增效添加物:10份;Component B includes the following components in parts by mass: citric acid: 9 parts, plant fiber: 11 parts, microbial inoculum: 9 parts, organic acid: 6 parts, coagulation agent: 12 parts, propylene carbonate : 10 parts, 3-butanediol: 2 parts, defoamer: 19 parts, solvent: 20 parts, polychloride salt: 13 parts, synergistic additive: 10 parts;
丙组分中按质量份数计包括以下组分:PVC发泡调节剂LP-40:3份,3-甲基苯酚:6份,抗氧剂:12份,木质纤维粉:29份,碳纤维粉:17份,水玻璃:18份,阻燃剂:3份,流平剂:12份,稳定剂:13份,辅料:16份。Component C includes the following components in parts by mass: PVC foaming regulator LP-40: 3 parts, 3-methylphenol: 6 parts, antioxidant: 12 parts, wood fiber powder: 29 parts, carbon fiber Powder: 17 parts, water glass: 18 parts, flame retardant: 3 parts, leveling agent: 12 parts, stabilizer: 13 parts, auxiliary materials: 16 parts.
前述的环保无毒污水处理剂,环保无毒污水处理剂由甲乙丙三组分按甲∶乙∶丙=3∶1∶2的比例复合而成,甲乙丙以质量份数计包含以下组分:The aforementioned environmentally friendly non-toxic sewage treatment agent, the environmentally friendly non-toxic sewage treatment agent is compounded by the three components of A, B: C = 3: 1: 2, and the A, B, and C comprise the following components in parts by mass :
甲组分中按质量份数计包括以下组分:有机硅改性环氧树脂:12份,分散剂:8份,石墨粉:16份,领苯二甲酸氢钾:7份,纳米二氧化硅:9份,活性炭:28份,磷酸二氢钾:17份,硫酸铁:8份,膨润土:18份,硫酸铝:8份,氢氧化钙:22份;Component A includes the following components in parts by mass: silicone modified epoxy resin: 12 parts, dispersant: 8 parts, graphite powder: 16 parts, potassium hydrogen phthalate: 7 parts, nano-dioxide Silicon: 9 parts, activated carbon: 28 parts, potassium dihydrogen phosphate: 17 parts, iron sulfate: 8 parts, bentonite: 18 parts, aluminum sulfate: 8 parts, calcium hydroxide: 22 parts;
乙组分中按质量份数计包括以下组分:柠檬酸:16份,植物纤维:18份,微生物菌剂:13份,有机酸:9份,聚沉剂:18份,碳酸亚丙脂:15份,3-丁二醇:6份,消泡剂:22份,溶剂:27份,聚合氯化盐:19份,增效添加物:16份;Component B includes the following components in parts by mass: citric acid: 16 parts, plant fiber: 18 parts, microbial inoculum: 13 parts, organic acid: 9 parts, coagulation agent: 18 parts, propylene carbonate : 15 parts, 3-butanediol: 6 parts, defoamer: 22 parts, solvent: 27 parts, polychloride salt: 19 parts, synergistic additive: 16 parts;
丙组分中按质量份数计包括以下组分:PVC发泡调节剂LP-40:8份,3-甲基苯酚:10 份,抗氧剂:18份,木质纤维粉:31份,碳纤维粉:20份,水玻璃:22份,阻燃剂:8份,流平剂:18份,稳定剂:18份,辅料:20份。Component C includes the following components in parts by mass: PVC foaming regulator LP-40: 8 parts, 3-methylphenol: 10 parts, antioxidant: 18 parts, wood fiber powder: 31 parts, carbon fiber Powder: 20 parts, water glass: 22 parts, flame retardant: 8 parts, leveling agent: 18 parts, stabilizer: 18 parts, auxiliary materials: 20 parts.
前述的环保无毒污水处理剂,环保无毒污水处理剂由甲乙丙三组分按甲∶乙∶丙=3∶1∶2的比例复合而成,甲乙丙以质量份数计包含以下组分:The aforementioned environmentally friendly non-toxic sewage treatment agent, the environmentally friendly non-toxic sewage treatment agent is compounded by the three components of A, B: C = 3: 1: 2, and the A, B, and C comprise the following components in parts by mass :
甲组分中按质量份数计包括以下组分:有机硅改性环氧树脂:11份,分散剂:6份,石墨粉:12份,领苯二甲酸氢钾:5份,纳米二氧化硅:6份,活性炭:25份,磷酸二氢钾:16份,硫酸铁:5份,膨润土:15份,硫酸铝:6份,氢氧化钙:20份;Component A includes the following components in parts by mass: silicone modified epoxy resin: 11 parts, dispersant: 6 parts, graphite powder: 12 parts, potassium hydrogen phthalate: 5 parts, nano-dioxide Silicon: 6 parts, activated carbon: 25 parts, potassium dihydrogen phosphate: 16 parts, iron sulfate: 5 parts, bentonite: 15 parts, aluminum sulfate: 6 parts, calcium hydroxide: 20 parts;
乙组分中按质量份数计包括以下组分:柠檬酸:12份,植物纤维:15份,微生物菌剂:12份,有机酸:8份,聚沉剂:14份,碳酸亚丙脂:12份,3-丁二醇:4份,消泡剂:20份,溶剂:24份,聚合氯化盐:17份,增效添加物:12份;Component B includes the following components in parts by mass: citric acid: 12 parts, plant fiber: 15 parts, microbial inoculum: 12 parts, organic acid: 8 parts, coagulation agent: 14 parts, propylene carbonate : 12 parts, 3-butanediol: 4 parts, defoamer: 20 parts, solvent: 24 parts, polychloride salt: 17 parts, synergistic additive: 12 parts;
丙组分中按质量份数计包括以下组分:PVC发泡调节剂LP-40:5份,3-甲基苯酚:8份,抗氧剂:14份,木质纤维粉:30份,碳纤维粉:18份,水玻璃:20份,阻燃剂:5份,流平剂:14份,稳定剂:15份,辅料:18份。Component C includes the following components in parts by mass: PVC foaming regulator LP-40: 5 parts, 3-methylphenol: 8 parts, antioxidant: 14 parts, wood fiber powder: 30 parts, carbon fiber Powder: 18 parts, water glass: 20 parts, flame retardant: 5 parts, leveling agent: 14 parts, stabilizer: 15 parts, auxiliary materials: 18 parts.
前述的环保无毒污水处理剂的制备方法,该制备方法包括以下步骤:The preparation method of the aforementioned environmentally friendly non-toxic sewage treatment agent, the preparation method comprises the following steps:
(一)将有机硅改性环氧树脂、分散剂、石墨粉以及领苯二甲酸氢钾加入分散缸中,控制分散缸的温度在60-65℃,高速搅拌均匀,搅拌速度为800-900r/min,搅拌时间为40-45min搅拌结束后加入纳米二氧化硅、活性炭以及磷酸二氢钾,高速搅拌30-40min,控制分散缸温度在70-80℃;;(1) Add silicone modified epoxy resin, dispersant, graphite powder and potassium hydrogen phthalate into the dispersing cylinder, control the temperature of the dispersing cylinder at 60-65°C, stir evenly at high speed, and the stirring speed is 800-900r /min, the stirring time is 40-45min. After stirring, nano-silica, activated carbon and potassium dihydrogen phosphate are added, and the high-speed stirring is 30-40min, and the temperature of the dispersion tank is controlled at 70-80 °C;
(二)再向步骤(一)中加入硫酸铁、膨润土、硫酸铝以及氢氧化钙,在常温下搅拌均匀,即可得到甲组份待用;(2) adding ferric sulfate, bentonite, aluminum sulfate and calcium hydroxide to step (1) again, stirring at normal temperature to obtain component A for later use;
(三)将柠檬酸、植物纤维、微生物菌剂以及有机酸加入搅拌机中进行搅拌,搅拌40-50min,搅拌速度为900-1000r/min,加入聚沉剂、碳酸亚丙脂以及3-丁二醇,搅拌20-30min,等充分混合均匀后加入消泡剂、溶剂以及聚合氯化盐,高速搅拌10-15min,搅拌速度为500-550r/min,最后添加适量的增效添加物至合适黏度,过滤得到乙组份待用;(3) adding citric acid, plant fiber, microbial inoculum and organic acid into the mixer and stirring, stirring for 40-50min, the stirring speed is 900-1000r/min, adding coagulation agent, propylene carbonate and 3-butanedi Alcohol, stir for 20-30min, add defoamer, solvent and polychloride salt after fully mixing, stir at high speed for 10-15min, stirring speed is 500-550r/min, and finally add an appropriate amount of synergistic additives to the appropriate viscosity , filtered to obtain component B for use;
(四)将PVC发泡调节剂LP-40、3-甲基苯酚以及抗氧剂加入搅拌机中进行搅拌,搅拌时间为30-40min,搅拌速度为300-350r/min,搅拌同时加入木质纤维粉、碳纤维粉、水玻璃以及阻燃剂继续搅拌30-35min,搅拌速度为200-250r/min,最后加入流平剂、稳定剂以及辅料搅拌至合适黏度,过滤得到丙组分。(4) The PVC foaming regulator LP-40, 3-methylphenol and antioxidant are added to the mixer for stirring, the stirring time is 30-40min, the stirring speed is 300-350r/min, and the wood fiber powder is added while stirring , carbon fiber powder, water glass and flame retardant continue to stir for 30-35min, stirring speed is 200-250r/min, finally add leveling agent, stabilizer and auxiliary materials and stir to appropriate viscosity, filter to obtain C component.
(五)将前述步骤中的到的甲组份、乙组份以及丙组分放入搅拌机中搅拌,保持温度在 50-60℃,搅拌速度为200-250r/min直至搅拌均匀即可得到环保无毒污水处理剂。(5) Put the A component, the B component and the C component obtained in the preceding steps into the mixer and stir, keep the temperature at 50-60 ℃, and the stirring speed is 200-250r/min until the stirring is uniform and the environmental protection can be obtained Non-toxic sewage treatment agent.
通过本发明的技术方案:本发明中添加了的一种微生物菌剂,对污水中的真菌、致病菌具有较好的抑制和杀灭作用,另一方面其避免了化学杀菌剂对水体的二次污染,其对人体无毒无害,大大提高了污水处理剂的环保性能;本发明中还添加了活性炭,对污水中含有的重金属离子具有较好的吸附能力,其次竹炭的成本较低,能有效降低污水处理的成本。并且本发明的污水处理剂可有效去除生活污水中的污染物,改善水质,并且不会对水质造成额外影响,长效改善水质,生产成本低,成分设计合理,绿色环保,经济效益好。Through the technical scheme of the present invention: a microbial inoculant added in the present invention has a better inhibitory and killing effect on fungi and pathogenic bacteria in sewage, and on the other hand, it avoids chemical bactericides on water bodies. Secondary pollution, which is non-toxic and harmless to the human body, greatly improves the environmental protection performance of the sewage treatment agent; activated carbon is also added in the present invention, which has better adsorption capacity for heavy metal ions contained in sewage, and the cost of bamboo charcoal is lower. , can effectively reduce the cost of sewage treatment. In addition, the sewage treatment agent of the invention can effectively remove pollutants in domestic sewage, improve water quality, and has no additional impact on water quality, long-term improvement of water quality, low production cost, reasonable component design, green environmental protection, and good economic benefits.
实施例1Example 1
本实施例提供一种环保无毒污水处理剂,环保无毒污水处理剂由甲乙丙三组分按甲∶乙∶丙=3∶1∶2的比例复合而成,甲乙丙以质量份数计包含以下组分:The present embodiment provides an environmentally friendly and non-toxic sewage treatment agent. The environmentally friendly and non-toxic sewage treatment agent is composed of three components of A, B and C in a ratio of A: B: C = 3: 1: 2, and A, B and C are calculated in parts by mass. Contains the following components:
甲组分中按质量份数计包括以下组分:有机硅改性环氧树脂:8份,分散剂:2份,石墨粉:10份,领苯二甲酸氢钾:2份,纳米二氧化硅:4份,活性炭:22份,磷酸二氢钾:11份,硫酸铁:3份,膨润土:12份,硫酸铝:3份,氢氧化钙:19份;Component A includes the following components in parts by mass: silicone modified epoxy resin: 8 parts, dispersant: 2 parts, graphite powder: 10 parts, potassium hydrogen phthalate: 2 parts, nanometer dioxide Silicon: 4 parts, activated carbon: 22 parts, potassium dihydrogen phosphate: 11 parts, iron sulfate: 3 parts, bentonite: 12 parts, aluminum sulfate: 3 parts, calcium hydroxide: 19 parts;
乙组分中按质量份数计包括以下组分:柠檬酸:9份,植物纤维:11份,微生物菌剂:9份,有机酸:6份,聚沉剂:12份,碳酸亚丙脂:10份,3-丁二醇:2份,消泡剂:19份,溶剂:20份,聚合氯化盐:13份,增效添加物:10份;Component B includes the following components in parts by mass: citric acid: 9 parts, plant fiber: 11 parts, microbial inoculum: 9 parts, organic acid: 6 parts, coagulation agent: 12 parts, propylene carbonate : 10 parts, 3-butanediol: 2 parts, defoamer: 19 parts, solvent: 20 parts, polychloride salt: 13 parts, synergistic additive: 10 parts;
丙组分中按质量份数计包括以下组分:PVC发泡调节剂LP-40:3份,3-甲基苯酚:6份,抗氧剂:12份,木质纤维粉:29份,碳纤维粉:17份,水玻璃:18份,阻燃剂:3份,流平剂:12份,稳定剂:13份,辅料:16份;Component C includes the following components in parts by mass: PVC foaming regulator LP-40: 3 parts, 3-methylphenol: 6 parts, antioxidant: 12 parts, wood fiber powder: 29 parts, carbon fiber Powder: 17 parts, water glass: 18 parts, flame retardant: 3 parts, leveling agent: 12 parts, stabilizer: 13 parts, accessories: 16 parts;
分散剂为硬脂酰胺、硬脂酸钡或硬脂酸锌中的一种;植物纤维为剑麻纤维、蓖麻纤维、椰棕纤维或榆树皮纤维中的一种;微生物菌剂为枯草芽孢杆菌、巨大芽孢杆菌、胶胨样芽孢杆菌、根瘤菌中的一种或多种的混合;有机酸为酒石酸或马来酸中的一种;聚沉剂为聚硅酸铁或聚丙烯酰胺中的一种;消泡剂为环氧丙烷或环氧乙烷与环氧丙烷的混合物;溶剂为水;增效添加剂为甲基异噻唑啉酮、木质素磺酸钠、壳聚糖按照重量比2:1:1.5组成的混合物;抗氧剂为抗氧剂1076和抗氧剂1010的混合物;阻燃剂为磷酸三酯;稳定剂为CH4O2钙锌稳定剂、二盐基邻苯二甲酸铅或硬脂酸钡中的一种;辅料为复合稀土,复合稀土按质量百分比计包括以下组分:镝:9%,铈:15%,镨:19%,钕:1%,其余为镧系元素,以上镧系稀土各组分之和为100%;The dispersant is one of stearamide, barium stearate or zinc stearate; the plant fiber is one of sisal fiber, castor fiber, coconut palm fiber or elm bark fiber; the microbial agent is Bacillus subtilis Mixture of one or more of Bacillus megaterium, Bacillus megaterium, Bacillus peptone, and Rhizobium; the organic acid is one of tartaric acid or maleic acid; the coagulation agent is polyiron silicate or polyacrylamide The antifoaming agent is propylene oxide or the mixture of ethylene oxide and propylene oxide; the solvent is water; the synergistic additive is methylisothiazolinone, sodium lignosulfonate, chitosan according to weight A mixture of 2:1:1.5; antioxidant is a mixture of antioxidant 1076 and antioxidant 1010; flame retardant is phosphate triester; stabilizer is CH4O2 calcium zinc stabilizer, dibasic lead phthalate Or one of barium stearate; the auxiliary material is composite rare earth, and the composite rare earth includes the following components by mass percentage: dysprosium: 9%, cerium: 15%, praseodymium: 19%, neodymium: 1%, and the rest are lanthanide series elements, the sum of the above lanthanide rare earth components is 100%;
上述的环保无毒污水处理剂的制备方法,该制备方法包括以下步骤:The preparation method of the above-mentioned environmentally friendly non-toxic sewage treatment agent, the preparation method comprises the following steps:
(一)将有机硅改性环氧树脂、分散剂、石墨粉以及领苯二甲酸氢钾加入分散缸中,控制分散缸的温度在60℃,高速搅拌均匀,搅拌速度为800r/min,搅拌时间为40min搅拌结束后加入纳米二氧化硅、活性炭以及磷酸二氢钾,高速搅拌30min,控制分散缸温度在70℃;(1) Add silicone modified epoxy resin, dispersant, graphite powder and potassium hydrogen phthalate into the dispersing cylinder, control the temperature of the dispersing cylinder at 60°C, stir evenly at high speed, and stir at a speed of 800 r/min. The time is 40min after stirring, adding nano-silica, activated carbon and potassium dihydrogen phosphate, stirring at high speed for 30min, and controlling the temperature of the dispersing cylinder at 70°C;
(二)再向步骤(一)中加入硫酸铁、膨润土、硫酸铝以及氢氧化钙,在常温下搅拌均匀,即可得到甲组份待用;(2) adding ferric sulfate, bentonite, aluminum sulfate and calcium hydroxide to step (1) again, stirring at normal temperature to obtain component A for later use;
(三)将柠檬酸、植物纤维、微生物菌剂以及有机酸加入搅拌机中进行搅拌,搅拌40min,搅拌速度为900-r/min,加入聚沉剂、碳酸亚丙脂以及3-丁二醇,搅拌20min,等充分混合均匀后加入消泡剂、溶剂以及聚合氯化盐,高速搅拌10min,搅拌速度为500r/min,最后添加适量的增效添加物至合适黏度,过滤得到乙组份待用;(3) adding citric acid, plant fiber, microbial inoculum and organic acid in the mixer and stirring, stirring for 40min, the stirring speed is 900-r/min, adding coagulation agent, propylene carbonate and 3-butanediol, Stir for 20 minutes, add antifoaming agent, solvent and polychlorinated salt after fully mixing, stir at high speed for 10 minutes, stirring speed is 500r/min, finally add an appropriate amount of synergistic additives to the appropriate viscosity, filter to obtain component B for use ;
(四)将PVC发泡调节剂LP-40、3-甲基苯酚以及抗氧剂加入搅拌机中进行搅拌,搅拌时间为30min,搅拌速度为300r/min,搅拌同时加入木质纤维粉、碳纤维粉、水玻璃以及阻燃剂继续搅拌30min,搅拌速度为200r/min,最后加入流平剂、稳定剂以及辅料搅拌至合适黏度,过滤得到丙组分。(4) The PVC foaming regulator LP-40, 3-methylphenol and antioxidant are added into the mixer for stirring, the stirring time is 30min, the stirring speed is 300r/min, and the wood fiber powder, carbon fiber powder, The water glass and the flame retardant were continuously stirred for 30 minutes, and the stirring speed was 200 r/min. Finally, the leveling agent, stabilizer and auxiliary materials were added and stirred to a suitable viscosity, and the C component was obtained by filtration.
(五)将前述步骤中的到的甲组份、乙组份以及丙组分放入搅拌机中搅拌,保持温度在50℃,搅拌速度为200r/min直至搅拌均匀即可得到环保无毒污水处理剂。(5) Put the A component, the B component and the C component obtained in the preceding steps into the mixer and stir, keep the temperature at 50 ℃, and the stirring speed is 200r/min until stirring can obtain the environmental protection non-toxic sewage treatment agent.
实施例2Example 2
本实施例提供一种环保无毒污水处理剂,环保无毒污水处理剂由甲乙丙三组分按甲∶乙∶丙=3∶1∶2的比例复合而成,甲乙丙以质量份数计包含以下组分:The present embodiment provides an environmentally friendly and non-toxic sewage treatment agent. The environmentally friendly and non-toxic sewage treatment agent is composed of three components of A, B and C in a ratio of A: B: C = 3: 1: 2, and A, B and C are calculated in parts by mass. Contains the following components:
甲组分中按质量份数计包括以下组分:有机硅改性环氧树脂:12份,分散剂:8份,石墨粉:16份,领苯二甲酸氢钾:7份,纳米二氧化硅:9份,活性炭:28份,磷酸二氢钾:17份,硫酸铁:8份,膨润土:18份,硫酸铝:8份,氢氧化钙:22份;Component A includes the following components in parts by mass: silicone modified epoxy resin: 12 parts, dispersant: 8 parts, graphite powder: 16 parts, potassium hydrogen phthalate: 7 parts, nano-dioxide Silicon: 9 parts, activated carbon: 28 parts, potassium dihydrogen phosphate: 17 parts, iron sulfate: 8 parts, bentonite: 18 parts, aluminum sulfate: 8 parts, calcium hydroxide: 22 parts;
乙组分中按质量份数计包括以下组分:柠檬酸:16份,植物纤维:18份,微生物菌剂:13份,有机酸:9份,聚沉剂:18份,碳酸亚丙脂:15份,3-丁二醇:6份,消泡剂:22份,溶剂:27份,聚合氯化盐:19份,增效添加物:16份;Component B includes the following components in parts by mass: citric acid: 16 parts, plant fiber: 18 parts, microbial inoculum: 13 parts, organic acid: 9 parts, coagulation agent: 18 parts, propylene carbonate : 15 parts, 3-butanediol: 6 parts, defoamer: 22 parts, solvent: 27 parts, polychloride salt: 19 parts, synergistic additive: 16 parts;
丙组分中按质量份数计包括以下组分:PVC发泡调节剂LP-40:8份,3-甲基苯酚:10份,抗氧剂:18份,木质纤维粉:31份,碳纤维粉:20份,水玻璃:22份,阻燃剂:8份,流平剂:18份,稳定剂:18份,辅料:20份;Component C includes the following components in parts by mass: PVC foaming regulator LP-40: 8 parts, 3-methylphenol: 10 parts, antioxidant: 18 parts, wood fiber powder: 31 parts, carbon fiber Powder: 20 parts, water glass: 22 parts, flame retardant: 8 parts, leveling agent: 18 parts, stabilizer: 18 parts, accessories: 20 parts;
分散剂为硬脂酰胺、硬脂酸钡或硬脂酸锌中的一种;植物纤维为剑麻纤维、蓖麻纤维、 椰棕纤维或榆树皮纤维中的一种;微生物菌剂为枯草芽孢杆菌、巨大芽孢杆菌、胶胨样芽孢杆菌、根瘤菌中的一种或多种的混合;有机酸为酒石酸或马来酸中的一种;聚沉剂为聚硅酸铁或聚丙烯酰胺中的一种;消泡剂为环氧丙烷或环氧乙烷与环氧丙烷的混合物;溶剂为水;增效添加剂为甲基异噻唑啉酮、木质素磺酸钠、壳聚糖按照重量比2:1:1.5组成的混合物;抗氧剂为抗氧剂1076和抗氧剂1010的混合物;阻燃剂为磷酸三酯;稳定剂为CH4O2钙锌稳定剂、二盐基邻苯二甲酸铅或硬脂酸钡中的一种;辅料为复合稀土,复合稀土按质量百分比计包括以下组分:镝:12%,铈:19%,镨:22%,钕:5%,其余为镧系元素,以上镧系稀土各组分之和为100%;Dispersant is a kind of in stearamide, barium stearate or zinc stearate; Plant fiber is a kind of in sisal fiber, castor fiber, coconut palm fiber or elm bark fiber; Microbial agent is Bacillus subtilis Mixture of one or more of Bacillus megaterium, Bacillus megaterium, Bacillus peptone, and Rhizobium; the organic acid is one of tartaric acid or maleic acid; the coagulation agent is polyiron silicate or polyacrylamide The antifoaming agent is propylene oxide or the mixture of ethylene oxide and propylene oxide; the solvent is water; the synergistic additive is methylisothiazolinone, sodium lignosulfonate, chitosan according to weight A mixture of 2:1:1.5; antioxidant is a mixture of antioxidant 1076 and antioxidant 1010; flame retardant is phosphate triester; stabilizer is CH4O2 calcium zinc stabilizer, dibasic lead phthalate Or one of barium stearate; the auxiliary material is composite rare earth, and the composite rare earth includes the following components by mass percentage: dysprosium: 12%, cerium: 19%, praseodymium: 22%, neodymium: 5%, and the rest are lanthanide series elements, the sum of the above lanthanide rare earth components is 100%;
上述的环保无毒污水处理剂的制备方法,该制备方法包括以下步骤:The preparation method of the above-mentioned environmentally friendly non-toxic sewage treatment agent, the preparation method comprises the following steps:
(一)将有机硅改性环氧树脂、分散剂、石墨粉以及领苯二甲酸氢钾加入分散缸中,控制分散缸的温度在65℃,高速搅拌均匀,搅拌速度为900r/min,搅拌时间为45min搅拌结束后加入纳米二氧化硅、活性炭以及磷酸二氢钾,高速搅拌40min,控制分散缸温度在80℃;;(1) Add silicone modified epoxy resin, dispersant, graphite powder and potassium hydrogen phthalate into the dispersing cylinder, control the temperature of the dispersing cylinder at 65°C, stir evenly at high speed, and stir at a speed of 900 r/min. The time is 45min after stirring, adding nano-silica, activated carbon and potassium dihydrogen phosphate, stirring at high speed for 40min, and controlling the temperature of the dispersion tank at 80 °C;
(二)再向步骤(一)中加入硫酸铁、膨润土、硫酸铝以及氢氧化钙,在常温下搅拌均匀,即可得到甲组份待用;(2) adding ferric sulfate, bentonite, aluminum sulfate and calcium hydroxide to step (1) again, stirring at normal temperature to obtain component A for later use;
(三)将柠檬酸、植物纤维、微生物菌剂以及有机酸加入搅拌机中进行搅拌,搅拌50min,搅拌速度为1000r/min,加入聚沉剂、碳酸亚丙脂以及3-丁二醇,搅拌30min,等充分混合均匀后加入消泡剂、溶剂以及聚合氯化盐,高速搅拌15min,搅拌速度为550r/min,最后添加适量的增效添加物至合适黏度,过滤得到乙组份待用;(3) adding citric acid, plant fiber, microbial inoculum and organic acid to the mixer and stirring, stirring for 50min, the stirring speed is 1000r/min, adding coagulation agent, propylene carbonate and 3-butanediol, stirring for 30min , after fully mixing, add defoamer, solvent and polychlorinated salt, stir at high speed for 15min, stirring speed is 550r/min, finally add an appropriate amount of synergistic additives to a suitable viscosity, filter to obtain component B for use;
(四)将PVC发泡调节剂LP-40、3-甲基苯酚以及抗氧剂加入搅拌机中进行搅拌,搅拌时间为40min,搅拌速度为350r/min,搅拌同时加入木质纤维粉、碳纤维粉、水玻璃以及阻燃剂继续搅拌35min,搅拌速度为250r/min,最后加入流平剂、稳定剂以及辅料搅拌至合适黏度,过滤得到丙组分。(4) Add the PVC foaming regulator LP-40, 3-methylphenol and antioxidant into the mixer for stirring, the stirring time is 40min, the stirring speed is 350r/min, and the wood fiber powder, carbon fiber powder, The water glass and the flame retardant were continuously stirred for 35 minutes, and the stirring speed was 250 r/min. Finally, the leveling agent, stabilizer and auxiliary materials were added and stirred to a suitable viscosity, and the C component was obtained by filtration.
(五)将前述步骤中的到的甲组份、乙组份以及丙组分放入搅拌机中搅拌,保持温度在60℃,搅拌速度为250r/min直至搅拌均匀即可得到环保无毒污水处理剂。(5) Put the A component, the B component and the C component obtained in the preceding steps into the mixer and stir, keep the temperature at 60 ℃, and the stirring speed is 250r/min until stirring can obtain the environmental protection non-toxic sewage treatment agent.
实施例3Example 3
本实施例提供一种环保无毒污水处理剂,环保无毒污水处理剂由甲乙丙三组分按甲∶乙∶丙=3∶1∶2的比例复合而成,甲乙丙以质量份数计包含以下组分:The present embodiment provides an environmentally friendly and non-toxic sewage treatment agent. The environmentally friendly and non-toxic sewage treatment agent is composed of three components of A, B and C in a ratio of A: B: C = 3: 1: 2, and A, B and C are calculated in parts by mass. Contains the following components:
甲组分中按质量份数计包括以下组分:有机硅改性环氧树脂:11份,分散剂:6份,石墨粉:12份,领苯二甲酸氢钾:5份,纳米二氧化硅:6份,活性炭:25份,磷酸二氢钾: 16份,硫酸铁:5份,膨润土:15份,硫酸铝:6份,氢氧化钙:20份;Component A includes the following components in parts by mass: silicone modified epoxy resin: 11 parts, dispersant: 6 parts, graphite powder: 12 parts, potassium hydrogen phthalate: 5 parts, nano-dioxide Silicon: 6 parts, activated carbon: 25 parts, potassium dihydrogen phosphate: 16 parts, iron sulfate: 5 parts, bentonite: 15 parts, aluminum sulfate: 6 parts, calcium hydroxide: 20 parts;
乙组分中按质量份数计包括以下组分:柠檬酸:12份,植物纤维:15份,微生物菌剂:12份,有机酸:8份,聚沉剂:14份,碳酸亚丙脂:12份,3-丁二醇:4份,消泡剂:20份,溶剂:24份,聚合氯化盐:17份,增效添加物:12份;Component B includes the following components in parts by mass: citric acid: 12 parts, plant fiber: 15 parts, microbial inoculum: 12 parts, organic acid: 8 parts, coagulation agent: 14 parts, propylene carbonate : 12 parts, 3-butanediol: 4 parts, defoamer: 20 parts, solvent: 24 parts, polychloride salt: 17 parts, synergistic additive: 12 parts;
丙组分中按质量份数计包括以下组分:PVC发泡调节剂LP-40:5份,3-甲基苯酚:8份,抗氧剂:14份,木质纤维粉:30份,碳纤维粉:18份,水玻璃:20份,阻燃剂:5份,流平剂:14份,稳定剂:15份,辅料:18份;Component C includes the following components in parts by mass: PVC foaming regulator LP-40: 5 parts, 3-methylphenol: 8 parts, antioxidant: 14 parts, wood fiber powder: 30 parts, carbon fiber Powder: 18 parts, water glass: 20 parts, flame retardant: 5 parts, leveling agent: 14 parts, stabilizer: 15 parts, accessories: 18 parts;
分散剂为硬脂酰胺、硬脂酸钡或硬脂酸锌中的一种;植物纤维为剑麻纤维、蓖麻纤维、椰棕纤维或榆树皮纤维中的一种;微生物菌剂为枯草芽孢杆菌、巨大芽孢杆菌、胶胨样芽孢杆菌、根瘤菌中的一种或多种的混合;有机酸为酒石酸或马来酸中的一种;聚沉剂为聚硅酸铁或聚丙烯酰胺中的一种;消泡剂为环氧丙烷或环氧乙烷与环氧丙烷的混合物;溶剂为水;增效添加剂为甲基异噻唑啉酮、木质素磺酸钠、壳聚糖按照重量比2:1:1.5组成的混合物;抗氧剂为抗氧剂1076和抗氧剂1010的混合物;阻燃剂为磷酸三酯;稳定剂为CH4O2钙锌稳定剂、二盐基邻苯二甲酸铅或硬脂酸钡中的一种;辅料为复合稀土,复合稀土按质量百分比计包括以下组分:镝:11%,铈:17%,镨:20%,钕:3%,其余为镧系元素,以上镧系稀土各组分之和为100%;The dispersant is one of stearamide, barium stearate or zinc stearate; the plant fiber is one of sisal fiber, castor fiber, coconut palm fiber or elm bark fiber; the microbial agent is Bacillus subtilis Mixture of one or more of Bacillus megaterium, Bacillus megaterium, Bacillus peptone, and Rhizobium; the organic acid is one of tartaric acid or maleic acid; the coagulation agent is polyiron silicate or polyacrylamide The antifoaming agent is propylene oxide or the mixture of ethylene oxide and propylene oxide; the solvent is water; the synergistic additive is methylisothiazolinone, sodium lignosulfonate, chitosan according to weight A mixture of 2:1:1.5; antioxidant is a mixture of antioxidant 1076 and antioxidant 1010; flame retardant is phosphate triester; stabilizer is CH4O2 calcium zinc stabilizer, dibasic lead phthalate Or one of barium stearate; the auxiliary material is composite rare earth, and the composite rare earth includes the following components by mass percentage: dysprosium: 11%, cerium: 17%, praseodymium: 20%, neodymium: 3%, and the rest are lanthanide series elements, the sum of the above lanthanide rare earth components is 100%;
上述的环保无毒污水处理剂的制备方法,该制备方法包括以下步骤:The preparation method of the above-mentioned environmentally friendly non-toxic sewage treatment agent, the preparation method comprises the following steps:
(一)将有机硅改性环氧树脂、分散剂、石墨粉以及领苯二甲酸氢钾加入分散缸中,控制分散缸的温度在62℃,高速搅拌均匀,搅拌速度为850r/min,搅拌时间为42min搅拌结束后加入纳米二氧化硅、活性炭以及磷酸二氢钾,高速搅拌35min,控制分散缸温度在75℃;;(1) Add silicone modified epoxy resin, dispersant, graphite powder and potassium hydrogen phthalate into the dispersing cylinder, control the temperature of the dispersing cylinder at 62°C, stir evenly at high speed, and stir at a speed of 850 r/min. The time is 42min after stirring, adding nano-silica, activated carbon and potassium dihydrogen phosphate, stirring at high speed for 35min, and controlling the temperature of the dispersing tank at 75°C;
(二)再向步骤(一)中加入硫酸铁、膨润土、硫酸铝以及氢氧化钙,在常温下搅拌均匀,即可得到甲组份待用;(2) adding ferric sulfate, bentonite, aluminum sulfate and calcium hydroxide to step (1) again, stirring at normal temperature to obtain component A for later use;
(三)将柠檬酸、植物纤维、微生物菌剂以及有机酸加入搅拌机中进行搅拌,搅拌45min,搅拌速度为950r/min,加入聚沉剂、碳酸亚丙脂以及3-丁二醇,搅拌25min,等充分混合均匀后加入消泡剂、溶剂以及聚合氯化盐,高速搅拌12min,搅拌速度为520r/min,最后添加适量的增效添加物至合适黏度,过滤得到乙组份待用;(3) adding citric acid, plant fiber, microbial inoculum and organic acid into the mixer and stirring, stirring for 45min, the stirring speed is 950r/min, adding coagulation agent, propylene carbonate and 3-butanediol, stirring for 25min , after fully mixing, add defoamer, solvent and polychlorinated salt, stir at high speed for 12min, stirring speed is 520r/min, finally add an appropriate amount of synergistic additives to a suitable viscosity, filter to obtain component B for use;
(四)将PVC发泡调节剂LP-40、3-甲基苯酚以及抗氧剂加入搅拌机中进行搅拌,搅拌时间为35min,搅拌速度为320r/min,搅拌同时加入木质纤维粉、碳纤维粉、水玻璃以及阻燃剂继续搅拌32min,搅拌速度为230r/min,最后加入流平剂、稳定剂以及辅料搅拌至合适黏度,过滤得到丙组分。(4) Add the PVC foaming regulator LP-40, 3-methylphenol and antioxidant into the mixer for stirring, the stirring time is 35min, the stirring speed is 320r/min, and the wood fiber powder, carbon fiber powder, The water glass and the flame retardant were continuously stirred for 32 minutes, and the stirring speed was 230 r/min. Finally, the leveling agent, stabilizer and auxiliary materials were added and stirred to a suitable viscosity, and the C component was obtained by filtration.
(五)将前述步骤中的到的甲组份、乙组份以及丙组分放入搅拌机中搅拌,保持温度在55℃,搅拌速度为230r/min直至搅拌均匀即可得到环保无毒污水处理剂。(5) Putting the components A, B and C obtained in the preceding steps into a mixer and stirring, keeping the temperature at 55 ° C, and stirring at a speed of 230 r/min until evenly stirred to obtain environmentally friendly non-toxic sewage treatment agent.
除上述实施例外,本发明还可以有其他实施方式。凡采用等同替换或等效变换形成的技术方案,均落在本发明要求的保护范围。In addition to the above-described embodiments, the present invention may also have other embodiments. All technical solutions formed by equivalent replacement or equivalent transformation fall within the protection scope of the present invention.
Claims (6)
- 一种环保无毒污水处理剂,其特征在于:所述环保无毒污水处理剂由甲乙丙三组分按甲∶乙∶丙=3∶1∶2的比例复合而成,所述甲乙丙以质量份数计包含以下组分:An environmentally friendly and non-toxic sewage treatment agent is characterized in that: the environmentally friendly and non-toxic sewage treatment agent is composed of three components of A, B and C in the ratio of A: B: C = 3: 1: 2, and the A, B and C are composed of three components. The part by mass meter contains the following components:所述甲组分中按质量份数计包括以下组分:有机硅改性环氧树脂:8-12份,分散剂:2-8份,石墨粉:10-16份,领苯二甲酸氢钾:2-7份,纳米二氧化硅:4-9份,活性炭:22-28份,磷酸二氢钾:11-17份,硫酸铁:3-8份,膨润土:12-18份,硫酸铝:3-8份,氢氧化钙:19-22份;The first component includes the following components in parts by mass: silicone-modified epoxy resin: 8-12 parts, dispersant: 2-8 parts, graphite powder: 10-16 parts, hydrogen phthalate Potassium: 2-7 parts, nano silica: 4-9 parts, activated carbon: 22-28 parts, potassium dihydrogen phosphate: 11-17 parts, iron sulfate: 3-8 parts, bentonite: 12-18 parts, sulfuric acid Aluminum: 3-8 parts, calcium hydroxide: 19-22 parts;所述乙组分中按质量份数计包括以下组分:柠檬酸:9-16份,植物纤维:11-18份,微生物菌剂:9-13份,有机酸:6-9份,聚沉剂:12-18份,碳酸亚丙脂:10-15份,3-丁二醇:2-6份,消泡剂:19-22份,溶剂:20-27份,聚合氯化盐:13-19份,增效添加物:10-16份;The B component includes the following components in parts by mass: citric acid: 9-16 parts, plant fiber: 11-18 parts, microbial inoculum: 9-13 parts, organic acid: 6-9 parts, poly Precipitation agent: 12-18 parts, propylene carbonate: 10-15 parts, 3-butanediol: 2-6 parts, defoamer: 19-22 parts, solvent: 20-27 parts, polychloride salt: 13-19 copies, synergistic additives: 10-16 copies;所述丙组分中按质量份数计包括以下组分:PVC发泡调节剂LP-40:3-8份,3-甲基苯酚:6-10份,抗氧剂:12-18份,木质纤维粉:29-31份,碳纤维粉:17-20份,水玻璃:18-22份,阻燃剂:3-8份,流平剂:12-18份,稳定剂:13-18份,辅料:16-20份。The third component includes the following components in parts by mass: PVC foaming regulator LP-40: 3-8 parts, 3-methylphenol: 6-10 parts, antioxidant: 12-18 parts, Wood fiber powder: 29-31 parts, carbon fiber powder: 17-20 parts, water glass: 18-22 parts, flame retardant: 3-8 parts, leveling agent: 12-18 parts, stabilizer: 13-18 parts , Accessories: 16-20 copies.
- 根据权利要求1所述的环保无毒污水处理剂,其特征在于:所述的分散剂为硬脂酰胺、硬脂酸钡或硬脂酸锌中的一种;,所述植物纤维为剑麻纤维、蓖麻纤维、椰棕纤维或榆树皮纤维中的一种;所述的微生物菌剂为枯草芽孢杆菌、巨大芽孢杆菌、胶胨样芽孢杆菌、根瘤菌中的一种或多种的混合;所述的有机酸为酒石酸或马来酸中的一种;所述的聚沉剂为聚硅酸铁或聚丙烯酰胺中的一种;所述的消泡剂为环氧丙烷或环氧乙烷与环氧丙烷的混合物;所述的溶剂为水;所述的增效添加剂为甲基异噻唑啉酮、木质素磺酸钠、壳聚糖按照重量比2:1:1.5组成的混合物;所述的抗氧剂为抗氧剂1076和抗氧剂1010的混合物;所述的阻燃剂为磷酸三酯;所述的稳定剂为CH4O2钙锌稳定剂、二盐基邻苯二甲酸铅或硬脂酸钡中的一种;所述的辅料为复合稀土,所述复合稀土按质量百分比计包括以下组分:镝:9-12%,铈:15-19%,镨:19-22%,钕:1-5%,其余为镧系元素,以上镧系稀土各组分之和为100%。The environmentally friendly nontoxic sewage treatment agent according to claim 1, wherein the dispersant is one of stearamide, barium stearate or zinc stearate; and the plant fiber is sisal A kind of in fiber, castor fiber, coconut palm fiber or elm bark fiber; Described microbial inoculum is a mixture of one or more of Bacillus subtilis, Bacillus megaterium, Bacillus peptone, Rhizobium ; Described organic acid is a kind of in tartaric acid or maleic acid; Described coagulation agent is a kind of in polyiron silicate or polyacrylamide; Described defoamer is propylene oxide or epoxy resin The mixture of ethane and propylene oxide; the solvent is water; the synergistic additive is the mixture of methylisothiazolinone, sodium lignosulfonate, and chitosan according to the weight ratio of 2:1:1.5 ; Described antioxidant is the mixture of antioxidant 1076 and antioxidant 1010; Described flame retardant is phosphate triester; Described stabilizer is CH4O2 calcium zinc stabilizer, dibasic phthalic acid One of lead or barium stearate; the auxiliary material is a composite rare earth, and the composite rare earth includes the following components by mass percentage: dysprosium: 9-12%, cerium: 15-19%, praseodymium: 19- 22%, neodymium: 1-5%, the rest are lanthanide elements, and the sum of the above lanthanide rare earth components is 100%.
- 根据权利要求1所述的环保无毒污水处理剂,其特征在于:所述环保无毒污水处理剂由甲乙丙三组分按甲∶乙∶丙=3∶1∶2的比例复合而成,所述甲乙丙以质量份数计包含以下组分:The environmentally friendly non-toxic sewage treatment agent according to claim 1, characterized in that: the environmentally friendly non-toxic sewage treatment agent is composed of three components of A, B and C in a ratio of A: B: C=3:1:2, Described methyl ethyl propylene comprises the following components in parts by mass:所述甲组分中按质量份数计包括以下组分:有机硅改性环氧树脂:8份,分散剂:2份,石墨粉:10份,领苯二甲酸氢钾:2份,纳米二氧化硅:4份,活性炭:22份,磷酸二氢钾:11份,硫酸铁:3份,膨润土:12份,硫酸铝:3份,氢氧化钙:19份;The first component includes the following components in parts by mass: silicone modified epoxy resin: 8 parts, dispersant: 2 parts, graphite powder: 10 parts, potassium hydrogen phthalate: 2 parts, nanometer Silicon dioxide: 4 parts, activated carbon: 22 parts, potassium dihydrogen phosphate: 11 parts, iron sulfate: 3 parts, bentonite: 12 parts, aluminum sulfate: 3 parts, calcium hydroxide: 19 parts;所述乙组分中按质量份数计包括以下组分:柠檬酸:9份,植物纤维:11份,微生物菌 剂:9份,有机酸:6份,聚沉剂:12份,碳酸亚丙脂:10份,3-丁二醇:2份,消泡剂:19份,溶剂:20份,聚合氯化盐:13份,增效添加物:10份;The B component includes the following components in parts by mass: citric acid: 9 parts, plant fiber: 11 parts, microbial inoculum: 9 parts, organic acid: 6 parts, coagulation agent: 12 parts, subcarbonate Propyl ester: 10 parts, 3-butanediol: 2 parts, defoamer: 19 parts, solvent: 20 parts, polychloride salt: 13 parts, synergistic additive: 10 parts;所述丙组分中按质量份数计包括以下组分:PVC发泡调节剂LP-40:3份,3-甲基苯酚:6份,抗氧剂:12份,木质纤维粉:29份,碳纤维粉:17份,水玻璃:18份,阻燃剂:3份,流平剂:12份,稳定剂:13份,辅料:16份。The C component includes the following components in parts by mass: PVC foaming regulator LP-40: 3 parts, 3-methylphenol: 6 parts, antioxidant: 12 parts, wood fiber powder: 29 parts , Carbon fiber powder: 17 parts, water glass: 18 parts, flame retardant: 3 parts, leveling agent: 12 parts, stabilizer: 13 parts, accessories: 16 parts.
- 根据权利要求1所述的环保无毒污水处理剂,其特征在于:所述环保无毒污水处理剂由甲乙丙三组分按甲∶乙∶丙=3∶1∶2的比例复合而成,所述甲乙丙以质量份数计包含以下组分:The environmentally friendly non-toxic sewage treatment agent according to claim 1, characterized in that: the environmentally friendly non-toxic sewage treatment agent is composed of three components of A, B and C in a ratio of A: B: C=3:1:2, Described methyl ethyl propylene comprises the following components in parts by mass:所述甲组分中按质量份数计包括以下组分:有机硅改性环氧树脂:12份,分散剂:8份,石墨粉:16份,领苯二甲酸氢钾:7份,纳米二氧化硅:9份,活性炭:28份,磷酸二氢钾:17份,硫酸铁:8份,膨润土:18份,硫酸铝:8份,氢氧化钙:22份;The first component includes the following components in parts by mass: silicone modified epoxy resin: 12 parts, dispersant: 8 parts, graphite powder: 16 parts, potassium hydrogen phthalate: 7 parts, nanometer Silicon dioxide: 9 parts, activated carbon: 28 parts, potassium dihydrogen phosphate: 17 parts, iron sulfate: 8 parts, bentonite: 18 parts, aluminum sulfate: 8 parts, calcium hydroxide: 22 parts;所述乙组分中按质量份数计包括以下组分:柠檬酸:16份,植物纤维:18份,微生物菌剂:13份,有机酸:9份,聚沉剂:18份,碳酸亚丙脂:15份,3-丁二醇:6份,消泡剂:22份,溶剂:27份,聚合氯化盐:19份,增效添加物:16份;The B component includes the following components in parts by mass: citric acid: 16 parts, plant fiber: 18 parts, microbial inoculum: 13 parts, organic acid: 9 parts, coagulation agent: 18 parts, subcarbonate Propyl ester: 15 parts, 3-butanediol: 6 parts, defoamer: 22 parts, solvent: 27 parts, polychloride salt: 19 parts, synergistic additive: 16 parts;所述丙组分中按质量份数计包括以下组分:PVC发泡调节剂LP-40:8份,3-甲基苯酚:10份,抗氧剂:18份,木质纤维粉:31份,碳纤维粉:20份,水玻璃:22份,阻燃剂:8份,流平剂:18份,稳定剂:18份,辅料:20份。The C component includes the following components in parts by mass: PVC foaming regulator LP-40: 8 parts, 3-methylphenol: 10 parts, antioxidant: 18 parts, wood fiber powder: 31 parts , Carbon fiber powder: 20 parts, water glass: 22 parts, flame retardant: 8 parts, leveling agent: 18 parts, stabilizer: 18 parts, accessories: 20 parts.
- 根据权利要求1所述的环保无毒污水处理剂,其特征在于:所述环保无毒污水处理剂由甲乙丙三组分按甲∶乙∶丙=3∶1∶2的比例复合而成,所述甲乙丙以质量份数计包含以下组分:The environmentally friendly non-toxic sewage treatment agent according to claim 1, characterized in that: the environmentally friendly non-toxic sewage treatment agent is composed of three components of A, B and C in a ratio of A: B: C=3:1:2, Described methyl ethyl propylene comprises the following components in parts by mass:所述甲组分中按质量份数计包括以下组分:有机硅改性环氧树脂:11份,分散剂:6份,石墨粉:12份,领苯二甲酸氢钾:5份,纳米二氧化硅:6份,活性炭:25份,磷酸二氢钾:16份,硫酸铁:5份,膨润土:15份,硫酸铝:6份,氢氧化钙:20份;The first component includes the following components in parts by mass: silicone modified epoxy resin: 11 parts, dispersant: 6 parts, graphite powder: 12 parts, potassium hydrogen phthalate: 5 parts, nanometer Silicon dioxide: 6 parts, activated carbon: 25 parts, potassium dihydrogen phosphate: 16 parts, iron sulfate: 5 parts, bentonite: 15 parts, aluminum sulfate: 6 parts, calcium hydroxide: 20 parts;所述乙组分中按质量份数计包括以下组分:柠檬酸:12份,植物纤维:15份,微生物菌剂:12份,有机酸:8份,聚沉剂:14份,碳酸亚丙脂:12份,3-丁二醇:4份,消泡剂:20份,溶剂:24份,聚合氯化盐:17份,增效添加物:12份;The B component includes the following components in parts by mass: citric acid: 12 parts, plant fiber: 15 parts, microbial inoculum: 12 parts, organic acid: 8 parts, coagulation agent: 14 parts, subcarbonate Propyl ester: 12 parts, 3-butanediol: 4 parts, defoamer: 20 parts, solvent: 24 parts, polychloride salt: 17 parts, synergistic additive: 12 parts;所述丙组分中按质量份数计包括以下组分:PVC发泡调节剂LP-40:5份,3-甲基苯酚:8份,抗氧剂:14份,木质纤维粉:30份,碳纤维粉:18份,水玻璃:20份,阻燃剂:5份,流平剂:14份,稳定剂:15份,辅料:18份。The C component includes the following components in parts by mass: PVC foaming regulator LP-40: 5 parts, 3-methylphenol: 8 parts, antioxidant: 14 parts, wood fiber powder: 30 parts , Carbon fiber powder: 18 parts, water glass: 20 parts, flame retardant: 5 parts, leveling agent: 14 parts, stabilizer: 15 parts, accessories: 18 parts.
- 一种环保无毒污水处理剂的制备方法,该制备方法设有权利要求1-5中任一权利要求 所述的环保无毒污水处理剂,其特征在于,该制备方法包括以下步骤:A preparation method of an environmentally friendly non-toxic sewage treatment agent, the preparation method is provided with the environmentally friendly non-toxic sewage treatment agent according to any one of claims 1-5, and is characterized in that, the preparation method comprises the following steps:(一)将有机硅改性环氧树脂、分散剂、石墨粉以及领苯二甲酸氢钾加入分散缸中,控制分散缸的温度在60-65℃,高速搅拌均匀,搅拌速度为800-900r/min,搅拌时间为40-45min搅拌结束后加入纳米二氧化硅、活性炭以及磷酸二氢钾,高速搅拌30-40min,控制分散缸温度在70-80℃;;(1) Add silicone modified epoxy resin, dispersant, graphite powder and potassium hydrogen phthalate into the dispersing cylinder, control the temperature of the dispersing cylinder at 60-65 °C, stir evenly at high speed, and the stirring speed is 800-900r /min, the stirring time is 40-45min. After stirring, nano-silica, activated carbon and potassium dihydrogen phosphate are added, and the high-speed stirring is 30-40min, and the temperature of the dispersion tank is controlled at 70-80 °C;(二)再向步骤(一)中加入硫酸铁、膨润土、硫酸铝以及氢氧化钙,在常温下搅拌均匀,即可得到甲组份待用;(2) adding ferric sulfate, bentonite, aluminum sulfate and calcium hydroxide to step (1) again, stirring at normal temperature to obtain component A for later use;(三)将柠檬酸、植物纤维、微生物菌剂以及有机酸加入搅拌机中进行搅拌,搅拌40-50min,搅拌速度为900-1000r/min,加入聚沉剂、碳酸亚丙脂以及3-丁二醇,搅拌20-30min,等充分混合均匀后加入消泡剂、溶剂以及聚合氯化盐,高速搅拌10-15min,搅拌速度为500-550r/min,最后添加适量的增效添加物至合适黏度,过滤得到乙组份待用;(3) adding citric acid, plant fiber, microbial inoculum and organic acid to the mixer and stirring, stirring for 40-50min, the stirring speed is 900-1000r/min, adding coagulation agent, propylene carbonate and 3-butanedi Alcohol, stir for 20-30min, add defoamer, solvent and polychloride salt after fully mixing, stir at high speed for 10-15min, stirring speed is 500-550r/min, and finally add an appropriate amount of synergistic additives to the appropriate viscosity , filtered to obtain component B for use;(四)将PVC发泡调节剂LP-40、3-甲基苯酚以及抗氧剂加入搅拌机中进行搅拌,搅拌时间为30-40min,搅拌速度为300-350r/min,搅拌同时加入木质纤维粉、碳纤维粉、水玻璃以及阻燃剂继续搅拌30-35min,搅拌速度为200-250r/min,最后加入流平剂、稳定剂以及辅料搅拌至合适黏度,过滤得到丙组分。(4) The PVC foaming regulator LP-40, 3-methylphenol and antioxidant are added to the mixer for stirring, the stirring time is 30-40min, the stirring speed is 300-350r/min, and the wood fiber powder is added while stirring , carbon fiber powder, water glass and flame retardant continue to stir for 30-35min, stirring speed is 200-250r/min, finally add leveling agent, stabilizer and auxiliary materials and stir to appropriate viscosity, filter to obtain C component.(五)将前述步骤中的到的甲组份、乙组份以及丙组分放入搅拌机中搅拌,保持温度在50-60℃,搅拌速度为200-250r/min直至搅拌均匀即可得到环保无毒污水处理剂。(5) Put the A component, the B component and the C component obtained in the preceding steps into the mixer and stir, keep the temperature at 50-60 ℃, and the stirring speed is 200-250r/min until the stirring is uniform and the environmental protection can be obtained Non-toxic sewage treatment agent.
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