CN1066999A - Silver-free copper-based brazing filler metal - Google Patents

Silver-free copper-based brazing filler metal Download PDF

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Publication number
CN1066999A
CN1066999A CN 91107056 CN91107056A CN1066999A CN 1066999 A CN1066999 A CN 1066999A CN 91107056 CN91107056 CN 91107056 CN 91107056 A CN91107056 A CN 91107056A CN 1066999 A CN1066999 A CN 1066999A
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CN
China
Prior art keywords
brazing
stainless steel
silver
free copper
filler metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 91107056
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Chinese (zh)
Inventor
浦瑞霆
程晓农
孙平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU POLYTECHNIC COLLEGE
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JIANGSU POLYTECHNIC COLLEGE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANGSU POLYTECHNIC COLLEGE filed Critical JIANGSU POLYTECHNIC COLLEGE
Priority to CN 91107056 priority Critical patent/CN1066999A/en
Publication of CN1066999A publication Critical patent/CN1066999A/en
Pending legal-status Critical Current

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Abstract

The present invention belongs to the field of non-ferrous alloy technology, and aims at developing one kind of low melting point silver-free copper-base brazing material with excellent wetting capacity to stainless steel and capacity of brazing stainless steel. The components (weight percent) are as follows: zn 30-40%, Mn 4-11%, Sn 1-4%, one or two of Re 0-1%, B0-0.50%, and Cu for the rest. The melting point of the invention is 777 ℃ of solidus line, 790 ℃ of liquidus line, 550MPa of tensile strength and delta of elongation5020 percent, the shear strength of a low-carbon steel brazing joint is more than 400MPa, and the shear strength of a stainless steel brazing joint is more than 200 MPa. It is suitable for salt bath and furnace brazing flame gas welding and high-frequency brazing.

Description

A kind of silverless Cu-base soldering material
The invention belongs to non-ferrous alloy technology, is a kind of coper-base solder alloy prescription that does not contain precious metal.
Traditional copper base solder, routine H62, S221 etc., all unsuitable soldering stainless steel part.So far, the solder of argentiferous is all used in the soldering of stainless part.For this reason, all be the brazing filler metal alloy of base both at home and abroad with copper in development, the characteristics that are intended to reduce fusing point and keep silver solder again.
State Patent Office's result for retrieval on February 14 nineteen ninety (entrusting numbering 90009) shows; Up to now, the relevant patented technology that has has in the world all reduced the fusing point of copper base solder to some extent, but is to be used for soldering steel, copper and copper alloy mostly, does not solve stainless soldering problem as yet well.As: Russian Patent (27.12.77(21) 2568518/25-27), its brazing filler metal alloy composition and content are: Z n(13-25) M n(13-17), S n(3-12), C e(0.1-0.3), about 800 ℃ of fusing point is used for brazed copper and copper alloy, and day disclosure is speciallyyed permit the M that the clear 56-165590 of communique (A) provides n(12-45), Z n(1-25), N i(2-14) be and M n(15-30) Z n(15-25), N i(4-6), F e(2-5) C of pore-free defective u-M nThe fusing point that is solder alloy is 800 ℃-870 ℃, is used for welding steel and carbide alloy, also unsuitable soldering stainless steel.The patent that the People's Republic of China (PRC) announces: the patent No. is Z for " a kind of silverless low melting-point coper-base solder " its component and the content of " 87100098 " n(33-37), M n(6-14), S i(0-2.0), F e(0-1.0), C o(0-1.0) R eA kind of, two kinds or three kinds of copper base solders, fusing point is 778-814 ℃.Be mainly used in the soldering of steel.
The objective of the invention is to develop a kind of copper base solder of new no silver, make it have good wettability stainless steel, but the soldering stainless steel.The soldering fusing point is reduced, realize energy-efficient.
Component of the present invention and content are: zinc (Z n) 30-40%, manganese (M n) 4-11%, tin (S n) 1-4%, rare earth (R e) in a kind of or two kinds of 0-1%, boron (B) 0-0.5%, surpluses be copper C u
Its processing sequence is: smelting-ingot casting-Jia is hot extruded into silk or is rolled into paper tinsel.
Smelting is in proper order: during melting, add Cu, Mn earlier in melting kettle or other smelting equipments, to reduce fusing point, add S after the fusing n,, add Z at last with further reduction fusing point n, R eAnd B.
Advantage of the present invention is that fusing point is low, is 777 ℃ of solidus, 790 ℃ of liquidus curves, and brazing temperature is 900-950 ℃, than low 200 ℃ of brass, remarkable energy saving effect (energy-conservation 30-40%) is arranged; Satisfactory mechanical property, tensile strength>550MP a, percentage elongation δ 50Be 20%, mild steel soldered fitting shearing strength>400MP a, stainless steel braze welding shearing strength>200MP a; Argentiferous, nickel, cobalt, bismuth, cadmium etc. are valuable and produce the element of pernicious gas when smelting in this solder, smelt simply, and processing characteristics is good; The solder good manufacturability, need not use special flux, stainless steel, steel, carbide alloy are had good sprawling and filling capacity, the butt joint gap is insensitive, can welding, stainless steel, steel, copper, copper alloy and carbide alloy, be suitable for salt bath and gas welding of furnace brazing flame and high frequency brazing.

Claims (1)

1, a kind of silverless Cu-base soldering material alloy is characterized in that its component and content (weight %) are:
Zinc (Z n) 30-40%
Manganese (M n) 4-11%
Tin (S n) 1-4%
Rare earth (R e) in a kind of or two kinds of 0-1%
Boron (B) 0-0.5%
Yu Weitong (C u)
CN 91107056 1991-05-20 1991-05-20 Silver-free copper-based brazing filler metal Pending CN1066999A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 91107056 CN1066999A (en) 1991-05-20 1991-05-20 Silver-free copper-based brazing filler metal

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 91107056 CN1066999A (en) 1991-05-20 1991-05-20 Silver-free copper-based brazing filler metal

Publications (1)

Publication Number Publication Date
CN1066999A true CN1066999A (en) 1992-12-16

Family

ID=4908419

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 91107056 Pending CN1066999A (en) 1991-05-20 1991-05-20 Silver-free copper-based brazing filler metal

Country Status (1)

Country Link
CN (1) CN1066999A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1108896C (en) * 1998-07-01 2003-05-21 洪若锋 Special crystalline soldering flux and its manufacture method
CN102862003A (en) * 2012-10-08 2013-01-09 佛山市泓实机械制造有限公司 Silver-free copper based solder and preparation method thereof
CN103042318A (en) * 2013-01-16 2013-04-17 苏州金仓合金新材料有限公司 Environment friendly tin zinc manganese copper alloy new material used for welding and preparation method thereof
CN103045900A (en) * 2013-01-16 2013-04-17 苏州金仓合金新材料有限公司 Novel high-stability copper alloy material for welding and preparation method for same
CN103480987A (en) * 2013-09-26 2014-01-01 郑州机械研究所 Preparation method for high-fragility copper-zinc welding wires/welding lugs

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1108896C (en) * 1998-07-01 2003-05-21 洪若锋 Special crystalline soldering flux and its manufacture method
CN102862003A (en) * 2012-10-08 2013-01-09 佛山市泓实机械制造有限公司 Silver-free copper based solder and preparation method thereof
CN104942470A (en) * 2013-01-16 2015-09-30 苏州金仓合金新材料有限公司 Environment-protecting tin zinc manganese copper alloy new material for welding and preparing method thereof
CN103045900A (en) * 2013-01-16 2013-04-17 苏州金仓合金新材料有限公司 Novel high-stability copper alloy material for welding and preparation method for same
CN103045900B (en) * 2013-01-16 2015-04-08 苏州金仓合金新材料有限公司 Novel high-stability copper alloy material for welding and preparation method for same
CN104942471A (en) * 2013-01-16 2015-09-30 苏州金仓合金新材料有限公司 Environment-protecting tin zinc manganese copper alloy new material for welding and preparing method thereof
CN104942472A (en) * 2013-01-16 2015-09-30 苏州金仓合金新材料有限公司 Environment-protecting tin zinc manganese copper alloy new material for welding and preparing method thereof
CN103042318A (en) * 2013-01-16 2013-04-17 苏州金仓合金新材料有限公司 Environment friendly tin zinc manganese copper alloy new material used for welding and preparation method thereof
CN104942472B (en) * 2013-01-16 2017-05-03 苏州金仓合金新材料有限公司 Environment-protecting tin zinc manganese copper alloy new material for welding and preparing method thereof
CN104942470B (en) * 2013-01-16 2017-05-03 苏州金仓合金新材料有限公司 Environment-protecting tin zinc manganese copper alloy new material for welding and preparing method thereof
CN104942464B (en) * 2013-01-16 2017-05-03 苏州金仓合金新材料有限公司 Environment-protecting tin zinc manganese copper alloy new material for welding and preparing method thereof
CN104942471B (en) * 2013-01-16 2017-05-03 苏州金仓合金新材料有限公司 Environment-protecting tin zinc manganese copper alloy new material for welding and preparing method thereof
CN103480987A (en) * 2013-09-26 2014-01-01 郑州机械研究所 Preparation method for high-fragility copper-zinc welding wires/welding lugs
CN103480987B (en) * 2013-09-26 2015-08-19 郑州机械研究所 A kind of preparation method of high fragility copper zinc welding rod/weld tabs

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