CN104942470B - Environment-protecting tin zinc manganese copper alloy new material for welding and preparing method thereof - Google Patents

Environment-protecting tin zinc manganese copper alloy new material for welding and preparing method thereof Download PDF

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Publication number
CN104942470B
CN104942470B CN201510386863.1A CN201510386863A CN104942470B CN 104942470 B CN104942470 B CN 104942470B CN 201510386863 A CN201510386863 A CN 201510386863A CN 104942470 B CN104942470 B CN 104942470B
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welding
degree
new material
alloy
copper alloy
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CN104942470A (en
Inventor
孙飞
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SUZHOU JINCANG ALLOY NEW-MATERIAL Co Ltd
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SUZHOU JINCANG ALLOY NEW-MATERIAL Co Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24—Selection of soldering or welding materials proper
    • B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/302—Cu as the principal constituent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24—Selection of soldering or welding materials proper
    • B23K35/28—Selection of soldering or welding materials proper with the principal constituent melting at less than 950 degrees C
    • B23K35/282—Zn as the principal constituent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0255—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in welding
    • B23K35/0261—Rods, electrodes, wires
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/40—Making wire or rods for soldering or welding
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/02—Making non-ferrous alloys by melting
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C30/00—Alloys containing less than 50% by weight of each constituent
    • C22C30/06—Alloys containing less than 50% by weight of each constituent containing zinc
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/16—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Arc Welding In General (AREA)

Abstract

The invention discloses an environment-protecting tin zinc manganese copper alloy new material for welding and a preparing method thereof. The copper alloy new material comprises the components of 34% of tin, 7% of manganese, 35% of zinc and the balance of copper. According to the copper alloy new material, the original traditional welding material performance is guaranteed, meanwhile, lead elements are replaced, the requirement for ROHS is met, manganese elements are added, zinc oxidation is avoided, material cost is greatly lowered, and the stability of a welding carrier is improved.

Description

A kind of environment friendly tin zinc manganese copper alloy new material for welding and preparation method thereof
The application is the artificial Suzhou Jincang Alloy New Material Co., Ltd. of application, a kind of entitled ring for welding Tin zinc-manganese copper alloy new material and preparation method thereof, Application No. 201310016419.1 are protected, the applying date is 01 month 2013 16 The divisional application of the application for a patent for invention of day.
Technical field
The present invention relates to the manufacturing technology field of welding material, more particularly to a kind of environment friendly tin zinc manganese copper conjunction for welding Golden new material and preparation method thereof.
Background technology
Existing welding material is generally two kinds on market：One kind is SAC, and another kind is tin-lead copper alloy.With 《The instruction of some harmful components used in regard to being limited in electronic and electrical equipment》(Restriction of Hazardous Substances, ROHS) policy execution for prohibiting lead instruction in the electronics industry, leaded soldering material can not meet height The environmental requirement of standard.And the application difficult point of SAC is not only to require that brazier temperature is higher than original metal 30 degree, And its cost is also high than tin-lead copper alloy by 25%, it is often more important that the raising of this temperature can substantially reduce the steady of exposure components and parts It is qualitative.Therefore, red brass is further studied.But, the oxidation of zinc prevents the application of red brass.
The content of the invention
The purpose of the present invention is for above-mentioned the deficiencies in the prior art, there is provided a kind of environment friendly tin zinc manganese copper for welding is closed Golden new material and preparation method thereof.The Alloy Materials can be played and prevent the purpose of zinc oxidation, and greatly reduce material The stability of welding carrier is also improved while cost.
For achieving the above object, the technical solution used in the present invention is as follows.
A kind of environment friendly tin zinc manganese copper alloy new material for welding, is made up of the component of following proportioning：Tin 34%；Manganese 7%；Zinc 35%；Balance of copper.
Invention further provides a kind of side for producing the above-mentioned environment friendly tin zinc manganese copper alloy new material for welding Method, comprises the following steps：
1) Xi ﹑ Xin ﹑ Meng ﹑ copper is placed in main frequency furnace according to proportioning, is heated to 1300-1350 degree, protected after being completely melt Temperature is to 1200 degree；
2) after the alloy liquid being completely melt is sufficiently stirred for graphite rod, cover high-purity flaky graphite powder to prevent Its oxidation, thickness is 15-20cm；
3) it is incubated after 2-2.5 hours, produces Spike direct-reading spectrometer with Germany and the sample taken out from main frequency furnace is entered Three composition inspections of row, to determine its alloying component within prescribed limit；
4) 1300 degree are warming up to further after insulation 50-60 minutes, again, and open the vibrating device of main frequency furnace, shaken Dynamic frequency be 1 time/second, adopt horizontal continuous casting method to be cast as a diameter of 40mm, length for 600mm solid alloy bar；
5) extruded using 800 tons of single action extruders, alloy pig heating-up temperature is 100-150 degree, extrusion temperature is 200 degree, Extrusion speed V=10mm/s, a diameter of 31mm of alloy bar, length are 990mm after extruding, then with high accuracy wolfram steel thin skin mould By alloy bar peeling once to 30mm；
6) alloy bar after extruding is made annealing treatment with box-annealing furnace, annealing temperature is 80-100 degree, during annealing Between be 1-1.5 hours；
7) the drawing section that length is 50mm, a diameter of 25mm is made in alloy bar one end after the completion of annealing with head machine processed, After alloy bar multi-drawing and will be annealed with finishing die so as to ultimately become the welding wire that a diameter of 10mm, tolerance are +/- 0.05mm Base rod, is then cut into length for 500mm, the specification that tolerance is+1/-0mm by welding wire base rod；
8) pack and put in storage.
The invention has the beneficial effects as follows：
The present invention replaces lead element while original traditional welding material property is ensured, meets ROHS requirements. Add manganese element in the environment friendly tin zinc manganese copper alloy new material for welding of the present invention, the mesh for preventing zinc oxidation can be reached , the stability of welding carrier is also improved while material cost is substantially reduced.
Description of the drawings
Fig. 1 is the flow chart of the preparation method of the environment friendly tin zinc manganese copper alloy new material for welding of the present invention.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, below in conjunction with the accompanying drawings and embodiment pair The present invention is described in further detail.It should be appreciated that specific embodiment described herein is only to explain the present invention, and without It is of the invention in limiting.
Embodiment
A kind of environment friendly tin zinc manganese copper alloy new material for welding, is made up of the component of following proportioning：Tin 34%；Manganese 7%；Zinc 35%；Balance of copper.
The preparation method of the environment friendly tin zinc manganese copper alloy new material for welding of embodiment, as shown in figure 1, including as follows Step：
1) Xi ﹑ Xin ﹑ Meng ﹑ copper is placed in main frequency furnace according to proportioning, is heated to 1300-1350 degree, protected after being completely melt Temperature is to 1200 degree；
2) after the alloy liquid being completely melt is sufficiently stirred for graphite rod, cover high-purity flaky graphite powder to prevent Its oxidation, thickness is 15-20cm；
3) it is incubated after 2-2.5 hours, produces Spike direct-reading spectrometer with Germany and the sample taken out from main frequency furnace is entered Three composition inspections of row, to determine its alloying component within prescribed limit；
4) 1300 degree are warming up to further after insulation 50-60 minutes, again, and open the vibrating device of main frequency furnace, shaken Dynamic frequency be 1 time/second, adopt horizontal continuous casting method to be cast as a diameter of 40mm, length for 600mm solid alloy bar；
5) extruded using 800 tons of single action extruders, alloy pig heating-up temperature is 100-150 degree, extrusion temperature is 200 degree, Extrusion speed V=10mm/s, a diameter of 31mm of alloy bar, length are 990mm after extruding, then with high accuracy wolfram steel thin skin mould By alloy bar peeling once to 30mm；
6) alloy bar after extruding is made annealing treatment with box-annealing furnace, annealing temperature is 80-100 degree, during annealing Between be 1-1.5 hours；
7) the drawing section that length is 50mm, a diameter of 25mm is made in alloy bar one end after the completion of annealing with head machine processed, After alloy bar multi-drawing and will be annealed with finishing die so as to ultimately become the welding wire that a diameter of 10mm, tolerance are +/- 0.05mm Base rod, is then cut into length for 500mm, the specification that tolerance is+1/-0mm by welding wire base rod；
8) pack and put in storage.
The performance of environment friendly tin zinc manganese copper alloy new material and traditional welding material provided by the present invention for welding is such as Shown in table 1.
Table 1 is used for the environment friendly tin zinc manganese copper alloy new material of welding and the performance comparison of traditional welding material
The foregoing is only presently preferred embodiments of the present invention, not for limit the present invention practical range；If do not taken off From the spirit and scope of the present invention, the present invention is modified or equivalent, all should be covered in the claims in the present invention In the middle of protection domain.

Claims (2)

1. it is a kind of for welding environment friendly tin zinc manganese copper alloy new material, it is characterised in that be made up of the component of following proportioning：Tin 34%；Manganese 7%；Zinc 35%；Balance of copper.
2. a kind of method of the environment friendly tin zinc manganese copper alloy new material for welding produced described in claim 1, including following Step：
1) Xi ﹑ Xin ﹑ Meng ﹑ copper is placed in main frequency furnace according to proportioning, is heated to 1300-1350 degree, be incubated after being completely melt to 1200 degree；
2) after the alloy liquid being completely melt is sufficiently stirred for graphite rod, cover high-purity flaky graphite powder to prevent its oxygen Change, thickness is 15-20cm；
3) it is incubated after 2-2.5 hours, produce Spike direct-reading spectrometer with Germany carries out three to the sample taken out from main frequency furnace Secondary composition inspection, to determine its alloying component within prescribed limit；
4) 1300 degree are warming up to further after insulation 50-60 minutes, again, and open the vibrating device of main frequency furnace, vibration frequency Rate be 1 time/second, adopt horizontal continuous casting method to be cast as a diameter of 40mm, length for 600mm solid alloy bar；
5) extruded using 800 tons of single action extruders, alloy pig heating-up temperature is 100-150 degree, extrusion temperature is 200 degree, extruding Speed V=10mm/s, a diameter of 31mm of alloy bar, length are 990mm after extruding, then will be closed with high accuracy wolfram steel thin skin mould Golden rod peeling is once to 30mm；
6) alloy bar after extruding is made annealing treatment with box-annealing furnace, annealing temperature is 80-100 degree, annealing time is 1-1.5 hour；
7) the drawing section that length is 50mm, a diameter of 25mm is made in alloy bar one end after the completion of annealing with head machine processed, with into Product mould after alloy bar multi-drawing and will be annealed so as to ultimately become the welding wire base that a diameter of 10mm, tolerance are +/- 0.05mm Rod, is then cut into length for 500mm, the specification that tolerance is+1/-0mm by welding wire base rod；
8) pack and put in storage.
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CN104353939A (en) * 2014-11-17 2015-02-18 安徽瑞研新材料技术研究院有限公司 Novel lead-free copper alloy new material and processing technology thereof
JP6803457B2 (en) 2017-03-24 2020-12-23 株式会社Ihi Abrasion resistant copper-zinc alloy and machinery using it
CN109175571B (en) * 2018-10-19 2021-02-02 广汽本田汽车有限公司 Laser brazing method for welding automobile parts by copper-manganese-zinc welding wire
CN111761156A (en) * 2020-07-22 2020-10-13 厦门福鑫特工贸有限公司 Brazing method for large computer radiator

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CN1066999A (en) * 1991-05-20 1992-12-16 江苏工学院 Silver-free copper-based brazing filler metal
CN1799760A (en) * 2005-01-05 2006-07-12 罗成林 Copper based brazing alloy
CN102361995A (en) * 2009-04-24 2012-02-22 三越金属株式会社 High-strength copper alloy
KR20110045477A (en) * 2009-10-27 2011-05-04 김문숙 powder composition for welding metal wire for accessory
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CN104942473A (en) 2015-09-30
CN103042318B (en) 2015-08-05
CN104942464B (en) 2017-05-03
CN104942471A (en) 2015-09-30
CN104942464A (en) 2015-09-30
CN104942473B (en) 2017-05-03
CN104942472A (en) 2015-09-30
CN104942472B (en) 2017-05-03
CN104942470A (en) 2015-09-30
CN103042318A (en) 2013-04-17
CN104942471B (en) 2017-05-03

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