CN106747465B - 一种HfC颗粒弥散增韧补强TiN基陶瓷刀具材料及制备方法 - Google Patents
一种HfC颗粒弥散增韧补强TiN基陶瓷刀具材料及制备方法 Download PDFInfo
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- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 239000000463 material Substances 0.000 title claims abstract description 37
- 239000000919 ceramic Substances 0.000 title claims abstract description 29
- 239000002245 particle Substances 0.000 title claims abstract description 27
- 239000006185 dispersion Substances 0.000 title claims abstract description 25
- 230000003014 reinforcing effect Effects 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 238000005520 cutting process Methods 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 238000005245 sintering Methods 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 12
- 239000011812 mixed powder Substances 0.000 claims description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- 229910002804 graphite Inorganic materials 0.000 claims description 10
- 239000010439 graphite Substances 0.000 claims description 10
- 239000000956 alloy Substances 0.000 claims description 5
- 229910045601 alloy Inorganic materials 0.000 claims description 5
- 238000000498 ball milling Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000007873 sieving Methods 0.000 claims description 5
- 239000011159 matrix material Substances 0.000 claims description 3
- 229910010293 ceramic material Inorganic materials 0.000 abstract description 8
- 238000013329 compounding Methods 0.000 abstract description 6
- 238000005452 bending Methods 0.000 abstract description 5
- 230000002787 reinforcement Effects 0.000 abstract description 5
- 238000007731 hot pressing Methods 0.000 abstract description 4
- 230000009286 beneficial effect Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000013078 crystal Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000011366 tin-based material Substances 0.000 description 1
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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- C04B35/58—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides
- C04B35/58007—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on refractory metal nitrides
- C04B35/58014—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on refractory metal nitrides based on titanium nitrides, e.g. TiAlON
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Abstract
本发明涉及颗粒弥散增韧陶瓷刀具材料领域,具体为一种HfC颗粒弥散增韧补强TiN基陶瓷刀具材料及制备方法,解决现有TiN基陶瓷材料复合时存在力学性能降低、工艺复杂且不利于产业化的问题。一种HfC颗粒弥散增韧补强TiN基陶瓷刀具材料,是由如下质量百分比的原料组成:TiN 67%‑83%,HfC 10%‑25%,Ni 2%‑6%,Mo 2%‑8%。本发明在保持材料硬度的基础上,提高了材料的抗弯强度和力学性能,制备出HfC颗粒弥散增韧补强TiN基陶瓷刀具材料,而且利用真空热压烧结法,工艺简化,成本低,利于产业化生产。
Description
技术领域
本发明涉及颗粒弥散增韧陶瓷刀具材料领域,具体为一种HfC颗粒弥散增韧补强TiN基陶瓷刀具材料及制备方法。
背景技术
TiN是一种具有高强度、高硬度、耐高温、耐酸碱、耐磨损的特点,同时具有良好的导电和导热性能,其在高温结构材料、耐磨、耐腐蚀以及在材料领域中有着广泛的应用前景。但是陶瓷刀具其固有的脆性从某种程度上限制了其应用,如何提高其韧性和强度是目前陶瓷材料领域研究的一个热点和难点。通过向基体中加入添加相采用多元复合的方法可以提高材料的性能,基于此,非常需要一种能够保持材料硬度(18~21GPa)的前提下,提高材料抗弯强度和断裂韧度的特性的TiN基陶瓷材料复合技术。
另外传统制备工艺存在制备设备与工艺复杂,成本高,不利于产业化等不足之处。因此这种新的TiN基陶瓷材料复合技术还应该同时具备制备工艺简单,成本低,有利于产业化的特点。
发明内容
本发明为了解决现有TiN基陶瓷材料复合时存在力学性能降低、工艺复杂且不利于产业化的问题,提供了一种HfC颗粒弥散增韧补强TiN基陶瓷刀具材料及制备方法。
本发明是采用如下技术方案实现的:一种HfC颗粒弥散增韧补强TiN基陶瓷刀具材料,是由如下质量百分比的原料组成:TiN 67%-83%,HfC 10%-25%,Ni 2%-6%,Mo 2%-8%。
采用上述组分制得的HfC颗粒弥散增韧补强TiN基陶瓷刀具材料的纯度高,HfC晶粒分布均匀,其平均尺寸为1μm,TiN晶粒的尺寸介于5μm-10μm,TiN基材料的硬度介于18.32~20.15GPa,克服了现有的TiN基陶瓷材料复合时存在力学性能降低的问题。
一种HfC颗粒弥散增韧补强TiN基陶瓷刀具材料的制备方法,采用如下步骤:a、将各原料的混合粉末装入卧式罐磨球磨机中,用硬质合金球球磨后过筛;b、将过筛后的原料装入上下封闭的石墨容器,再放入高温烧结炉内;c、在升温速率10℃/min、压力25MPa、烧结温度1600℃-1700℃的条件下,保温时间20min-40min,得到的HfC颗粒弥散增韧补强TiN基陶瓷刀具材料。
本发明采用真空热压烧结制备工艺制备的TiN基陶瓷材料的性能优异,抗弯强度介于930.48~1210.22MPa和断裂韧度介于6.85~8.12 MPa·m½,提高了氮化钛陶瓷刀具材料的切削性能。
本发明采用真空热压烧结法,在合适的升温速率、压力、生长温度和保温时间下,合成HfC颗粒弥散增韧补强TiN基陶瓷刀具材料,克服了现有TiN基陶瓷材料复合时存在工艺复杂且不利于产业化的问题。
本发明在保持材料复合后断裂韧度和抗弯强度提高的基础上,保证了材料的高硬度特性,而且利用真空热压烧结法,工艺简化,成本低,利于产业化生产,适合于切削加工高硬度的材料。
附图说明
图1为本发明的扫描电镜图。
由图可见,约为1μm的HfC颗粒均匀的分布在TiN基体中,其有利于提高材料的抗弯强度和断裂韧度。
具体实施方式
实施例1
一种HfC颗粒弥散增韧补强TiN基陶瓷刀具材料,是由如下质量百分比的原料组成:TiN 67%,HfC 25%,Ni 6%,Mo 2%。
一种HfC颗粒弥散增韧补强TiN基陶瓷刀具材料的制备方法,采用如下步骤:a、将各原料的混合粉末装入卧式罐磨球磨机中,用硬质合金球球磨后过筛;b、将过筛后的原料装入上下封闭的石墨容器,再放入高温烧结炉内;c、 在升温速率10℃/min、压力25MPa、烧结温度1600℃的条件下,保温时间20min,得到的HfC颗粒弥散增韧补强TiN基陶瓷刀具材料。
实施例2
一种HfC颗粒弥散增韧补强TiN基陶瓷刀具材料,是由如下质量百分比的原料组成:TiN 75%,HfC 15%,Ni 2%,Mo 8%。
一种HfC颗粒弥散增韧补强TiN基陶瓷刀具材料的制备方法,采用如下步骤:a、将各原料的混合粉末装入卧式罐磨球磨机中,用硬质合金球球磨后过筛;b、将过筛后的原料装入上下封闭的石墨容器,再放入高温烧结炉内;c、在升温速率10℃/min、压力25MPa、烧结温度1650℃的条件下,保温时间30min,得到的HfC颗粒弥散增韧补强TiN基陶瓷刀具材料。
实施例3
一种HfC颗粒弥散增韧补强TiN基陶瓷刀具材料,是由如下质量百分比的原料组成:TiN 83%,HfC 10%,Ni 4%,Mo 3%。
一种HfC颗粒弥散增韧补强TiN基陶瓷刀具材料的制备方法,采用如下步骤:a、将各原料的混合粉末装入卧式罐磨球磨机中,用硬质合金球球磨后过筛;b、将过筛后的原料装入上下封闭的石墨容器,再放入高温烧结炉内;c、在升温速率10℃/min、压力25MPa、烧结温度1700℃的条件下,保温时间40min,得到的HfC颗粒弥散增韧补强TiN基陶瓷刀具材料。
Claims (1)
1.一种HfC颗粒弥散增韧补强TiN基陶瓷刀具材料的制备方法,所述HfC颗粒弥散增韧补强TiN基陶瓷刀具材料是由如下质量百分比的原料组成:TiN 67%-83%,HfC 10%-25%,Ni2%-6%,Mo 2%-8%,HfC晶粒分布均匀,其平均尺寸为1μm,TiN晶粒的尺寸介于5μm-10μm,1μm的HfC颗粒均匀的分布在TiN基体中;
其特征在于:所述方法采用如下步骤:a、将各原料的混合粉末装入卧式罐磨球磨机中,用硬质合金球球磨后过筛;b、将过筛后的原料装入上下封闭的石墨容器,再放入高温烧结炉内;c、 在升温速率10℃/min、压力25MPa、烧结温度1600℃-1700℃的条件下,保温时间20min-40min,得到的HfC颗粒弥散增韧补强TiN基陶瓷刀具材料。
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CN1592795A (zh) * | 2003-01-13 | 2005-03-09 | 杰出金属实业公司 | 硬质合金组合物及其制备方法 |
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CN104446396A (zh) * | 2014-12-11 | 2015-03-25 | 中国石油大学(华东) | 一种微纳米复合氧化铝-氮化钛-氧化锆-镍-钼陶瓷材料的制备方法 |
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CN1592795A (zh) * | 2003-01-13 | 2005-03-09 | 杰出金属实业公司 | 硬质合金组合物及其制备方法 |
CN1778757A (zh) * | 2004-10-19 | 2006-05-31 | 通用电气公司 | 多相陶瓷纳米复合材料和其制造方法 |
CN102094144A (zh) * | 2010-12-16 | 2011-06-15 | 山东大学 | 超细WC颗粒增韧补强TiB2基复合陶瓷刀具材料及其制备方法 |
CN104446396A (zh) * | 2014-12-11 | 2015-03-25 | 中国石油大学(华东) | 一种微纳米复合氧化铝-氮化钛-氧化锆-镍-钼陶瓷材料的制备方法 |
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