CN106634681A - Environment-friendly wood board adhesive and preparation method thereof - Google Patents
Environment-friendly wood board adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN106634681A CN106634681A CN201611171641.9A CN201611171641A CN106634681A CN 106634681 A CN106634681 A CN 106634681A CN 201611171641 A CN201611171641 A CN 201611171641A CN 106634681 A CN106634681 A CN 106634681A
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- Prior art keywords
- parts
- wood board
- friendly wood
- starch
- environmental
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses an environment-friendly wood board adhesive and a preparation method thereof. The environment-friendly wood board adhesive is composed of the following components in parts by mass: 25-35 parts of starch, 10-20 parts of natural latex, 6-8 parts of methyltrimethoxy silane, 6-10 parts of copper sulfate, 10-12 parts of sodium silicate, 6-8 parts of polyketone amine, 6-8 parts of polyacrylate, 6-8 parts of potassium hydroxide, 7-9 parts of calcium carbonate, 15-25 parts of natural resin, 1-2 parts of initiator and 10-20 parts of base adhesive mother solution. The waste plastics and rubber are used as raw materials, thereby being beneficial to reducing the environmental pollution and saving the material resources. The environment-friendly wood board adhesive has the advantage of low production cost, and can be used for bonding multiple materials, particularly wood boards, plywoods, fiberboards and other wood board materials.
Description
Technical field
The present invention relates to glued board technical field, in particular to a kind of environmental-friendly wood board bonder and its preparation
Method.
Background technology
At present adhesive has many types, and due to the difference of its raw material, the performance of glue is different according to respective composition
In having very big difference, but most of adhesive, such as benzene,toluene,xylene, formaldehyde nuisance are contained such as in phenolic resin glue
Matter composition, Long-Time Service is not only to environment, and the health of infringement people, in addition, the manufacturing process of these binding agents
It is complex, it is relatively costly.
On the other hand, the consumption of China's polystyrene foam plastics and rubber is increasing, and major part is all one
Secondary property is used, and millions of ton of white garbage and waste rubber goodses dissipate and can neither rot to convert in nature, again can not be certainly
So degraded, forms serious pollution, and the processing mode current for these pollutants is usually burned and filled, wherein landfill will
Substantial amounts of place is taken, and burning can then produce new air pollution problems inherent.
The content of the invention
The invention provides a kind of environmental-friendly wood board bonder and preparation method thereof, the present invention using waste or used plastics and
Rubber is raw material, is conducive to reducing environmental pollution, saves material goods, and low production cost, respectively special for multiple material
It is the bonding of the wooden boards such as plank, glued board, fiberboard.
For achieving the above object, the present invention provides following technical scheme：
A kind of environmental-friendly wood board bonder and preparation method thereof, is made up of following mass fraction formula components：Starch
25-35 parts, natural emulsion 10-20 parts, MTMS 6-8 parts, copper sulphate 6-10 parts, sodium metasilicate 10-12 parts, polyketone
Amine 6-8 parts, polyacrylate salts 6-8 parts, potassium hydroxide 6-8 parts, calcium carbonate 7-9 parts, natural resin 15-25 parts, initiator 1-2
Part, base-material glue mother liquor 10-20 parts.
Further：It is made up of following mass fraction formula components：25 parts of starch, 10 parts of natural emulsion, methyl trimethoxy epoxide
6 parts of silane, 6 parts of copper sulphate, 10 parts of sodium metasilicate, 6 parts of polyketone amine, 6 parts of polyacrylate salts, 6 parts of potassium hydroxide, calcium carbonate 7 part, day
Right 15 parts of resin, 1 part of initiator, 10 parts of base-material glue mother liquor.
Further：It is made up of following mass fraction formula components：30 parts of starch, 15 parts of natural emulsion, methyl trimethoxy epoxide
7 parts of silane, 8 parts of copper sulphate, 11 parts of sodium metasilicate, 7 parts of polyketone amine, 7 parts of polyacrylate salts, 7 parts of potassium hydroxide, calcium carbonate 8 part, day
Right 20 parts of resin, 1.5 parts of initiator, 15 parts of base-material glue mother liquor.
Further：It is made up of following mass fraction formula components：35 parts of starch, 20 parts of natural emulsion, methyl trimethoxy epoxide
8 parts of silane, 10 parts of copper sulphate, 12 parts of sodium metasilicate, 8 parts of polyketone amine, 8 parts of polyacrylate salts, 8 parts of potassium hydroxide, 9 parts of calcium carbonate,
25 parts of natural resin, 2 parts of initiator, 20 parts of base-material glue mother liquor.
Further：Preparation method of the present invention has following steps：
Step one, with starch, natural emulsion, natural resin, base-material glue mother liquor as main material, support solvent；
Step 2, initiator is added in batches；
Step 3, various raw materials are put into retort, stirred at a temperature of 65 DEG C -100 DEG C, be allowed to fully polymerization anti-
Answer 2 hours, cooling obtains final product the binder product of the present invention.
The invention has the beneficial effects as follows：The present invention adopts waste or used plastics and rubber for raw material, is conducive to reducing environmental pollution,
Material goods, and low production cost are saved, respectively the wooden boards such as plank, glued board, fiberboard is particularly for multiple material
Bonding.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment one：
A kind of environmental-friendly wood board bonder is made up of following mass fraction formula components：Starch 25-35 parts, genuine milk
Glue 10-20 parts, MTMS 6-8 parts, copper sulphate 6-10 parts, sodium metasilicate 10-12 parts, polyketone amine 6-8 parts, polypropylene
Hydrochlorate 6-8 parts, potassium hydroxide 6-8 parts, calcium carbonate 7-9 parts, natural resin 15-25 parts, initiator 1-2 parts, base-material glue mother liquor 10-
20 parts.
Embodiment two：
A kind of environmental-friendly wood board bonder is made up of following mass fraction formula components：25 parts of starch, natural emulsion
10 parts, 6 parts of MTMS, 6 parts of copper sulphate, 10 parts of sodium metasilicate, 6 parts of polyketone amine, 6 parts of polyacrylate salts, hydroxide
6 parts of potassium, 7 parts of calcium carbonate, 15 parts of natural resin, 1 part of initiator, 10 parts of base-material glue mother liquor.
Embodiment three：
A kind of environmental-friendly wood board bonder is made up of following mass fraction formula components：30 parts of starch, natural emulsion
15 parts, 7 parts of MTMS, 8 parts of copper sulphate, 11 parts of sodium metasilicate, 7 parts of polyketone amine, 7 parts of polyacrylate salts, hydroxide
7 parts of potassium, 8 parts of calcium carbonate, 20 parts of natural resin, 1.5 parts of initiator, 15 parts of base-material glue mother liquor.
Example IV：
A kind of environmental-friendly wood board bonder is made up of following mass fraction formula components：35 parts of starch, natural emulsion
20 parts, 8 parts of MTMS, 10 parts of copper sulphate, 12 parts of sodium metasilicate, 8 parts of polyketone amine, 8 parts of polyacrylate salts, hydroxide
8 parts of potassium, 9 parts of calcium carbonate, 25 parts of natural resin, 2 parts of initiator, 20 parts of base-material glue mother liquor.
Embodiment five：
A kind of preparation method preparation method of environmental-friendly wood board bonder comprises the steps：
Step one, with starch, natural emulsion, natural resin, base-material glue mother liquor as main material, support solvent；
Step 2, initiator is added in batches；
Step 3, various raw materials are put into retort, stirred at a temperature of 65 DEG C -100 DEG C, be allowed to fully polymerization anti-
Answer 2 hours, cooling obtains final product the binder product of the present invention.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity those skilled in the art should
Using specification as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art
Understandable other embodiment.
Claims (5)
1. a kind of environmental-friendly wood board bonder, it is characterised in that：It is made up of following mass fraction formula components：
Starch 25-35 parts, natural emulsion 10-20 parts, MTMS 6-8 parts, copper sulphate 6-10 parts, sodium metasilicate 10-
12 parts, polyketone amine 6-8 parts, polyacrylate salts 6-8 parts, potassium hydroxide 6-8 parts, calcium carbonate 7-9 parts, natural resin 15-25 parts, draw
Send out agent 1-2 parts, base-material glue mother liquor 10-20 parts.
2. a kind of environmental-friendly wood board bonder according to claim 1, it is characterised in that：Matched somebody with somebody by following mass fraction
Side is into being grouped into：
25 parts of starch, 10 parts of natural emulsion, 6 parts of MTMS, 6 parts of copper sulphate, 10 parts of sodium metasilicate, 6 parts of polyketone amine,
6 parts of polyacrylate salts, 6 parts of potassium hydroxide, 7 parts of calcium carbonate, 15 parts of natural resin, 1 part of initiator, 10 parts of base-material glue mother liquor.
3. a kind of environmental-friendly wood board bonder according to claim 1, it is characterised in that：Matched somebody with somebody by following mass fraction
Side is into being grouped into：
30 parts of starch, 15 parts of natural emulsion, 7 parts of MTMS, 8 parts of copper sulphate, 11 parts of sodium metasilicate, 7 parts of polyketone amine,
7 parts of polyacrylate salts, 7 parts of potassium hydroxide, 8 parts of calcium carbonate, 20 parts of natural resin, 1.5 parts of initiator, 15 parts of base-material glue mother liquor.
4. a kind of environmental-friendly wood board bonder according to claim 1, it is characterised in that：Matched somebody with somebody by following mass fraction
Side is into being grouped into：
35 parts of starch, 20 parts of natural emulsion, 8 parts of MTMS, 10 parts of copper sulphate, 12 parts of sodium metasilicate, polyketone amine 8
Part, 8 parts of polyacrylate salts, 8 parts of potassium hydroxide, 9 parts of calcium carbonate, 25 parts of natural resin, 2 parts of initiator, 20 parts of base-material glue mother liquor.
5. a kind of a kind of preparation method of environmental-friendly wood board bonder according to claim 1, it is characterised in that：Bag
Include following steps：
Step one, with starch, natural emulsion, natural resin, base-material glue mother liquor as main material, support solvent；
Step 2, initiator is added in batches；
Step 3, by various raw materials put into retort, stir at a temperature of 65 DEG C -100 DEG C, be allowed to abundant polymerisation 2
Hour, cooling obtains final product the binder product of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611171641.9A CN106634681A (en) | 2016-12-17 | 2016-12-17 | Environment-friendly wood board adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611171641.9A CN106634681A (en) | 2016-12-17 | 2016-12-17 | Environment-friendly wood board adhesive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106634681A true CN106634681A (en) | 2017-05-10 |
Family
ID=58823170
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611171641.9A Pending CN106634681A (en) | 2016-12-17 | 2016-12-17 | Environment-friendly wood board adhesive and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109233690A (en) * | 2018-07-17 | 2019-01-18 | 林昭佳 | A kind of emulsion adhesive |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101580692A (en) * | 2008-05-14 | 2009-11-18 | 北京道顺国际技术开发有限责任公司 | Multifunctional bonder prepared by utilizing waste materials and preparation method thereof |
| CN101580697A (en) * | 2008-05-14 | 2009-11-18 | 北京道顺国际技术开发有限责任公司 | Environmental-friendly wood board bonder and preparation method thereof |
| CN101580691A (en) * | 2008-05-14 | 2009-11-18 | 北京道顺国际技术开发有限责任公司 | Wood board bonder prepared by adopting waste materials and preparation method thereof |
-
2016
- 2016-12-17 CN CN201611171641.9A patent/CN106634681A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101580692A (en) * | 2008-05-14 | 2009-11-18 | 北京道顺国际技术开发有限责任公司 | Multifunctional bonder prepared by utilizing waste materials and preparation method thereof |
| CN101580697A (en) * | 2008-05-14 | 2009-11-18 | 北京道顺国际技术开发有限责任公司 | Environmental-friendly wood board bonder and preparation method thereof |
| CN101580691A (en) * | 2008-05-14 | 2009-11-18 | 北京道顺国际技术开发有限责任公司 | Wood board bonder prepared by adopting waste materials and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109233690A (en) * | 2018-07-17 | 2019-01-18 | 林昭佳 | A kind of emulsion adhesive |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170510 |
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| RJ01 | Rejection of invention patent application after publication |