CN106680333A - Humidity sensitive capacitor and manufacturing method thereof - Google Patents

Humidity sensitive capacitor and manufacturing method thereof Download PDF

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Publication number
CN106680333A
CN106680333A CN201710076264.9A CN201710076264A CN106680333A CN 106680333 A CN106680333 A CN 106680333A CN 201710076264 A CN201710076264 A CN 201710076264A CN 106680333 A CN106680333 A CN 106680333A
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China
Prior art keywords
humidity
substrate
humicap
dielectric layer
housing
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Pending
Application number
CN201710076264.9A
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Chinese (zh)
Inventor
张宾
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Guangzhou Aosong Electronics Co Ltd
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Aosong (guangzhou) Electronics Co Ltd
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Priority to CN201710076264.9A priority Critical patent/CN106680333A/en
Publication of CN106680333A publication Critical patent/CN106680333A/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/02Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
    • G01N27/22Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating capacitance
    • G01N27/227Sensors changing capacitance upon adsorption or absorption of fluid components, e.g. electrolyte-insulator-semiconductor sensors, MOS capacitors
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/02Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
    • G01N27/22Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating capacitance
    • G01N27/223Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating capacitance for determining moisture content, e.g. humidity

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Physics & Mathematics (AREA)
  • Pathology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Immunology (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Power Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)

Abstract

The invention discloses a humidity sensitive capacitor and a manufacturing method thereof. The humidity sensitive capacitor comprises a chip and a casing, wherein the chip is packaged in the casing, and comprises an upper electrode, a humidity sensitive membrane, a dielectric layer, a substrate and a lower electrode; the humidity sensitive membrane is an organic polymer humidity sensitive membrane; the dielectric layer is deposited on the surface of the substrate; the humidity sensitive membrane is attached to the surface of the dielectric layer; the upper electrode is arranged on the humidity sensitive membrane, and is provided with a through hole; the lower electrode is arranged below the substrate; the dielectric layer is a silicon nitride or silicon oxide dielectric layer; the substrate is a monocrystalline silicon substrate. The manufacturing method comprises a step of pretreating the substrate, a step of growing the dielectric layer on the surface of the substrate by virtue of a chemical vapor deposition method and a step of laying the humidity sensitive membrane on the surface of the dielectric layer by virtue of an automatic spin coater. The humidity sensitive capacitor is low in power consumption, high in sensitivity and long-term stable.

Description

A kind of humicap and its manufacture method
Technical field
The present invention relates to a kind of humicap and its manufacture method, belong to capacity cell technical field.
Background technology
In fields such as meteorology, environmental protection, national defence, Aeronautics and Astronautics, navigation, industry, agricultural, electronics microelectronics, it is often necessary to right Ambient humidity is measured and controlled.Condenser type high molecule humidity sensor is high because of reliability, is the advantages of product good weatherability Moisture measurement element the most frequently used at present.
Condenser type high molecule humidity sensor is to produce to be situated between by electricity of high molecule sensitivity material in a kind of dielectric substrate The electric capacity of matter, the dielectric constant of polymeric dielectrics layer changes with the moisture that it is adsorbed.The upper bottom crown of the electric capacity It is made up of metallic film, capacitance signal is drawn from two electrodes, this requires that two electrodes all have certain thickness and solderable. To ensure that, to humidity sensitive, the electrode on sensitive layer needs porous breathable, it is ensured that steam can pass in and out sensitive layer.
Due to the technique and the particularity of performance requirement of dew cell, traditional humicap preparation method is general to select Potsherd or alkali-free glass piece are used as backing material, and volume is larger, and due to potsherd and alkali-free glass piece and COMS and MEMS technology is incompatible, and automated production cannot be realized during production humicap, and cost of labor is high, low production efficiency.
The conventional production method of current humicap has two kinds:One is that the pad that signal is drawn is produced on into base material On, porous electrode is produced on macromolecule humidity sensitive thin film, forms two electric capacity of series connection, and such one is increased the chi of element It is very little, capacitance on the other hand is reduced under same size, reduce sensitivity.Later stage Transform Type design is using two minor metal film forming Method, the thicker metal film of redeposited last layer between porous metallic film and the pad made with bottom electrode simultaneously Layer, Vented metal film is connected with pad, and sensitivity is improved in the case of the size of so guarantee element is not increased, but thoroughly The thickness of gas metallic film can only be at tens nanometers, and technique controllability is bad, and the layer can not be effective to sensitive material Protection, easily scratches, and subsequent applications are more inconvenient, cause this condenser type high molecule humidity sensor poor reliability.
The content of the invention
In order to overcome the deficiencies in the prior art, first purpose of the invention is to provide a kind of humicap, the wet sensitive Capacitive power dissipation is small, and sensitivity is strong, and steadily in the long term.
Realize that the purpose of the present invention can reach by adopting the following technical scheme that:A kind of humicap, including chip and Housing;The chip package is in the housing;The chip includes:Top electrode, humidity-sensitive film, dielectric layer, substrate and bottom electrode;It is described Humidity-sensitive film is organic polymer humidity-sensitive film;The cvd dielectric layer is on the surface of substrate;The humidity-sensitive film is attached to dielectric layer Surface;The Top electrode is arranged on humidity-sensitive film;The Top electrode is provided with through hole;The bottom electrode is arranged on the lower section of substrate; The dielectric layer is silicon nitride or silicon oxide dielectric layer;The substrate is monocrystalline substrate.
Preferably, the housing includes the first conductive part, the second conductive part and encapsulating film;The bottom electrode is fixed on On one conductive part;The Top electrode is electrically connected with by electric-conductor and the second conductive part;The encapsulating film covers the opening of housing, And by chip package in the housing.
Preferably, the electric-conductor is gold thread.
Preferably, the Top electrode is gold, silver, aluminium, platinum, tantalum, copper, chromium, nickel, molybdenum, niobium or titanium Top electrode, or comprising extremely The alloy Top electrode of few two or more metals;The bottom electrode is electricity under gold, silver, aluminium, platinum, tantalum, copper, chromium, nickel, molybdenum, niobium or titanium Pole, or the alloy bottom electrode comprising more than at least two metals.
More preferably, the Top electrode is molybdenum-Cr-Ni Electroplating on Al Alloys pole;The bottom electrode is molybdenum-aluminium alloy bottom electrode.
Preferably, the through hole is grid-shaped through hole, grill-shaped through hole or manhole.
Preferably, the organic polymer humidity-sensitive film is that poly hydroxy ethyl acrylate humidity-sensitive film or polyimides sense are wet Film.
Preferably, the thickness of the humidity-sensitive film is 0.4~1.2um.
Second object of the present invention is the manufacture method for providing above-mentioned humicap, realizes the production of humicap Automation, production in enormous quantities, compared with traditional manufacturing process, production cost reduction, product quality stabilization, reliability obtains pole Big raising.
Realize that the purpose of the present invention can reach by adopting the following technical scheme that:A kind of humicap as described above Manufacture method, comprises the following steps:
1) substrate acid solution, alkaline solution are cleaned successively, ionized water, acetone and absolute ethyl alcohol is then used successively 10~20min for the treatment of is carried out to substrate under ultrasound condition, is finally dried up with nitrogen;
2) by the method for chemical vapor deposition, in one layer of dielectric layer of superficial growth of substrate;
3) humidity-sensitive film is laid on the surface of dielectric layer by automatic sol evenning machine;
4) Top electrode is set in the way of vacuum evaporation on humidity-sensitive film, bottom electrode is set in the lower section of substrate;
5) through hole is etched in Top electrode in the method for photoetching;
6) by automatic scribing machine by chip cutting;
7) by chip package in the housing.
Preferably, the step 7) including procedure below:
1. chip is fixed on the first conductive part of housing by conducting resinl by automatic bonder;
2. Top electrode is bound with the second conductive part electric-conductor by automatic wire binding machine and is connected;
3. the opening of housing is covered using encapsulating film, and, obtains humicap by chip package in the housing.
Compared to existing technology, the beneficial effects of the present invention are:
1st, humicap of the invention uses monocrystalline silicon as substrate, using organic polymer humidity-sensitive film so that chip Thickness and size are substantially reduced, and humicap small volume, sensitivity is high;
2nd, humicap of the invention preferably uses molybdenum-Cr-Ni Electroplating on Al Alloys pole and molybdenum-aluminium alloy bottom electrode, greatly improves electricity The sensitivity of pole and corrosion resistance;
3rd, the preferred poly hydroxy ethyl acrylate humidity-sensitive film of humicap of the invention, it is only necessary to the thickness of micron level, i.e., Good hygroscopicity can be shown;
4th, manufacture method of the invention realizes the production automation of humicap, can be adapted to produce in enormous quantities, product matter Amount stabilization.
Brief description of the drawings
Fig. 1 is the structural representation of humicap;
Fig. 2 is the curve map that the capacitance that embodiment 1 is detected changes with humidity.
Wherein, 1, chip;11st, Top electrode;111st, through hole;12nd, humidity-sensitive film;13rd, dielectric layer;14th, substrate;15th, bottom electrode; 2nd, housing;21st, the first conductive part;22nd, the second conductive part;23rd, encapsulating film;3rd, gold thread.
Specific embodiment
Below, with reference to accompanying drawing and specific embodiment, the present invention is described further:
Reference picture 1, a kind of humicap, including chip 1 and housing 2;The chip 1 is encapsulated in housing 2;The chip 1 includes:Top electrode 11, humidity-sensitive film 12, dielectric layer 13, substrate 14 and bottom electrode 15;The dielectric layer 13 is deposited on substrate 14 Surface;The humidity-sensitive film 12 is attached to the surface of dielectric layer 13;The Top electrode 11 is arranged on humidity-sensitive film 12;The Top electrode 11 are provided with through hole 111;The bottom electrode 15 is arranged on the lower section of substrate 14;The housing 2 includes that the first conductive part 21, second are led Electric portion 22 and encapsulating film 23;The bottom electrode 15 is fixed on the first conductive part 21;The Top electrode 11 passes through gold thread 3 and second Conductive part 22 is electrically connected with;The encapsulating film 23 covers the opening of housing 2, and chip 1 is encapsulated in housing 2.
The dielectric layer is silicon nitride or silicon oxide dielectric layer, and its thickness is 50~90nm;The substrate is served as a contrast for monocrystalline silicon Bottom, its thickness is 200~400um.
In specific embodiment, the Top electrode is molybdenum-Cr-Ni Electroplating on Al Alloys pole;The bottom electrode is electricity under molybdenum-aluminium alloy Pole.
In specific embodiment, the through hole is grid-shaped through hole, grill-shaped through hole or manhole.
In specific embodiment, the humidity-sensitive film be poly hydroxy ethyl acrylate humidity-sensitive film or polyimides humidity-sensitive film, Thickness is 0.6~2um.
Above humicap is manufactured by following steps and obtained:
1) substrate acid solution, alkaline solution are cleaned successively, ionized water, acetone and absolute ethyl alcohol is then used successively Treatment 18min is carried out to substrate under ultrasound condition, is finally dried up with nitrogen;
2) by the method for chemical vapor deposition, in one layer of dielectric layer of superficial growth of substrate;
3) humidity-sensitive film is laid on the surface of dielectric layer by automatic sol evenning machine;
4) Top electrode is set in the way of vacuum evaporation on humidity-sensitive film, bottom electrode is set in the lower section of substrate;
5) through hole is etched in Top electrode in the method for photoetching;
6) by automatic scribing machine by chip cutting into 1.5X1.5mm2
7) chip is fixed on the first conductive part of housing by conducting resinl by automatic bonder;
8) Top electrode is bound with the second conductive part electric-conductor by automatic wire binding machine and is connected;
9) opening of housing is covered using encapsulating film, and, obtains humicap by chip package in the housing.
Embodiment 1~3
Embodiment 1~3 is manufactured by the manufacture method in specific embodiment and obtained with the material and parameter in form 1 Humicap.
The material and parameter setting of the humicap of the embodiment 1~3 of form 1
Humicap to being obtained in embodiment 1 is detected:The humicap that will be obtained is positioned over temperature/humidity verification box In, humidity graded from the range of 10~90RH% is adjusted, the capacitance of humicap is detected, capacitance changes with humidity Curve map from figure as shown in Fig. 2 can obtain:In the range of 10~90RH% of humidity, change of the humicap to humidity has line Property response, and in gamut, humidity hysteresis is less than 1RH%, and response speed is less than 5 seconds, show good stability with it is accurate Property.
For a person skilled in the art, technical scheme that can be as described above and design, make other each Plant corresponding change and deform, and all these changes and deforms the protection model that should all belong to the claims in the present invention Within enclosing.

Claims (10)

1. a kind of humicap, including chip and housing;The chip package is in the housing;The chip includes:Top electrode, sense Wet film, dielectric layer, substrate and bottom electrode;It is characterized in that:The humidity-sensitive film is organic polymer humidity-sensitive film;The dielectric layer sinks Product is on the surface of substrate;The humidity-sensitive film is attached to the surface of dielectric layer;The Top electrode is arranged on humidity-sensitive film;The upper electricity Pole is provided with through hole;The bottom electrode is arranged on the lower section of substrate;The dielectric layer is silicon nitride or silicon oxide dielectric layer;The lining Bottom is monocrystalline substrate.
2. humicap as claimed in claim 1, it is characterised in that:The housing includes the first conductive part, the second conductive part And encapsulating film;The bottom electrode is fixed on the first conductive part;The Top electrode is electrically connected by electric-conductor with the second conductive part Connect;The encapsulating film covers the opening of housing, and by chip package in the housing.
3. humicap as claimed in claim 2, it is characterised in that:The electric-conductor is gold thread.
4. humicap as claimed in claim 1, it is characterised in that:The Top electrode be gold, silver, aluminium, platinum, tantalum, copper, chromium, Nickel, molybdenum, niobium or titanium Top electrode, or the alloy Top electrode comprising more than at least two metals;The bottom electrode be gold, silver, aluminium, Platinum, tantalum, copper, chromium, nickel, molybdenum, niobium or titanium bottom electrode, or the alloy bottom electrode comprising more than at least two metals.
5. humicap as claimed in claim 4, it is characterised in that:The Top electrode is molybdenum-Cr-Ni Electroplating on Al Alloys pole;Under described Electrode is molybdenum-aluminium alloy bottom electrode.
6. humicap as claimed in claim 1, it is characterised in that:The through hole be grid-shaped through hole, grill-shaped through hole or Manhole.
7. humicap as claimed in claim 1, it is characterised in that:The organic polymer humidity-sensitive film is polymethylacrylic acid Hydroxyl ethyl ester humidity-sensitive film or polyimides humidity-sensitive film.
8. humicap as claimed in claim 1, it is characterised in that:The thickness of the humidity-sensitive film is 0.4~1.2um.
9. a kind of manufacture method of humicap as claimed in claim 1, it is characterised in that:Comprise the following steps:
1) substrate acid solution, alkaline solution are cleaned successively, then successively using ionized water, acetone and absolute ethyl alcohol super 10~20min for the treatment of is carried out to substrate under the conditions of sound, is finally dried up with nitrogen;
2) by the method for chemical vapor deposition, in one layer of dielectric layer of superficial growth of substrate;
3) humidity-sensitive film is laid on the surface of dielectric layer by automatic sol evenning machine;
4) Top electrode is set in the way of vacuum evaporation on humidity-sensitive film, bottom electrode is set in the lower section of substrate;
5) through hole is etched in Top electrode in the method for photoetching;
6) by automatic scribing machine by chip cutting;
7) by chip package in the housing.
10. the manufacture method of humicap as claimed in claim 9, it is characterised in that:The step 7) including procedure below:
1. chip is fixed on the first conductive part of housing by conducting resinl by automatic bonder;
2. Top electrode is bound with the second conductive part electric-conductor by automatic wire binding machine and is connected;
3. the opening of housing is covered using encapsulating film, and, obtains humicap by chip package in the housing.
CN201710076264.9A 2017-02-13 2017-02-13 Humidity sensitive capacitor and manufacturing method thereof Pending CN106680333A (en)

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111909376A (en) * 2020-06-21 2020-11-10 浙江大学 Oil liquid corrosion resistant dynamic absorption-dehydration high polymer composite sensitive material and preparation method thereof
CN112710706A (en) * 2020-12-08 2021-04-27 北京智芯微电子科技有限公司 Humidity sensor
CN113390931A (en) * 2021-05-28 2021-09-14 苏州锐光科技有限公司 Upper electrode material for capacitive humidity sensor and preparation method thereof

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CN202837224U (en) * 2012-10-31 2013-03-27 中国电子科技集团公司第四十九研究所 Capacitive high molecular humidity sensor with micron grid-shaped porous electrode
CN103149246A (en) * 2012-09-27 2013-06-12 中国石油大学(华东) Graphene film humidity sensor
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CN104409485A (en) * 2014-12-05 2015-03-11 国家电网公司 Planar gate IGBT with low-reverse transfer capacitance and anti-latch-up structure and manufacturing method of planar gate IGBT
CN104810283A (en) * 2015-05-13 2015-07-29 国网智能电网研究院 IGBT (Insulated Gate Bipolar Transistor) chip manufacturing method for crimped type package
CN104914138A (en) * 2015-07-03 2015-09-16 深圳市共进电子股份有限公司 Humidity sensor, humidity sensor array and preparation method thereof
CN106298897A (en) * 2015-05-15 2017-01-04 国网智能电网研究院 A kind of planar gate IGBT with separate type colelctor electrode and preparation method thereof
CN206557144U (en) * 2017-02-13 2017-10-13 广州奥松电子有限公司 A kind of humicap

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CN1117196A (en) * 1994-07-16 1996-02-21 东南大学 Inorganic thin film humidity-sensitive element with high performance and its producing method
JP2000009635A (en) * 1998-06-25 2000-01-14 Sanyo Electric Co Ltd Water content sensor and organic material treatment apparatus using the same
JP2000046785A (en) * 1998-07-27 2000-02-18 Sanyo Electric Co Ltd Water content sensor and organic material treating apparatus using the same
CN2397609Y (en) * 1999-09-02 2000-09-20 清华同方股份有限公司 High-capacity high-molecular humidity sensitive element
CN1455250A (en) * 2003-06-12 2003-11-12 东南大学 Capacitance type relative humidity sensor
CN1577866A (en) * 2003-07-25 2005-02-09 台湾积体电路制造股份有限公司 Capacitor with improved capacitance density and method of manufacture
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111909376A (en) * 2020-06-21 2020-11-10 浙江大学 Oil liquid corrosion resistant dynamic absorption-dehydration high polymer composite sensitive material and preparation method thereof
CN111909376B (en) * 2020-06-21 2021-06-01 浙江大学 Oil liquid corrosion resistant dynamic absorption-dehydration high polymer composite sensitive material and preparation method thereof
CN112710706A (en) * 2020-12-08 2021-04-27 北京智芯微电子科技有限公司 Humidity sensor
CN113390931A (en) * 2021-05-28 2021-09-14 苏州锐光科技有限公司 Upper electrode material for capacitive humidity sensor and preparation method thereof

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