CN106750805A - A kind of beverage bottle wear-resisting PE plastic alloys of antibacterial - Google Patents
A kind of beverage bottle wear-resisting PE plastic alloys of antibacterial Download PDFInfo
- Publication number
- CN106750805A CN106750805A CN201611196571.2A CN201611196571A CN106750805A CN 106750805 A CN106750805 A CN 106750805A CN 201611196571 A CN201611196571 A CN 201611196571A CN 106750805 A CN106750805 A CN 106750805A
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- resisting
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- plastic alloys
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/10—Applications used for bottles
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of beverage bottle wear-resisting PE plastic alloys of antibacterial, the PE plastic alloys are made from the following raw materials in parts by weight:140 150 parts of HDPE, 60 65 parts of ABS, 2 15 parts of Dimethyl Trimethylsilylmethylphosphonate, 2 15 parts of sldium lauryl sulfate, 25 parts of the new heptanoic acid tert-butyl ester of peroxidating, 15 parts of antimony dithiocarbamate, 25 parts of monoglyceride, 68 parts of 26 part, nanometer boron fibre of potassium peroxydisulfate.The wear-resisting PE plastic alloys of beverage bottle antibacterial that the present invention is provided have the advantages that antibacterial and mouldproof is functional, long service life, and processing cost is low, and preparation process is simple, parameter are easily-controllable, production process safety and environmental protection, are adapted to large-scale industrial production.
Description
Technical field
The invention belongs to plastic alloy field, and in particular to a kind of beverage bottle wear-resisting PE plastic alloys of antibacterial.
Background technology
Polyethylene(Polyethylene, abbreviation PE)It is a kind of aggregated obtained thermoplastic resin of ethene.Polyethylene is
One of five big synthetic resin, polyethylene according to polymerization, molecular weight height, chain structure difference, it is point high density polyethylene (HDPE), low close
Degree polyethylene and LLDPE.Industrially, the also copolymer including ethene with a small amount of alpha-olefin.Polyethylene without
It is smelly, nontoxic, feel ceraceous, with excellent resistance to low temperature(Reachable -100 ~ -70 °C of minimum temperature in use), chemical stability
It is good, it is resistant to the erosion of most of soda acids(Intolerant to the acid with oxidizing property).Common solvent is not dissolved under normal temperature, water imbibition is small,
Electrical insulating property is excellent.
Plastic alloy is high-performance, functionalization, the customizations obtained using the method for physical blending or chemical graft
One class material.Product can be widely used for the fields such as automobile, electronics, precision instrument, office equipment, packaging material, construction material.It
Can improve or improve the performance and reduces cost of existing plastics, it has also become one of kind the most active in plastics industry, increase
It is very rapid.And this process for causing high-polymer material functional and high performance by high polymer alloy technology, it is crucial
One of technology is the selection and preparation of compatilizer, and the compatilizer matched by selection and preparation could allow thermodynamics incompatible
PE and other high polymers each superior performance is overlapped, realized high-performance and functionalized macromolecular alloying green wood
The purpose of material.After the consistency problem between solving different component, also alloy material is increased by modes such as modified, grafting
Compatibility between component, and enable to granulate the industrialization that production process forms alloy material by reactively blending
Production.And China also lags far behind and foreign countries, general-purpose plastics alloy on the market in the research and development of plastic alloy at present
Compared with external product, there is a problem of that of poor quality, added value is low, therefore how to solve the added value of product of PE plastic alloys
The problems such as low, poor compatibility, be problem that PE plastic alloys need to be solved urgently.Therefore, we set about from the formula of product, exploitation
A kind of new, annex performance high formula good with compatibility, there is provided beverage bottle wear-resisting PE plastic alloys of antibacterial.
The content of the invention
To achieve these goals, the invention provides a kind of beverage bottle wear-resisting PE plastic alloys of antibacterial.
The purpose of the present invention is achieved through the following technical solutions:
A kind of beverage bottle wear-resisting PE plastic alloys of antibacterial, are made from the following raw materials in parts by weight:HDPE 140-150 parts, ABS
60-65 parts, Dimethyl Trimethylsilylmethylphosphonate 2-15 parts, sldium lauryl sulfate 2-15 parts, the new heptanoic acid tert-butyl ester 2-5 of peroxidating
Part, antimony dithiocarbamate 1-5 parts, monoglyceride 2-5 parts, potassium peroxydisulfate 2-6 parts, 6-8 parts of nanometer boron fibre.
It also includes Bronyl acetate 1-2 parts.
It also includes pentachlorophenol 2-5 parts.
It also includes octadecanoid acid 5-8 parts.
The beverage bottle preparation method of the wear-resisting PE plastic alloys of antibacterial, the method preparation process is:By described weight
Amount number is weighed in each raw material addition mixing and blending machine, carries out dispersion mixing treatment, then will be dispersed through the batch mixing of mixed processing
It is added in double screw extruder, carries out extruding pelletization.
Beneficial effect:The present invention provide the wear-resisting PE plastic alloys of beverage bottle antibacterial have antibacterial and mouldproof it is functional,
The advantage of long service life, and processing cost is low, preparation process is simple, parameter are easily-controllable, production process safety and environmental protection, are adapted to big rule
The industrialized production of mould.
Specific embodiment
As described below is only the preferred embodiments of the present invention, is not intended to limit the invention, although with reference to foregoing reality
Apply example to be described in detail the present invention, for a person skilled in the art, it still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent to which part technical characteristic.It is all in essence of the invention
Within god and principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.
Embodiment 1
A kind of beverage bottle wear-resisting PE plastic alloys of antibacterial, are made from the following raw materials in parts by weight:140 parts of HDPE, ABS 60
Part, 2 parts of Dimethyl Trimethylsilylmethylphosphonate, 2 parts of sldium lauryl sulfate, 2 parts of the new heptanoic acid tert-butyl ester of peroxidating, dithiocarbamates
1 part of formic acid antimony, 2 parts of monoglyceride, 6 parts of 2 part, nanometer boron fibre of potassium peroxydisulfate.
Its preparation methods steps are:Weighed during each raw material adds mixing and blending machine by described parts by weight, disperseed
Mixed processing, the batch mixing that then will be dispersed through mixed processing is added in double screw extruder, carries out extruding pelletization.
Embodiment 2
A kind of beverage bottle wear-resisting PE plastic alloys of antibacterial, are made from the following raw materials in parts by weight:150 parts of HDPE, ABS 65
Part, 15 parts of Dimethyl Trimethylsilylmethylphosphonate, 15 parts of sldium lauryl sulfate, 5 parts of the new heptanoic acid tert-butyl ester of peroxidating, two thio ammonia
5 parts of base formic acid antimony, 5 parts of monoglyceride, 8 parts of 6 part, nanometer boron fibre of potassium peroxydisulfate, 2 parts of Bronyl acetate.
Its preparation methods steps are:Weighed during each raw material adds mixing and blending machine by described parts by weight, disperseed
Mixed processing, the batch mixing that then will be dispersed through mixed processing is added in double screw extruder, carries out extruding pelletization.
Embodiment 3
A kind of beverage bottle wear-resisting PE plastic alloys of antibacterial, are made from the following raw materials in parts by weight:140 parts of HDPE, ABS 60
Part, 2 parts of Dimethyl Trimethylsilylmethylphosphonate, 2 parts of sldium lauryl sulfate, 2 parts of the new heptanoic acid tert-butyl ester of peroxidating, dithiocarbamates
1 part of formic acid antimony, 2 parts of monoglyceride, 6 parts of 2 part, nanometer boron fibre of potassium peroxydisulfate, 1 part of Bronyl acetate, 2 parts of pentachlorophenol.
Its preparation methods steps are:Weighed during each raw material adds mixing and blending machine by described parts by weight, disperseed
Mixed processing, the batch mixing that then will be dispersed through mixed processing is added in double screw extruder, carries out extruding pelletization.
Embodiment 4
A kind of beverage bottle wear-resisting PE plastic alloys of antibacterial, are made from the following raw materials in parts by weight:150 parts of HDPE, ABS 65
Part, 15 parts of Dimethyl Trimethylsilylmethylphosphonate, 15 parts of sldium lauryl sulfate, 5 parts of the new heptanoic acid tert-butyl ester of peroxidating, two thio ammonia
5 parts of base formic acid antimony, 5 parts of monoglyceride, 8 parts of 6 part, nanometer boron fibre of potassium peroxydisulfate, 2 parts of Bronyl acetate, 5 parts of pentachlorophenol, ten
Eight 8 parts of alkanoic acids.
Its preparation methods steps are:Weighed during each raw material adds mixing and blending machine by described parts by weight, disperseed
Mixed processing, the batch mixing that then will be dispersed through mixed processing is added in double screw extruder, carries out extruding pelletization.
Claims (4)
1. a kind of beverage bottle wear-resisting PE plastic alloys of antibacterial, it is characterised in that be made from the following raw materials in parts by weight:HDPE
140-150 parts, ABS 60-65 parts, Dimethyl Trimethylsilylmethylphosphonate 2-15 parts, sldium lauryl sulfate 2-15 parts, peroxidating
New 2-5 parts of heptanoic acid tert-butyl ester, antimony dithiocarbamate 1-5 parts, monoglyceride 2-5 parts, potassium peroxydisulfate 2-6 parts, nanometer boron fibre
6-8 parts.
2. a kind of beverage bottle wear-resisting PE plastic alloys of antibacterial according to claim 1, it is characterised in that:It also includes acetic acid
Borneol acetate 1-2 parts.
3. a kind of beverage bottle wear-resisting PE plastic alloys of antibacterial according to claim 1, it is characterised in that:It also includes pentachloro-
Phenol 2-5 parts.
4. a kind of beverage bottle wear-resisting PE plastic alloys of antibacterial according to claim 1, it is characterised in that:It also includes 18
Alkanoic acid 5-8 parts.
Priority Applications (1)
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CN201611196571.2A CN106750805A (en) | 2016-12-22 | 2016-12-22 | A kind of beverage bottle wear-resisting PE plastic alloys of antibacterial |
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CN201611196571.2A CN106750805A (en) | 2016-12-22 | 2016-12-22 | A kind of beverage bottle wear-resisting PE plastic alloys of antibacterial |
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CN201611196571.2A Pending CN106750805A (en) | 2016-12-22 | 2016-12-22 | A kind of beverage bottle wear-resisting PE plastic alloys of antibacterial |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107629292A (en) * | 2017-09-29 | 2018-01-26 | 安徽嘉美包装有限公司 | A kind of beverage bottle special plastic material and preparation method thereof |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103849049A (en) * | 2012-12-04 | 2014-06-11 | 青岛三利中德美水设备有限公司 | Modified polyethylene powder and preparation method thereof |
-
2016
- 2016-12-22 CN CN201611196571.2A patent/CN106750805A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103849049A (en) * | 2012-12-04 | 2014-06-11 | 青岛三利中德美水设备有限公司 | Modified polyethylene powder and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107629292A (en) * | 2017-09-29 | 2018-01-26 | 安徽嘉美包装有限公司 | A kind of beverage bottle special plastic material and preparation method thereof |
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