CN106432880A - Low temperature anti-impact PE plastic alloy - Google Patents
Low temperature anti-impact PE plastic alloy Download PDFInfo
- Publication number
- CN106432880A CN106432880A CN201610909887.5A CN201610909887A CN106432880A CN 106432880 A CN106432880 A CN 106432880A CN 201610909887 A CN201610909887 A CN 201610909887A CN 106432880 A CN106432880 A CN 106432880A
- Authority
- CN
- China
- Prior art keywords
- parts
- low temperature
- plastic alloy
- impact
- alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
The invention discloses a low temperature anti-impact PE plastic alloy. The alloy comprises, by weight, 140-150 parts of PE, 40-50 parts of ABS, 20-30 parts of acrylonitrile-butadiene rubber, 5-12 parts of acetyl tributyl citrate, 4-5 parts of sodium polymethacrylate, 1-4 parts of octyl mercaptan, 2-4 parts of alkylphenol polyoxyethylene, 3-5 parts of antimony trioxide, 3-5 parts of carbamide, 2-3 parts of aluminium nitride and 3-7 parts of sodium hydroxide. The alloy has the advantages of low temperature resistance, high mechanical strength, anti-impact, long service life, low processing cost, simple preparation, easily controllable parameters, safety and environmental friendliness in the production process and suitability for large scale industrialized production.
Description
Technical field
The invention belongs to plastic alloy field, be specifically related to a kind of low temperature impact PE plastic alloy.
Background technology
Polyethylene（Polyethylene, is called for short PE）It is the aggregated prepared a kind of thermoplastic resin of ethene.Polyethylene is
One of five big synthetic resin, polyethylene is according to polymerization, molecular weight height, the difference of chain structure, point high density polyethylene (HDPE), low close
Degree polyethylene and LLDPE.Industrially, the copolymer of ethene and a small amount of alpha-olefin is also included.Polyethylene without
Smelly, nontoxic, feel ceraceous, there is excellent resistance to low temperature（Minimum use temperature up to-100 ~-70 ° of C）, chemical stability
Good, it is resistant to the erosion of most of soda acid（It is weak to the acid with oxidizing property）.Not dissolving in common solvent under normal temperature, water imbibition is little,
Electrical insulating property is excellent.
Plastic alloy be to utilize the method for physical blending or chemical graft and obtain high-performance, functionalization, customizations
One class material.Product can be widely used for the fields such as automobile, electronics, precision instrument, office equipment, packaging material, construction material.It
Can improve or improve the performance of existing plastics and reduce cost, it has also become one of kind enlivened the most in plastics industry, increasing
Very rapid.And this process being made high-polymer material functional and high performance by high polymer alloy technology, it is crucial
One of technology is selection and the preparation of compatilizer, by selecting and preparing the compatilizer matching, thermodynamics could be allowed incompatible
PE with other high polymers, each superior performance is overlapped, realized high-performance and functionalized macromolecular alloying green wood
The purpose of material.After the consistency problem solving between different component, also to increase alloy material by modes such as modification, grafting
Compatibility between component, and enable to be formed the industrialization of alloy material by reactively blending granulation production process
Produce.And current China also lag far behind with abroad in the research and development of plastic alloy, the general-purpose plastics alloy that market is sold
Compared with external product, there is problem of poor quality, that added value is low, therefore how to solve the added value of product of PE plastic alloy
The problems such as low, poor compatibility, are the problems that PE plastic alloy need to urgently solve.To this end, we set about from the formula of product, exploitation
New to have compatibility good, and the high formula of annex performance provides a kind of low temperature impact PE plastic alloy.
Content of the invention
To achieve these goals, the invention provides a kind of low temperature impact PE plastic alloy.
It is an object of the invention to be achieved through the following technical solutions：
A kind of low temperature impact PE plastic alloy, is prepared by the raw materials in：PE140-150 part, ABS 40-50 part,
Butyronitrile rubber 20-30 part, tributyl 2-acetylcitrate 5-12 part, sodium polymethacrylate 4-5 part, octyl mercaptan tin 1-4 part, alkane
Base phenol polyethenoxy ether 2-4 part, antimony oxide 3-5 part, carbonyl diamide 3-5 part, aluminium nitride 2-3 part, NaOH 3-7 part.
It also comprises nanometer boron fibre 6-8 part.
It also comprises ethyl acetate 10-15 part.
It also comprises sodium bentonite 10-15 part.
The preparation method of described low temperature impact PE plastic alloy, the method preparation process is：By described parts by weight
Weigh each raw material to add in mixing and blending machine, carry out dispersion mixing process, then the batch mixing being dispersed through mixed processing is joined
In double screw extruder, carry out extruding pelletization.
Beneficial effect：The present invention provide low temperature impact PE plastic alloy have low temperature resistant, mechanical strength is high, impact resistance
And the advantage of length in service life, and processing cost is low, preparation technology is simple, parameter is easily-controllable, production process safety and environmental protection, is suitable for big
The industrialized production of scale.
Detailed description of the invention
The following stated is only the preferred embodiments of the present invention, is not limited to the present invention, although with reference to aforementioned reality
Executing example to be described in detail the present invention, for a person skilled in the art, it still can be to aforementioned each enforcement
Technical scheme described in example is modified, or carries out equivalent to wherein portion of techniques feature.All essences in the present invention
Within god and principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.
Embodiment 1
A kind of low temperature impact PE plastic alloy, is prepared by the raw materials in：PE140 part, ABS 40 parts, butyronitrile rubber
20 parts, tributyl 2-acetylcitrate 5 parts, sodium polymethacrylate 4 parts, 1 part of octyl mercaptan tin, APES 2 parts,
Antimony oxide 3 parts, carbonyl diamide 3 parts, aluminium nitride 2 parts, 3 parts of NaOH.
Its preparation methods steps is：Weigh each raw material by described parts by weight to add in mixing and blending machine, disperse
Then the batch mixing being dispersed through mixed processing is joined in double screw extruder by mixed processing, carries out extruding pelletization.
Embodiment 2
A kind of low temperature impact PE plastic alloy, is prepared by the raw materials in：PE150 part, ABS 50 parts, butyronitrile rubber
30 parts, tributyl 2-acetylcitrate 12 parts, sodium polymethacrylate 5 parts, 4 parts of octyl mercaptan tin, APES 4
Part, antimony oxide 5 parts, carbonyl diamide 5 parts, aluminium nitride 3 parts, 7 parts of NaOH, nanometer boron fibre 8 parts.
Its preparation methods steps is：Weigh each raw material by described parts by weight to add in mixing and blending machine, disperse
Then the batch mixing being dispersed through mixed processing is joined in double screw extruder by mixed processing, carries out extruding pelletization.
Embodiment 3
A kind of low temperature impact PE plastic alloy, is prepared by the raw materials in：PE140 part, ABS 40 parts, butyronitrile rubber
20 parts, tributyl 2-acetylcitrate 5 parts, sodium polymethacrylate 4 parts, 1 part of octyl mercaptan tin, APES 2 parts,
Antimony oxide 3 parts, carbonyl diamide 3 parts, aluminium nitride 2 parts, 3 parts of NaOH, nanometer boron fibre 6 parts, ethyl acetate 10 parts.
Its preparation methods steps is：Weigh each raw material by described parts by weight to add in mixing and blending machine, disperse
Then the batch mixing being dispersed through mixed processing is joined in double screw extruder by mixed processing, carries out extruding pelletization.
Embodiment 4
A kind of low temperature impact PE plastic alloy, is prepared by the raw materials in：PE150 part, ABS 50 parts, butyronitrile rubber
30 parts, tributyl 2-acetylcitrate 12 parts, sodium polymethacrylate 5 parts, 4 parts of octyl mercaptan tin, APES 4
Part, antimony oxide 5 parts, carbonyl diamide 5 parts, aluminium nitride 3 parts, 7 parts of NaOH, nanometer boron fibre 8 parts, ethyl acetate 15
Part, sodium bentonite 15 parts.
Its preparation methods steps is：Weigh each raw material by described parts by weight to add in mixing and blending machine, disperse
Then the batch mixing being dispersed through mixed processing is joined in double screw extruder by mixed processing, carries out extruding pelletization.
Claims (4)
1. a low temperature impact PE plastic alloy, it is characterised in that be prepared by the raw materials in：PE140-150 part,
ABS 40-50 part, butyronitrile rubber 20-30 part, tributyl 2-acetylcitrate 5-12 part, sodium polymethacrylate 4-5 part, octyl group sulphur
Alcohol tin 1-4 part, APES 2-4 part, antimony oxide 3-5 part, carbonyl diamide 3-5 part, aluminium nitride 2-3 part, hydrogen
Sodium oxide molybdena 3-7 part.
2. a kind of low temperature impact PE plastic alloy according to claim 1, it is characterised in that：It also comprises nanometer boron fibre
6-8 part.
3. a kind of low temperature impact PE plastic alloy according to claim 1, it is characterised in that：It also comprises ethyl acetate
10-15 part.
4. a kind of low temperature impact PE plastic alloy according to claim 1, it is characterised in that：It also comprises sodium bentonite
10-15 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610909887.5A CN106432880A (en) | 2016-10-19 | 2016-10-19 | Low temperature anti-impact PE plastic alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610909887.5A CN106432880A (en) | 2016-10-19 | 2016-10-19 | Low temperature anti-impact PE plastic alloy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106432880A true CN106432880A (en) | 2017-02-22 |
Family
ID=58176265
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610909887.5A Pending CN106432880A (en) | 2016-10-19 | 2016-10-19 | Low temperature anti-impact PE plastic alloy |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106432880A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103849049A (en) * | 2012-12-04 | 2014-06-11 | 青岛三利中德美水设备有限公司 | Modified polyethylene powder and preparation method thereof |
-
2016
- 2016-10-19 CN CN201610909887.5A patent/CN106432880A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103849049A (en) * | 2012-12-04 | 2014-06-11 | 青岛三利中德美水设备有限公司 | Modified polyethylene powder and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107033456B (en) | One kind is based on POSS organic-inorganic hybrid nanometer compatilizer and its preparation and application | |
| CN107082977A (en) | A kind of high-impact high fluidity PVC injected plastics materials formula and preparation method thereof | |
| CN103044837B (en) | HIPS composite, its preparation method and application | |
| CN104292741A (en) | ABS (acrylonitrile butadiene styrene copolymers) composite material and preparation method thereof | |
| CN102516464B (en) | Epoxypropyl methacrylate grafting acrylonitrile butadiene styrene (ABS) copolymer and preparation method thereof | |
| CN112694708A (en) | Environment-friendly modified ABS (acrylonitrile butadiene styrene) composite plastic and preparation method thereof | |
| CN105623233B (en) | A kind of injection grade PC/ABS alloy materials of wear-resisting scratch-resistant and preparation method thereof | |
| CN111995856A (en) | PC composition | |
| CN110157109A (en) | A kind of moisture-proof high intensity IC carrier material | |
| CN106432880A (en) | Low temperature anti-impact PE plastic alloy | |
| CN105061949A (en) | Insulating PVC (polyvinyl chloride) plastic particle | |
| CN103396643A (en) | Modifier-containing polyacrylate grafted vinyl chloride composite resin composition | |
| CN110938248A (en) | High-barrier heat-resistant PE plastic bottle and preparation process thereof | |
| CN106750805A (en) | A kind of beverage bottle wear-resisting PE plastic alloys of antibacterial | |
| CN109280268A (en) | A kind of polypropylene plastics of superior performance and preparation method thereof | |
| CN106188853A (en) | A kind of high tenacity high temperature resistant PP/PBT plastic alloy and preparation method thereof | |
| CN106674689A (en) | Anti-impact wear-resistant PE (polyethylene) plastic alloy for turnover box | |
| CN106479019A (en) | A kind of wear-resisting PE plastic alloy of high impact-resistant | |
| CN106750804A (en) | A kind of wear-resisting PA/PE plastic alloys of antibacterial | |
| CN106674690A (en) | Antibacterial and anti-aging polyethylene (PE) plastic alloy | |
| CN106589526A (en) | PP-PE alloy and preparation method thereof | |
| CN106554610A (en) | A kind of PC PE alloys and preparation method thereof | |
| CN110885489A (en) | Low-temperature-resistant polyethylene plastic barrel and preparation process thereof | |
| CN105907052A (en) | Environment-friendly impact resistant PC (polycarbonate)/PBT (polybutylene terephthalate)/PP (polypropylene) plastic alloy and preparation method thereof | |
| CN105622817B (en) | The method that body in-situ polymerization prepares EVA/ graphene composite materials |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170222 |
|
| WD01 | Invention patent application deemed withdrawn after publication |