CN106750803A - A kind of sealing container high-strength abrasion-proof PE plastic alloys - Google Patents
A kind of sealing container high-strength abrasion-proof PE plastic alloys Download PDFInfo
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- CN106750803A CN106750803A CN201611196530.3A CN201611196530A CN106750803A CN 106750803 A CN106750803 A CN 106750803A CN 201611196530 A CN201611196530 A CN 201611196530A CN 106750803 A CN106750803 A CN 106750803A
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- parts
- proof
- sealing container
- plastic alloys
- strength abrasion
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of sealing container high-strength abrasion-proof PE plastic alloys, the PE plastic alloys are made from the following raw materials in parts by weight：140 150 parts of HDPE, 35 45 parts of MMB methyl methacrylate butadiene styrol copolymer, 5 12 parts of ACM, 24 parts of Dimethyl Trimethylsilylmethylphosphonate, 48 parts of aluminum oxide, 25 parts of the new heptanoic acid tert-butyl ester of peroxidating, 26 parts of potassium peroxydisulfate, 10 15 parts of carbon fiber, 12 parts of carbon tetrachloride, 25 parts of Bronyl acetate.The sealing container high-strength abrasion-proof PE plastic alloys that the present invention is provided have the advantages that good high mechanical strength, wearability, safety and environmental protection and long service life, and processing cost is low, preparation process is simple, parameter are easily-controllable, production process safety and environmental protection, are adapted to large-scale industrial production.
Description
Technical field
The invention belongs to plastic alloy field, and in particular to a kind of sealing container high-strength abrasion-proof PE plastic alloys.
Background technology
Polyethylene（Polyethylene, abbreviation PE）It is a kind of aggregated obtained thermoplastic resin of ethene.Polyethylene is
One of five big synthetic resin, polyethylene according to polymerization, molecular weight height, chain structure difference, it is point high density polyethylene (HDPE), low close
Degree polyethylene and LLDPE.Industrially, the also copolymer including ethene with a small amount of alpha-olefin.Polyethylene without
It is smelly, nontoxic, feel ceraceous, with excellent resistance to low temperature（Reachable -100 ~ -70 °C of minimum temperature in use）, chemical stability
It is good, it is resistant to the erosion of most of soda acids（Intolerant to the acid with oxidizing property）.Common solvent is not dissolved under normal temperature, water imbibition is small,
Electrical insulating property is excellent.
Plastic alloy is high-performance, functionalization, the customizations obtained using the method for physical blending or chemical graft
One class material.Product can be widely used for the fields such as automobile, electronics, precision instrument, office equipment, packaging material, construction material.It
Can improve or improve the performance and reduces cost of existing plastics, it has also become one of kind the most active in plastics industry, increase
It is very rapid.And this process for causing high-polymer material functional and high performance by high polymer alloy technology, it is crucial
One of technology is the selection and preparation of compatilizer, and the compatilizer matched by selection and preparation could allow thermodynamics incompatible
PE and other high polymers each superior performance is overlapped, realized high-performance and functionalized macromolecular alloying green wood
The purpose of material.After the consistency problem between solving different component, also alloy material is increased by modes such as modified, grafting
Compatibility between component, and enable to granulate the industrialization that production process forms alloy material by reactively blending
Production.And China also lags far behind and foreign countries, general-purpose plastics alloy on the market in the research and development of plastic alloy at present
Compared with external product, there is a problem of that of poor quality, added value is low, therefore how to solve the added value of product of PE plastic alloys
The problems such as low, poor compatibility, be problem that PE plastic alloys need to be solved urgently.Therefore, we set about from the formula of product, exploitation
A kind of new, annex performance high formula good with compatibility, there is provided sealing container high-strength abrasion-proof PE plastic alloys.
The content of the invention
To achieve these goals, the invention provides a kind of sealing container high-strength abrasion-proof PE plastic alloys.
The purpose of the present invention is achieved through the following technical solutions：
A kind of sealing container high-strength abrasion-proof PE plastic alloys, are made from the following raw materials in parts by weight：HDPE 140-150 parts,
MBS 35-45 parts, ACM 5-12 parts, trimethylsilyl methylphosphonic acid
Dimethyl ester 2-4 parts, aluminum oxide 4-8 parts, new heptanoic acid tert-butyl ester 2-5 parts of peroxidating, potassium peroxydisulfate 2-6 parts, carbon fiber 10-15 parts,
Carbon tetrachloride 1-2 parts, Bronyl acetate 2-5 parts.
It also includes tributyl 2-acetylcitrate 4-8 parts.
It also includes epoxidized soybean oil 1-4 parts.
It also includes octadecanoid acid 5-8 parts.
The sealing container preparation method of high-strength abrasion-proof PE plastic alloys, the method preparation process is：By described
Parts by weight weigh during each raw material adds mixing and blending machine, carry out dispersion mixing treatment, then will be dispersed through mixed processing
Batch mixing is added in double screw extruder, carries out extruding pelletization.
Beneficial effect：The sealing container high-strength abrasion-proof PE plastic alloys that the present invention is provided have high mechanical strength, resistance to
Mill property is good, the advantage of safety and environmental protection and long service life, and processing cost is low, and preparation process is simple, parameter are easily-controllable, produce
Journey safety and environmental protection, is adapted to large-scale industrial production.
Specific embodiment
As described below is only the preferred embodiments of the present invention, is not intended to limit the invention, although with reference to foregoing reality
Apply example to be described in detail the present invention, for a person skilled in the art, it still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent to which part technical characteristic.It is all in essence of the invention
Within god and principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.
Embodiment 1
A kind of sealing container high-strength abrasion-proof PE plastic alloys, are made from the following raw materials in parts by weight：140 parts of HDPE, methyl
35 parts of methylacrylate-butadiene-styrol copolymer, 5 parts of ACM, 2 parts of Dimethyl Trimethylsilylmethylphosphonate,
4 parts of aluminum oxide, 2 parts of the new heptanoic acid tert-butyl ester of peroxidating, 2 parts of potassium peroxydisulfate, 10 parts of carbon fiber, carbon tetrachloride 1-2 parts, acetic acid borneol
2 parts of ester.
Its preparation methods steps are：Weighed during each raw material adds mixing and blending machine by described parts by weight, disperseed
Mixed processing, the batch mixing that then will be dispersed through mixed processing is added in double screw extruder, carries out extruding pelletization.
Embodiment 2
A kind of sealing container high-strength abrasion-proof PE plastic alloys, are made from the following raw materials in parts by weight：HDPE150 parts, methyl
45 parts of methylacrylate-butadiene-styrol copolymer, 12 parts of ACM, Dimethyl Trimethylsilylmethylphosphonate 4
Part, 8 parts of aluminum oxide, 5 parts of the new heptanoic acid tert-butyl ester of peroxidating, 6 parts of potassium peroxydisulfate, 15 parts of carbon fiber, 2 parts of carbon tetrachloride, acetic acid dragon
5 parts of brain ester, 8 parts of tributyl 2-acetylcitrate.
Its preparation methods steps are：Weighed during each raw material adds mixing and blending machine by described parts by weight, disperseed
Mixed processing, the batch mixing that then will be dispersed through mixed processing is added in double screw extruder, carries out extruding pelletization.
Embodiment 3
A kind of sealing container high-strength abrasion-proof PE plastic alloys, are made from the following raw materials in parts by weight：140 parts of HDPE, methyl
35 parts of methylacrylate-butadiene-styrol copolymer, 5 parts of ACM, 2 parts of Dimethyl Trimethylsilylmethylphosphonate,
4 parts of aluminum oxide, 2 parts of the new heptanoic acid tert-butyl ester of peroxidating, 2 parts of potassium peroxydisulfate, 10 parts of carbon fiber, carbon tetrachloride 1-2 parts, acetic acid borneol
2 parts of ester, 4 parts of tributyl 2-acetylcitrate, 1 part of epoxidized soybean oil.
Its preparation methods steps are：Weighed during each raw material adds mixing and blending machine by described parts by weight, disperseed
Mixed processing, the batch mixing that then will be dispersed through mixed processing is added in double screw extruder, carries out extruding pelletization.
Embodiment 4
A kind of sealing container high-strength abrasion-proof PE plastic alloys, are made from the following raw materials in parts by weight：HDPE150 parts, methyl
45 parts of methylacrylate-butadiene-styrol copolymer, 12 parts of ACM, Dimethyl Trimethylsilylmethylphosphonate 4
Part, 8 parts of aluminum oxide, 5 parts of the new heptanoic acid tert-butyl ester of peroxidating, 6 parts of potassium peroxydisulfate, 15 parts of carbon fiber, 2 parts of carbon tetrachloride, acetic acid dragon
5 parts of brain ester, 8 parts of tributyl 2-acetylcitrate, 4 parts of epoxidized soybean oil, 8 parts of octadecanoid acid.
Its preparation methods steps are：Weighed during each raw material adds mixing and blending machine by described parts by weight, disperseed
Mixed processing, the batch mixing that then will be dispersed through mixed processing is added in double screw extruder, carries out extruding pelletization.
Claims (4)
1. a kind of sealing container high-strength abrasion-proof PE plastic alloys, it is characterised in that be made from the following raw materials in parts by weight：
HDPE 140-150 parts, MBS 35-45 parts, ACM 5-12 parts,
Dimethyl Trimethylsilylmethylphosphonate 2-4 parts, aluminum oxide 4-8 parts, new heptanoic acid tert-butyl ester 2-5 parts of peroxidating, potassium peroxydisulfate 2-6
Part, carbon fiber 10-15 parts, carbon tetrachloride 1-2 parts, Bronyl acetate 2-5 parts.
2. a kind of sealing container high-strength abrasion-proof PE plastic alloys according to claim 1, it is characterised in that：It is also included
Tributyl 2-acetylcitrate 4-8 parts.
3. a kind of sealing container high-strength abrasion-proof PE plastic alloys according to claim 1, it is characterised in that：It is also included
Epoxidized soybean oil 1-4 parts.
4. a kind of sealing container high-strength abrasion-proof PE plastic alloys according to claim 1, it is characterised in that：It is also included
Octadecanoid acid 5-8 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611196530.3A CN106750803A (en) | 2016-12-22 | 2016-12-22 | A kind of sealing container high-strength abrasion-proof PE plastic alloys |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611196530.3A CN106750803A (en) | 2016-12-22 | 2016-12-22 | A kind of sealing container high-strength abrasion-proof PE plastic alloys |
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| CN106750803A true CN106750803A (en) | 2017-05-31 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611196530.3A Pending CN106750803A (en) | 2016-12-22 | 2016-12-22 | A kind of sealing container high-strength abrasion-proof PE plastic alloys |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102352065A (en) * | 2011-08-22 | 2012-02-15 | 长沙前元塑料技术开发有限公司 | Macromolecular composite material and preparation method thereof |
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- 2016-12-22 CN CN201611196530.3A patent/CN106750803A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102352065A (en) * | 2011-08-22 | 2012-02-15 | 长沙前元塑料技术开发有限公司 | Macromolecular composite material and preparation method thereof |
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Application publication date: 20170531 |