CN106715664A - 液体增白组合物 - Google Patents
液体增白组合物 Download PDFInfo
- Publication number
- CN106715664A CN106715664A CN201580050339.5A CN201580050339A CN106715664A CN 106715664 A CN106715664 A CN 106715664A CN 201580050339 A CN201580050339 A CN 201580050339A CN 106715664 A CN106715664 A CN 106715664A
- Authority
- CN
- China
- Prior art keywords
- uncharged
- weight
- laundry detergent
- alkyl
- alkoxylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 61
- 239000007788 liquid Substances 0.000 title claims abstract description 13
- 230000002087 whitening effect Effects 0.000 title abstract description 3
- 239000004094 surface-active agent Substances 0.000 claims abstract description 18
- 239000003599 detergent Substances 0.000 claims description 44
- -1 Alkenyl phenol Chemical compound 0.000 claims description 35
- 235000013599 spices Nutrition 0.000 claims description 29
- 238000005406 washing Methods 0.000 claims description 21
- 125000000217 alkyl group Chemical group 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 15
- 102000004190 Enzymes Human genes 0.000 claims description 13
- 108090000790 Enzymes Proteins 0.000 claims description 13
- 239000003945 anionic surfactant Substances 0.000 claims description 12
- 229940088598 enzyme Drugs 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 11
- 239000004744 fabric Substances 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 102000004882 Lipase Human genes 0.000 claims description 10
- 108090001060 Lipase Proteins 0.000 claims description 10
- 239000004367 Lipase Substances 0.000 claims description 10
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 10
- 235000019421 lipase Nutrition 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 8
- 108010059892 Cellulase Proteins 0.000 claims description 8
- 108091005804 Peptidases Proteins 0.000 claims description 8
- 239000004365 Protease Substances 0.000 claims description 8
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 8
- 229940106157 cellulase Drugs 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 8
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 claims description 8
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 6
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 5
- 239000012752 auxiliary agent Substances 0.000 claims description 5
- 238000007046 ethoxylation reaction Methods 0.000 claims description 5
- 239000002736 nonionic surfactant Substances 0.000 claims description 5
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 claims description 4
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 claims description 4
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 claims description 4
- WLJVXDMOQOGPHL-UHFFFAOYSA-N benzyl-alpha-carboxylic acid Natural products OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 claims description 4
- HQKQRXZEXPXXIG-VJOHVRBBSA-N chembl2333940 Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@H]1[C@@](OC(C)=O)(C)CC2 HQKQRXZEXPXXIG-VJOHVRBBSA-N 0.000 claims description 4
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 claims description 4
- HFJRKMMYBMWEAD-UHFFFAOYSA-N dodecanal Chemical compound CCCCCCCCCCCC=O HFJRKMMYBMWEAD-UHFFFAOYSA-N 0.000 claims description 4
- 229930007744 linalool Natural products 0.000 claims description 4
- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- XEJGJTYRUWUFFD-FNORWQNLSA-N (e)-1-(2,6,6-trimethyl-1-cyclohex-3-enyl)but-2-en-1-one Chemical compound C\C=C\C(=O)C1C(C)C=CCC1(C)C XEJGJTYRUWUFFD-FNORWQNLSA-N 0.000 claims description 3
- OWYSSKOUATWAAO-UHFFFAOYSA-N C1(=CC=CC=C1)C=1C(=C(C(=C(C1)O)C=C)C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound C1(=CC=CC=C1)C=1C(=C(C(=C(C1)O)C=C)C1=CC=CC=C1)C1=CC=CC=C1 OWYSSKOUATWAAO-UHFFFAOYSA-N 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- 229940007550 benzyl acetate Drugs 0.000 claims description 3
- 239000000796 flavoring agent Substances 0.000 claims description 3
- 235000019634 flavors Nutrition 0.000 claims description 3
- 229960003424 phenylacetic acid Drugs 0.000 claims description 3
- 239000003279 phenylacetic acid Substances 0.000 claims description 3
- JZQOJFLIJNRDHK-UHFFFAOYSA-N (+)-(1S,5R)-cis-alpha-irone Natural products CC1CC=C(C)C(C=CC(C)=O)C1(C)C JZQOJFLIJNRDHK-UHFFFAOYSA-N 0.000 claims description 2
- 239000001306 (7E,9E,11E,13E)-pentadeca-7,9,11,13-tetraen-1-ol Substances 0.000 claims description 2
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 claims description 2
- WGPCZPLRVAWXPW-NSHDSACASA-N 5-octyloxolan-2-one Chemical compound CCCCCCCC[C@H]1CCC(=O)O1 WGPCZPLRVAWXPW-NSHDSACASA-N 0.000 claims description 2
- PQMOXTJVIYEOQL-UHFFFAOYSA-N Cumarin Natural products CC(C)=CCC1=C(O)C(C(=O)C(C)CC)=C(O)C2=C1OC(=O)C=C2CCC PQMOXTJVIYEOQL-UHFFFAOYSA-N 0.000 claims description 2
- HZPKNSYIDSNZKW-UHFFFAOYSA-N Ethyl 2-methylpentanoate Chemical compound CCCC(C)C(=O)OCC HZPKNSYIDSNZKW-UHFFFAOYSA-N 0.000 claims description 2
- PDEQKAVEYSOLJX-UHFFFAOYSA-N Hexahydronerolidol Natural products C1C2C3(C)C2CC1C3(C)CCC=C(CO)C PDEQKAVEYSOLJX-UHFFFAOYSA-N 0.000 claims description 2
- FSOGIJPGPZWNGO-UHFFFAOYSA-N Meomammein Natural products CCC(C)C(=O)C1=C(O)C(CC=C(C)C)=C(O)C2=C1OC(=O)C=C2CCC FSOGIJPGPZWNGO-UHFFFAOYSA-N 0.000 claims description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N Salicylic acid Natural products OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 2
- QLRICECRKJGSKQ-SDNWHVSQSA-N [(2e)-3,7-dimethylocta-2,6-dienyl] 2-aminobenzoate Chemical compound CC(C)=CCC\C(C)=C\COC(=O)C1=CC=CC=C1N QLRICECRKJGSKQ-SDNWHVSQSA-N 0.000 claims description 2
- 230000003213 activating effect Effects 0.000 claims description 2
- PDEQKAVEYSOLJX-AIEDFZFUSA-N alpha-Santalol Natural products CC(=CCC[C@@]1(C)[C@H]2C[C@@H]3[C@H](C2)[C@]13C)CO PDEQKAVEYSOLJX-AIEDFZFUSA-N 0.000 claims description 2
- UZFLPKAIBPNNCA-BQYQJAHWSA-N alpha-ionone Chemical compound CC(=O)\C=C\C1C(C)=CCCC1(C)C UZFLPKAIBPNNCA-BQYQJAHWSA-N 0.000 claims description 2
- JZQOJFLIJNRDHK-CMDGGOBGSA-N alpha-irone Chemical compound CC1CC=C(C)C(\C=C\C(C)=O)C1(C)C JZQOJFLIJNRDHK-CMDGGOBGSA-N 0.000 claims description 2
- PDEQKAVEYSOLJX-BKKZDLJQSA-N alpha-santalol Chemical compound C1C2[C@]3(C)C2C[C@H]1[C@@]3(C)CC/C=C(CO)/C PDEQKAVEYSOLJX-BKKZDLJQSA-N 0.000 claims description 2
- 229940062909 amyl salicylate Drugs 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims description 2
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 claims description 2
- AHZYNUWTBDLJHG-RHBQXOTJSA-N cedryl formate Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1[C@@](OC=O)(C)CC2 AHZYNUWTBDLJHG-RHBQXOTJSA-N 0.000 claims description 2
- 235000000484 citronellol Nutrition 0.000 claims description 2
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- NYNCZOLNVTXTTP-UHFFFAOYSA-N ethyl 2-(1,3-dioxoisoindol-2-yl)acetate Chemical compound C1=CC=C2C(=O)N(CC(=O)OCC)C(=O)C2=C1 NYNCZOLNVTXTTP-UHFFFAOYSA-N 0.000 claims description 2
- WGPCZPLRVAWXPW-LLVKDONJSA-N gamma-Dodecalactone Natural products CCCCCCCC[C@@H]1CCC(=O)O1 WGPCZPLRVAWXPW-LLVKDONJSA-N 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 2
- 229960004889 salicylic acid Drugs 0.000 claims description 2
- 239000000344 soap Substances 0.000 claims description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims 2
- WLJVXDMOQOGPHL-PPJXEINESA-N 2-phenylacetic acid Chemical compound O[14C](=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-PPJXEINESA-N 0.000 claims 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims 1
- 235000017491 Bambusa tulda Nutrition 0.000 claims 1
- 241001330002 Bambuseae Species 0.000 claims 1
- 239000005711 Benzoic acid Substances 0.000 claims 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 1
- 241000218646 Cedrus deodara Species 0.000 claims 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims 1
- 150000004996 alkyl benzenes Chemical class 0.000 claims 1
- 239000011425 bamboo Substances 0.000 claims 1
- 235000010233 benzoic acid Nutrition 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- 239000002304 perfume Substances 0.000 abstract description 12
- 229910019142 PO4 Inorganic materials 0.000 abstract description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 3
- 239000010452 phosphate Substances 0.000 abstract description 3
- 238000005282 brightening Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 14
- 239000002585 base Substances 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 8
- 241000193830 Bacillus <bacterium> Species 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 241000894006 Bacteria Species 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- 241000233866 Fungi Species 0.000 description 6
- 229920002873 Polyethylenimine Polymers 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 102000003992 Peroxidases Human genes 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 108040007629 peroxidase activity proteins Proteins 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 241001480714 Humicola insolens Species 0.000 description 4
- 241000589516 Pseudomonas Species 0.000 description 4
- 238000007385 chemical modification Methods 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 108010005400 cutinase Proteins 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 102000004169 proteins and genes Human genes 0.000 description 4
- 108090000623 proteins and genes Proteins 0.000 description 4
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 4
- CZCBTSFUTPZVKJ-UHFFFAOYSA-N rose oxide Chemical compound CC1CCOC(C=C(C)C)C1 CZCBTSFUTPZVKJ-UHFFFAOYSA-N 0.000 description 4
- 239000004382 Amylase Substances 0.000 description 3
- 108010065511 Amylases Proteins 0.000 description 3
- 102000013142 Amylases Human genes 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 241000223198 Humicola Species 0.000 description 3
- 102100037611 Lysophospholipase Human genes 0.000 description 3
- 108020002496 Lysophospholipase Proteins 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 235000019418 amylase Nutrition 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical class COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- QUMXDOLUJCHOAY-UHFFFAOYSA-N 1-Phenylethyl acetate Chemical compound CC(=O)OC(C)C1=CC=CC=C1 QUMXDOLUJCHOAY-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 2-octanone Chemical compound CCCCCCC(C)=O ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- FUDNBFMOXDUIIE-UHFFFAOYSA-N 3,7-dimethylocta-1,6-diene Chemical compound C=CC(C)CCC=C(C)C FUDNBFMOXDUIIE-UHFFFAOYSA-N 0.000 description 2
- OIGWAXDAPKFNCQ-UHFFFAOYSA-N 4-isopropylbenzyl alcohol Chemical compound CC(C)C1=CC=C(CO)C=C1 OIGWAXDAPKFNCQ-UHFFFAOYSA-N 0.000 description 2
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 2
- 241001019659 Acremonium <Plectosphaerellaceae> Species 0.000 description 2
- 241000194103 Bacillus pumilus Species 0.000 description 2
- HVJKZICIMIWFCP-UHFFFAOYSA-N Benzyl 3-methylbutanoate Chemical compound CC(C)CC(=O)OCC1=CC=CC=C1 HVJKZICIMIWFCP-UHFFFAOYSA-N 0.000 description 2
- UYWQUFXKFGHYNT-UHFFFAOYSA-N Benzylformate Chemical compound O=COCC1=CC=CC=C1 UYWQUFXKFGHYNT-UHFFFAOYSA-N 0.000 description 2
- 241000589513 Burkholderia cepacia Species 0.000 description 2
- 241000723346 Cinnamomum camphora Species 0.000 description 2
- 241000222511 Coprinus Species 0.000 description 2
- 244000251987 Coprinus macrorhizus Species 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 241000223218 Fusarium Species 0.000 description 2
- 241000223221 Fusarium oxysporum Species 0.000 description 2
- 241000193385 Geobacillus stearothermophilus Species 0.000 description 2
- 244000178870 Lavandula angustifolia Species 0.000 description 2
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 2
- IYTXKIXETAELAV-UHFFFAOYSA-N Nonan-3-one Chemical compound CCCCCCC(=O)CC IYTXKIXETAELAV-UHFFFAOYSA-N 0.000 description 2
- ZYEMGPIYFIJGTP-UHFFFAOYSA-N O-methyleugenol Chemical compound COC1=CC=C(CC=C)C=C1OC ZYEMGPIYFIJGTP-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 241000589540 Pseudomonas fluorescens Species 0.000 description 2
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 241000223258 Thermomyces lanuginosus Species 0.000 description 2
- 241001494489 Thielavia Species 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 101150039403 ams gene Proteins 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 239000003715 calcium chelating agent Substances 0.000 description 2
- 150000001767 cationic compounds Chemical class 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 229960001484 edetic acid Drugs 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- 239000002979 fabric softener Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000002538 fungal effect Effects 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- AOGQPLXWSUTHQB-UHFFFAOYSA-N hexyl acetate Chemical compound CCCCCCOC(C)=O AOGQPLXWSUTHQB-UHFFFAOYSA-N 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000001102 lavandula vera Substances 0.000 description 2
- 235000018219 lavender Nutrition 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- VAMXMNNIEUEQDV-UHFFFAOYSA-N methyl anthranilate Chemical compound COC(=O)C1=CC=CC=C1N VAMXMNNIEUEQDV-UHFFFAOYSA-N 0.000 description 2
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
- VKCYHJWLYTUGCC-UHFFFAOYSA-N nonan-2-one Chemical compound CCCCCCCC(C)=O VKCYHJWLYTUGCC-UHFFFAOYSA-N 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- PGMYKACGEOXYJE-UHFFFAOYSA-N pentyl acetate Chemical compound CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 2
- MDHYEMXUFSJLGV-UHFFFAOYSA-N phenethyl acetate Chemical compound CC(=O)OCCC1=CC=CC=C1 MDHYEMXUFSJLGV-UHFFFAOYSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- 229930007790 rose oxide Natural products 0.000 description 2
- ZMQAAUBTXCXRIC-UHFFFAOYSA-N safrole Chemical compound C=CCC1=CC=C2OCOC2=C1 ZMQAAUBTXCXRIC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229940057950 sodium laureth sulfate Drugs 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 2
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 235000021286 stilbenes Nutrition 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- 210000004885 white matter Anatomy 0.000 description 2
- NZGWDASTMWDZIW-MRVPVSSYSA-N (+)-pulegone Chemical compound C[C@@H]1CCC(=C(C)C)C(=O)C1 NZGWDASTMWDZIW-MRVPVSSYSA-N 0.000 description 1
- NFLGAXVYCFJBMK-IUCAKERBSA-N (-)-isomenthone Chemical compound CC(C)[C@@H]1CC[C@H](C)CC1=O NFLGAXVYCFJBMK-IUCAKERBSA-N 0.000 description 1
- 239000001303 (5-methyl-2-prop-1-en-2-ylcyclohexyl) acetate Substances 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- WUOACPNHFRMFPN-SECBINFHSA-N (S)-(-)-alpha-terpineol Chemical compound CC1=CC[C@@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-SECBINFHSA-N 0.000 description 1
- UFLHIIWVXFIJGU-ARJAWSKDSA-N (Z)-hex-3-en-1-ol Chemical compound CC\C=C/CCO UFLHIIWVXFIJGU-ARJAWSKDSA-N 0.000 description 1
- LRGXCBHOBRUTJN-UHFFFAOYSA-N 1,1'-biphenyl;sodium Chemical compound [Na].[Na].C1=CC=CC=C1C1=CC=CC=C1 LRGXCBHOBRUTJN-UHFFFAOYSA-N 0.000 description 1
- JLIDRDJNLAWIKT-UHFFFAOYSA-N 1,2-dimethyl-3h-benzo[e]indole Chemical compound C1=CC=CC2=C(C(=C(C)N3)C)C3=CC=C21 JLIDRDJNLAWIKT-UHFFFAOYSA-N 0.000 description 1
- KCZIUKYAJJEIQG-UHFFFAOYSA-N 1,3,5-triazin-2-amine Chemical class NC1=NC=NC=N1 KCZIUKYAJJEIQG-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- SEXKDZSOKXPFFH-UHFFFAOYSA-N 1-(2-benzoylphenyl)ethanone Chemical compound CC(=O)C1=CC=CC=C1C(=O)C1=CC=CC=C1 SEXKDZSOKXPFFH-UHFFFAOYSA-N 0.000 description 1
- CHLICZRVGGXEOD-UHFFFAOYSA-N 1-Methoxy-4-methylbenzene Chemical compound COC1=CC=C(C)C=C1 CHLICZRVGGXEOD-UHFFFAOYSA-N 0.000 description 1
- HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 description 1
- BFNMZJQMWPPBKE-UHFFFAOYSA-N 1-oxo-3h-2-benzofuran-4-carbonitrile Chemical compound C1=CC=C(C#N)C2=C1C(=O)OC2 BFNMZJQMWPPBKE-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- WNJSKZBEWNVKGU-UHFFFAOYSA-N 2,2-dimethoxyethylbenzene Chemical compound COC(OC)CC1=CC=CC=C1 WNJSKZBEWNVKGU-UHFFFAOYSA-N 0.000 description 1
- ZIIUUSVHCHPIQD-UHFFFAOYSA-N 2,4,6-trimethyl-N-[3-(trifluoromethyl)phenyl]benzenesulfonamide Chemical compound CC1=CC(C)=CC(C)=C1S(=O)(=O)NC1=CC=CC(C(F)(F)F)=C1 ZIIUUSVHCHPIQD-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- MZZRKEIUNOYYDF-UHFFFAOYSA-N 2,4-dimethylcyclohex-3-ene-1-carbaldehyde Chemical compound CC1C=C(C)CCC1C=O MZZRKEIUNOYYDF-UHFFFAOYSA-N 0.000 description 1
- 239000001278 2-(5-ethenyl-5-methyloxolan-2-yl)propan-2-ol Substances 0.000 description 1
- RNDNSYIPLPAXAZ-UHFFFAOYSA-N 2-Phenyl-1-propanol Chemical compound OCC(C)C1=CC=CC=C1 RNDNSYIPLPAXAZ-UHFFFAOYSA-N 0.000 description 1
- RCSBILYQLVXLJG-UHFFFAOYSA-N 2-Propenyl hexanoate Chemical compound CCCCCC(=O)OCC=C RCSBILYQLVXLJG-UHFFFAOYSA-N 0.000 description 1
- QGLVWTFUWVTDEQ-UHFFFAOYSA-N 2-chloro-3-methoxyphenol Chemical compound COC1=CC=CC(O)=C1Cl QGLVWTFUWVTDEQ-UHFFFAOYSA-N 0.000 description 1
- XWRBMHSLXKNRJX-UHFFFAOYSA-N 2-ethenyl-1-oxidopyridin-1-ium Chemical class [O-][N+]1=CC=CC=C1C=C XWRBMHSLXKNRJX-UHFFFAOYSA-N 0.000 description 1
- YRNDGUSDBCARGC-UHFFFAOYSA-N 2-methoxyacetophenone Chemical compound COCC(=O)C1=CC=CC=C1 YRNDGUSDBCARGC-UHFFFAOYSA-N 0.000 description 1
- RIWRBSMFKVOJMN-UHFFFAOYSA-N 2-methyl-1-phenylpropan-2-ol Chemical compound CC(C)(O)CC1=CC=CC=C1 RIWRBSMFKVOJMN-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- BJLRAKFWOUAROE-UHFFFAOYSA-N 2500-83-6 Chemical compound C12C=CCC2C2CC(OC(=O)C)C1C2 BJLRAKFWOUAROE-UHFFFAOYSA-N 0.000 description 1
- ZHDQGHCZWWDMRS-UHFFFAOYSA-N 3,5-dimethylcyclohex-3-ene-1-carbaldehyde Chemical compound CC1CC(C=O)CC(C)=C1 ZHDQGHCZWWDMRS-UHFFFAOYSA-N 0.000 description 1
- 239000001623 3-phenylprop-2-enyl formate Substances 0.000 description 1
- GNKZMNRKLCTJAY-UHFFFAOYSA-N 4'-Methylacetophenone Chemical compound CC(=O)C1=CC=C(C)C=C1 GNKZMNRKLCTJAY-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- AJIZFKGVFSUKIP-UHFFFAOYSA-N 4-morpholin-4-yl-n-phenyl-1,3,5-triazin-2-amine Chemical compound C1COCCN1C1=NC=NC(NC=2C=CC=CC=2)=N1 AJIZFKGVFSUKIP-UHFFFAOYSA-N 0.000 description 1
- YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 101100313763 Arabidopsis thaliana TIM22-2 gene Proteins 0.000 description 1
- 241000194108 Bacillus licheniformis Species 0.000 description 1
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 235000014469 Bacillus subtilis Nutrition 0.000 description 1
- 102100032487 Beta-mannosidase Human genes 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- 235000011293 Brassica napus Nutrition 0.000 description 1
- 240000008100 Brassica rapa Species 0.000 description 1
- 235000000540 Brassica rapa subsp rapa Nutrition 0.000 description 1
- YCSMVPSDJIOXGN-UHFFFAOYSA-N CCCCCCCCCCCC[Na] Chemical compound CCCCCCCCCCCC[Na] YCSMVPSDJIOXGN-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000005973 Carvone Substances 0.000 description 1
- 108010084185 Cellulases Proteins 0.000 description 1
- 102000005575 Cellulases Human genes 0.000 description 1
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 description 1
- 241000040710 Chela Species 0.000 description 1
- 241000675108 Citrus tangerina Species 0.000 description 1
- 235000001673 Coprinus macrorhizus Nutrition 0.000 description 1
- XHXUANMFYXWVNG-UHFFFAOYSA-N D-menthyl acetate Natural products CC(C)C1CCC(C)CC1OC(C)=O XHXUANMFYXWVNG-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical class NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 240000002943 Elettaria cardamomum Species 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 1
- 244000004281 Eucalyptus maculata Species 0.000 description 1
- 239000005770 Eugenol Substances 0.000 description 1
- 239000005792 Geraniol Substances 0.000 description 1
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 1
- 102100031415 Hepatic triacylglycerol lipase Human genes 0.000 description 1
- OUGPMNMLWKSBRI-UHFFFAOYSA-N Hexyl formate Chemical compound CCCCCCOC=O OUGPMNMLWKSBRI-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- HLHIVJRLODSUCI-ADEWGFFLSA-N Isopulegol acetate Chemical compound C[C@@H]1CC[C@@H](C(C)=C)[C@H](OC(C)=O)C1 HLHIVJRLODSUCI-ADEWGFFLSA-N 0.000 description 1
- 102100027612 Kallikrein-11 Human genes 0.000 description 1
- BRHDDEIRQPDPMG-UHFFFAOYSA-N Linalyl oxide Chemical compound CC(C)(O)C1CCC(C)(C=C)O1 BRHDDEIRQPDPMG-UHFFFAOYSA-N 0.000 description 1
- 108010013563 Lipoprotein Lipase Proteins 0.000 description 1
- 102000004317 Lyases Human genes 0.000 description 1
- 108090000856 Lyases Proteins 0.000 description 1
- 235000014749 Mentha crispa Nutrition 0.000 description 1
- 244000078639 Mentha spicata Species 0.000 description 1
- 102000005741 Metalloproteases Human genes 0.000 description 1
- 108010006035 Metalloproteases Proteins 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- FRLZQXRXIKQFNS-UHFFFAOYSA-N Methyl 2-octynoate Chemical compound CCCCCC#CC(=O)OC FRLZQXRXIKQFNS-UHFFFAOYSA-N 0.000 description 1
- GLZPCOQZEFWAFX-JXMROGBWSA-N Nerol Natural products CC(C)=CCC\C(C)=C\CO GLZPCOQZEFWAFX-JXMROGBWSA-N 0.000 description 1
- 241000208181 Pelargonium Species 0.000 description 1
- 240000009164 Petroselinum crispum Species 0.000 description 1
- 235000002770 Petroselinum crispum Nutrition 0.000 description 1
- ZOZIRNMDEZKZHM-UHFFFAOYSA-N Phenethyl phenylacetate Chemical compound C=1C=CC=CC=1CCOC(=O)CC1=CC=CC=C1 ZOZIRNMDEZKZHM-UHFFFAOYSA-N 0.000 description 1
- 102100035200 Phospholipase A and acyltransferase 4 Human genes 0.000 description 1
- 102100037883 Phospholipase B1, membrane-associated Human genes 0.000 description 1
- 102000011420 Phospholipase D Human genes 0.000 description 1
- 108090000553 Phospholipase D Proteins 0.000 description 1
- 108010064785 Phospholipases Proteins 0.000 description 1
- 102000015439 Phospholipases Human genes 0.000 description 1
- 108010058864 Phospholipases A2 Proteins 0.000 description 1
- 102000004861 Phosphoric Diester Hydrolases Human genes 0.000 description 1
- 108090001050 Phosphoric Diester Hydrolases Proteins 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 description 1
- 241000168225 Pseudomonas alcaligenes Species 0.000 description 1
- 241000589630 Pseudomonas pseudoalcaligenes Species 0.000 description 1
- 241000589774 Pseudomonas sp. Species 0.000 description 1
- 241000589614 Pseudomonas stutzeri Species 0.000 description 1
- 241000577556 Pseudomonas wisconsinensis Species 0.000 description 1
- NZGWDASTMWDZIW-UHFFFAOYSA-N Pulegone Natural products CC1CCC(=C(C)C)C(=O)C1 NZGWDASTMWDZIW-UHFFFAOYSA-N 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 244000143590 Salvia chinensis Species 0.000 description 1
- 235000007154 Salvia chinensis Nutrition 0.000 description 1
- 235000005794 Salvia japonica Nutrition 0.000 description 1
- 102000012479 Serine Proteases Human genes 0.000 description 1
- 108010022999 Serine Proteases Proteins 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 235000002594 Solanum nigrum Nutrition 0.000 description 1
- 240000002307 Solanum ptychanthum Species 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 241000223257 Thermomyces Species 0.000 description 1
- 241001313536 Thermothelomyces thermophila Species 0.000 description 1
- 241001495429 Thielavia terrestris Species 0.000 description 1
- 101710152431 Trypsin-like protease Proteins 0.000 description 1
- 102000014384 Type C Phospholipases Human genes 0.000 description 1
- 108010079194 Type C Phospholipases Proteins 0.000 description 1
- 244000126014 Valeriana officinalis Species 0.000 description 1
- 235000013832 Valeriana officinalis Nutrition 0.000 description 1
- 241000235017 Zygosaccharomyces Species 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- LRVDECHXXILTOV-UHFFFAOYSA-N acetic acid;2-methyl-1-phenylpropan-2-ol Chemical class CC(O)=O.CC(C)(O)CC1=CC=CC=C1 LRVDECHXXILTOV-UHFFFAOYSA-N 0.000 description 1
- WDJHALXBUFZDSR-UHFFFAOYSA-M acetoacetate Chemical compound CC(=O)CC([O-])=O WDJHALXBUFZDSR-UHFFFAOYSA-M 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000004450 alkenylene group Chemical group 0.000 description 1
- 125000005466 alkylenyl group Chemical group 0.000 description 1
- OOCCDEMITAIZTP-UHFFFAOYSA-N allylic benzylic alcohol Natural products OCC=CC1=CC=CC=C1 OOCCDEMITAIZTP-UHFFFAOYSA-N 0.000 description 1
- OVKDFILSBMEKLT-UHFFFAOYSA-N alpha-Terpineol Natural products CC(=C)C1(O)CCC(C)=CC1 OVKDFILSBMEKLT-UHFFFAOYSA-N 0.000 description 1
- 229940088601 alpha-terpineol Drugs 0.000 description 1
- USMNOWBWPHYOEA-UHFFFAOYSA-N alpha-thujone Natural products CC1C(=O)CC2(C(C)C)C1C2 USMNOWBWPHYOEA-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- DULCUDSUACXJJC-UHFFFAOYSA-N benzeneacetic acid ethyl ester Natural products CCOC(=O)CC1=CC=CC=C1 DULCUDSUACXJJC-UHFFFAOYSA-N 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 229960004365 benzoic acid Drugs 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 108010055059 beta-Mannosidase Proteins 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- OBNCKNCVKJNDBV-UHFFFAOYSA-N butanoic acid ethyl ester Natural products CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 229940084030 carboxymethylcellulose calcium Drugs 0.000 description 1
- 235000005300 cardamomo Nutrition 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- SVURIXNDRWRAFU-OGMFBOKVSA-N cedrol Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1[C@@](O)(C)CC2 SVURIXNDRWRAFU-OGMFBOKVSA-N 0.000 description 1
- 229940026455 cedrol Drugs 0.000 description 1
- PCROEXHGMUJCDB-UHFFFAOYSA-N cedrol Natural products CC1CCC2C(C)(C)C3CC(C)(O)CC12C3 PCROEXHGMUJCDB-UHFFFAOYSA-N 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229930007050 cineol Natural products 0.000 description 1
- 229960005233 cineole Drugs 0.000 description 1
- 239000001524 citrus aurantium oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 229920000891 common polymer Polymers 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- XSNQECSCDATQEL-UHFFFAOYSA-N dihydromyrcenol Chemical compound C=CC(C)CCCC(C)(C)O XSNQECSCDATQEL-UHFFFAOYSA-N 0.000 description 1
- 229930008394 dihydromyrcenol Natural products 0.000 description 1
- VUJGKADZTYCLIL-YHPRVSEPSA-L disodium;5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfonatophenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S([O-])(=O)=O)C(S(=O)(=O)[O-])=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 VUJGKADZTYCLIL-YHPRVSEPSA-L 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002085 enols Chemical class 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002168 ethanoic acid esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229960002217 eugenol Drugs 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 150000002190 fatty acyls Chemical group 0.000 description 1
- 125000001924 fatty-acyl group Chemical group 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 229940113087 geraniol Drugs 0.000 description 1
- RBNPOMFGQQGHHO-UHFFFAOYSA-N glyceric acid Chemical compound OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- WPFVBOQKRVRMJB-UHFFFAOYSA-N hydroxycitronellal Chemical compound O=CCC(C)CCCC(C)(C)O WPFVBOQKRVRMJB-UHFFFAOYSA-N 0.000 description 1
- 125000003392 indanyl group Chemical group C1(CCC2=CC=CC=C12)* 0.000 description 1
- SNWQUNCRDLUDEX-UHFFFAOYSA-N inden-1-one Chemical compound C1=CC=C2C(=O)C=CC2=C1 SNWQUNCRDLUDEX-UHFFFAOYSA-N 0.000 description 1
- 150000002469 indenes Chemical class 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- NFLGAXVYCFJBMK-UHFFFAOYSA-N isomenthone Natural products CC(C)C1CCC(C)CC1=O NFLGAXVYCFJBMK-UHFFFAOYSA-N 0.000 description 1
- VDBNYAPERZTOOF-UHFFFAOYSA-N isoquinolin-1(2H)-one Chemical compound C1=CC=C2C(=O)NC=CC2=C1 VDBNYAPERZTOOF-UHFFFAOYSA-N 0.000 description 1
- SVURIXNDRWRAFU-UHFFFAOYSA-N juniperanol Natural products C1C23C(C)CCC3C(C)(C)C1C(O)(C)CC2 SVURIXNDRWRAFU-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 150000002729 menthone derivatives Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- GVOWHGSUZUUUDR-UHFFFAOYSA-N methyl N-methylanthranilate Chemical class CNC1=CC=CC=C1C(=O)OC GVOWHGSUZUUUDR-UHFFFAOYSA-N 0.000 description 1
- 229940102398 methyl anthranilate Drugs 0.000 description 1
- 229940095102 methyl benzoate Drugs 0.000 description 1
- 229940116837 methyleugenol Drugs 0.000 description 1
- PRHTXAOWJQTLBO-UHFFFAOYSA-N methyleugenol Natural products COC1=CC=C(C(C)=C)C=C1OC PRHTXAOWJQTLBO-UHFFFAOYSA-N 0.000 description 1
- JPTOCTSNXXKSSN-UHFFFAOYSA-N methylheptenone Chemical compound CCCC=CC(=O)CC JPTOCTSNXXKSSN-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- ZOCHHNOQQHDWHG-UHFFFAOYSA-N n-hexan-3-ol Natural products CCCC(O)CC ZOCHHNOQQHDWHG-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- ZYDGQQTXLBNSGJ-UHFFFAOYSA-N oxonan-2-one Chemical compound O=C1CCCCCCCO1 ZYDGQQTXLBNSGJ-UHFFFAOYSA-N 0.000 description 1
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 1
- 229930007459 p-menth-8-en-3-one Natural products 0.000 description 1
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- TWSRVQVEYJNFKQ-UHFFFAOYSA-N pentyl propanoate Chemical compound CCCCCOC(=O)CC TWSRVQVEYJNFKQ-UHFFFAOYSA-N 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- HXITXNWTGFUOAU-UHFFFAOYSA-N phenylboronic acid Chemical class OB(O)C1=CC=CC=C1 HXITXNWTGFUOAU-UHFFFAOYSA-N 0.000 description 1
- 229940067107 phenylethyl alcohol Drugs 0.000 description 1
- WTJKGGKOPKCXLL-RRHRGVEJSA-N phosphatidylcholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCCC=CCCCCCCCC WTJKGGKOPKCXLL-RRHRGVEJSA-N 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- JMVWCCOXRGFPJZ-UHFFFAOYSA-N propoxyboronic acid Chemical compound CCCOB(O)O JMVWCCOXRGFPJZ-UHFFFAOYSA-N 0.000 description 1
- 150000003219 pyrazolines Chemical class 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 125000005493 quinolyl group Chemical group 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 229960005137 succinic acid Drugs 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000016788 valerian Nutrition 0.000 description 1
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 description 1
- YEIGUXGHHKAURB-UHFFFAOYSA-N viridine Natural products O=C1C2=C3CCC(=O)C3=CC=C2C2(C)C(O)C(OC)C(=O)C3=COC1=C23 YEIGUXGHHKAURB-UHFFFAOYSA-N 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本发明提供了一种水性液体非磷酸盐作为助剂的家用洗衣增白增亮组合物，其包含带电荷的表面活性剂、不带电荷的烷氧基化多芳基苯酚和香料。
Description
技术领域
本发明涉及增白和增亮洗衣组合物的用途。
发明背景
在家庭洗衣过程中期望保持和改善织物的白度和亮度。问题是从一件衣服上除去的污垢又沉积到另一件衣服上。该问题被衣服上和洗涤中存在的人油(皮脂)而加剧，其有助于增强洗涤中的污垢的沉积。该过程导致整个洗涤加载物的白度和清洁的整体损失。为了改善这个问题，分散聚合物例如烷氧基化聚乙烯亚胺已被广泛地加入到洗涤剂中。已知乙氧基化PEI(PEI＝聚乙烯亚胺)是来自CA1210009的抗再沉积聚合物。某些纤维素酶也通过改变棉织物的表面性质已经用于防止再沉积。Novozymes在WO02/099091和WO04/053039中描述了用于家庭洗衣的纤维素酶。
EP1321510(Shipley)描述了一种含有烷氧基化多芳基苯酚的工业清洁组合物，用于从制造半导体和其它电子器件和电路中使用的光致抗蚀剂中剥离有机化学残留物。有机化学残留物是生产过程中剩余的材料，包括光引发剂、热引发剂、丙烯酸和甲基丙烯酸单体。
发明内容
需要进一步的技术在家用洗衣产品中减少再沉积并增强清洁。
我们已经发现，不带电荷的烷氧基化多芳基苯酚在家庭洗衣过程中增强衣服的白度和亮度。
在一个方面，本发明提供了非磷酸盐作为助剂的洗衣用洗涤剂，其包含：
(i)带电荷的表面活性剂，带电荷的表面活性剂的水平优选为4-50重量％，更优选6-30重量％，最优选8-20重量％；
(ii)不带电荷的烷氧基化多芳基苯酚，其优选为0.1-20重量％，更优选0.5-10重量％，最优选2-9重量％的水平；和
(iii)香料，优选0.05-0.5重量％的香料；其中所述洗衣用洗涤剂是水性液体洗衣用洗涤剂。
在另一方面，本发明提供了非磷酸盐作为助剂的洗衣用洗涤剂，其包含：
(i)4-50重量％、更优选6-30重量％、最优选8-20重量％的阴离子表面活性剂，其选自：直链烷基苯磺酸盐、烷基硫酸盐、烷基醚硫酸盐及其混合物；
(ii)0.5-10重量％、优选2-9重量％的具有以下结构的不带电荷的烷氧基化多芳基苯酚：
其中n选自：10、11、12、13、14、15、16、17、18、19、20、21、22、23、24、25、26、27、28、29、30、31、32、33、34、35、36、37、38、39、40、41、42、43、44、45、46、47、48、49、50、51、52、53和54；和
(iii)香料，优选0.05-0.5重量％的香料；其中所述洗衣用洗涤剂是水性液体洗衣用洗涤剂。
在另一方面，本发明提供了处理织物的家用方法，所述方法包括以下步骤：
(i)用不带电荷的烷氧基化多芳基苯酚的水溶液处理织物，所述水溶液包含10ppm至5000ppm的不带电荷的烷氧基化多芳基苯酚；和至多6g/L、优选0.2-4g/L的一种或多种表面活性剂；和
(ii)任选地漂洗和干燥所述织物。
在该方法中，水溶液中香料的水平优选为0.1-100ppm，更优选1-10ppm。
在本发明的方法方面中，所用的表面活性剂优选为在本发明的组合物方面优选的。
织物优选是衣服、床上用品或桌布的一项。优选的衣服是含棉衬衫、裤子、内衣和连裤装(jumper)。
发明详述
烷氧基化多芳基苯酚
优选地，不带电荷的(中性的)烷氧基化多芳基苯酚是烷氧基化三苯乙烯基苯酚。
优选地，烷氧基化三苯乙烯基苯酚是聚乙二醇单(2,4,6-三(1-苯乙基)苯基)醚。优选地，烷氧基化多芳基苯酚含有平均2-70个烷氧基，最优选10-54个烷氧基。
优选地，烷氧基化是乙氧基化。
优选地，烷氧基化多芳基苯酚具有连接到苯酚上的2或3个芳基。优选地，它们在苯酚上的2、4位或2、4、6位。烷氧基化部分连接到1位。优选地，烷氧基化部分被氢原子封端。
烷氧基化多芳基苯酚中的芳基优选选自苯基、甲苯基、萘基、四氢萘基、茚满基、茚基、苯乙烯基、吡啶基、喹啉基及其混合物。
最优选地，烷氧基化多芳基苯酚是具有以下结构的聚乙二醇单(2,4,6-三(1-苯乙基)苯基)醚(CAS号：70559-25-0)：
优选n＝2-70，更优选n＝10-54，最优选n＝16和n＝20。符号n是聚烷氧基链中烷氧基单元的平均摩尔数。
化合物可从工业供应商获得，例如来自Rhodia的商品名Soprophor；来自Clariant的商品名Emulsogen；Aoki Oil实业公司的商品名Blaunon；来自Stepan的商品名Makon；来自TOHO化学工业公司的商品名Sorpol。
在本发明的上下文中，烷氧基化多芳基苯酚不被认为是表面活性剂，并且不对本文定义的表面活性剂在数值上起作用。
表面活性剂
洗衣组合物包含带电荷的表面活性剂，并且最优选带电荷的表面活性剂是阴离子表面活性剂(其包括其的混合物)。
可以使用的合适的阴离子洗涤剂化合物通常是具有含约8至约22个碳原子的烷基的有机硫酸和磺酸的水溶性碱金属盐，术语烷基用于包括高级烷基的烷基部分。
合适的合成阴离子洗涤剂化合物的实例是烷基硫酸钠和烷基硫酸钾，特别是通过硫酸化例如由牛油或椰子油制得的高级C8-C18醇获得的那些，C9-C20烷基苯磺酸钠和C9-C20烷基苯磺酸钾，特别是直链仲烷基C10-C15苯磺酸钠；和烷基甘油醚硫酸钠，特别是衍生自牛油或椰子油的高级醇和衍生自石油的合成醇的那些醚。
阴离子表面活性剂优选选自：直链烷基苯磺酸盐、烷基硫酸盐、烷基醚硫酸盐、皂、烷基(优选甲基)酯磺酸盐及其混合物。
最优选的阴离子表面活性剂选自：直链烷基苯磺酸盐、烷基硫酸盐、烷基醚硫酸盐及其混合物。优选地，烷基醚硫酸盐是平均具有1至3个EO(乙氧基化物)单元的C12-C14正烷基醚硫酸盐。月桂基醚硫酸钠是特别优选的(SLES)。优选地，直链烷基苯磺酸盐是C11-C15烷基苯磺酸钠。优选地，烷基硫酸盐是直链或支链C12-C18烷基硫酸钠。十二烷基硫酸钠是特别优选的(SDS，也称为伯烷基硫酸盐)。
洗衣组合物中的阴离子表面活性剂的水平优选为4-50重量％，更优选为6-30重量％，且最优选为8-20重量％。
优选存在两种或更多种阴离子表面活性剂，例如直链烷基苯磺酸盐与烷基醚硫酸盐。
优选地，除了阴离子表面活性剂之外，洗衣组合物还包含烷基乙氧基化的非离子表面活性剂，优选2-8重量％的烷基烷氧基化的，优选乙氧基化的非离子表面活性剂。
可以使用的合适的非离子洗涤剂化合物特别包括具有脂族疏水基团和反应性氢原子的化合物的反应产物，例如脂族醇、酸或酰胺，特别是单独的环氧乙烷或环氧乙烷与环氧丙烷。具体的非离子洗涤剂化合物是脂族C8-C18伯或仲直链或支链醇与环氧乙烷的缩合产物。
优选地，烷基乙氧基化非离子表面活性剂是平均乙氧基化度为7EO至9EO单元的C8-C18伯醇。
表面活性剂体系的非离子和阴离子表面活性剂可以选自描述于“Surface ActiveAgents”卷1,Schwartz&Perry,Interscience 1949,卷2,Schwartz,Perry&Berch,Interscience 1958,由Manufacturing Confectioners公司出版的“McCutcheon'sEmulsifiers and Detergents”的当前版本或“Tenside-Taschenbuch”,H.Stache，第2版，Carl Hauser Verlag,1981中的表面活性剂。
优选地，使用的表面活性剂是饱和的。
还可使用例如EP-A-328 177(Unilever)中描述的表现出抗盐析性的那些表面活性剂、EP-A-070 074中描述的烷基多糖苷表面活性剂和烷基单糖苷。
在另一方面，带电荷的表面活性剂可以是阳离子的，使得制剂是织物调理剂。然而，基于阴离子或阴离子/非离子表面活性剂的洗涤剂组合物是更优选的实施方案。
阳离子化合物
当本发明用作织物调理剂时，它需要含有阳离子化合物。
最优选的是季铵化合物。
如果季铵化合物是具有至少一个C12至C22烷基链的季铵化合物，则是有利的。
优选地，季铵化合物具有下式：
其中R1是C12-C22烷基或烯基链；R2、R3和R4独立地选自C1-C4烷基链，且X-是相容的阴离子。这种类型的优选化合物是季铵化合物十六烷基三甲基季铵溴化物。
用于本发明的第二类材料是上述结构的季铵，其中R1和R2独立地选自C12-C22烷基或烯基链；R3和R4独立地选自C1-C4烷基链，且X-是相容的阴离子。
组合物任选地包含硅树脂。
助洗剂或络合剂
助洗剂材料可以选自1)钙螯合剂材料，2)沉淀材料，3)钙离子交换材料和4)其混合物。
钙螯合剂助洗剂材料的实例包括碱金属多磷酸盐例如三聚磷酸钠，和有机多价螯合剂例如乙二胺四乙酸。
沉淀助剂材料的实例包括正磷酸钠和碳酸钠。
组合物还可以含有0-65％的助洗剂或络合剂，例如乙二胺四乙酸、二亚乙基三胺五乙酸、烷基或烯基琥珀酸、次氮基三乙酸或下面提及的其他助洗剂。由于具有络合金属离子的能力，许多助洗剂也是漂白稳定剂。
优选地，洗衣用洗涤剂制剂是非磷酸盐作为助剂的衣物洗涤剂制剂，即含有小于1重量％的磷酸盐。
洗衣用洗涤剂是水性液体洗衣用洗涤剂，优选具有7-9的pH。
在水性液体洗衣用洗涤剂中，优选单丙二醇以1-30重量％，最优选2-18重量％的水平存在，以提供具有适当的可倾倒粘度的制剂。
荧光剂
组合物优选包含荧光剂(荧光增白剂)。荧光剂是众所周知的，许多这样的荧光剂可商购获得。通常，这些荧光剂以其碱金属盐例如钠盐的形式提供和使用。
优选类型的荧光剂是：二苯乙烯基联苯化合物例如Tinopal(商标)CBS-X，二胺芪二磺酸化合物例如Tinopal DMS pure Xtra和Blankophor(商标)HRH，以及吡唑啉化合物例如Blankophor SN。
优选的荧光剂是：2-(4-苯乙烯基-3-磺基苯基)-2H-萘酚[1,2-d]三唑钠，4,4'-双{[(4-苯胺基-6-(N甲基-N-2-羟乙基)氨基1,3,5-三嗪-2-基)]氨基}芪-2-2'二磺酸二钠，4,4'-双{[(4-苯胺基-6-吗啉代-1,3,5-三嗪-2-基)]氨基}芪-2-2'-二磺酸二钠和4,4'-双(2-磺基苯乙烯基)联苯二钠。
香料
组合物包含香料。香料优选范围为0.001-3重量％，更优选0.05-0.5重量％，最优选0.1-1重量％。许多合适的香料实例提供在由CFTA Publications出版的CTFA(Cosmetic，Toiletry and Fragrance Association)1992International Buyers Guide和由SchnellPublishing Co.出版的OPD 1993Chemicals Buyers Directory 80th Annual Edition中。
优选地，香料包含以下至少一种香料(化合物)：α-异甲基紫罗兰酮，水杨酸苄酯；香茅醇；香豆素；己基肉桂醛；芳樟醇；2-甲基戊酸乙酯；辛醛；乙酸苄酯；3,7-二甲基-1,6-辛二烯-3-醇-3-乙酸酯；2-(1,1-二甲基乙基)-环己醇-1-乙酸酯；δ-突厥酮(delta-damascone)；β-紫罗兰酮；乙酸三环癸烯酯；十二烷醛；己基肉桂醛；环十五内酯；苯乙酸，2-苯基乙基酯；水杨酸戊酯；β-石竹烯；十一碳烯酸乙酯；邻氨基苯甲酸香叶酯；α-鸢尾酮；苯甲酸β-苯乙酯；α-檀香醇；雪松醇；醋酸柏木酯；甲酸柏木酯；水杨酸环己酯；γ-十二内酯；和苯乙酸β-苯乙酯。
香料的有用组分包括天然和合成来源的材料。它们包括单一化合物和混合物。这些组分的具体实例可以在现有文献中找到，例如Fenaroli's Handbook of FlavorIngredients,1975,CRC Press；Synthetic Food Adjuncts,1947,作者M.B.Jacobs,编辑Van Nostrand；或Perfume and Flavor Chemicals,S.Arctander 1969,Montclair,N.J.(USA)。
通常，多种香料组分存在于制剂中。在本发明的组合物中，设想将存在四种或更多种，优选五种或更多种，更优选六种或更多种或甚至七种或更多种不同的香料组分。
在香料混合物中，优选15-25重量％是头香香料。头香香料由Poucher(Journal ofthe Society of Cosmetic Chemists 6(2)：80[1955])定义。优选的头香香料选自柑橘油、芳樟醇、乙酸芳樟酯、薰衣草、二氢月桂烯醇、玫瑰醚和顺式-3-己醇。
国际香料协会在2011年公布了芳香成分(香料)的列表(http://www.ifraorg.org/en-us/ingredients#.U7Z4hPldWzk)。
芳香材料研究所提供了有安全信息的香料(芳香剂)数据库。
香料头香香料可用于提示本发明的白度和亮度益处。
一些或所有香料可以被包封，有利于包封的典型的香料组分包括具有相对低沸点的那些，优选沸点小于300℃、优选100-250℃的那些。还有利的是包封具有低CLog P(即具有被分配到水中的更大倾向的那些)，优选具有小于3.0的CLog P的香料组分。这些具有相对低沸点和相对低CLogP的材料被称为“延迟释香”香料成分，并且包括一种或多种以下材料：
己酸烯丙酯、乙酸戊酯、丙酸戊酯、大茴香醛、苯甲醚、苯甲醛、乙酸苄酯、苄基丙酮、苯甲醇、甲酸苄酯、异戊酸苄酯、丙酸苄酯、β-γ-己烯醇、樟脑胶、左旋香芹酮、d-香芹酮、肉桂醇、甲酸肉桂酯、顺式-茉莉酮、顺式-3-己烯基乙酸酯、孜然醇、2,4-二甲基-3-环己-1-烯羰醛(cyclal C)、二甲基苄基甲醇、二甲基苄基甲醇乙酸酯、乙酸乙酯、乙酰乙酸乙酯、乙基戊基酮、苯甲酸乙酯、丁酸乙酯、乙基己基酮、苯乙酸乙酯、桉油醇、丁子香酚、乙酸葑酯、弗洛尔(Flor)乙酸酯(乙酸三环癸烯基酯)、Frutene(丙酸三环癸烯基酯)、香叶醇、己烯醇、乙酸己烯酯、乙酸己酯、甲酸己酯、龙葵醇(Hydratropic Alcohol)、羟基香茅醛、二氢茚酮、异戊醇、异薄荷酮、乙酸异胡薄荷酯、异喹诺酮、女贞醛、芳樟醇、芳樟醇氧化物、甲酸芳樟酯、薄荷酮、薄荷基乙酰苯酮、甲基戊基酮、邻氨基苯甲酸甲酯、苯甲酸甲酯、苯乙酸甲酯、甲基丁香酚、甲基庚烯酮、庚炔羧酸甲酯、甲基庚基酮、甲基己基酮、乙酸甲基苯基原酯、水杨酸甲酯、甲基-n-甲基邻氨基苯甲酸酯、橙花醇、辛内酯、辛醇、对甲酚、对甲酚甲醚、对甲氧基苯乙酮、对甲基苯乙酮、苯氧基乙醇、苯基乙醛、苯基乙基乙酸酯、苯基乙基醇、苯基乙基二甲基甲醇、乙酸戊烯酯、硼酸丙酯、蒲勒酮、玫瑰醚、黄樟素、4-萜品醇、α-萜品醇和/或锰红柱石。通常，多种香料组分存在于制剂中。在本发明的组合物中，设想将存在四种或更多种，优选五种或更多种，更优选六种或更多种，或甚至七种或更多种不同的香料组分，其来自上面给出的延迟释香香料。
本发明可以应用的另一组香料是所谓的“芳香疗法”材料。这些包括也用于香料中的许多组分，包括精油组分，例如鼠尾草、桉树、天竺葵、薰衣草、肉豆蔻提取物、橙花油、肉豆蔻、绿薄荷、甜紫叶和缬草。
优选的是，洗衣处理组合物不含有过氧漂白剂，例如过碳酸钠、过硼酸钠和过酸。
聚合物
组合物可以包含一种或多种另外的聚合物。实例是羧甲基纤维素，聚(乙二醇)，聚(乙烯醇)，聚羧酸酯如聚丙烯酸酯，马来酸/丙烯酸共聚物和甲基丙烯酸月桂酯/丙烯酸共聚物。
可存在用于防止染料沉积的聚合物，例如聚(乙烯基吡咯烷酮)、聚(乙烯基吡啶-N-氧化物)和聚(乙烯基咪唑)。
酶
当实施本发明的方法时一种或多种酶优选存在于本发明的洗衣组合物中。
优选地，本发明的洗衣组合物中每种酶的水平为0.0001重量％至0.1重量％的蛋白质。
优选地，酶选自：蛋白酶、脂肪酶和纤维素酶，优选蛋白酶。
特别考虑的酶包括蛋白酶、α-淀粉酶、纤维素酶、脂肪酶、过氧化物酶/氧化酶、果胶酸裂合酶和甘露聚糖酶或其混合物。
合适的脂肪酶包括细菌或真菌来源的那些。包括化学修饰或蛋白质工程改造的突变体。有用的脂肪酶的实例包括来自腐质霉属(Humicola)(同义词嗜热霉属(Thermomyces))的脂肪酶，如来自EP 258068和EP 305 216中所述的H.lanuginosa(疏棉状嗜热真菌属(T.lanuginosus))，或来自WO 96/13580中所述的特异腐质霉(H.insolens)，假单胞菌属(Pseudomonas)脂肪酶，例如来自产碱假杆属菌(P.alcaligenes)或假产碱假单胞菌属(P.pseudoalcaligenes)(EP 218272)，洋葱假单胞菌(P.cepacia)(EP 331 376)，施氏假单胞菌(P.stutzeri)(GB 1,372,034)，荧光假单胞菌(P.fluorescens)，假单胞菌菌株SD705(Pseudomonas sp.strain SD 705)(WO 95/06720和WO 96/27002)，威斯康星假单胞菌属(P.wisconsinensis)(WO 96/12012)，芽孢杆菌(Bacillus)脂肪酶，例如来自枯草芽孢杆菌(B.subtilis)(Dartois等人(1993)，Biochemica et Biophysica Acta，1131,253-360)，嗜热脂肪芽孢杆菌(B.stearothermophilus)(JP 64/744992)或短小芽孢杆菌(B.pumilus)(WO 91/16422)。
其他实例是脂肪酶变体，例如WO 92/05249、WO 94/01541、EP 407 225、EP 260105、WO 95/35381、WO 96/00292、WO 95/30744、WO 94/25578、WO 95/14783、WO 95/22615、WO 97/04079和WO 97/07202、WO 00/60063中描述的那些。
优选的市售脂肪酶包括LipolaseTM和Lipolase UltraTM、LipexTM和LipocleanTM(Novozymes A/S)。
本发明的方法可以在归类为EC 3.1.1.4和/或EC 3.1.1.32的磷脂酶的存在下进行。如本文所用，术语磷脂酶是对磷脂具有活性的酶。
磷脂，例如卵磷脂或磷脂酰胆碱，由在外面(sn-1)和中间(sn-2)位置与两个脂肪酸酯化并在被第三个位置被磷酸酯化的甘油组成；该磷酸进而可被酯化成氨基醇。磷脂酶是参与磷脂水解的酶。可以区分几种类型的磷脂酶活性，包括水解一个脂肪酰基(分别在sn-1和sn-2位置)以形成溶血磷脂的磷脂酶A1和A2；和可以水解溶血磷脂中的剩余脂肪酰基的溶血磷脂酶(或磷脂酶B)。磷脂酶C和磷脂酶D(磷酸二酯酶)分别释放二酰基甘油或磷脂酸。
合适的蛋白酶包括动物、植物或微生物来源的那些。优选微生物来源。包括化学修饰或蛋白质工程改造的突变体。蛋白酶可以是丝氨酸蛋白酶或金属蛋白酶，优选碱性微生物蛋白酶或胰蛋白酶样蛋白酶。优选的市售蛋白酶包括AlcalaseTM、SavinaseTM、PrimaseTM、DuralaseTM、DyrazymTM、EsperaseTM、EverlaseTM、PolarzymeTM和KannaseTM(Novozymes A/S)、MaxataseTM、MaxacalTM、MaxapemTM、ProperaseTM、PurafectTM、Purafect OxPTM、FN2TM和FN3TM(Genencor International Inc.)。
本发明的方法可以在分类在EC 3.1.1.74的角质酶的存在下进行。根据本发明使用的角质酶可以是任何来源的。优选地，角质酶是微生物来源的，特别是细菌、真菌或酵母来源的。
合适的淀粉酶(α和/或β)包括细菌或真菌来源的那些。包括化学修饰或蛋白质工程改造的突变体。淀粉酶包括例如从芽孢杆菌(Bacillus)，例如在GB 1,296,839中更详细地描述的地衣芽孢杆菌的特殊菌株，或在WO 95/026397或WO 00/060060中公开的芽孢杆菌属菌株获得的α-淀粉酶。可商购的淀粉酶是DuramylTM、TermamylTM、Termamyl UltraTM、NatalaseTM、StainzymeTM、FungamylTM和BANTM(Novozymes A/S)、RapidaseTM和PurastarTM(来自Genencor International Inc.)。
合适的纤维素酶包括细菌或真菌来源的那些。包括化学修饰或蛋白质工程改造的突变体。合适的纤维素酶包括来自芽孢杆菌属(Bacillus)、假单胞菌属(Pseudomonas)、腐质霉属(Humicola)、镰刀菌属(Fusarium)、梭孢壳属(Thielavia)、枝顶孢属(Acremonium)的纤维素酶，例如由公开于US 4,435,307、US 5,648,263、US 5,691,178、US5,776,757、WO89/09259、WO 96/029397和WO 98/012307的特异腐质霉(Humicola insolens)、土生梭孢壳(Thielavia terrestris)、嗜热毁丝霉(Myceliophthora thermophila)和尖孢镰刀菌(Fusarium oxysporum)产生的真菌纤维素酶。市售纤维素酶包括CelluzymeTM、CarezymeTM、CellucleanTM、EndolaseTM、RenozymeTM(Novozymes A/S)、ClazinaseTM和Puradax HATM(Genencor International Inc.)以及KAC-500(B)(Kao Corporation)。优选CellucleanTM。
合适的过氧化物酶/氧化酶包括植物、细菌或真菌来源的那些。包括化学修饰或蛋白质工程改造的突变体。有用的过氧化物酶的实例包括来自鬼伞属(Coprinus)，例如来自灰盖鬼伞(C.cinereus)及其变体的过氧化物酶，如WO 93/24618、WO 95/10602和WO 98/15257中所述的。市售的过氧化物酶包括GuardzymeTM和NovozymTM51004(Novozymes A/S)。
适合使用的其他酶在WO2009/087524、WO2009/090576、WO2009/107091、WO2009/111258和WO2009/148983中讨论。
酶稳定剂
组合物中存在的任何酶可以使用常规稳定剂稳定，例如多元醇，如丙二醇或甘油，糖或糖醇，乳酸，硼酸或硼酸衍生物，例如芳族硼酸酯，或苯基硼酸衍生物例如4-甲酰基苯基硼酸，并且所述组合物可以按照例如WO 92/19709和WO 92/19708中所述配制。
当烷基足够长以形成支链或环状链时，烷基包括支链、环状和直链烷基链。烷基优选是直链或支链的，最优选是直链的。
除非另有说明，否则不定冠词“一”或“一个”及其相应的定冠词“所述”是指至少一个或一个或多个。
实验
实施例1
制备具有以下配方的水性液体洗衣用洗涤剂：
| 成分 | 重量％ |
| 单丙二醇 | 2 |
| 三甲胺 | 1.5 |
| 具有7摩尔环氧乙烷的C12-C15醇乙氧基化物 | 2.1 |
| 直链烷基苯磺酸盐 | 8.4 |
| 具有3摩尔环氧乙烷的月桂基醚硫酸钠 | 10.5 |
| 柠檬酸 | 0.5 |
| 香料 | 0.3 |
| 抗再沉积技术 | 参见文本 |
| 氢氧化钠 | 至pH＝8.4 |
| 水 | 余量 |
该制剂用于在设定为200rpm的Tergotometer中洗涤8个5×5cm的针织棉布片。在800ml 6°法国硬水中在20℃下用2.3g/L的制剂进行1小时的洗涤。为了模拟颗粒污垢，将0.04g/L的100％压缩炭黑(来自Sigma-Aldrich)加入到洗涤液中。为了模拟油性污垢，将12.5g的SBL2004污垢条(来自Warwick Equest)加入洗涤液中。
一旦洗涤完成，将棉布测试片在500ml清水中漂洗两次，取出干燥并在反射计上测量颜色并表示为CIE L*a*b*值。
测试含有不同水平的Sokalan HP20(BASF)(乙氧基化聚乙烯亚胺聚合物PEI(600)20EO)作为抗再沉积益处的对比聚合物的制剂。
测试含有不同水平的烷氧基化多芳基苯酚：具有平均16个乙氧基化物基团的聚乙二醇单(2,4,6-三(1-苯乙基)苯基)醚的制剂。(Emulsogen TS160，购自Clariant)。
结果总结在下表中。还从8个测试片的测量的标准偏差计算95％置信限。L*值是来自8个测试片的测量的平均值。
烷氧基化多芳基苯酚以剂量依赖性方式增加了测试片的L*。高L*值相当于更干净、更白的织物。烷氧基化多芳基苯酚提供了比乙氧基化聚乙烯亚胺显著更好的益处。
Claims (18)
1.一种非磷酸盐作为助剂的洗衣用洗涤剂，其包含：
(i)4-50重量％的带电荷的表面活性剂；
(ii)0.1-20wt％的不带电荷的烷氧基化多芳基苯酚；和
(iii)0.001-3重量％的香料，其中所述洗衣用洗涤剂是水性液体洗衣用洗涤剂。
2.根据权利要求1所述的洗衣用洗涤剂组合物，其中所述不带电荷的烷氧基化多芳基苯酚是不带电荷的烷氧基化三苯乙烯基苯酚，所述水性液体洗衣用洗涤剂的pH为7至9。
3.根据权利要求1所述的洗衣用洗涤剂组合物，其中所述不带电荷的烷氧基化多芳基苯酚是不带电荷的乙氧基化多芳基苯酚，所述水性液体洗衣用洗涤剂的pH为7至9。
4.根据权利要求2所述的洗衣用洗涤剂组合物，其中所述不带电荷的烷氧基化三苯乙烯基苯酚是不带电荷的聚乙二醇单(2,4,6-三(1-苯乙基)苯基)醚。
5.根据权利要求1-4中任一项所述的洗衣用洗涤剂组合物，其中所述不带电荷的烷氧基化多芳基酚包含平均2-70个烷氧基。
6.根据权利要求5所述的洗衣用洗涤剂组合物，其中所述不带电荷的烷氧基化多芳基苯酚包含平均10-54个烷氧基。
7.根据前述权利要求中任一项所述的洗衣用洗涤剂组合物，其中所述不带电荷的烷氧基化多芳基苯酚以0.5-10重量％，最优选2-9重量％的水平存在。
8.根据前述权利要求中任一项所述的洗衣用洗涤剂组合物，其中所述带电荷的表面活性剂是阴离子表面活性剂。
9.根据权利要求8所述的洗衣用洗涤剂组合物，其中所述阴离子表面活性剂选自：直链烷基苯磺酸盐、烷基硫酸盐、烷基醚硫酸盐、皂、烷基(优选甲基)酯磺酸盐及其混合物。
10.根据权利要求9所述的洗衣用洗涤剂组合物，其中所述阴离子表面活性剂选自：直链烷基苯磺酸盐、烷基硫酸盐、烷基醚硫酸盐及其混合物。
11.根据前述权利要求中任一项所述的洗衣用洗涤剂组合物，其中所述阴离子表面活性剂的水平为4-50重量％。
12.根据前述权利要求中任一项所述的洗衣用洗涤剂组合物，其中所述组合物包含2-8重量％的烷基乙氧基化非离子表面活性剂。
13.根据前述权利要求中任一项所述的洗衣用洗涤剂组合物，其中香料以0.001-3重量％存在并且包含一种或多种以下香料化合物：α-异甲基紫罗兰酮，水杨酸苄酯；香茅醇；香豆素；己基肉桂醛；芳樟醇；2-甲基戊酸--乙酯；辛醛；乙酸苄酯；3,7-二甲基-1,6-辛二烯-3-醇-3-乙酸酯；2-(1,1-二甲基乙基)-环己醇-1-乙酸酯；δ-突厥酮；β-紫罗兰酮；乙酸三环癸烯酯；十二烷醛；己基肉桂醛；环十五内酯；苯乙酸，2-苯基乙基酯；水杨酸戊酯；β-石竹烯；十一碳烯酸乙酯；邻氨基苯甲酸香叶酯；α-鸢尾酮；苯甲酸β-苯乙酯；α-檀香醇；雪松醇；醋酸柏木酯；甲酸柏木酯；水杨酸环己酯；γ-十二内酯；和苯乙酸β-苯乙酯。
14.根据权利要求1所述的非磷酸盐作为助剂的洗衣用洗涤剂，其包含：
(i)4-50重量％的阴离子表面活性剂，其选自：直链烷基苯磺酸盐、烷基硫酸盐、烷基醚硫酸盐及其混合物；
(ii)0.5-10重量％的具有以下结构的不带电荷的烷氧基化多芳基苯酚：
其中n选自：10、11、12、13、14、15、16、17、18、19、20、21、22、23、24、25、26、27、28、29、30、31、32、33、34、35、36、37、38、39、40、41、42、43、44、45、46、47、48、49、50、51、52、53和54；和
(iii)香料，其中所述洗衣用洗涤剂是水性液体洗衣用洗涤剂。
15.根据前述权利要求中任一项所述的洗衣用洗涤剂组合物，其中所述组合物包含0.0001重量％至0.1重量％的酶蛋白质，所述酶选自：蛋白酶、脂肪酶、纤维素酶及其混合物，优选包含蛋白酶。
16.根据前述权利要求中任一项所述的洗衣用洗涤剂组合物，其中所述洗衣用洗涤剂组合物是洗衣用水性液体洗涤剂组合物。
17.一种处理织物的家用方法，所述方法包括以下步骤：
(i)用权利要求1-16中任一项所述的洗衣用洗涤剂组合物的水溶液处理所述织物，所述水溶液包含10ppm至5000ppm的不带电荷的烷氧基化多芳基苯酚；和至多6g/L的表面活性剂；和
(ii)任选地漂洗和干燥所述织物。
18.根据权利要求17所述的处理织物的家用方法，其中所述水溶液包含0.2-4g/L的表面活性剂。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14185263 | 2014-09-18 | ||
| EP14185263.2 | 2014-09-18 | ||
| PCT/EP2015/063927 WO2016041649A1 (en) | 2014-09-18 | 2015-06-22 | Liquid whitening composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106715664A true CN106715664A (zh) | 2017-05-24 |
| CN106715664B CN106715664B (zh) | 2019-09-17 |
Family
ID=51564531
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580050339.5A Active CN106715664B (zh) | 2014-09-18 | 2015-06-22 | 液体增白组合物 |
| CN201580044390.5A Pending CN106661502A (zh) | 2014-09-18 | 2015-07-28 | 增白组合物 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580044390.5A Pending CN106661502A (zh) | 2014-09-18 | 2015-07-28 | 增白组合物 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20170247636A1 (zh) |
| EP (2) | EP3194541B1 (zh) |
| CN (2) | CN106715664B (zh) |
| AR (2) | AR101877A1 (zh) |
| BR (2) | BR112017004976B1 (zh) |
| TR (1) | TR201906861T4 (zh) |
| WO (2) | WO2016041649A1 (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019120183A1 (en) * | 2017-12-22 | 2019-06-27 | Rhodia Operations | Method for improving scrub resistance of coatings |
| CN112236508A (zh) * | 2018-06-14 | 2021-01-15 | 荷兰联合利华有限公司 | 洗涤剂 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017174296A1 (en) | 2016-04-04 | 2017-10-12 | Unilever Plc | Fragranced compositions and their use |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2007692A (en) * | 1977-11-02 | 1979-05-23 | Rhone Poulenc Ind | Anti-soiling and anti-redesposition compositions which can be used in detergency |
| CA1210009A (en) * | 1982-12-23 | 1986-08-19 | Eugene P. Gosselink | Ethoxylated amine polymers having clay soil removal/anti-redeposition properties useful in detergent compositions |
| WO1996023864A1 (en) * | 1995-01-31 | 1996-08-08 | Rhone-Poulenc Inc. | Nonionic surfactants with enhanced aqueous dissolution rates |
| US20040087458A1 (en) * | 2002-11-01 | 2004-05-06 | Nicca U.S.A., Inc. | Surfactant blends for removing oligomer deposits from polyester fibers and polyester processing equipment |
| CN102202639A (zh) * | 2008-09-02 | 2011-09-28 | 巴斯夫欧洲公司 | 用作流变改性剂和家庭和个人护理组合物的共聚物 |
| CN103781893A (zh) * | 2011-08-31 | 2014-05-07 | 阿克佐诺贝尔化学国际公司 | 包含去污剂的洗衣剂组合物 |
| CN103857781A (zh) * | 2011-07-21 | 2014-06-11 | 荷兰联合利华有限公司 | 液体洗衣组合物 |
-
2015
- 2015-06-22 CN CN201580050339.5A patent/CN106715664B/zh active Active
- 2015-06-22 TR TR2019/06861T patent/TR201906861T4/tr unknown
- 2015-06-22 BR BR112017004976-7A patent/BR112017004976B1/pt active IP Right Grant
- 2015-06-22 US US15/509,036 patent/US20170247636A1/en not_active Abandoned
- 2015-06-22 WO PCT/EP2015/063927 patent/WO2016041649A1/en active Application Filing
- 2015-06-22 EP EP15732580.4A patent/EP3194541B1/en active Active
- 2015-07-28 CN CN201580044390.5A patent/CN106661502A/zh active Pending
- 2015-07-28 WO PCT/EP2015/067302 patent/WO2016041677A1/en active Application Filing
- 2015-07-28 EP EP15742294.0A patent/EP3194544A1/en not_active Withdrawn
- 2015-07-28 BR BR112017004985A patent/BR112017004985A2/pt not_active Application Discontinuation
- 2015-09-16 AR ARP150102949A patent/AR101877A1/es active IP Right Grant
- 2015-09-17 AR ARP150102982A patent/AR101907A1/es active IP Right Grant
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2007692A (en) * | 1977-11-02 | 1979-05-23 | Rhone Poulenc Ind | Anti-soiling and anti-redesposition compositions which can be used in detergency |
| CA1210009A (en) * | 1982-12-23 | 1986-08-19 | Eugene P. Gosselink | Ethoxylated amine polymers having clay soil removal/anti-redeposition properties useful in detergent compositions |
| WO1996023864A1 (en) * | 1995-01-31 | 1996-08-08 | Rhone-Poulenc Inc. | Nonionic surfactants with enhanced aqueous dissolution rates |
| US20040087458A1 (en) * | 2002-11-01 | 2004-05-06 | Nicca U.S.A., Inc. | Surfactant blends for removing oligomer deposits from polyester fibers and polyester processing equipment |
| CN102202639A (zh) * | 2008-09-02 | 2011-09-28 | 巴斯夫欧洲公司 | 用作流变改性剂和家庭和个人护理组合物的共聚物 |
| CN103857781A (zh) * | 2011-07-21 | 2014-06-11 | 荷兰联合利华有限公司 | 液体洗衣组合物 |
| CN103781893A (zh) * | 2011-08-31 | 2014-05-07 | 阿克佐诺贝尔化学国际公司 | 包含去污剂的洗衣剂组合物 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019120183A1 (en) * | 2017-12-22 | 2019-06-27 | Rhodia Operations | Method for improving scrub resistance of coatings |
| CN112236508A (zh) * | 2018-06-14 | 2021-01-15 | 荷兰联合利华有限公司 | 洗涤剂 |
Also Published As
| Publication number | Publication date |
|---|---|
| AR101907A1 (es) | 2017-01-18 |
| BR112017004976A2 (pt) | 2018-01-23 |
| EP3194544A1 (en) | 2017-07-26 |
| TR201906861T4 (tr) | 2019-05-21 |
| BR112017004976B1 (pt) | 2022-02-01 |
| AR101877A1 (es) | 2017-01-18 |
| CN106715664B (zh) | 2019-09-17 |
| US20170247636A1 (en) | 2017-08-31 |
| CN106661502A (zh) | 2017-05-10 |
| WO2016041649A1 (en) | 2016-03-24 |
| BR112017004985A2 (pt) | 2018-01-23 |
| WO2016041677A1 (en) | 2016-03-24 |
| EP3194541A1 (en) | 2017-07-26 |
| EP3194541B1 (en) | 2019-04-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107207999B (zh) | 增白组合物 | |
| CN106661504B (zh) | 增白组合物 | |
| CN109072131A (zh) | 洗衣洗涤剂组合物 | |
| CN107075416A (zh) | 增白组合物 | |
| CN106715664B (zh) | 液体增白组合物 | |
| US20220364022A1 (en) | Detergent composition | |
| CN108884415A (zh) | 洗衣洗涤剂组合物 | |
| CN107075412B (zh) | 增白组合物 | |
| EP3313968B1 (en) | Laundry detergent composition | |
| CN109844083A (zh) | 增白组合物 | |
| CN106661503B (zh) | 增白组合物 | |
| CN108603140A (zh) | 增白组合物 | |
| CN108699490B (zh) | 增白组合物 | |
| CN108603139B (zh) | 增白组合物 | |
| CN110023469A (zh) | 洗衣洗涤剂组合物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210804 Address after: Rotterdam Patentee after: Unilever Intellectual Property Holdings Ltd. Address before: Rotterdam Patentee before: Netherlands Unilever Co.,Ltd. |
|
| TR01 | Transfer of patent right |