CN106673697A - Ceramic for purifying water and preparation method of ceramic - Google Patents

Ceramic for purifying water and preparation method of ceramic Download PDF

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CN106673697A
CN106673697A CN201710018156.6A CN201710018156A CN106673697A CN 106673697 A CN106673697 A CN 106673697A CN 201710018156 A CN201710018156 A CN 201710018156A CN 106673697 A CN106673697 A CN 106673697A
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parts
powder
ceramics
ceramic
diluent
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郑颖馨
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Yongan City Renmai Information Technology Service Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/03Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on magnesium oxide, calcium oxide or oxide mixtures derived from dolomite
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    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • C04B38/063Preparing or treating the raw materials individually or as batches
    • C04B38/0635Compounding ingredients
    • C04B38/0645Burnable, meltable, sublimable materials
    • C04B38/068Carbonaceous materials, e.g. coal, carbon, graphite, hydrocarbons
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    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5007Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with salts or salty compositions, e.g. for salt glazing
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3201Alkali metal oxides or oxide-forming salts thereof
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3232Titanium oxides or titanates, e.g. rutile or anatase
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3232Titanium oxides or titanates, e.g. rutile or anatase
    • C04B2235/3234Titanates, not containing zirconia
    • C04B2235/3236Alkaline earth titanates
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/48Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The invention discloses ceramic for purifying water. The ceramic is prepared from the raw materials in parts by weight as follows: 24-38 parts of calcium oxide powder, 10-26 parts of alumina powder, 4-43 parts of titanium dioxide powder, 11-23 parts of barium titanate powder, 3 parts of silicon dioxide powder, 1-8 parts of sodium oxide powder, 2-4 parts of radix scutellariae, 0.8-2.3 parts of lonicera japonica, 3-6 parts of organic resin, 4-8 parts of an organic thinner and 1.5-2.6 parts of isopropyl alcohol. The ceramic for purifying water contains a certain amount of uniformly distributed carbonate in sintered powder, and carbonate and other insoluble oxides play a role in increasing hydrolysis resistance during hydrolysis of the oxides; the ceramic has the porosity of a material and oxidizability of raw materials after aging, has the special performance of releasing different types of reactive oxygen in the presence of water and long enough service life, has the effect of reducing toxic organic matter, has the function of killing microbes and algae spores, and is low and smooth in hydrolysis speed and long in service life.

Description

A kind of ceramics for purified water and preparation method thereof
Technical field
The present invention relates to a kind of ceramics, a kind of ceramics for purified water and preparation method thereof are referred specifically to.
Background technology
With the progress and the improvement of people's living standards of society, people propose requirement higher, people to quality of the life The situation of water of life and living environment is increasingly paid attention to, on the one hand the development of industrial technology improves the life of people Quality, on the other hand also causes certain pollution to environment, and particularly to the pollution of water, water is Source of life, improves the mankind The quality of drinking water has unusual meaning to health.
The sterilized and sterilizing function of ceramic material and its product is a key property of such material and its product, at present What is used is always physical sterilization and chemical disinfection, and physical sterilization includes high temperature, radiation, drying, ultrasonic wave, osmotic pressure And filtering.Chemical disinfection includes mating type disinfectant and oxidized form disinfectant, and physical sterilization is convenient economical, but uses bar Part is difficult to meet;Chemical disinfection Disinfection Effect is preferable, but use cost is high, and physical sterilization and chemical disinfection make Secondary pollution can be all caused with improper.
The content of the invention
Require that low, Disinfection Effect is good, economical and practical and is difficult it is a primary object of the present invention to provide a kind of use condition Cause ceramics for purified water of secondary pollution and preparation method thereof.
In order to solve the above-mentioned technical problem, the present invention is adopted the following technical scheme that:
A kind of ceramics for purified water, are prepared from by the raw material of following weight portion:Calcium oxide powder 24-38 parts, alumina powder 10-26 parts, titanium dioxide powder 4-43 parts, barium titanate powder 11-23 parts, silicon dioxide powder 3-20 parts, oxidation 1-8 parts of sodium powder, scutellaria 2-4 parts, honeysuckle 0.8-2.3 parts, organic resin 3-6 parts, organic solvent or diluent 4-8 parts and b propanol 1.5-2.6 parts.
A kind of described ceramics for purified water, are prepared from by the raw material of following weight portion:Calcium oxide powder 30-38 Part, alumina powder 16-26 parts, titanium dioxide powder 16-43 parts, barium titanate powder 16-23 parts, silicon dioxide powder 8-20 parts, sodium oxide molybdena Powder 3-8 parts, scutellaria 2-4 parts, honeysuckle 1.2-2.3 parts, organic resin 4-6 parts, organic solvent or diluent 6-8 parts and b propanol 1.9-2.6 Part.
A kind of described ceramics for purified water, are prepared from by the raw material of following weight portion:34 parts of calcium oxide powder, oxygen Change 20 parts of aluminium powder, 31 parts of titanium dioxide powder, 19 parts of barium titanate powder, 13 parts of silicon dioxide powder, 6 parts of sodium powder of oxidation, 3 parts of scutellaria, gold 2 parts of 1.8 parts of honeysuckle flower, 5 parts of organic resin, 7 parts of organic solvent or diluent and b propanol.
A kind of described ceramic preparation method for purified water, its step is as follows:
(1)Scutellaria and honeysuckle are mixed, is crushed after drying, obtain herbal powder;
(2)Calcium oxide powder, alumina powder, titanium dioxide powder, silicon dioxide powder and oxidation sodium powder are respectively adopted ball mill and carried out 150-300 mesh is crushed and be ground to, is uniformly mixed with herbal powder, deionized water and b propanol are added, using 5- The pressure extrusion shaping of 8Mpa, shaping idiosome is dried 30-60 minutes at 70-95 DEG C, then in 1000-1200 DEG C of sintering furnace Middle sintering 2-4 hours, obtains porous ceramics;
(3)Barium titanate powder is incorporated while stirring in organic resin, while adding organic solvent or diluent, stirring is added after 2-3 hours and gone Ionized water, is stirred for 20-55 minutes, obtains colloidal sol;
(4)Porous ceramics is used into spray-on process plated film with colloidal sol, treatment is then dried;
(5)Porous ceramics after plated film is carried out into acid treatment, is then washed, be finally dried with clean hot-air, Obtain final product ceramics.
Knowable to the above-mentioned description of this invention, compared to the prior art, the advantage of the invention is that:Use prepared by the present invention Comprising carbonate that is a number of, being evenly distributed in the ceramics of purified water, the powder after sintering, in oxide hydrolysis During, carbonate and other slightly solubility oxides play a part of to increase hydrolysis resistance;Possess the porous and raw material of material Oxidisability after curing, possesses and meets property and enough service life that water discharges different type active oxygen, possesses The effect of degraded toxic organic compound, possesses the function of the robe of destroying microorganisms and algae, and hydrolysis rate is slow and steady, uses Life-span is permanent.
Specific embodiment
Specific embodiment of the invention is illustrated below
Embodiment one
A kind of ceramics for purified water, are prepared from by the raw material of following weight portion:34 parts of calcium oxide powder, alumina powder 20 Part, 31 parts of titanium dioxide powder, 19 parts of barium titanate powder, 13 parts of silicon dioxide powder, 6 parts of sodium powder of oxidation, 3 parts of scutellaria, honeysuckle 1.8 Part, 5 parts of organic resin, 7 parts of organic solvent or diluent and 2 parts of b propanol.
Organic solvent or diluent is organic diluent, and the main component of organic solvent or diluent used by the present embodiment is cyclohexanone and positive fourth Alcohol.
A kind of described ceramic preparation method for purified water, its step is as follows:
(1)Scutellaria and honeysuckle are mixed, is crushed after drying, obtain herbal powder;
(2)Calcium oxide powder, alumina powder, titanium dioxide powder, silicon dioxide powder and oxidation sodium powder are respectively adopted ball mill and carried out 260 mesh are crushed and be ground to, is uniformly mixed with herbal powder, add deionized water and b propanol, using the pressure of 7Mpa Power extrusion forming, shaping idiosome is dried 50 minutes at 88 DEG C, is then sintered 2.7 hours in 1120 DEG C of sintering furnace, is obtained Porous ceramics;
(3)During barium titanate powder to incorporate organic resin while stirring, while add organic solvent or diluent, stirring added after 3 hours go from Sub- water, is stirred for 50 minutes, obtains colloidal sol;
(4)Porous ceramics is used into spray-on process plated film with colloidal sol, treatment is then dried;
(5)Porous ceramics after plated film is carried out into acid treatment, is then washed, be finally dried with clean hot-air, Obtain final product ceramics.
Embodiment two
A kind of ceramics for purified water, are prepared from by the raw material of following weight portion:24 parts of calcium oxide powder, alumina powder 10 Part, 4 parts of titanium dioxide powder, 11 parts of barium titanate powder, 3 parts of silicon dioxide powder, oxidation 1 part of sodium powder, 2 parts of scutellaria, 0.8 part of honeysuckle, 1.5 parts of 3 parts of organic resin, 4 parts of organic solvent or diluent and b propanol.
Organic solvent or diluent is organic diluent, and the main component of organic solvent or diluent used by the present embodiment is cyclohexanone and positive fourth Alcohol.
A kind of described ceramic preparation method for purified water, its step is as follows:
(1)Scutellaria and honeysuckle are mixed, is crushed after drying, obtain herbal powder;
(2)Calcium oxide powder, alumina powder, titanium dioxide powder, silicon dioxide powder and oxidation sodium powder are respectively adopted ball mill and carried out 150 mesh are crushed and be ground to, is uniformly mixed with herbal powder, add deionized water and b propanol, using the pressure of 5Mpa Power extrusion forming, shaping idiosome is dried 30 minutes at 70 DEG C, is then sintered 2 hours in 1000 DEG C of sintering furnace, obtains many Hole ceramics;
(3)During barium titanate powder to incorporate organic resin while stirring, while add organic solvent or diluent, stirring added after 2 hours go from Sub- water, is stirred for 20 minutes, obtains colloidal sol;
(4)Porous ceramics is used into spray-on process plated film with colloidal sol, treatment is then dried;
(5)Porous ceramics after plated film is carried out into acid treatment, is then washed, be finally dried with clean hot-air, Obtain final product ceramics.
Embodiment three
A kind of ceramics for purified water, are prepared from by the raw material of following weight portion:38 parts of calcium oxide powder, alumina powder 26 Part, 43 parts of titanium dioxide powder, 23 parts of barium titanate powder, 20 parts of silicon dioxide powder, 8 parts of sodium powder of oxidation, 4 parts of scutellaria, honeysuckle 2.3 Part, 6 parts of organic resin, 8 parts of organic solvent or diluent and 2.6 parts of b propanol.
Organic solvent or diluent is organic diluent, and the main component of organic solvent or diluent used by the present embodiment is cyclohexanone and positive fourth Alcohol.
A kind of described ceramic preparation method for purified water, its step is as follows:
(1)Scutellaria and honeysuckle are mixed, is crushed after drying, obtain herbal powder;
(2)Calcium oxide powder, alumina powder, titanium dioxide powder, silicon dioxide powder and oxidation sodium powder are respectively adopted ball mill and carried out 300 mesh are crushed and be ground to, is uniformly mixed with herbal powder, add deionized water and b propanol, using the pressure of 8Mpa Power extrusion forming, shaping idiosome is dried 60 minutes at 95 DEG C, is then sintered 4 hours in 1200 DEG C of sintering furnace, obtains many Hole ceramics;
(3)During barium titanate powder to incorporate organic resin while stirring, while add organic solvent or diluent, stirring added after 3 hours go from Sub- water, is stirred for 55 minutes, obtains colloidal sol;
(4)Porous ceramics is used into spray-on process plated film with colloidal sol, treatment is then dried;
(5)Porous ceramics after plated film is carried out into acid treatment, is then washed, be finally dried with clean hot-air, Obtain final product ceramics.
Sewage using the porous ceramic filter element made by above-described embodiment respectively to being gathered is purified, water after purification Indices it is as shown in table 1.
Water quality index after the sewage of table 1 and its purification
As seen from Table 1, the ceramics obtained by the inventive method have obvious clean-up effect to water.Colourity reduction, the face of water Discoloration it is limpid.Haze reduction, illustrates that suspension is reduced in water, to light through when the obstruction degree reduction that produces.PH value is One index of reaction water acid-base property, the suitable human body for showing slightly alkalescence is drunk.Soluble solid content is reduced, the impurity in water Reduce.Total hardness refers to the total concentration of the precipitation that some metal ions in water are produced together with some anion bindings, firmly The easy fouling of the degree water capacity high produces precipitation, precipitates fewer in the lower water of hardness number.Total plate count is that reaction water quality receives biological pollution One index of degree, the reduction explanation water quality of total plate count is made moderate progress by the degree of biological pollution.
Specific embodiment of the invention is above are only, but design concept of the invention is not limited thereto, it is all to utilize this Design carries out the change of unsubstantiality to the present invention, all should belong to the behavior for invading the scope of the present invention.

Claims (4)

1. a kind of ceramics for purified water, it is characterised in that be prepared from by the raw material of following weight portion:Calcium oxide powder 24- 38 parts, alumina powder 10-26 parts, titanium dioxide powder 4-43 parts, barium titanate powder 11-23 parts, silicon dioxide powder 3-20 parts, sodium oxide molybdena Powder 1-8 parts, scutellaria 2-4 parts, honeysuckle 0.8-2.3 parts, organic resin 3-6 parts, organic solvent or diluent 4-8 parts and b propanol 1.5-2.6 Part.
2. a kind of ceramics for purified water as claimed in claim 1, it is characterised in that prepared by the raw material of following weight portion Form:Calcium oxide powder 30-38 parts, alumina powder 16-26 parts, titanium dioxide powder 16-43 parts, barium titanate powder 16-23 parts, titanium dioxide Silica flour 8-20 parts, oxidation 3-8 parts of sodium powder, scutellaria 2-4 parts, honeysuckle 1.2-2.3 parts, organic resin 4-6 parts, organic solvent or diluent 6-8 Part and b propanol 1.9-2.6 parts.
3. a kind of ceramics for purified water as claimed in claim 2, it is characterised in that prepared by the raw material of following weight portion Form:34 parts of calcium oxide powder, 20 parts of alumina powder, 31 parts of titanium dioxide powder, 19 parts of barium titanate powder, 13 parts of silicon dioxide powder, oxygen Change 2 parts of 6 parts of sodium powder, 3 parts of scutellaria, 1.8 parts of honeysuckle, 5 parts of organic resin, 7 parts of organic solvent or diluent and b propanol.
4. a kind of ceramic preparation method for purified water as described in claim 1 or 2 or 3, it is characterised in that its step It is as follows:
(1)Scutellaria and honeysuckle are mixed, is crushed after drying, obtain herbal powder;
(2)Calcium oxide powder, alumina powder, titanium dioxide powder, silicon dioxide powder and oxidation sodium powder are respectively adopted ball mill and carried out 150-300 mesh is crushed and be ground to, is uniformly mixed with herbal powder, deionized water and b propanol are added, using 5- The pressure extrusion shaping of 8Mpa, shaping idiosome is dried 30-60 minutes at 70-95 DEG C, then in 1000-1200 DEG C of sintering furnace Middle sintering 2-4 hours, obtains porous ceramics;
(3)Barium titanate powder is incorporated while stirring in organic resin, while adding organic solvent or diluent, stirring is added after 2-3 hours and gone Ionized water, is stirred for 20-55 minutes, obtains colloidal sol;
(4)Porous ceramics is used into spray-on process plated film with colloidal sol, treatment is then dried;
(5)Porous ceramics after plated film is carried out into acid treatment, is then washed, be finally dried with clean hot-air, Obtain final product ceramics.
CN201710018156.6A 2017-01-11 2017-01-11 Ceramic for purifying water and preparation method of ceramic Pending CN106673697A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107640964A (en) * 2017-11-09 2018-01-30 江西新景象陶瓷有限公司 A kind of ceramic material for filter water and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107640964A (en) * 2017-11-09 2018-01-30 江西新景象陶瓷有限公司 A kind of ceramic material for filter water and preparation method thereof

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