CN106726698A - A kind of amino acid pattern mildy wash and preparation method thereof - Google Patents
A kind of amino acid pattern mildy wash and preparation method thereof Download PDFInfo
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- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8194—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Compositions of derivatives of such polymers
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- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/645—Proteins of vegetable origin; Derivatives or degradation products thereof
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- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
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Abstract
The present invention provides a kind of amino acid pattern mildy wash, and its raw material includes：10 30wt% amino acid surfactants, 0.5 2wt% thickeners, 0.2 2.5wt% nertralizers, 0.1 1wt% conditioners and deionized water.Present invention also offers the preparation method of amino acid pattern mildy wash, dilution agent will be thickened first, then be added thereto to amino acid surfactant, conditioner etc. will be added after stirring and dissolving, stood overnight, obtain amino acid pattern mildy wash.The amino acid pattern mildy wash that the present invention is provided is in neutrality, and gentle pro-skin is safe and non-stimulating, and skin burden is not increased, can deep layer cleaning skin, skin recovers oil-water balance, acid-base balance quickly after clean skin, is adapted to any skin quality, and can be with long-term use.Product is emulsion appearance quality, with excellent perception and moisture retention, and high/low temperature excellent in stability, with certain denseness, disclosure satisfy that good user experience.
Description
Technical field
The invention belongs to daily cosmetics technical field, it is related to a kind of amino acid pattern mildy wash and preparation method thereof, especially
It is related to containing at least two amino acid surfactants, with mildy wash of height temperature stability higher and preparation method thereof.
Background technology
For facial skin care, face cleaning is a particularly important step.If do not cleaned up, the grease of delay and
Dirt not only easy cooperating microorganisms, damage skin, and skin surface can also form closure barrier, influence the infiltration of follow-up skin care item
And absorption.
Traditional Soap-base facial cleanser, is its degreasing power using by the fatty acid soaps after highly basic saponification as main cleansing
Relatively strong, long-term use can be such that facial sebum is excessively lost in, and damage cuticula, cause the excessive dehydration and drying of skin tight；Separately
Outer its pH value is larger, there is sizable negative effect to skin acid or alkali environment in itself, and can be to causing larger thorn to skin
Swash property.
Amino acid cleansing cream, its using the amino acid surfactant of pro-skin as main cleansing, with moderate washing
Power and security higher.Amino acid cleansing cream is in faintly acid or neutrality, and residual is less, because the pH value with skin surface relatively connects
Closely, therefore, such product could really protect skin health, lead face cleaning product trend.But with amino acid surfactant
The face cleaning product being the theme can face following challenge in technology development process：1) it is more difficult to thicken and remain stable over, produce
Not bright and clean enough the exquisiteness of product outward appearance, occurs bleed phenomenon in shelf life.2) not enough, product can be sent out height temperature stability in high temperature
Raw desaturation, and at low ambient temperatures, surface can be layered again becomes rougher.These are resulted in cannot ensure product quality, therefore
Consumer's Experience is not good.
Application No. 201410332325, invention and created name is：A kind of skin care moisturizing amino acid mildy wash and its preparation
Method, patent application provide a kind of amino acid mildy wash containing sodium lauroyl glutamate surfactant, but it is not
The stability of the amino acid mildy wash is disclosed, the high temperature performance of the mildy wash is not detected yet.
Application No. 201010523235, invention and created name is：A kind of amino acid cleansing cream and preparation method thereof, in
State's patent, discloses amino acid cleansing cream and its making of a kind of sodium lauroyl glutamate surface-active contents more than 25%
Method.The product high/low temperature stability for obtaining is preferable, but surfactant is limited to sodium lauroyl glutamate by it, due to it
It is expensive, limit the large-scale production of the product.
The content of the invention
For not enough present in existing amino acid cleansing breast or face cleaning cream technology, the invention provides comprising various amino
Amino acid cleansing breast of acid surfaces activating agent and particular thickener and preparation method thereof, amino acid cleansing breast high temperature performance is steady
Fixed, denseness is appropriate, with good user experience.
The first aspect of the invention is to provide a kind of amino acid pattern mildy wash, and its raw material includes：
Preferably, the raw material of the amino acid pattern mildy wash includes：
In a preferred embodiment, the amino acid surfactant is fat acidyl glycine salt, preferably fat
The mixture of acylglycine potassium and fatty acyl group Sodium Glycinate, the more preferably sweet ammonia of cocoyl Sodium Glycinate, cocoyl
Any two kinds or several in sour potassium, cocoyl disodium glutamate, sodium lauroyl glutamate and cocoyl glutamic acid TEA salt etc.
Plant the composition of sylvite and sodium salt.
In a preferred embodiment, the fatty acyl group Sodium Glycinate and the mass ratio of fatty acyl group glycine potassium are 1：
0.1-1：10, preferably 1：0.3-1：5, it is higher to be preferably 1：0.5-1：3.
In a preferred embodiment, the thickener is polyvinylpyrrolidone, Carbomer, acrylic acid and/or acrylic acid
The cross-linked polymer of ester/C10-30 alkylol acrylamide acid esters cross-linked polymer, polyvinyl methyl ethermaleic anhydride/methyl acrylate and decadinene,
Any one or a few combination in soybean protein glue and Silica hydrogel.
In a preferred embodiment, the amino acid pattern mildy wash also includes non-amino acids surfactant, moisturizing
Any one or a few in agent, plant extraction liquid, pigment, pearling agent, inorganic salts.
Wherein, the non-amino acids surfactant include laruate, myristate, lauryl sodium sulfate,
Laureth sulfuric acid, Cocoamidopropyl betaine, coco betaine, lauroylamidopropyl betaine, lauryl
Any one or a few combination in glycine betaine, cocounut oil both sexes acetate etc..
Preferably, the content of the non-amino acid surfactant be 1-15wt%, preferably 4-10wt%, such as 5wt%,
8wt% etc..
Preferably, the inorganic salts are any one or its combination in sodium chloride, potassium chloride, and preferably sodium chloride,
The content of the sodium chloride is 0.2-6wt%, and preferably 2-5wt%, such as 3wt%, 4wt%.
Preferably, the NMF is polyalcohols, the one or more combination of polysaccharide.It is highly preferred that the moisturizing
Agent is glycerine, trehalose, Sodium Hyaluronate, the one or more combination of NMF NMF.
Further, the content of the NMF is 5-30wt%, and most preferably, the content of the NMF is 8-
15wt%, such as 10wt%, 12wt%.
In a preferred embodiment, the nertralizer is triethanolamine, tetrahydroxypropyl ethylenediamine, aminomethyl propanol, ammonia
Any one or a few combination in methyl propanediol, tromethamine, arginine, adjusts the pH value of the amino acid pattern mildy wash
=4.0-10.0.
In a preferred embodiment, it is cation opsonizing agent that the conditioner is preferably, the cation opsonizing agent choosing
From polyquaternium -7, polyquaternium -39, polyquaternium -44, hexadecyltrimethylammonium chloride, double octadecyldimethyl chlorine
Change the one or more combination of ammonium.
In a preferred embodiment, the plant extraction liquid is soapberry extract, Rhodiola crenulata extract, camellia
Any one or a few combination in flower extract and hamamelis extract, the content of the plant extraction liquid is 0.1-1wt%,
Preferably 0.2-0.5wt%.
In a preferred embodiment, the pigment is titania powder, and the content of the pigment is 0.1-2wt%,
Preferably 0.4-1wt%.
In a preferred embodiment, the pearling agent includes glycol distearate and/or ethylene glycol stearate,
It is highly preferred that the content of the pearling agent is 0.1-2wt%, such as 0.5wt%, 1.8wt%, most preferably 0.8-1.5wt%,
Such as 1.0wt%, 1.3wt%.
Additionally, the amino acid pattern mildy wash provided in the present invention, can also be added as needed on appropriate essence, anti-corrosion
Any one or a few combination in agent, pigment used for cosmetic, nutrition class additive etc..
It is another aspect of the invention to provide a kind of preparation method of amino acid pattern mildy wash, the preparation method includes
Following steps：
Step 1,0.5-2wt% thickeners add appropriate deionized water, stir, the thickening for being diluted
Agent；
Step 2, in the thickener of the dilution obtained in step 1 add 10-30wt% amino acid surfactants, heating
To 80-90 DEG C, stirring and dissolving 30-60min stands and then is added thereto to 0.2-2.5wt% nertralizers；45-55 DEG C is cooled to,
Obtain intermediate products；
0.1-1wt% conditioners are added in step 3, the intermediate products obtained to step 2, continues to stir 30-
60min, stands overnight, and obtains the amino acid pattern mildy wash.
In a preferred embodiment, before adding 0.1-1wt% conditioners in the intermediate products for obtaining to step 2,
Also need to, to nertralizer is added in the intermediate products, adjust pH value=4.0-10.0, preferably pH value=6.0-8.0.
In a preferred embodiment, also include adding the brightening agent of 0.1-2wt% in step 3, when adding conditioner.
The invention has the advantages that：
(1) the amino acid pattern mildy wash that the present invention is provided is in neutral, pH value=4.0-10.0, and gentle pro-skin is safe stingless
Swash, skin burden is not increased, can deep layer cleaning skin, skin recovers oil-water balance, acid-base balance quickly after clean skin, be adapted to appoint
What skin quality, and can be with long-term use.
(2) product is emulsion appearance quality, with excellent perception and moisture retention.
(3) product high/low temperature excellent in stability, and meet good user experience with certain denseness.
Brief description of the drawings
The influence of the amino acid pattern mildy wash viscosity that Fig. 1 is provided the present invention for inorganic salt content.
Specific embodiment
Performance of amino acid pattern mildy wash provided below in conjunction with the specific embodiment explanation present invention and preparation method thereof.
Embodiment one is to embodiment eight
U20 (acrylic acid or acrylate/C10-30 alkylol acrylamide acid esters cross-linked polymer) is added together with deionized water
In entering to emulsify pot, and stirring is allowed to be uniformly dispersed, then to adding cocoyl Sodium Glycinate and cocoyl sweet in emulsification pot
Propylhomoserin potassium, is heated to 80-85 DEG C, and stirring and dissolving 45min slightly stands 30-60min to eliminate liquid level steam bubble；It is cooled to 45-55
DEG C, add triethanolamine to neutralize；Continue to be cooled to 45-50 DEG C, other components are added in mass ratio, continue to stir 30min and protect
Temperature is allowed to be completely dispersed uniformly to 45-50 DEG C, after discharging, amino acid pattern mildy wash is obtained final product after standing 12h, and the amino acid pattern is clean
Face breast is emulsus product, and as shown in table 1, amino acid pattern mildy wash prepared by each embodiment is examined for the weight/mass percentage composition of each component
Data are commented as shown in Fig. 1 and Biao 2.
Influence of the table 1, sodium chloride content to properties of product
Wherein, U20 be acrylic acid or acrylate/C10-30 alkylol acrylamide acid esters cross-linked polymer (
Ultrez 20Polymer, Lu Borun manage (Shanghai) Co., Ltd.)；
Table 2, embodiment one prepare the performance test of product to embodiment eight
Wherein, pH value surveys method measurement using straight, i.e., under the conditions of 25 DEG C, pH meter electrode is put into not diluted sample
Measured pH value.
Viscosity uses detection method measurement described in GB/T15357-2014, and rotating speed is 20rpm.
- 15 DEG C/25 DEG C (3 circulations) tests：Sample is put into 24 hours in -15 DEG C of refrigerating chambers, at 25 DEG C after taking-up
Constant temperature 25 hours, is a circulation, and repetitive cycling is observed and tested for 3 times.Tests below, using same test method.
O：Representative has good stability；×：Representative sample is layered and/or outward appearance is roughening.
From Fig. 1 and Biao 2, in same formula system, U20 is used as thickener, and the content of U20 is when being 1wt%, chlorine
Change the addition of sodium in the range of 0.5-4wt%, with the increase of salt content, the viscosity of amino acid pattern mildy wash quickly increases.It is real
Apply in example one to embodiment three, the content of sodium chloride is less than 2wt%, and the amino acid pattern mildy wash of preparation, product viscosity is less than
3000MPas, is easily presented the thicker unstable state of high temperature batch, low temperature.Because the foam that sodium chloride can reduce product contains
Amount, it is therefore preferable that sodium chloride content is less than 5wt%.
Embodiment nine is to embodiment 14
U20 (acrylic acid or acrylate/C10-30 alkylol acrylamide acid esters cross-linked polymer) is added together with deionized water
In entering to emulsify pot, and stirring is allowed to be uniformly dispersed, then to adding cocoyl Sodium Glycinate and/or cocoyl in emulsification pot
Glycine potassium, is heated to 80-85 DEG C, and stirring and dissolving 45min slightly stands 30-60min to eliminate liquid level steam bubble；It is cooled to 45-55
DEG C, add triethanolamine to neutralize；Continue to be cooled to 45-50 DEG C, other components are added in mass ratio, continue to stir 30min and protect
Temperature is allowed to be completely dispersed uniformly to 45-50 DEG C, after discharging, amino acid pattern mildy wash is obtained final product after standing 12h, and the amino acid pattern is clean
Face breast is emulsus product, and the weight/mass percentage composition of each component is as shown in table 3, and it is clean to investigate the amino acid pattern of different embodiments preparations
The performance of face breast, as a result as shown in table 4.
Table 3, amino acid surfactant species and the influence with comparison properties of product
The performance test of product is prepared in table 4, embodiment nine to embodiment 14
Wherein, the method for testing of the implication of each symbol and each performance is identical with table 2.
Data analysis more than we can obtain as drawn a conclusion：
Embodiment nine to embodiment 11 investigates influence of the amino acid compounding to properties of product, and the species of salt, content (are
Sodium chloride, content is 0.8wt%) and the species of thickener, content (being U20, content is 0.8wt%) keep not
Become.Single cocoyl Sodium Glycinate, amino acid pattern mildy wash is used easily to reach viscosity higher in embodiment nine, it glues
It is 8280MPas to spend, but it is easily thicker and cause system unstable under cryogenic.Using single in embodiment ten
Cocoyl glycine potassium, the viscosity of amino acid pattern mildy wash is relatively low, and its viscosity is 1900MPas, causes product height easily occur
Warm lamination.
And in embodiment 11, under conditions of total amount is not changed, regulation cocoyl Sodium Glycinate and cocoyl are sweet
The proportioning of propylhomoserin potassium, the viscosity of the amino acid pattern mildy wash for obtaining is 5100MPas, and the height temperature stability of product is more excellent.
Compared with embodiment 11, in embodiment 12, cocoyl Sodium Glycinate and cocoyl glycine are not changed
The total amount of potassium, the relative amount of cocoyl Sodium Glycinate is improved to 9wt% by 7wt%, obtain the viscosity of product by
5100MPas increases to 6000MPas, it was therefore concluded that：Sodium salt is more easy to promote the increase of product viscosity compared with sylvite.
Influence due to sylvite to product viscosity is smaller, therefore, the content of cocoyl glycine potassium is reduced, can't be big
The viscosity of width reduction product, and in embodiment 13, the content of cocoyl glycine potassium is reduced, greatly improve containing for sodium chloride
Amount, the product for obtaining does not increase not only relative to the viscosity of embodiment 12, decreases on the contrary, illustrates that salt exists with amino acid
Synergy is there occurs during preparing product.By adjusting amino acid and sodium chloride in embodiment 13, embodiment 14
Relative amount, can be by the control of the viscosity of product within the specific limits, the product for obtaining is protected in high/low temperature stability test
It is fixed to keep steady.
Five to the embodiment 18 of embodiment 10：
During thickener to add together with deionized water emulsification pot, and stirring is allowed to be uniformly dispersed, then in emulsification pot
The myristoyl glycine potassium and myristoyl Sodium Glycinate of different ratio are added, 80-85 DEG C, stirring and dissolving is heated to
45min, stands 30-60min to eliminate liquid level steam bubble；45-55 DEG C is cooled to, the pH of corresponding nertralizer regulation system is added
Value；Continue to be cooled to 45-50 DEG C, other components are added in mass ratio, continue to stir 30min and be incubated to 45-50 DEG C, be allowed to
It is uniformly dispersed entirely, after discharging, amino acid pattern mildy wash is obtained final product after standing 12h, the amino acid pattern mildy wash is emulsus product, each group
The weight/mass percentage composition for dividing is as shown in table 5, and investigates the performance of amino acid pattern mildy wash prepared by different embodiments, as a result such as table
Shown in 6.
The influence of table 5, thickener species to properties of product
Wherein, U20 be acrylic acid or acrylate/C 10-30 alkylol acrylamide acid esters cross-linked polymer (
Ultrez 20Polymer, Lu Borun manage (Shanghai) Co., Ltd.)；
SC200 be acrylic acid or acrylate/C10-30 alkylol acrylamide acid esters cross-linked polymer ( SC-
200Polymer, Lu Borun manage (Shanghai) Co., Ltd.)；
(Carbopol Aqua SF-1, Lu Borun management (Shanghai) are limited for acrylic acid or acrylate copolymer for SF-1
Company)；
STRUCTURE XL (hydroxypropyl starch phosphate, Akzo Nobel (Shanghai) Co., Ltd.).
Table 6, five to the embodiment 18 of embodiment 10 prepare the performance test of product
Wherein, the implication of each symbol and the method for testing of each performance are identical with table 2 in table 6.
As shown in Table 6, the amino acid pattern mildy wash that prepared by 10 five to embodiment of embodiment 17 has relatively stable height
Warm nature energy, the viscosity of product is in more than 3000MPas, and amino acid pattern mildy wash high temperature, low temperature properties prepared by embodiment 18
Can be unstable, occur layering during high temperature, and product becomes more coarse under cryogenic conditions, can not meet under high/low temperature condition
Requirement to stability.Amino acid pattern mildy wash viscosity prepared by embodiment 18 is 1200MPas, thus it is speculated that may be due to
Titanium dioxide is added with amino acid pattern mildy wash prepared by the present invention, in order to keep titanium dioxide stability in the product,
It is required that thickener provides certain suspending power while thickening, as known from Table 4, in more than 3000MPas, product has viscosity
There are excellent stability, acrylic acid or acrylate/C10-30 alkylol acrylamide acid esters cross-linked polymers, Typical Representative source commodity
Name：Ultrez 20Polymer andSC-200Polymer, acrylic acid or acrylic ester copolymer
Thing, Typical Representative source commodity name：Carbopol Aqua SF-1.This kind of thickener is while thickening with certain suspension
The function of particle.And hydroxypropyl starch phosphate (STRUCTURE XL) though with certain thickening effect, suspending power phase
To weaker, therefore cause product stability inadequate.
Nine to the embodiment 20 of embodiment 10
By SC200 be acrylic acid or acrylate/C10-30 alkylol acrylamide acid esters cross-linked polymer (SC-
200Polymer, Lu Borun additive (Zhuhai) Co., Ltd) add emulsification pot together with deionized water, and stir and be allowed to point
Dissipate uniform, then to cocoyl Sodium Glycinate and cocoyl glycine potassium is added in emulsification pot, be heated to 80-85 DEG C, stir
Dissolving 45min is mixed, 30-60min is slightly stood to eliminate liquid level steam bubble；45-55 DEG C is cooled to, adds triethanolamine to neutralize；Continue
45-50 DEG C is cooled to, other components are added in mass ratio, continue to stir 30min and be incubated to 45-50 DEG C, be allowed to be completely dispersed
Uniformly, after discharging, amino acid pattern mildy wash is obtained final product after standing 12h, the amino acid pattern mildy wash is emulsus product, the matter of each component
Amount percentage composition is as shown in table 7, and investigates the performance of amino acid pattern mildy wash prepared by different embodiments, as a result as shown in table 8.
The influence of table 7, thickener species to properties of product
Table 8, implementation case 19 and embodiment 20 prepare the performance test of product
Wherein, the implication of each symbol and the method for testing of each performance are identical with table 2 in table 8.
Embodiment 20 increase only the content of sodium chloride and triethanolamine compared with embodiment 19.By embodiment one
Understand that in the range of 0.5-4wt%, with the increase of sodium chloride content, amino acid pattern is clean for the addition of sodium chloride to embodiment eight
The viscosity of face breast quickly increases.And embodiment 20, relative to embodiment 19, the viscosity of amino acid pattern mildy wash does not increase, instead
And decrease, illustrating the viscosity of the amino acid pattern mildy wash of present invention offer can reduce with the rising of pH value, because
The solubility of cocounut oil acyl glycinate is more than the solubility of cocounut oil acyl glycine, and pH value is lower, and insoluble matter is more, and viscosity is bigger,
But when pH value is lower, to relatively rough, this time optimal pH of formula is set as 6.0-8.0 to material body phase.
Claims (10)
1. a kind of amino acid pattern mildy wash, it is characterised in that raw material includes：
2. amino acid pattern mildy wash according to claim 1, it is characterised in that raw material includes：
3. amino acid pattern mildy wash according to claim 1, it is characterised in that the amino acid surfactant is fat
The mixture of acylglycine sodium and fatty acyl group glycine potassium, the fatty acyl group Sodium Glycinate and fatty acyl group glycine potassium
Mass ratio be 1：0.1-1：10.
4. amino acid pattern mildy wash according to claim 1, it is characterised in that the thickener is polyvinylpyrrolidine
Ketone, Carbomer, acrylic acid or acrylate/C10-30 alkylol acrylamide acid esters cross-linked polymer, polyvinyl methyl ethermaleic anhydride/acrylic acid first
Any one or a few in the cross-linked polymer of ester and decadinene, soybean protein glue and Silica hydrogel is combined.
5. amino acid pattern mildy wash according to claim 1, it is characterised in that the amino acid pattern mildy wash also includes non-
Any one or a few in amino acid surfactant, inorganic salts, NMF, plant extraction liquid, pigment, pearling agent.
6. amino acid pattern mildy wash according to claim 5, it is characterised in that the inorganic salts are sodium chloride, potassium chloride
In any one or its combination, the content of the inorganic salts is 0.2-6wt%.
7. amino acid pattern mildy wash according to claim 5, it is characterised in that the non-amino acids surfactant is
Laruate, myristate, lauryl sodium sulfate, laureth sulfuric acid, Cocoamidopropyl betaine, cocounut oil
Any one or a few group in base glycine betaine, lauroylamidopropyl betaine, lauryl betaine, cocounut oil both sexes acetate etc.
Close, the content of the non-amino acid surfactant is 1-15wt%.
8. amino acid pattern mildy wash according to claim 1, it is characterised in that the nertralizer is triethanolamine, four hydroxyls
Any one or a few combination in propyl group ethylenediamine, aminomethyl propanol, aminomethyl propane diols, tromethamine, arginine, regulation
PH value=the 4.0-10.0 of the amino acid pattern mildy wash.
9. a kind of preparation method of amino acid pattern mildy wash, it is characterised in that the preparation method comprises the following steps：
Step 1,0.5-2wt% thickeners add appropriate deionized water, stir, the thickener for being diluted；
Step 2, in the thickener of the dilution obtained in step 1 add 10-30wt% amino acid surfactants, be heated to
80-90 DEG C, stirring and dissolving 30-60min stands and then is added thereto to 0.2-2.5wt% nertralizers；45-55 DEG C is cooled to, is obtained
To intermediate products；
0.1-1wt% conditioners are added in step 3, the intermediate products obtained to step 2, continues to stir 30-60min, it is quiet
Put overnight, obtain the amino acid pattern mildy wash.
10. the preparation method of amino acid pattern mildy wash according to claim 9, it is characterised in that the institute obtained to step 2
State before adding 0.1-1wt% conditioners in intermediate products, in addition it is also necessary to adding nertralizer in the intermediate products, regulation pH value=
4.0-10.0。
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| CN107569410A (en) * | 2017-09-30 | 2018-01-12 | 广州环亚化妆品科技有限公司 | A kind of amino acid cleansing breast and preparation method thereof |
| CN108852945A (en) * | 2018-09-14 | 2018-11-23 | 广州艾蓓生物科技有限公司 | A kind of amino acid cleansing cream from foaming |
| CN110090161A (en) * | 2019-05-24 | 2019-08-06 | 安徽强旺调味食品有限公司 | A kind of mildy wash and preparation method thereof |
| CN113208948A (en) * | 2021-04-21 | 2021-08-06 | 安婕妤化妆品科技股份有限公司 | Moisturizing facial cleanser and preparation method thereof |
| CN114392204A (en) * | 2021-12-24 | 2022-04-26 | 广州那比昂生物科技有限公司 | Skin cleaning composition and preparation method and application thereof |
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| CN107569410A (en) * | 2017-09-30 | 2018-01-12 | 广州环亚化妆品科技有限公司 | A kind of amino acid cleansing breast and preparation method thereof |
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| CN114903834A (en) * | 2022-06-30 | 2022-08-16 | 羽楠(广州)化妆品有限公司 | Cold-storable mild double-tube facial cleanser and preparation method thereof |
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