CN106674690A - Antibacterial and anti-aging polyethylene (PE) plastic alloy - Google Patents
Antibacterial and anti-aging polyethylene (PE) plastic alloy Download PDFInfo
- Publication number
- CN106674690A CN106674690A CN201611196596.2A CN201611196596A CN106674690A CN 106674690 A CN106674690 A CN 106674690A CN 201611196596 A CN201611196596 A CN 201611196596A CN 106674690 A CN106674690 A CN 106674690A
- Authority
- CN
- China
- Prior art keywords
- parts
- aging
- antibacterial
- resistant
- plastic alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses antibacterial and anti-aging polyethylene (PE) plastic alloy. The PE plastic alloy is prepared from the following raw materials in parts by weight: 130-140 parts of PE, 80-85 parts of polybenzimidazole (PBI), 8-23 parts of acetyl tributyl citrate, 15-28 parts of allyl acetoacetate, 2-3 parts of aluminum nitride, 3-7 parts of sodium hydroxide, 6-8 parts of nano boron fiber and 10-15 parts of ethyl acetate. The antibacterial and anti-aging PE plastic alloy provided by the invention has the advantages of good antibacterial and anti-mildew properties, high strength, high aging resistance, long service life, low processing cost, simple preparation technology, easiness in parameter control as well as safe and environmentally-friendly in production process, thus being suitable for large-scale industrial production.
Description
Technical field
The invention belongs to plastic alloy field, and in particular to a kind of antibiotic aging-resistant PE plastic alloys.
Background technology
Polyethylene（Polyethylene, abbreviation PE）It is a kind of aggregated obtained thermoplastic resin of ethylene.Polyethylene is
One of five big synthetic resin, polyethylene according to polymerization, molecular weight height, chain structure difference, it is point high density polyethylene (HDPE), low close
Degree polyethylene and linear low density polyethylene.Industrially, also including the copolymer of ethylene and a small amount of alpha-olefin.Polyethylene without
It is smelly, nontoxic, feel ceraceous, with excellent resistance to low temperature（Minimum use temperature is reachable -100 ~ -70 °C）, chemical stability
It is good, it is resistant to the erosion of most of soda acids（Intolerant to the acid with oxidizing property）.Common solvent is not dissolved under room temperature, water absorption is little,
Electrical insulating property is excellent.
Plastic alloy is high-performance, functionalization, the customizations obtained using the method for physical blending or chemical graft
One class material.Product can be widely used for the fields such as automobile, electronics, precision instrument, office equipment, packaging material, construction material.It
Can improve or improve the performance and reduces cost of existing plastics, it has also become one of kind the most active in plastics industry, increase
It is very rapid.And this process for causing high-polymer material functional and high performance by high polymer alloy technology, it is crucial
One of technology is the selection and preparation of compatilizer, by selecting and preparing the compatilizer for matching, thermodynamics could be allowed incompatible
PE and other high polymers each superior performance is overlapped, high-performance and functionalized macromolecular alloying green wood have been realized
The purpose of material.After the consistency problem between different component is solved, also alloy material is increased by modes such as modified, grafting
The compatibility between component, and enable to form the industrialization of alloy material by reactively blending pelletize production process
Production.And at present China also lags far behind and foreign countries in the research and development of plastic alloy, general-purpose plastics alloy on the market
Compared with external product, there is a problem of that of poor quality, added value is low, therefore how to solve the added value of product of PE plastic alloys
The problems such as low, poor compatibility, be problem that PE plastic alloys need to be solved urgently.For this purpose, we set about from the formula of product, exploitation
A kind of new, adnexa performance high formula good with the compatibility, there is provided antibiotic aging-resistant PE plastic alloys.
The content of the invention
To achieve these goals, the invention provides a kind of antibiotic aging-resistant PE plastic alloys.
The purpose of the present invention is achieved through the following technical solutions：
A kind of antibiotic aging-resistant PE plastic alloys, are prepared by the raw materials in：PE130-140 parts, PBI 80-85 parts,
Tributyl 2-acetylcitrate 8-23 parts, acetoacetic acid allyl ester 15-28 parts, aluminium nitride 2-3 parts, sodium hydroxide 3-7 parts, nanometer boron
Fiber 6-8 parts, ethyl acetate 10-15 parts.
It also includes synthetic wax 12-16 parts.
It also includes antimony oxide 4-8 parts.
It also includes sodium bentonite 10-15 parts.
The preparation method of the antibiotic aging-resistant PE plastic alloys, the method preparation process is：By described parts by weight
Weigh each raw material to add in mixing and blending machine, carry out dispersion mixing process, be then added to the batch mixing for being dispersed through mixed processing
In double screw extruder, extruding pelletization is carried out.
Beneficial effect：The antibiotic aging-resistant PE plastic alloys that the present invention is provided have good antibacterial and mouldproof performance, intensity
Height, resistance to ag(e)ing is strong, long service life, and processing cost is low, and preparation process is simple, parameter are easily-controllable, production process safety and environmental protection,
Suitable large-scale industrial production.
Specific embodiment
Described below is only the preferred embodiments of the present invention, is not limited to the present invention, although with reference to aforementioned reality
Apply example to be described in detail the present invention, for a person skilled in the art, it still can be to aforementioned each enforcement
Technical scheme described in example is modified, or carries out equivalent to which part technical characteristic.All essences in the present invention
Within god and principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.
Embodiment 1
A kind of antibiotic aging-resistant PE plastic alloys, are prepared by the raw materials in：PE130 parts, 80 parts of PBI, acetyl Fructus Citri Limoniae
8 parts of sour tributyl, 15 parts of acetoacetic acid allyl ester, 2 parts of aluminium nitride, 6 parts of 3 part, nanometer boron fibre of sodium hydroxide, ethyl acetate 10
Part.
Its preparation methods steps are：Each raw material is weighed by described parts by weight to add in mixing and blending machine, disperseed
Mixed processing, is then added to the batch mixing for being dispersed through mixed processing in double screw extruder, carries out extruding pelletization.
Embodiment 2
A kind of antibiotic aging-resistant PE plastic alloys, are prepared by the raw materials in：PE140 parts, 85 parts of PBI, acetyl Fructus Citri Limoniae
23 parts of sour tributyl, 28 parts of acetoacetic acid allyl ester, 3 parts of aluminium nitride, 8 parts of 7 part, nanometer boron fibre of sodium hydroxide, ethyl acetate
15 parts, 16 parts of synthetic wax.
Its preparation methods steps are：Each raw material is weighed by described parts by weight to add in mixing and blending machine, disperseed
Mixed processing, is then added to the batch mixing for being dispersed through mixed processing in double screw extruder, carries out extruding pelletization.
Embodiment 3
A kind of antibiotic aging-resistant PE plastic alloys, are prepared by the raw materials in：PE130 parts, 80 parts of PBI, acetyl Fructus Citri Limoniae
8 parts of sour tributyl, 15 parts of acetoacetic acid allyl ester, 2 parts of aluminium nitride, 6 parts of 3 part, nanometer boron fibre of sodium hydroxide, ethyl acetate 10
Part, 12 parts of synthetic wax, 4 parts of antimony oxide.
Its preparation methods steps are：Each raw material is weighed by described parts by weight to add in mixing and blending machine, disperseed
Mixed processing, is then added to the batch mixing for being dispersed through mixed processing in double screw extruder, carries out extruding pelletization.
Embodiment 4
A kind of antibiotic aging-resistant PE plastic alloys, are prepared by the raw materials in：PE140 parts, 85 parts of PBI, acetyl Fructus Citri Limoniae
23 parts of sour tributyl, 28 parts of acetoacetic acid allyl ester, 3 parts of aluminium nitride, 8 parts of 7 part, nanometer boron fibre of sodium hydroxide, ethyl acetate
15 parts, 16 parts of synthetic wax, 8 parts of antimony oxide, 15 parts of sodium bentonite.
Its preparation methods steps are：Each raw material is weighed by described parts by weight to add in mixing and blending machine, disperseed
Mixed processing, is then added to the batch mixing for being dispersed through mixed processing in double screw extruder, carries out extruding pelletization.
Claims (4)
1. a kind of antibiotic aging-resistant PE plastic alloys, it is characterised in that be prepared by the raw materials in：PE130-140 parts,
PBI 80-85 parts, tributyl 2-acetylcitrate 8-23 parts, acetoacetic acid allyl ester 15-28 parts, aluminium nitride 2-3 parts, sodium hydroxide
3-7 parts, nanometer boron fibre 6-8 parts, ethyl acetate 10-15 parts.
2. a kind of antibiotic aging-resistant PE plastic alloys according to claim 1, it is characterised in that：It also includes synthetic wax 12-
16 parts.
3. a kind of antibiotic aging-resistant PE plastic alloys according to claim 1, it is characterised in that：It also includes antimony oxide
4-8 parts.
4. a kind of antibiotic aging-resistant PE plastic alloys according to claim 1, it is characterised in that：It also includes sodium bentonite
10-15 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611196596.2A CN106674690A (en) | 2016-12-22 | 2016-12-22 | Antibacterial and anti-aging polyethylene (PE) plastic alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611196596.2A CN106674690A (en) | 2016-12-22 | 2016-12-22 | Antibacterial and anti-aging polyethylene (PE) plastic alloy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106674690A true CN106674690A (en) | 2017-05-17 |
Family
ID=58871032
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611196596.2A Pending CN106674690A (en) | 2016-12-22 | 2016-12-22 | Antibacterial and anti-aging polyethylene (PE) plastic alloy |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106674690A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103342843A (en) * | 2013-05-29 | 2013-10-09 | 安徽荣玖光纤通信科技有限公司 | PTC high-molecular conductive material with low-density polyethylene as main material and preparation method thereof |
-
2016
- 2016-12-22 CN CN201611196596.2A patent/CN106674690A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103342843A (en) * | 2013-05-29 | 2013-10-09 | 安徽荣玖光纤通信科技有限公司 | PTC high-molecular conductive material with low-density polyethylene as main material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104672697B (en) | A kind of wood plastic composite | |
| CN107459830A (en) | One kind is based on the bionical interface modifier enhancing bamboo fibre of poly-dopamine and poly butylene succinate interface compatibility technology | |
| CN105199412A (en) | Interpenetrating polymer network enhanced fully-degradable biomass matrix composite material and preparation method thereof | |
| CN107033456B (en) | One kind is based on POSS organic-inorganic hybrid nanometer compatilizer and its preparation and application | |
| CN104592722B (en) | The low warp glass fiber of high glaze strengthens PBT/PP Alloy And Preparation Method | |
| CN107903498B (en) | Halogen flame-retardant polypropylene material and preparation method and application thereof | |
| CN105820522A (en) | Calcium sulfate whisker reinforced and toughened polylactic acid composite and preparation method thereof | |
| CN107057334A (en) | Toughness reinforcing strengthens the preparation method of polymer composites | |
| CN104194371A (en) | High-lignin-content flame-retardant polyolefin composite material and preparation method thereof | |
| CN104292391A (en) | Melting production method for unsaturated anhydride grafted chlorinated polyethylene | |
| CN104861331A (en) | Carbon fiber filling modification polyvinyl chloride material and preparation method thereof | |
| CN106674690A (en) | Antibacterial and anti-aging polyethylene (PE) plastic alloy | |
| CN106188853A (en) | A kind of high tenacity high temperature resistant PP/PBT plastic alloy and preparation method thereof | |
| CN111073553A (en) | High-strength high-fluidity polypropylene bonding resin and preparation method thereof | |
| CN103435753B (en) | Anti-stress cracking agent, preparation method and application thereof as well as anti-stress PC (Poly Carbonate) polyester | |
| CN111234471A (en) | PBT composite material with low linear thermal expansion coefficient and preparation method thereof | |
| CN106674689A (en) | Anti-impact wear-resistant PE (polyethylene) plastic alloy for turnover box | |
| CN105061949A (en) | Insulating PVC (polyvinyl chloride) plastic particle | |
| CN106750804A (en) | A kind of wear-resisting PA/PE plastic alloys of antibacterial | |
| CN106496732A (en) | A kind of refrigerator lining wear-resisting PE plastic alloys of low temperature | |
| CN108699299A (en) | Polyolefin resin composite and polyolefin-based resins film | |
| CN106380670A (en) | Antibacterial antistatic PE (polyethylene) plastic alloy | |
| CN106554610A (en) | A kind of PC PE alloys and preparation method thereof | |
| CN106479019A (en) | A kind of wear-resisting PE plastic alloy of high impact-resistant | |
| CN106674713A (en) | Anti-ageing and weather-resisting PS/PE (Polystyrene/Polyethylene) plastic alloy |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170517 |