CN106750806A - A kind of outdoor plastic platen is with anti-aging wear-resisting PE plastic alloys - Google Patents

A kind of outdoor plastic platen is with anti-aging wear-resisting PE plastic alloys Download PDF

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Publication number
CN106750806A
CN106750806A CN201611196599.6A CN201611196599A CN106750806A CN 106750806 A CN106750806 A CN 106750806A CN 201611196599 A CN201611196599 A CN 201611196599A CN 106750806 A CN106750806 A CN 106750806A
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China
Prior art keywords
parts
plastic
resisting
platen
alloys
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Pending
Application number
CN201611196599.6A
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Chinese (zh)
Inventor
王建萍
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Suzhou Shu Fan Letter Electronic Technology Co Ltd
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Suzhou Shu Fan Letter Electronic Technology Co Ltd
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Priority to CN201611196599.6A priority Critical patent/CN106750806A/en
Publication of CN106750806A publication Critical patent/CN106750806A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE

Abstract

The invention discloses a kind of outdoor plastic platen with anti-aging wear-resisting PE plastic alloys, the PE plastic alloys are made from the following raw materials in parts by weight:130 170 parts of HDPE, 30 40 parts of haloflex, 8 20 parts of cellulose diacetate, 12 14 parts of propylgallate, 12 parts of 2,4 dihydroxy benaophenonel, 5 10 parts of ammonium hydrogen carbonate, 23 parts of bayberry wax, 10 15 parts of glass fibre, 25 parts of nano zine oxide.The anti-aging wear-resisting PE plastic alloys of the outdoor plastic platen that the present invention is provided have the advantages that ageing resistance is good, wearability good and long service life, and processing cost is low, preparation process is simple, parameter are easily-controllable, production process safety and environmental protection, are adapted to large-scale industrial production.

Description

A kind of outdoor plastic platen is with anti-aging wear-resisting PE plastic alloys
Technical field
The invention belongs to plastic alloy field, and in particular to a kind of outdoor plastic platen is closed with anti-aging wear-resisting PE plastics Gold.
Background technology
Polyethylene(Polyethylene, abbreviation PE)It is a kind of aggregated obtained thermoplastic resin of ethene.Polyethylene is One of five big synthetic resin, polyethylene according to polymerization, molecular weight height, chain structure difference, it is point high density polyethylene (HDPE), low close Degree polyethylene and LLDPE.Industrially, the also copolymer including ethene with a small amount of alpha-olefin.Polyethylene without It is smelly, nontoxic, feel ceraceous, with excellent resistance to low temperature(Reachable -100 ~ -70 °C of minimum temperature in use), chemical stability It is good, it is resistant to the erosion of most of soda acids(Intolerant to the acid with oxidizing property).Common solvent is not dissolved under normal temperature, water imbibition is small, Electrical insulating property is excellent.
Plastic alloy is high-performance, functionalization, the customizations obtained using the method for physical blending or chemical graft One class material.Product can be widely used for the fields such as automobile, electronics, precision instrument, office equipment, packaging material, construction material.It Can improve or improve the performance and reduces cost of existing plastics, it has also become one of kind the most active in plastics industry, increase It is very rapid.And this process for causing high-polymer material functional and high performance by high polymer alloy technology, it is crucial One of technology is the selection and preparation of compatilizer, and the compatilizer matched by selection and preparation could allow thermodynamics incompatible PE and other high polymers each superior performance is overlapped, realized high-performance and functionalized macromolecular alloying green wood The purpose of material.After the consistency problem between solving different component, also alloy material is increased by modes such as modified, grafting Compatibility between component, and enable to granulate the industrialization that production process forms alloy material by reactively blending Production.And China also lags far behind and foreign countries, general-purpose plastics alloy on the market in the research and development of plastic alloy at present Compared with external product, there is a problem of that of poor quality, added value is low, therefore how to solve the added value of product of PE plastic alloys The problems such as low, poor compatibility, be problem that PE plastic alloys need to be solved urgently.Therefore, we set about from the formula of product, exploitation New, annex performance high formula good with compatibility, there is provided a kind of outdoor plastic platen is with anti-aging wear-resisting PE plastic alloys.
The content of the invention
To achieve these goals, the invention provides a kind of outdoor plastic platen with anti-aging wear-resisting PE plastic alloys.
The purpose of the present invention is achieved through the following technical solutions:
A kind of outdoor plastic platen is made from the following raw materials in parts by weight with anti-aging wear-resisting PE plastic alloys:HDPE 130- 170 parts, haloflex 30-40 parts, cellulose diacetate 8-20 parts, propylgallate 12-14 parts, 2,4- dihydroxy two Benzophenone 1-2 parts, ammonium hydrogen carbonate 5-10 parts, bayberry wax 2-3 parts, glass fibre 10-15 parts, nano zine oxide 2-5 parts.
It also includes tributyl 2-acetylcitrate 2-5 parts.
It also includes silica 4-8 parts.
It also includes nano-calcium carbonate 5-10 parts.
The outdoor plastic platen preparation method of anti-aging wear-resisting PE plastic alloys, the method preparation process is:Press Described parts by weight are weighed in each raw material addition mixing and blending machine, carry out dispersion mixing treatment, then will be dispersed through at mixing The batch mixing of reason is added in double screw extruder, carries out extruding pelletization.
Beneficial effect:The outdoor plastic platen that the present invention is provided has ageing resistance good with anti-aging wear-resisting PE plastic alloys Good, wearability is good and advantage of long service life, and processing cost is low, and preparation process is simple, parameter are easily-controllable, production process peace Loopful is protected, and is adapted to large-scale industrial production.
Specific embodiment
As described below is only the preferred embodiments of the present invention, is not intended to limit the invention, although with reference to foregoing reality Apply example to be described in detail the present invention, for a person skilled in the art, it still can be to foregoing each implementation Technical scheme described in example is modified, or carries out equivalent to which part technical characteristic.It is all in essence of the invention Within god and principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.
Embodiment 1
A kind of outdoor plastic platen is made from the following raw materials in parts by weight with anti-aging wear-resisting PE plastic alloys:130 parts of HDPE, 30 parts of haloflex, 8 parts of cellulose diacetate, 12 parts of propylgallate, 1 part of 2,4-DihydroxyBenzophenone, bicarbonate 5 parts of ammonium, 2 parts of bayberry wax, 10 parts of glass fibre, 2 parts of nano zine oxide.
Its preparation methods steps are:Weighed during each raw material adds mixing and blending machine by described parts by weight, disperseed Mixed processing, the batch mixing that then will be dispersed through mixed processing is added in double screw extruder, carries out extruding pelletization.
Embodiment 2
A kind of outdoor plastic platen is made from the following raw materials in parts by weight with anti-aging wear-resisting PE plastic alloys:170 parts of HDPE, 40 parts of haloflex, 20 parts of cellulose diacetate, 14 parts of propylgallate, 2 parts of 2,4-DihydroxyBenzophenone, carbonic acid 10 parts of hydrogen ammonium, 3 parts of bayberry wax, 15 parts of glass fibre, 5 parts of nano zine oxide, 5 parts of tributyl 2-acetylcitrate.
Its preparation methods steps are:Weighed during each raw material adds mixing and blending machine by described parts by weight, disperseed Mixed processing, the batch mixing that then will be dispersed through mixed processing is added in double screw extruder, carries out extruding pelletization.
Embodiment 3
A kind of outdoor plastic platen is made from the following raw materials in parts by weight with anti-aging wear-resisting PE plastic alloys:130 parts of HDPE, 30 parts of haloflex, 8 parts of cellulose diacetate, 12 parts of propylgallate, 1 part of 2,4-DihydroxyBenzophenone, bicarbonate 5 parts of ammonium, 2 parts of bayberry wax, 10 parts of glass fibre, 2 parts of nano zine oxide, 2 parts of tributyl 2-acetylcitrate, 4 parts of silica.
Its preparation methods steps are:Weighed during each raw material adds mixing and blending machine by described parts by weight, disperseed Mixed processing, the batch mixing that then will be dispersed through mixed processing is added in double screw extruder, carries out extruding pelletization.
Embodiment 4
A kind of outdoor plastic platen is made from the following raw materials in parts by weight with anti-aging wear-resisting PE plastic alloys:170 parts of HDPE, 40 parts of haloflex, 20 parts of cellulose diacetate, 14 parts of propylgallate, 2 parts of 2,4-DihydroxyBenzophenone, carbonic acid 10 parts of hydrogen ammonium, 3 parts of bayberry wax, 15 parts of glass fibre, 5 parts of nano zine oxide, 5 parts of tributyl 2-acetylcitrate, silica 8 Part, 10 parts of nano-calcium carbonate.
Its preparation methods steps are:Weighed during each raw material adds mixing and blending machine by described parts by weight, disperseed Mixed processing, the batch mixing that then will be dispersed through mixed processing is added in double screw extruder, carries out extruding pelletization.

Claims (4)

1. a kind of outdoor plastic platen is with anti-aging wear-resisting PE plastic alloys, it is characterised in that by the raw material system of following weight portion Into:HDPE 130-170 parts, haloflex 30-40 parts, cellulose diacetate 8-20 parts, propylgallate 12-14 parts, 2,4-DihydroxyBenzophenone 1-2 parts, ammonium hydrogen carbonate 5-10 parts, bayberry wax 2-3 parts, glass fibre 10-15 parts, nano zine oxide 2-5 parts.
2. according to claim 1 a kind of outdoor plastic platen with anti-aging wear-resisting PE plastic alloys, it is characterised in that:It is also Comprising tributyl 2-acetylcitrate 2-5 parts.
3. according to claim 1 a kind of outdoor plastic platen with anti-aging wear-resisting PE plastic alloys, it is characterised in that:It is also Comprising silica 4-8 parts.
4. according to claim 1 a kind of outdoor plastic platen with anti-aging wear-resisting PE plastic alloys, it is characterised in that:It is also Comprising nano-calcium carbonate 5-10 parts.
CN201611196599.6A 2016-12-22 2016-12-22 A kind of outdoor plastic platen is with anti-aging wear-resisting PE plastic alloys Pending CN106750806A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611196599.6A CN106750806A (en) 2016-12-22 2016-12-22 A kind of outdoor plastic platen is with anti-aging wear-resisting PE plastic alloys

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611196599.6A CN106750806A (en) 2016-12-22 2016-12-22 A kind of outdoor plastic platen is with anti-aging wear-resisting PE plastic alloys

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CN106750806A true CN106750806A (en) 2017-05-31

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102241846A (en) * 2011-04-18 2011-11-16 刘立文 Calcium sulfate whisker modified high density polyethylene composite material and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102241846A (en) * 2011-04-18 2011-11-16 刘立文 Calcium sulfate whisker modified high density polyethylene composite material and preparation method thereof

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