CN106748383A - A kind of cake of camellia oleifera seeds organic fertilizer and preparation method thereof - Google Patents
A kind of cake of camellia oleifera seeds organic fertilizer and preparation method thereof Download PDFInfo
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- CN106748383A CN106748383A CN201611257381.7A CN201611257381A CN106748383A CN 106748383 A CN106748383 A CN 106748383A CN 201611257381 A CN201611257381 A CN 201611257381A CN 106748383 A CN106748383 A CN 106748383A
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- oleifera seeds
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/12—Granules or flakes
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D1/00—Fertilisers containing potassium
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Soil Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a kind of cake of camellia oleifera seeds organic fertilizer, it is made up of the raw material of following quality proportioning:Cake of camellia oleifera seeds 40%~80%；Ashes 10%~50%；Tea oil soap stock 5%~20%, and its preparation method is provided.The present invention recycles the scrap feed material of oil tea deep processing enterprise, improve resource recycling rate, and the cake of camellia oleifera seeds organic fertilizer for providing contains abundant organic matter and potassium carbonate, improve plant products and resistance, contain 5%~15% Tea Saponin, there is strong toxic action to cold-blooded insect pest, it is possible to reduce pest and disease damage occurs.
Description
Technical field
The invention belongs to organic fertilizer technical field, a kind of organic fertilizer is related generally to, and in particular to a kind of cake of camellia oleifera seeds is organic
Fertilizer and preparation method thereof.
Background technology
Existing 382.17 ten thousand hectares of the camellia oleifera lam gross area of China in 2015, oil tea relevant enterprise 2208, tea seed yield
216.35 ten thousand tons.At this stage, China year tea oil yield produces 1,500,000 tons or so of cake of camellia oleifera seeds discarded object at 500,000 tons or so.
Tea seed gained grouts after extracting tea oil, because rich in saponin, spicy has strong haemocylolysis, often add it
For extracting Tea Saponin.But because current Tea Saponin extractive technique is not yet ripe, more using methyl alcohol equal solvent extraction Tea Saponin,
Not only energy consumption is very big, and yield is extremely low, and saponin content is up to more than 6% in gained saponin slag；Therefore by directly as discarded object
Or as fuel treatment.Even if directly as Fertilizer application also because the nutriment deficiency such as nitrogen, phosphorus, potassium causes fertility faint.
In the deep-processing process of oil tea, in order to lift the quality of camellia seed oil, it will usually using alkali refining, decolouring, deodorization
Technique Deng appropriateness refining is processed to camellia seed oil.Wherein alkali refining is particularly important, in alkali refining process, with neutralization reaction
Constantly carry out, be enclosed in the alkali drop in soap-film, influenceed constantly to be diffused into the outer layer of aquation soap-film by concentration difference, continue and trip
Soap-film is constantly thickeied from fatty acid response, gradually form relatively stable colloidal ion film, this glued membrane is a surface-active substance
Matter, can adsorb the impurity such as colloid, pigment in crude oil, and under the effect such as electrolyte, temperature and stirring, attract each other and flocculate into
Micelle, by small and big, forms " soap stock ", and is separated from oil and settled down, referred to as tea oil soap stock.Tea oil soap stock is sticky thing
Matter, on-liquid is also non-solid, it is impossible to it is processed according to conventional liq or solid.Therefore, intractability is very big.Mesh
Before, the main purposes of tea oil soap stock be exactly for producing acidification oil, most traditional way be exactly by add sulfuric acid make alkali soap and
There is acidification reaction generation free fatty in phosphatide.But environmental pollution is easily caused using sulfuric acid, production scene acid is smelly soaring,
Almost each acidification oil factory is exactly a pollution sources.Acid-bearing wastewater intractability is big, high cost, and the processing cost of waste water causes life
Cost is produced to increase significantly.
In the deep-processing process of tea seed, many critical processes are required for high-temperature steam heat supply；And it is most at present
Oil tea deep processing enterprise uses self-built boiler room heat supply.All it is under normal circumstances come real by coal-fired or biomass fuel etc.
It is existing.Fuel produces substantial amounts of ashes solid residue (ashes) during burning；Usual coal ash is by directly as solid rubbish
The direct waste treatment of rubbish, many troubles are brought to enterprise.With the increasingly raising of environmental requirement, gradually limit the quantity and forbid coal
Burning, it is recommended to use biomass fuel；Ashes discarded object after biomass fuel not only high cost, and burning similarly expends
A large amount of manpower and materials are processed；Cause the rising of production cost and the waste of resource.
For problem above, seek a kind of convenient, fast, effectively comprehensive utilization cake of camellia oleifera seeds, tea oil soap stock and boiler combustion
The method for burning the ashes for producing, can substantially reduce the environmentally friendly cost of oil tea processing enterprise.
The content of the invention
The present invention solves the technical problem of offer a kind of cake of camellia oleifera seeds, the tea of the environmental protection of oil tea deep processing business economic
The processing method of oil soap pin and ashes, particularly provides one kind and prepares Oil-tea-cake with cake of camellia oleifera seeds, ashes and tea oil soap stock
The production technology of dregs of rice organic fertilizer, has the advantages that reliability high, environmental protection, process is simple, while in the application of organic fertilizer
There are good market prospects.
In order to solve the above technical problems, realizing above-mentioned purpose, the present invention is achieved through the following technical solutions：
A kind of cake of camellia oleifera seeds organic fertilizer, is made up of the raw material of following quality proportioning:
Cake of camellia oleifera seeds 40%~80%
Ashes 10%~50%
Tea oil soap stock 5%~20%
The cake of camellia oleifera seeds is one of following or two kinds of mixing of arbitrary proportion：Residue of the tea seed after extracting grease
Saponin slag of the saponin content more than 5% of thing, tea seed after extracting Tea Saponin again after extraction grease.
The ashes are one of following or two kinds of mixing of arbitrary proportion：Ashes, mark after biomass solid fuel burning
Coal ash after quasi- coal or anthracite combustion, the heavy metal arsenic content of the coal ash contains less than 15ppm, mercury content less than 2ppm, lead
Amount is less than 3ppm less than 50ppm, chromium content less than 150ppm, cadmium content.
The tea oil soap stock is tea oil by the sodium soap mixed sediment separated after alkali refining.
The cake of camellia oleifera seeds and ashes raw material are preferably all the powder below 10 mesh.
The cake of camellia oleifera seeds organic fertilizer, is preferably made up of the raw material of following quality proportioning:
Cake of camellia oleifera seeds 50%~75%
Ashes 15%~45%
Tea oil soap stock 5%~15%.
The cake of camellia oleifera seeds organic fertilizer that the present invention is provided can be obtained by the following method：Cake of camellia oleifera seeds and 10 mesh below 10 mesh with
Under ashes press formula rate mixing after, through expanding treatment so that material moisture be less than 30% (preferably less than 20%), then
Mixed by formula rate with tea oil soap stock, through extrusion forming, the cake of camellia oleifera seeds organic fertilizer is obtained.
Expanded temperature 50 C~90 DEG C, preferably 60~80 DEG C, puffing time 30min~90min, preferably 30~
50min, bulking pressure 0.1Mpa~1.0Mpa, preferably 0.4~0.8MPa.
The present invention also provides the preparation method of cake of camellia oleifera seeds organic fertilizer, and methods described is：Cake of camellia oleifera seeds below 10 mesh and
After ashes below 10 mesh press formula rate mixing, through expanding treatment so that material moisture less than 30% (preferably 20% with
Under), then mixed by formula rate with tea oil soap stock, through extrusion forming, the cake of camellia oleifera seeds organic fertilizer is obtained.
Obtained cake of camellia oleifera seeds organic fertilizer is put in storage using damp-prrof packing.
The cake of camellia oleifera seeds organic fertilizer that the present invention is provided is with cake of camellia oleifera seeds as primary raw material, with improving plant products and anti-
Property, reduce the Multifucntional organic fertilizer that pest and disease damage occurs.Not only contain abundant organic matter, wherein albumen in cake of camellia oleifera seeds
Matter and carbohydrate content more than 45%, contain 5%~15% Tea Saponin simultaneously.Tea Saponin has strong to cold-blooded insect pest
Toxic action, while soil can also be improved, prevents heavy metal accumulation.Containing abundant potassium carbonate in ashes, added to Oil-tea-cake
Total nutrient content is greatly improved in the dregs of rice.Tea oil soap stock has good stickiness, is effectively sticky in cake of camellia oleifera seeds and ashes
Together；Residual oil containing part plays certain lubrication to extrusion formation equipment in oil tea soap stock simultaneously, is more beneficial for being manufactured into
Type particle.
The beneficial effects of the present invention are:
(1) oil tea deep processing enterprise need not process tea oil soap stock with sulfuric acid, and Treatment stations are without acid pollution；Resource has been reached to follow
Ring is utilized, and does not result in the pollution of air, and whole production technology does not have the discharge of discarded object, economic and environment-friendly.
(2) oil tea deep processing enterprise need not waste the ashes produced by a large amount of manpower and materials treatment burning boilers, both reach
It is cost-effective and serve economic and environment-friendly effect.
(3) oil tea deep processing enterprise can directly use cake of camellia oleifera seeds, ashes and tea oil soap stock, can gather materials on the spot, section
About cost of transportation, reduces production cost.
(4) gained cake of camellia oleifera seeds granular organic fertilizer, it is convenient not only to apply fertilizer, and also efficiently solves caused by blowing or raining
The problem of fertilizer loss.
Specific embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, this area is common
All other embodiment that technical staff is obtained under the premise of creative work is not made, belongs to the model of present invention protection
Enclose.
Embodiment 1
A kind of cake of camellia oleifera seeds organic fertilizer, is made up per 100kg of the following raw material of quality proportioning:
Cake of camellia oleifera seeds 75kg
Ashes 20kg
Tea oil soap stock 5kg
The cake of camellia oleifera seeds is residue of the tea seed after extracting grease.
The ashes are the ashes after biomass solid fuel combustion.
The tea oil soap stock is tea oil by the sodium soap mixed sediment separated after alkali refining.
The above raw material is the offer of Zhejiang Jiu Sheng oil teas Science and Technology Co., Ltd..
Its preparation method is as follows：
(1) cake of camellia oleifera seeds is crushed, then crosses the screening of 10 mesh sieve extension sets, take the following powder of 10 mesh, 10 mesh above sections are entered
This step is repeated after row separating twice.
(2) ashes are sieved, is taken the following powder of 10 mesh, this step is repeated after 10 mesh above sections progress pulverization process
Suddenly.
(3) powder in step (1), step (2) is pressed into quality proportioning 15:4 uniformly mix, then 60 DEG C of expanded 40min,
Bulking pressure 0.5Mpa；Gained mixed material moisture 20%.
(4) gained mixture in step (3) and tea oil soap stock are pressed into quality proportioning 19:1 is well mixed.
(5) material in step (4) is made granular organic fertilizer by ring die pelleter.
(6) gained cake of camellia oleifera seeds organic fertilizer in step (5) is put in storage using damp-prrof packing.
The implementation case gained cake of camellia oleifera seeds organic fertilizer is diameter 5mm, length is less than 10mm brown granulateds, ordorless.
Detected through third party inspection mechanism：The content of organic matter (in terms of butt) 86.03%；Total nutrient (N+P2O5+K2O) (in terms of butt)
10.15%, wherein total nitrogen content 2.58%, content of tatal phosphorus 3.56%, full potassium content 4.01%；Moisture (free water) content
8.37%；Acid-base value (pH) 8.0；Tea Saponin content (in terms of TS) 12.58%；Heavy metal content index and content of microorganisms
Index meets NY 525-2012《Organic fertilizer》Standard specifies.
Embodiment 2
A kind of cake of camellia oleifera seeds organic fertilizer, is made up per 100kg of the following raw material of quality proportioning:
Cake of camellia oleifera seeds 60kg
Ashes 30kg
Tea oil soap stock 10kg
The cake of camellia oleifera seeds is tea seed saponin slag after extracting grease again after extracting Tea Saponin.
The ashes are the ashes after biomass solid fuel combustion.
The tea oil soap stock is tea oil by the sodium soap mixed sediment separated after alkali refining.
The above raw material is the offer of Zhejiang Jiu Sheng oil teas Science and Technology Co., Ltd..
Its preparation method is as follows：
(1) cake of camellia oleifera seeds is crushed, then crosses the screening of 10 mesh sieve extension sets, take the following powder of 10 mesh, 10 mesh above sections are entered
This step is repeated after row separating twice.
(2) ashes are sieved, is taken the following powder of 10 mesh, this step is repeated after 10 mesh above sections progress pulverization process
Suddenly.
(3) powder in step (1), step (2) is pressed into quality proportioning 2:1 uniformly mixes, then 80 DEG C of expanded 30min,
Bulking pressure 0.5Mpa；Gained mixed material moisture 20%.
(4) gained mixture in step (3) and tea oil soap stock are pressed into quality proportioning 9:1 is well mixed.
(5) material in step (4) is made granular organic fertilizer by ring die pelleter.
(6) gained cake of camellia oleifera seeds organic fertilizer in step (5) is put in storage using damp-prrof packing.
The implementation case gained cake of camellia oleifera seeds organic fertilizer is diameter 5mm, length is less than 10mm brown granulateds, ordorless.
Detected through third party inspection mechanism：The content of organic matter (in terms of butt) 90.05%；Total nutrient (N+P2O5+K2O) (in terms of butt)
11.60%, wherein total nitrogen content 3.58%, content of tatal phosphorus 3.86%, full potassium content 4.16%；Moisture (free water) content
8.53%；Acid-base value (pH) 8.0；Tea Saponin content (in terms of TS) 9.68%；Heavy metal content index and content of microorganisms
Index meets NY 525-2012《Organic fertilizer》Standard specifies.
Embodiment 3
A kind of cake of camellia oleifera seeds organic fertilizer, is made up per 100kg of the following raw material of quality proportioning:
Cake of camellia oleifera seeds 50kg
Ashes 45kg
Tea oil soap stock 5kg
The cake of camellia oleifera seeds is the saponin slag after tea seed extracts Tea Saponin again after extracting grease.
The ashes are the coal ash after standard coal combustion, and the heavy metal arsenic content of coal ash is 10.01ppm, mercury content is
1.50ppm, lead content are 20.10ppm, chromium content is 50.01ppm, cadmium content is 1.01ppm.
The tea oil soap stock is tea oil by the sodium soap mixed sediment separated after alkali refining.
The above raw material is the offer of Zhejiang Jiu Sheng oil teas Science and Technology Co., Ltd..
Its preparation method is as follows：
(1) cake of camellia oleifera seeds is crushed, then crosses the screening of 10 mesh sieve extension sets, take the following powder of 10 mesh, 10 mesh above sections are entered
This step is repeated after row separating twice.
(2) ashes are sieved, is taken the following powder of 10 mesh, this step is repeated after 10 mesh above sections progress pulverization process
Suddenly.
(3) powder in step (1), step (2) is pressed into quality proportioning 10:9 uniformly mix, then 75 DEG C of expanded 45min,
Bulking pressure 0.5Mpa；Gained mixed material moisture 20%.
(4) gained mixture in step (3) and tea oil soap stock are pressed into quality proportioning 19:1 is well mixed.
(5) material in step (4) is made granular organic fertilizer by ring die pelleter.
(6) gained cake of camellia oleifera seeds organic fertilizer in step (5) is put in storage using damp-prrof packing.
The implementation case gained cake of camellia oleifera seeds organic fertilizer is diameter 5mm, length is less than 10mm brown granulateds, ordorless.
Detected through third party inspection mechanism：The content of organic matter (in terms of butt) 85.08%；Total nutrient (N+P2O5+K2O) (in terms of butt)
10.65%, wherein total nitrogen content 2.68%, content of tatal phosphorus 3.46%, full potassium content 4.51%；Moisture (free water) content
8.57%；Acid-base value (pH) 8.1；Tea Saponin content (in terms of TS) 7.88%；Heavy metal content index and content of microorganisms
Index meets NY 525-2012《Organic fertilizer》Standard specifies.
Embodiment 4
A kind of cake of camellia oleifera seeds organic fertilizer, is made up per 100kg of the following raw material of quality proportioning:
Cake of camellia oleifera seeds 68kg
Ashes 18kg
Tea oil soap stock 14kg
The cake of camellia oleifera seeds is that residue of the tea seed after extracting grease is carried again with tea seed after extracting grease
The saponin slag mixture after Tea Saponin is taken, mixing quality ratio is 1:1.
The ashes are the mixture of the ashes after biomass solid fuel combustion and the coal ash after standard coal combustion, mixing
Mass ratio is 1:1；The heavy metal arsenic content of coal ash is 11.0ppm, mercury content is 1.2ppm, lead content is 18.0ppm, chromium contains
Measure as 40.0ppm, cadmium content are 1.0ppm.
The tea oil soap stock is tea oil by the sodium soap mixed sediment separated after alkali refining.
The above raw material is the offer of Zhejiang Jiu Sheng oil teas Science and Technology Co., Ltd..
Its preparation method is as follows：
(1) cake of camellia oleifera seeds is crushed, then crosses the screening of 10 mesh sieve extension sets, take the following powder of 10 mesh, 10 mesh above sections are entered
This step is repeated after row separating twice.
(2) ashes are sieved, is taken the following powder of 10 mesh, this step is repeated after 10 mesh above sections progress pulverization process
Suddenly.
(3) powder in step (1), step (2) is pressed into quality proportioning 39:9 uniformly mix, then 60 DEG C of expanded 30min,
Bulking pressure 0.8Mpa；Gained mixed material moisture 20%.
(4) gained mixture in step (3) and tea oil soap stock are pressed into quality proportioning 43:7 are well mixed.
(5) material in step (4) is made granular organic fertilizer by ring die pelleter.
(6) gained cake of camellia oleifera seeds organic fertilizer in step (5) is put in storage using damp-prrof packing.
The implementation case gained cake of camellia oleifera seeds organic fertilizer is diameter 5mm, length is less than 10mm brown granulateds, ordorless.
Detected through third party inspection mechanism：The content of organic matter (in terms of butt) 85.53%；Total nutrient (N+P2O5+K2O) (in terms of butt)
10.35%, wherein total nitrogen content 3.56%, content of tatal phosphorus 3.46%, full potassium content 3.33%；Moisture (free water) content
9.37%；Acid-base value (pH) 8.2；Tea Saponin amount (in terms of TS) 8.37%；Heavy metal content index refers to content of microorganisms
Mark meets NY 525-2012《Organic fertilizer》Standard specifies.
Above case study on implementation gained cake of camellia oleifera seeds organic fertilizer is by the red group strawberry base in Jiande City, Zhejiang Province, Zhejiang Province's Jiande
City Hang Tou towns strawberry base and Hangzhou day kitchen lotus flower biology Co., Ltd's dendrobium candidum base use, and not only can effectively prevent snail
The insect pests such as ox, slug, cutworm, and strawberry and dendrobium candidum per mu yield increase by more than 15%.Implement in embodiments above
Scheme 2 is preferred scheme.
Claims (8)
1. a kind of cake of camellia oleifera seeds organic fertilizer, it is characterised in that the cake of camellia oleifera seeds organic fertilizer by following quality proportioning raw material group
Into:
Cake of camellia oleifera seeds 40%~80%
Ashes 10%~50%
Tea oil soap stock 5%~20%.
2. cake of camellia oleifera seeds organic fertilizer as claimed in claim 1, it is characterised in that the cake of camellia oleifera seeds is one of following or two kinds
The mixing of arbitrary proportion：Residue, tea seed of the tea seed after extracting grease by extracting Tea Saponin again after extraction grease
Saponin slag of the saponin content afterwards more than 5%.
3. cake of camellia oleifera seeds organic fertilizer as claimed in claim 1, it is characterised in that the ashes for it is one of following or two kinds it is any
The mixing of ratio：The coal ash after ashes, standard coal or anthracite combustion after biomass solid fuel burning, the weight of the coal ash
Metallic arsenic content is small less than 150ppm, cadmium content less than 50ppm, chromium content less than 2ppm, lead content less than 15ppm, mercury content
In 3ppm.
4. cake of camellia oleifera seeds organic fertilizer as claimed in claim 1, it is characterised in that the tea oil soap stock is tea oil by after alkali refining
The sodium soap mixed sediment separated.
5. cake of camellia oleifera seeds organic fertilizer as claimed in claim 1, it is characterised in that the cake of camellia oleifera seeds organic fertilizer is by following quality
The raw material composition of proportioning:
Cake of camellia oleifera seeds 50%~75%
Ashes 15%~45%
Tea oil soap stock 5%~15%.
6. the cake of camellia oleifera seeds organic fertilizer as described in one of Claims 1 to 5, it is characterised in that the cake of camellia oleifera seeds organic fertilizer according to
Following preparation method is made：After the ashes below cake of camellia oleifera seeds and 10 mesh below 10 mesh press formula rate mixing, through expanded place
Reason causes that moisture content of material is less than 30%, is then mixed by formula rate with tea oil soap stock, through extrusion forming, the oil is obtained
Tea-cake dregs organic fertilizer.
7. cake of camellia oleifera seeds organic fertilizer as claimed in claim 6, it is characterised in that expanded temperature 50 C~90 DEG C, it is expanded
Time 30min~90min, bulking pressure 0.1Mpa~1.0Mpa.
8. the preparation method of the cake of camellia oleifera seeds organic fertilizer as described in one of Claims 1 to 5, it is characterised in that methods described is：
After the ashes below cake of camellia oleifera seeds and 10 mesh below 10 mesh press formula rate mixing, through expanding treatment so that moisture content of material
Less than 30%, then mixed by formula rate with tea oil soap stock, through extrusion forming, the cake of camellia oleifera seeds organic fertilizer is obtained.
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| CN201611257381.7A CN106748383A (en) | 2016-12-30 | 2016-12-30 | A kind of cake of camellia oleifera seeds organic fertilizer and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109293413A (en) * | 2018-11-13 | 2019-02-01 | 贵州省中国科学院天然产物化学重点实验室 | A kind of cake of camellia oleifera seeds residue organic fertilizer and preparation method thereof extracting Tea Saponin |
| CN110204395A (en) * | 2019-06-26 | 2019-09-06 | 黄思维 | A kind of tea oil tree fertilizer |
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| CN1789215A (en) * | 2004-12-13 | 2006-06-21 | 刘义冬 | Ecological substrate fertilizer and preparation method thereof |
| CN101823905A (en) * | 2009-03-05 | 2010-09-08 | 徐新宋 | Method for preventing and controlling rhizome acarid mites of Allium chinense |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109293413A (en) * | 2018-11-13 | 2019-02-01 | 贵州省中国科学院天然产物化学重点实验室 | A kind of cake of camellia oleifera seeds residue organic fertilizer and preparation method thereof extracting Tea Saponin |
| CN110204395A (en) * | 2019-06-26 | 2019-09-06 | 黄思维 | A kind of tea oil tree fertilizer |
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