CN106726644A - A kind of face cleaning powder with anti-oxidation efficacy and preparation method thereof - Google Patents
A kind of face cleaning powder with anti-oxidation efficacy and preparation method thereof Download PDFInfo
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- CN106726644A CN106726644A CN201710012672.8A CN201710012672A CN106726644A CN 106726644 A CN106726644 A CN 106726644A CN 201710012672 A CN201710012672 A CN 201710012672A CN 106726644 A CN106726644 A CN 106726644A
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- face cleaning
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/98—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
- A61K8/987—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin of species other than mammals or birds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/22—Gas releasing
Abstract
The present invention relates to a kind of face cleaning powder with anti-oxidation efficacy and preparation method thereof, it is used as hydrogen manufacturing composition by using coral calcium hydroxide, and it is aided with sodium lauroyl glutamate, alkyl glucoside, Silk Powder, trehalose, Sodium Hyaluronate and the citric acid of certain proportioning, make products obtained therefrom that not only there is good anti-oxidation efficacy, also with good nutrition, moisturizing and detergency ability.Face cleaning powder of the present invention carries out massage cleaning using the foam for producing to face; infiltration and the facial blood circulation of hydrogen can not only be promoted; absorption beneficial to skin to trophism and both effectiveness material; and the natural sebum film of face skin will not be destroyed; long-term use can protect epidermal cell from the infringement of free radical, and then reach wrinkle resistant anti-ageing, anti-inflammatory toxin expelling, effect of skin-moisturizing, skin.
Description
Technical field
The invention belongs to daily chemicals field, and in particular to a kind of face cleaning powder and its preparation side with anti-oxidation efficacy
Method.
Background technology
Free radical is the intermediate product of body eubolism, with extremely strong oxidability, once excess accumulation will be right
The materials such as nucleic acid, protein, sugar, lipid in skin produce irreversible damage, and cause permeability of cell membrane and hardness to increase
Plus, collagen, elastin laminin and epidermal growth factor receptor protein produce crosslinking denaturation in the change of intracellular environment and skin, so that
Promote thinning of skin, corrugation, elasticity is reduced, cell growth slows down, and ultimately results in the skins such as thick microgroove, pore, jaundice, color spot
The generation of problem.Therefore, develop effective antioxidant and be resistant to above-mentioned skin removing the harmful free radicals of internal accumulation and ask
The powerful measure of topic.But general polyphenoils is difficult to enter intracellular, limits the use of many polyphenoils.At present,
There is scholar using means such as chemical reaction, cytology, it was demonstrated that hydrogen has selective antioxidation, and biomembrane can be penetrated and arrive
Up to organelle and nucleus, harmful ROS that other medicines are difficult to reach position is removed.But hydrogen solubility in water it is very low and
It is highly susceptible to diffusion effusion, causes hydrogeneous shipwreck to preserve.
Chinese patent application 103432063A, discloses a kind of elite for treating whelk and pigment patch and whitening
Liquid, the Essence is by by hydrogen-rich heavy-oxygen-enriched water and microelement composition, collagen, sodium hyaluronate, superoxide dismutase etc.
Mixing and stirring, sterilization filling is formed.Because hydrogen molecule amount is small, permeability is strong, easily expands during stirring is made
Leakage is dissipated, hydrogen content is reduced in making product, not even hydrogen.Chinese patent application 105078874A, discloses one kind and matches somebody with somebody
Close the new cosmetic water that uses of hydrogen-rich instrument and a kind of preparation method of the toner rich in hydrogen, the invention is by by first inhibition and generation adornment
In water input hydrogen-rich instrument, hydrogen-rich toner is obtained after being processed through hydrogen-rich instrument.Although the invention solves hydrogen permeability and by force, easily spreads
Problem, but want instant system, be also easy to produce poisonous and harmful element using cumbersome, and after electrolyte is processed through hydrogen-rich instrument.Therefore, such as
What effectively applies in cosmetics hydrogen, and preserves an important indicator for turning into and weighing hydrogen-rich cosmetics well.
The content of the invention
It is an object of the present invention to meet the market demand, solve above-mentioned technological deficiency, there is provided one kind has anti-oxidant work(
Face cleaning powder of effect and preparation method thereof.
The present invention is achieved through the following technical solutions:
A kind of face cleaning powder with anti-oxidation efficacy, including 1~3 weight portion coral calcium hydroxide.
Preferably, a kind of face cleaning powder with anti-oxidation efficacy, also including the raw material of following weight proportioning:Lauroyl paddy ammonia
10~45 parts of sour sodium, 1~10 part of alkyl glucoside, 1~5 part of Silk Powder, 1~10 part of trehalose, Sodium Hyaluronate 0.1~0.5
Part, 0.05~2.5 part of citric acid.
Preferably, a kind of raw material of face cleaning powder with anti-oxidation efficacy, including following weight proportioning:Coral calcium hydroxide 1
~3 parts, it is 18~40 parts of sodium lauroyl glutamate, 3~8 parts of alkyl glucoside, 2~4 parts of Silk Powder, 3~7 parts of trehalose, transparent
0.1~0.3 part of sodium of matter acid, 0.05~2 part of citric acid.
Preferably, a kind of raw material of face cleaning powder with anti-oxidation efficacy, including following weight proportioning:Coral calcium hydroxide 2
Part, 25 parts of sodium lauroyl glutamate, 6 parts of alkyl glucoside, 3 parts of Silk Powder, 5 parts of trehalose, 0.2 part of Sodium Hyaluronate, lemon
1 part of acid.
Coral calcium hydroxide is that the coral calcium of purity about 99.5% is put into iron pan to be placed in high-temperature atmosphere sintering furnace reative cell,
It is 1 to then pass to ratio:10~1:20 nitrogen hydrogen mixeding gas, are heated to 800~950 DEG C, have been fired through about 2~12h reduction
Into the coral calcium hydroxide of generation is porous pale white crystals powder.The hydrogen that coral calcium hydroxide discharges after being reacted with water is one
Natural is planted, with very strong restoring function, it has the advantage that:(1) selective antioxidation:Hydrogen can
Optionally the active oxygen with strong toxicity reacts, without active chalcogen of the influence with important biomolecule function, such as H2O2With
O2-;(2) activity of endogenous anti-oxidative system is improved, promotes cell metabolism, cell is kept fit state, and increase
The synthetic quantity of skin collagen, makes skin water tender fine and smooth;(3) molecular weight is small, diffusion is fast:Hydrogen can penetrate biomembrane and reach organelle
And nucleus, remove harmful ROS that other antioxidants are difficult to reach position;(4) anti-inflammatory, anti-apoptotic effect;(5) pacify
Entirely, few side effects, and aboundresources, it is cheap, easily produce.
Sodium lauroyl glutamate is in faintly acid, is a kind of anion surfactant, and its foaming, foam stability are good, decontamination energy
Power is strong, and biodegradability is good, and to skin action temperature and, excitant is small, low toxicity, and with good restraining and sterilizing bacteria performance,
There is preferable compatibility with other various surfactants.
Alkyl glucoside is a class nonionic surfactant, is obtained with glucose response by fatty alcohol, its surface tension
Low, moistening effect is good, strong detergency, foaming abundancy are fine and smooth, and compatibility is strong, excitant is low, and biodegradability is good, is a kind of
The surfactant of green.
Silk Powder includes high protein and ten several amino acid, and its structure is quite similar with human body skin, due to its granularity pole
When carefully, for cosmetic industry, can organically be combined with human epidermal cell, and can be absorbed by epidermal cell, be increased epidermis thin
Born of the same parents' vigor, enhances metabolism.Also there is good gas permeability, tack, hygroscopicity and moisture retention simultaneously, and can with temperature and
The change of humidity absorbs or release moisture, keeps hydrophilic, oleophylic balance, to protecting skin and preventing dry skin, tanned, solarization
Wound has special efficacy.The skin of people can be made to keep moistening commonly using the cosmetics of addition silk ultra-fine element powder, it is tender it is white, be rich in bullet
Property.
Trehalose is the nonreducing sugar being made up of special disaccharide molecule, and property is highly stable, can high temperature, it is high and cold,
Dry dehydration etc. it is severe under conditions of form special diaphragm in cell surface, be effectively protected biomolecular structure and do not broken
It is bad, so as to the life process and biological characteristic of the body that sustains life.The moisture-keeping function of trehalose is:Hydroxyl 1. in glycan molecule,
Suo Ji and other polar groups can form hydrogen bond and combine substantial amounts of moisture with hydrone, meanwhile, sugar subchain is also interweaved
Reticulate, in addition with the Hydrogenbond of water, play very strong water retention.Additionally, in extracellular matrix, its with skin in its
His polysaccharide component and fibrous proteins collectively constitute the extracellular gelatinised matrix containing large quantity of moisture, for skin provides moisture;2. it is many
Sugar has good filming performance, can form one layer of uniform film in skin surface, reduces the moisture evaporation of skin surface, makes
Moisture permeates into cuticula from substrate microstructure, induces the further aquation of cuticula, preserves the moisture of skin itself, and completes moisturizing
Effect.Therefore, the high water absorbing ability of trehalose and good film forming are ideally combined, and can provide good moisturizing effect for skin
Really.In addition, trehalose also has promotes cell growth and oxidation resistant effect, it compounds with Sodium Hyaluronate and goes wrinkle for crease-resistant
Class, sun-proof class cosmetics, facial mask, eye patch excellent.
Citric acid is natural acid-base modifier, and the alkalescence produced when product is used can be neutralized with coral calcium hydroxide compounding use
Material, reduces the excitant of product.
A kind of preparation method of the face cleaning powder with anti-oxidation efficacy, comprises the following steps:
(1) each raw material is weighed by formulation weight proportioning;
(2) it is particles more than 2000 mesh each raw material that step (1) is weighed to be crushed into fineness respectively;
(3) each raw material after step (2) is crushed mixes, and 50-70min is stirred under the conditions of 100-200r/min, seals
Packaging prepares the face cleaning powder.
Further, the application method of the face cleaning powder with anti-oxidation efficacy is:
(1) face is moistened with water, face cleaning powder is applied on the face, thickness is 0.3-0.7mm;
(2) massage is covered with the facial 5~10 minutes of face cleaning powder, promotes the infiltration of hydrogen and the absorption of nutriment;
(3) cleaned with clear water.
Beneficial effects of the present invention:
1st, face cleaning powder of the present invention makes full use of the hydrogen that product is produced when in use using coral calcium hydroxide as hydrogen manufacturing composition
Gas, solves the problems, such as that hydrogen permeability is strong, is difficult storage, the characteristics of with stability and high efficiency;
2nd, coral calcium hydroxide and water reaction after discharge hydrogen be a kind of natural, with selectivity it is anti-oxidant,
The effect of anti-inflammatory and anti-apoptotic, and biomembrane arrival organelle and nucleus can be penetrated, remove other antioxidants and be difficult to
Reach harmful ROS at position;Secondly, hydrogen can also improve endogenous anti-oxidative system activity, promote cell metabolism, make thin
Born of the same parents keep fit state, and increase the synthetic quantity of skin collagen, make skin water tender fine and smooth;
3rd, face cleaning powder of the present invention add the sodium lauroyl glutamate of certain proportioning, alkyl glucoside, Silk Powder, trehalose,
Sodium Hyaluronate and citric acid so that product not only has good anti-oxidation efficacy, also with good nutrition, moisturizing, increasing
Bubble, foam stabilizing and detergency ability;
4th, face cleaning powder of the present invention needs gently to massage 5~10 minutes when in use, can so promote hydrogen to penetrate into flesh
Skin and facial blood circulation, the absorption beneficial to skin to trophism and both effectiveness material reach wrinkle resistant anti-ageing, anti-inflammatory toxin expelling, protect
Moisten effect of skin.
Specific embodiment
With reference to specific embodiment, the present invention is further elaborated and explanation.
Embodiment 1~5
A kind of 5 specific embodiments of face cleaning powder with anti-oxidation efficacy of the present invention are listed in table 1.
Table 1
The face cleaning powder described in embodiment 1~5 is prepared in accordance with the following steps:
(1) each raw material is weighed by formulation weight proportioning;
(2) it is particles more than 2000 mesh each raw material that step (1) is weighed to be crushed into fineness respectively;
(3) each raw material after step (2) is crushed mixes, and 50-70min is stirred under the conditions of 100-200r/min, seals
Packaging prepares the face cleaning powder.
The application method of face cleaning powder of the present invention is:
(1) face is moistened with water, face cleaning powder is applied on the face, thickness is 0.3-0.7mm;
(2) massage is covered with the facial 5~10 minutes of face cleaning powder, promotes the infiltration of hydrogen and the absorption of nutriment;
(3) cleaned with clear water.
Comparative example 1~3
A kind of 3 specific comparative examples of face cleaning powder with anti-oxidation efficacy of the present invention are listed in table 2.
Table 2
Sensory quality assessment
According to the indices in table 3, sensory quality assessment is carried out to embodiment 1~5 and reference examples 1~3.Specific method
It is as follows:Judge group is constituted by 20 people, single factor evaluation is carried out one by one by organoleptic quality characteristic to each sample.Before evaluation, to
Every evaluation personnel explanation evaluation content, evaluation criterion and evaluation method, then by numbered 8 samples identical vessel
Laboratory technician is delivered, sample is quantitatively then smeared to every appraiser's predetermined portion by laboratory technician respectively.Sensory evaluation is set to 6 etc.
Level, it is specific as follows:6 represent it is fabulous;5 represent;4 represent preferably;3 represent typically;2 represent it is poor;1 representative is poor.Table 3 is test
Index and result.
Table 3
Result shows:The wetability and excitant of embodiment 1~5 are substantially better than comparative example 1~3, but detergency, foaming power
Illustrate that coral calcium hydroxide and citric acid compounding use can effectively reduce this hair without significant difference with comparative example 1~3 with dispersiveness
The excitant of clear and bright flour, and strengthen its wetability.
The evaluation test of face cleaning powder using effect
Research object:Choose pachylosis, dark, have the volunteer totally 100 of pigmentation, wrinkle or microgroove, at random
It is divided into 5 groups, every group of 20 people use face cleaning powder obtained in embodiment 1~5 respectively.Application method:Subject directly uses and is test-manufactured
Product, it is daily to moisten face with warm water using preceding sooner or later respectively using once, face cleaning powder is applied on the face, thickness is 0.3-0.7mm,
Then massage is covered with the facial 5~10 minutes of face cleaning powder, is cleaned with clear water, every time more than repetition operation.Experiment carries out 60 days, often
At least check in week and once had no adverse reaction with understanding, and record result in detail, count its efficient (%).Criterion of therapeutical effect:(1)
It is obviously improved:Subjective symptoms to be had significantly mitigate or disappear.(2) alleviate:Subjective symptoms have it is a certain degree of mitigation but not
It is too obvious.(3) it is invalid:Face's situation substantially or does not mitigate still.(4) deteriorate:Face's situation becomes worse.Table 4 is test index
And result.
Table 4
Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
It is obviously improved | 13 | 15 | 17 | 15 | 16 |
Alleviate | 4 | 3 | 2 | 3 | 2 |
It is invalid | 3 | 2 | 1 | 2 | 2 |
Deteriorate | 0 | 0 | 0 | 0 | 0 |
Total effective rate (%) | 85.0 | 90.0 | 95.0 | 90.0 | 90.0 |
Result shows:For pachylosis, dark, there are the personage of pigmentation, wrinkle or microgroove, the long-term use present invention
Face cleaning powder, have a preferable effect, and the effect of embodiment 3 is better than other embodiment.
Protection scope of the present invention is not limited thereto, any those of ordinary skill in the art disclosed herein
In technical scope, without the modification or replacement of creative work, should all be included within the scope of the present invention.
Claims (5)
1. a kind of face cleaning powder with anti-oxidation efficacy, it is characterised in that the face cleaning powder includes the coral hydrogen of 1~3 weight portion
Change calcium.
2. a kind of face cleaning powder with anti-oxidation efficacy according to claim 1, it is characterised in that the face cleaning powder is also wrapped
Include the raw material of following weight proportioning:10~45 parts of sodium lauroyl glutamate, 1~10 part of alkyl glucoside, 1~5 part of Silk Powder, sea
1~10 part of algae sugar, 0.1~0.5 part of Sodium Hyaluronate, 0.05~2.5 part of citric acid.
3. a kind of face cleaning powder with anti-oxidation efficacy according to claim 2, it is characterised in that the face cleaning powder includes
The raw material of following weight proportioning:1~3 part of coral calcium hydroxide, 18~40 parts of sodium lauroyl glutamate, 3~8 parts of alkyl glucoside,
2~4 parts of Silk Powder, 3~7 parts of trehalose, 0.1~0.3 part of Sodium Hyaluronate, 0.05~2 part of citric acid.
4. a kind of face cleaning powder with anti-oxidation efficacy according to claim 2, it is characterised in that the face cleaning powder includes
The raw material of following weight proportioning:2 parts of coral calcium hydroxide, 25 parts of sodium lauroyl glutamate, 6 parts of alkyl glucoside, 3 parts of Silk Powder,
5 parts of trehalose, 0.2 part of Sodium Hyaluronate, 1 part of citric acid.
5. it is a kind of prepare described in claim any one of 1-4 with anti-oxidation efficacy face cleaning powder method, it is characterised in that bag
Include following steps:
(1) each raw material is weighed by formulation weight proportioning;
(2) it is particles more than 2000 mesh each raw material that step (1) is weighed to be crushed into fineness respectively;
(3) each raw material after step (2) is crushed mixes, and 50-70min is stirred under the conditions of 100-200r/min, packs
Prepare the face cleaning powder.
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CN201710012672.8A CN106726644A (en) | 2017-01-06 | 2017-01-06 | A kind of face cleaning powder with anti-oxidation efficacy and preparation method thereof |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006117612A (en) * | 2004-10-25 | 2006-05-11 | Ichimaru Pharcos Co Ltd | Active oxygen eliminating agent |
CN102100699A (en) * | 2011-01-27 | 2011-06-22 | 上海全人生物科技有限公司 | Composition of coral calcium hydroxide and arginine and application thereof |
CN102783691A (en) * | 2012-08-20 | 2012-11-21 | 李志林 | Calcium-magnesium hydrogen producing agent |
-
2017
- 2017-01-06 CN CN201710012672.8A patent/CN106726644A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006117612A (en) * | 2004-10-25 | 2006-05-11 | Ichimaru Pharcos Co Ltd | Active oxygen eliminating agent |
CN102100699A (en) * | 2011-01-27 | 2011-06-22 | 上海全人生物科技有限公司 | Composition of coral calcium hydroxide and arginine and application thereof |
CN102783691A (en) * | 2012-08-20 | 2012-11-21 | 李志林 | Calcium-magnesium hydrogen producing agent |
Non-Patent Citations (2)
Title |
---|
CHRISTINACWH: "SanDaWha Natural Mild Cleanser 2014", 《获取网址:HTTP://WWW.COSDNA.COM/CHS/COSMETIC_BEAD157532.HTML》 * |
佚名: "蚕丝粉的美容功效", 《山东蚕业》 * |
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