CN106734183A - A kind of mining area nickel contamination soil remediation method - Google Patents
A kind of mining area nickel contamination soil remediation method Download PDFInfo
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Abstract
A kind of mining area nickel contamination soil remediation method, collecting soil sample is carried out using grid multipoint method first, then the nickel content of the pedotheque to being gathered is measured, and according to soil nickel content measurement result by soil divided rank, then turn over the soil of 10 18cm of nickel contamination upper soll layer thickness, the soil-repairing agent and slow-releasing granules to application amount are applied further according to the soil degree for being divided, finally nickel contamination soil is irrigated, water irrigating depth is more than 20cm, relative moisture of the soil is up to more than 85%, and keep the relative humidity 10~20 days, the soil-repairing agent is made up of absorption carrier and the effective viable bacteria being adsorbed on the carrier.This method remediation efficiency is high, low cost, non-secondary pollution, suit measures to local conditions, more precisely can quickly repair mining area nickel contamination soil, nickel is effectively prevented to be migrated in soil, prevent soil pollution scope from expanding, and it is long-term for soil provides nutrient in soil remediation process, improve the use value of soil.
Description
Technical field
The present invention relates to mining soil recovery technique field, and in particular to a kind of mining area nickel contamination soil remediation method.
Background technology
Diggings soil nickel contamination is serious, and agricultural use is typically used as after China's mining area nickel contamination soil remediation, if repaired
Not exclusively, nickel is entered in plant by root system, causes plant undergrowth, and plant is caused harm, and even results in Plant death.
Nickel can be put aside in plant, when nickel savings beyond normal contents plant enter food chain when, will influence animal or even
The health of the mankind.
At present, China's nickel contamination soil majority is not governed, and huge hidden danger is caused to environment.Soil nickel contamination has
Disguised, hysteresis quality and chronicity, cause harm to ecological environment, and nickel is animal migration pollutant, after nickel enters in soil, quilt
Contaminated soil scope gradually expands.
The recovery technique for nickel contamination soil mainly includes microorganism removal method, chemical method in the prior art（Medicament is washed
Wash, thermally decompose）, Physical（Electric current makes charged particle migration etc.）And planting plants, substantial amounts of method is also in laboratory
Conceptual phase, field conduct is more difficult, meanwhile, existing nickel contamination land treatment technique technique falls behind relatively, result in nickel contamination
Land remediation efficiency is low, high cost, secondary pollution and the big problem of environmental risk.
The soil in mining area is uneven, and soil nickel content differs greatly, therefore when being repaired to soil, it is necessary to carry out
Collecting soil sample and analysis are tested.During collection pedotheque, because soil nickel content difference is too big, traditional is " S " or " right
Linea angulata " method is difficult to react the actual conditions of soil nickel content, when being repaired to nickel contamination soil at present, does not take into full account soil
The Spatial Difference of earth nickel content, Spatial Difference is not accounted in collecting soil sample and on repairing, and there is certain deficiency.
The content of the invention
In order to solve the above-mentioned technical problem, it is an object of the invention to provide a kind of mining area nickel contamination soil remediation method, repair
Multiple efficiency high, low cost, non-secondary pollution are suited measures to local conditions, and more precisely can quickly repair mining area nickel contamination soil, effectively resistance
Only nickel is migrated in soil, prevents soil pollution scope from expanding, and long-term for soil provides nutrition in soil remediation process
Element, improves the use value of soil.
The technical solution adopted in the present invention is：A kind of mining area nickel contamination soil remediation method, first using grid multiple spot
Method carries out collecting soil sample, and then the nickel content of the pedotheque to being gathered is measured, and is surveyed according to soil nickel content
Result is determined by soil divided rank, the soil of the nickel contamination upper soll layer thickness 10-18cm that then turns over, further according to the soil for being divided
Grade applies the soil-repairing agent and slow-releasing granules to application amount, and finally nickel contamination soil is irrigated, and water irrigating depth is
More than 20cm, relative moisture of the soil keeps the relative humidity 10~20 days up to more than 85%, and the soil-repairing agent is
It is made up of absorption carrier and the effective viable bacteria being adsorbed on the carrier, and the effective viable bacteria contained in every gram of soil-repairing agent is total
Number is（5~150）×108CFU；Effective viable bacteria is made up of the mixing of Halomonas, colloid bacillus and rainbow conk keyhole bacterium,
And the living bacteria count ratio of Halomonas, colloid bacillus and rainbow conk keyhole bacterium is 1.5~2：1~2：2~3.5, it is described
Absorption carrier is to compare 1 according to weight by coconut palm chaff, diatomite and bentonite：2：1 is mixed；
The slow-releasing granules are by 120~140 parts of Flaxseed cakes, 50~60 parts of peony seeds shells, 100~120 according to weight ratio
Part stalk, 30~40 parts of bamboo charcoal powders and 150~200 parts of modified rice bran protein solution are made, and the modified rice bran protein solution is pressed
It is to sequentially add 0.5~1 part of glutamine after being mixed with 100-120 parts of distilled water by 10-15 parts of rice bran protein to turn according to weight ratio
Ammonia enzyme and 0.1~0.2 part of potassium diformate heat 2h at a temperature of 45~50 DEG C and are obtained.
Size of mesh opening in the grid multipoint method for being used for（10~45）m×（10~45）m.
The specific preparation method of the slow-releasing granules is：Flaxseed cake, peony seeds shell, straw are weighed according to above-mentioned weight ratio
Stalk, bamboo charcoal powder, rice bran protein, distilled water, glutamine transaminage and potassium diformate, peony seeds shell and the stalk mixing that will be weighed
Crushing is the powder of 200~400 mesh in being put into pulverizer afterwards, and the powder that will be obtained dries after mixing with bamboo charcoal powder, Flaxseed cake
It is dry, granulation in comminutor is subsequently placed in, hybrid particles are obtained, then take addition glutamine turn after rice bran protein and distilled water mixing
Ammonia enzyme and potassium diformate are simultaneously heated to 45~50 DEG C, keep the temperature 2 hours, obtain modified rice bran protein solution, then will be modified
Rice bran protein solution spraying is obtained slow-releasing granules on hybrid particles after drying.
It is described to refer to by soil divided rank according to soil nickel content measurement result：According to soil nickel content measurement result,
Soil is divided into five grades, the soil nickel content of one-level soil is less than 9.5mg/kg, and the soil nickel content of second grade soil is not
Less than 9.5mg/kg and less than 20 mg/kg, the soil nickel content of three-level soil is not less than 20 mg/kg and less than 38 mg/kg,
The soil nickel content of level Four soil is not less than 38mg/kg and less than 49mg/kg, and the soil nickel content of Pyatyi soil is not less than
56mg/kg；
Soil-repairing agent and sustained release grain amount applied in the soil of five grades are：Soil in grid is one-level soil
During earth, the amount of applying of soil-repairing agent is every mu of 3~4kg, and the amount of applying of slow-releasing granules is every mu of 250~450kg；In grid
When soil is second grade soil, the amount of applying of soil-repairing agent is every mu of 4~6kg, the amount of applying of slow-releasing granules is every mu 450~
650kg；When soil in grid is three-level soil, the amount of applying of soil-repairing agent is every mu of 6~8kg, and slow-releasing granules are applied
Amount is every mu of 650~850kg；When soil in grid is level Four soil, the amount of applying of soil-repairing agent is every mu of 8~10kg,
The amount of applying of slow-releasing granules is every mu of 850~1050kg；When soil in grid is Pyatyi soil, the amount of applying of soil-repairing agent
It is every mu of 10~12kg, the amount of applying of slow-releasing granules is every mu of 1050~1250kg.
Compared with prior art, the invention has the advantages that：
First, the present invention can in a short time repair nickel contamination soil, increase soil fertility, and remediation efficiency is high, low cost, without secondary
Pollution, can recover the use function of Subsidence Land in Coal Mining Area nickel contamination soil；
2nd, the collection of pedotheque is carried out using grid multi-point sampling method, classification applies soil-repairing agent and slow-releasing granules, overcomes
Mining soil nickel content spatial diversity big shortcoming, has reached the effect of accurate reparation, and reduces cost, can Quick uniform
Increase soil fertility；
3rd, soil is repaired by applying soil-repairing agent and slow-releasing granules so that the soil after reparation can be used as agricultural
Arable land, and effective nutrient can be provided for microorganism and plant；
4th, the soil-repairing agent used in the present invention can be effectively improved existing forms of the nickel in soil, be repaiied using the soil
After multiple agent is repaired to nickel contamination soil, the soil after reparation can serve as agricultural planting, can reduce nickel and be entered by root system
Enter the amount in plant, while greatly reducing accumulation of the nickel in plant, the absorption carrier used in the soil-repairing agent leads to
Permeability, water holding capacity and nutrition supply ability are all good, can effectively keep the activity of effective viable bacteria, and the soil-repairing agent to reduce
The activity of nickel in soil, the nickel in fixing soil effectively prevents nickel migration, nickel contamination soil scope is not further expanded；
5th, the mobility that the slow-releasing granules that use can be that soil provides nutrient and reduce nickel particles in soil in the present invention,
Linseed oil grouts in slow-releasing granules can provide multiple element for soil, can be effectively improved the physical behavior of soil, overcome ore deposit
The shortcoming of the hard physical arrangement difference of area's nickel contamination soil, the slow-releasing granules can be decomposed slowly, extend action period, and rice bran protein is in paddy
It is modified under glutamine transaminase and potassium diformate collective effect, is conducive to the expansion of protein molecule, and catalytic proteins polypeptide
Generation intramolecular and intermolecular generation covalent cross-linking, are embodied in viscosity increase, with shearing force repellence higher and glue
Viscosity so that after the modified rice bran protein solution being made is coated to hybrid particles, slow decomposition is formed in hybrid particles outer layer
Albumin layer, it is long-term for soil provides nutrient；
6th, by applying soil conditioner and slow-releasing granules, combine organic and biofacies, quick-acting and slow is combined, advantage
Complementation, reaches the effect for thoroughly repairing Subsidence Land in Coal Mining Area nickel contamination soil.
Specifically apply mode
With reference to specific embodiment, the present invention is further elaborated, and protection scope of the present invention is not limited to following implementation
Example.Implement process of the invention, condition, reagent etc., in addition to the following special content for referring to, be the universal knowledege of this area
And common knowledge, the present invention is not particularly limited content.
Embodiment 1
A kind of mining area nickel contamination soil remediation method, comprises the following steps：
（1）The collection of pedotheque is carried out using grid multi-point sampling method, sampling depth is 10cm；
（2）The nickel content of the pedotheque to being gathered is measured, and divides soil according to soil nickel content measurement result
It is five grades, the soil nickel content of one-level soil is less than 9.5mg/kg, and the soil nickel content of second grade soil is not less than 9.5mg/
Kg and less than 20 mg/kg, the soil nickel content of three-level soil is not less than 20 mg/kg and less than 38 mg/kg, level Four soil
Soil nickel content is not less than 38mg/kg and less than 49mg/kg, and the soil nickel content of Pyatyi soil is not less than 56mg/kg；
（3）Compare 1 according to weight：2：1 take coconut palm chaff, diatomite and bentonite after be mixed and made into absorption carrier, then take Halomonas,
Colloid bacillus and rainbow conk keyhole bacterium simultaneously mix to be made soil-repairing agent with absorption carrier, wherein, Halomonas, colloid bud
The living bacteria count ratio of born of the same parents bacillus and rainbow conk keyhole bacterium is 1.5：1：2, in described soil-repairing agent, every gram of soil-repairing agent
In effective total viable count for containing be 5 × 108CFU；
（4）Taken according to weight ratio added after 10 parts of rice bran proteins mix with 100 parts of distilled water 0.5 part of glutamine transaminage with
And 0.1 part of potassium diformate heats 2h at a temperature of 45 DEG C, modified rice bran protein solution is obtained, 120 parts are weighed according still further to weight ratio
Flaxseed cake, 50 parts of peony seeds shells, 100 parts of stalks, 30 parts of bamboo charcoal powders and 150 parts of modified rice bran protein solution, by what is weighed
Crushing is the powder of 200 mesh, the powder that will be obtained and bamboo charcoal powder, linseed during pulverizer is put into after peony seeds shell and stalk mixing
Dried after grouts mixing, be subsequently placed in granulation in comminutor, obtain hybrid particles, finally arrive modified rice bran protein solution spraying
On hybrid particles, slow-releasing granules are obtained after drying；
（5）Turn over the soil of nickel contamination upper soll layer thickness 10cm, and the soil to application amount is applied according to the soil degree for being divided
Earth renovation agent and slow-releasing granules, when the soil in grid is one-level soil, the amount of applying of soil-repairing agent is every mu of 3kg, sustained release
The amount of applying of particle is every mu of 250kg；When soil in grid is second grade soil, the amount of applying of soil-repairing agent is every mu of 4kg,
The amount of applying of slow-releasing granules is every mu of 450kg；When soil in grid is three-level soil, the amount of applying of soil-repairing agent is every mu
6kg, the amount of applying of slow-releasing granules is every mu of 650kg；When soil in grid is level Four soil, the amount of applying of soil-repairing agent is
Every mu of 8kg, the amount of applying of slow-releasing granules is every mu of 850kg；When soil in grid is Pyatyi soil, soil-repairing agent is applied
Amount is every mu of 10kg, and the amount of applying of slow-releasing granules is every mu of 1050kg；
（6）Nickel contamination soil is irrigated, water irrigating depth is more than 20cm, relative moisture of the soil keeps up to more than 85%
The relative humidity 10 days.
In the present embodiment, step（1）In size of mesh opening be 10m × 10m.
Embodiment 2
A kind of mining area nickel contamination soil remediation method, comprises the following steps：
（1）The collection of pedotheque is carried out using grid multi-point sampling method, sampling depth is 14cm；
（2）The nickel content of the pedotheque to being gathered is measured, and divides soil according to soil nickel content measurement result
It is five grades, the soil nickel content of one-level soil is less than 9.5mg/kg, and the soil nickel content of second grade soil is not less than 9.5mg/
Kg and less than 20 mg/kg, the soil nickel content of three-level soil is not less than 20 mg/kg and less than 38 mg/kg, level Four soil
Soil nickel content is not less than 38mg/kg and less than 49mg/kg, and the soil nickel content of Pyatyi soil is not less than 56mg/kg；
（3）Compare 1 according to weight：2：1 take coconut palm chaff, diatomite and bentonite after be mixed and made into absorption carrier, then take Halomonas,
Colloid bacillus and rainbow conk keyhole bacterium simultaneously mix to be made soil-repairing agent with absorption carrier, wherein, Halomonas, colloid bud
The living bacteria count ratio of born of the same parents bacillus and rainbow conk keyhole bacterium is 1.5：2：3, in described soil-repairing agent, every gram of soil-repairing agent
In effective total viable count for containing be 80 × 108CFU；
（4）Taken according to weight ratio added after 13 parts of rice bran proteins mix with 110 parts of distilled water 0.7 part of glutamine transaminage with
And 0.15 part of potassium diformate heats 2h at a temperature of 47 DEG C, modified rice bran protein solution is obtained, 130 parts are weighed according still further to weight ratio
Flaxseed cake, 55 parts of peony seeds shells, 110 parts of stalks, 35 parts of bamboo charcoal powders and 175 parts of modified rice bran protein solution, by what is weighed
Crushing is the powder of 300 mesh, the powder that will be obtained and bamboo charcoal powder, linseed during pulverizer is put into after peony seeds shell and stalk mixing
Dried after grouts mixing, be subsequently placed in granulation in comminutor, obtain hybrid particles, finally arrive modified rice bran protein solution spraying
On hybrid particles, slow-releasing granules are obtained after drying；
（5）Turn over the soil of nickel contamination upper soll layer thickness 14cm, and the soil to application amount is applied according to the soil degree for being divided
Earth renovation agent and slow-releasing granules, when the soil in grid is one-level soil, the amount of applying of soil-repairing agent is every mu of 3.5kg, is delayed
The amount of applying for releasing particle is every mu of 350kg；When soil in grid is second grade soil, the amount of applying of soil-repairing agent is every mu
5kg, the amount of applying of slow-releasing granules is every mu of 550kg；When soil in grid is three-level soil, the amount of applying of soil-repairing agent is
Every mu of 7kg, the amount of applying of slow-releasing granules is every mu of 750kg；When soil in grid is level Four soil, soil-repairing agent is applied
Amount is every mu of 9kg, and the amount of applying of slow-releasing granules is every mu of 950kg；When soil in grid is Pyatyi soil, soil-repairing agent
The amount of applying is every mu of 11kg, and the amount of applying of slow-releasing granules is every mu of 1150kg；
（6）Nickel contamination soil is irrigated, water irrigating depth is more than 20cm, relative moisture of the soil keeps up to more than 85%
The relative humidity 15 days.
In the present embodiment, step（1）In size of mesh opening be 25m × 25m.
Embodiment 3
A kind of mining area nickel contamination soil remediation method, comprises the following steps：
（1）The collection of pedotheque is carried out using grid multi-point sampling method, sampling depth is 18cm；
（2）The nickel content of the pedotheque to being gathered is measured, and divides soil according to soil nickel content measurement result
It is five grades, the soil nickel content of one-level soil is less than 9.5mg/kg, and the soil nickel content of second grade soil is not less than 9.5mg/
Kg and less than 20 mg/kg, the soil nickel content of three-level soil is not less than 20 mg/kg and less than 38 mg/kg, level Four soil
Soil nickel content is not less than 38mg/kg and less than 49mg/kg, and the soil nickel content of Pyatyi soil is not less than 56mg/kg；
（3）Compare 1 according to weight：2：1 take coconut palm chaff, diatomite and bentonite after be mixed and made into absorption carrier, then take Halomonas,
Colloid bacillus and rainbow conk keyhole bacterium simultaneously mix to be made soil-repairing agent with absorption carrier, wherein, Halomonas, colloid bud
The living bacteria count ratio of born of the same parents bacillus and rainbow conk keyhole bacterium is 2： 2：3.5, in described soil-repairing agent, every gram of soil remediation
The effective total viable count contained in agent is 150 × 108CFU；
（4）Taken according to weight ratio added after 15 parts of rice bran proteins mix with 120 parts of distilled water 1 part of glutamine transaminage and
0.2 part of potassium diformate heats 2h at a temperature of 50 DEG C, obtains modified rice bran protein solution, and 140 parts of Asias are weighed according still further to weight ratio
The numb seedcake dregs of rice, 60 parts of peony seeds shells, 120 parts of stalks, 40 parts of bamboo charcoal powders and 200 parts of modified rice bran protein solution, it is male by what is weighed
Crushing is the powder of 400 mesh, the powder that will be obtained and bamboo charcoal powder, linseed cake during pulverizer is put into after red seed shell and stalk mixing
Dried after dregs of rice mixing, be subsequently placed in comminutor and granulate, obtain hybrid particles, finally by modified rice bran protein solution spraying to mixing
Close on particle, slow-releasing granules are obtained after drying；
（5）Turn over the soil of nickel contamination upper soll layer thickness 18cm, and the soil to application amount is applied according to the soil degree for being divided
Earth renovation agent and slow-releasing granules, when the soil in grid is one-level soil, the amount of applying of soil-repairing agent is every mu of 4kg, sustained release
The amount of applying of particle is every mu of 450kg；When soil in grid is second grade soil, the amount of applying of soil-repairing agent is every mu of 6kg,
The amount of applying of slow-releasing granules is every mu of 650kg；When soil in grid is three-level soil, the amount of applying of soil-repairing agent is every mu
8kg, the amount of applying of slow-releasing granules is every mu of 850kg；When soil in grid is level Four soil, the amount of applying of soil-repairing agent is
Every mu of 10kg, the amount of applying of slow-releasing granules is every mu of 1050kg；When soil in grid is Pyatyi soil, soil-repairing agent is applied
The amount of spreading is every mu of 12kg, and the amount of applying of slow-releasing granules is every mu of 1250kg；
（6）Nickel contamination soil is irrigated, water irrigating depth is more than 20cm, relative moisture of the soil keeps up to more than 85%
The relative humidity 20 days.
In the present embodiment, step（1）In size of mesh opening be 45m × 45m.
Claims (5)
1. a kind of mining area nickel contamination soil remediation method, carries out collecting soil sample using grid multipoint method first, then to institute
The nickel content of the pedotheque of collection is measured, and then turns over soil divided rank according to soil nickel content measurement result
The soil of 10~18cm of nickel contamination upper soll layer thickness is ploughed, the soil remediation to application amount is applied further according to the soil degree for being divided
Agent and slow-releasing granules, finally irrigate nickel contamination soil, water irrigating depth be more than 20cm, relative moisture of the soil up to 85% with
On, and keep the relative humidity 10~20 days, it is characterised in that：The soil-repairing agent is by absorption carrier and is adsorbed in
Effective viable bacteria on the carrier constitutes, and the effective total viable count contained in every gram of soil-repairing agent is（5~150）×
108CFU；Effective viable bacteria is made up of the mixing of Halomonas, colloid bacillus and rainbow conk keyhole bacterium, and Halomonas, glue
The living bacteria count ratio of matter bacillus and rainbow conk keyhole bacterium is 1.5~2：1~2：2~3.5, the absorption carrier is by coconut palm
Chaff, diatomite and bentonite compare 1 according to weight：2：1 is mixed；
The slow-releasing granules are by 120~140 parts of Flaxseed cakes, 50~60 parts of peony seeds shells, 100~120 according to weight ratio
Part stalk, 30~40 parts of bamboo charcoal powders and 150~200 parts of modified rice bran protein solution are made, and the modified rice bran protein solution is pressed
It is to sequentially add 0.5~1 part of glutamine after being mixed with 100~120 parts of distilled water by 10~15 parts of rice bran proteins according to weight ratio
Transaminase and 0.1~0.2 part of potassium diformate heat 2h at a temperature of 45~50 DEG C and are obtained.
2. a kind of mining area nickel contamination soil remediation method as claimed in claim 1, it is characterised in that：The grid multiple spot for being used
Size of mesh opening in method is（10~45）m×（10~45）m.
3. a kind of mining area nickel contamination soil remediation method as claimed in claim 1, it is characterised in that：The tool of the slow-releasing granules
Preparation is：Flaxseed cake, peony seeds shell, stalk, bamboo charcoal powder, rice bran are weighed according to weight ratio described in claim 1
Albumen, distilled water, glutamine transaminage and potassium diformate, are put into pulverizer after peony seeds shell and the stalk mixing that will be weighed
It is the powder of 200~400 mesh to crush, and the powder that will be obtained is dried after mixing with bamboo charcoal powder, Flaxseed cake, is subsequently placed in granulation
Granulated in machine, obtain hybrid particles, then take addition glutamine transaminage and potassium diformate after rice bran protein and distilled water mixing
And it is heated to 45~50 DEG C, and keep the temperature 2 hours, obtain modified rice bran protein solution, then by the spray of modified rice bran protein solution
It is coated onto on hybrid particles, slow-releasing granules is obtained after drying.
4. a kind of mining area nickel contamination soil remediation method as claimed in claim 1, it is characterised in that described to contain according to soil nickel
Measure measurement result refers to by soil divided rank：According to soil nickel content measurement result, soil is divided into five grades, one-level
The soil nickel content of soil is less than 9.5mg/kg, and the soil nickel content of second grade soil is not less than 9.5mg/kg and less than 20 mg/
Kg, the soil nickel content of three-level soil is not less than 20 mg/kg and less than 38 mg/kg, and the soil nickel content of level Four soil is not low
In 38mg/kg and less than 49mg/kg, the soil nickel content of Pyatyi soil is not less than 56mg/kg.
5. a kind of mining area nickel contamination soil remediation method as claimed in claim 4, it is characterised in that the soil of five grades
Soil-repairing agent and sustained release grain amount applied in earth are：When soil in grid is one-level soil, soil-repairing agent is applied
The amount of spreading is every mu of 3~4kg, and the amount of applying of slow-releasing granules is every mu of 250~450kg；When soil in grid is second grade soil, soil
The amount of applying of earth renovation agent is every mu of 4~6kg, and the amount of applying of slow-releasing granules is every mu of 450~650kg；Soil in grid is
During three-level soil, the amount of applying of soil-repairing agent is every mu of 6~8kg, and the amount of applying of slow-releasing granules is every mu of 650~850kg；Net
When soil in lattice is level Four soil, the amount of applying of soil-repairing agent is every mu of 8~10kg, and the amount of applying of slow-releasing granules is every mu
850~1050kg；When soil in grid is Pyatyi soil, the amount of applying of soil-repairing agent is every mu of 10~12kg, sustained release
The amount of applying of grain is every mu of 1050~1250kg.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114130811A (en) * | 2021-11-13 | 2022-03-04 | 北京工业大学 | Method for restoring cadmium-polychlorinated biphenyl composite polluted soil by crop rotation of astragalus sinicus and sedum plumbizincicola |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104531552A (en) * | 2014-11-24 | 2015-04-22 | 苏州嘉禧萝生物科技有限公司 | Heavy metal contaminated soil microbe repairing agent and application thereof |
| CN105618478A (en) * | 2016-03-24 | 2016-06-01 | 南京盖亚生物工程有限公司 | Biological soil remediation agent and method for remediating soil |
| CN105967819A (en) * | 2016-02-25 | 2016-09-28 | 马鞍山市全润农业科技有限公司 | Good-stability long-action-period modified-Chinese-chestnut-protein-coated slow-release fertilizer |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104531552A (en) * | 2014-11-24 | 2015-04-22 | 苏州嘉禧萝生物科技有限公司 | Heavy metal contaminated soil microbe repairing agent and application thereof |
| CN105967819A (en) * | 2016-02-25 | 2016-09-28 | 马鞍山市全润农业科技有限公司 | Good-stability long-action-period modified-Chinese-chestnut-protein-coated slow-release fertilizer |
| CN105618478A (en) * | 2016-03-24 | 2016-06-01 | 南京盖亚生物工程有限公司 | Biological soil remediation agent and method for remediating soil |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114130811A (en) * | 2021-11-13 | 2022-03-04 | 北京工业大学 | Method for restoring cadmium-polychlorinated biphenyl composite polluted soil by crop rotation of astragalus sinicus and sedum plumbizincicola |
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