CN101580691A - Wood board bonder prepared by adopting waste materials and preparation method thereof - Google Patents
Wood board bonder prepared by adopting waste materials and preparation method thereof Download PDFInfo
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- CN101580691A CN101580691A CNA2008101065510A CN200810106551A CN101580691A CN 101580691 A CN101580691 A CN 101580691A CN A2008101065510 A CNA2008101065510 A CN A2008101065510A CN 200810106551 A CN200810106551 A CN 200810106551A CN 101580691 A CN101580691 A CN 101580691A
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Abstract
The invention relates to wood board bonder prepared by adopting waste materials and a preparation method thereof. The bonder comprises raw materials of 45-55 portions of base glue mother liquid, 10-15 portions of natural emulsion, 5-10 portions of special organosilicone coupling agent, 1.5-3 portions of polyacrylate, 0.5-1 portion of potassium hydroxide, 1.5-3 portions of zinc oxide and 1-6 portions of calcium carbonate, wherein the special base glue mother liquid is prepared by adopting No.200 solvent naphtha to dissolve waste polystyrene and waste rubber tires, and the special organosilicone coupling agent is obtained in such a way that asphaltum and waste glass react in a high-temperature reactor. The raw materials are put in a retort and are evenly stirred at the temperature of 65-100 DEG C so as to be processed by polymerization for 2 hours, and the bonder is obtained after cooling the product of reaction. The invention is beneficial to reducing environmental pollution and reducing production cost and being suitable for the binding of various materials, in particular the wood boards such as boards, veneers, fiberboards, and the like.
Description
Technical field
The present invention relates to a kind of wood board bonder that adopts the waste materials preparation and preparation method thereof.
Background technology
Tackiness agent has many types at present, because its raw-material difference, the performance of glue has very big-difference according to composition difference separately, but in most of tackiness agent, as containing in the Phenol aldehyde resin such as objectionable impurities compositions such as benzene,toluene,xylene, formaldehyde, life-time service not only pollutes environment, and infringement people's health, in addition, the manufacturing process of these binding agents is comparatively complicated, and cost is higher.
On the other hand, the consumption of China's polystyrene foamed plastics and rubber item is increasing, and major part all is disposable use, millions of ton white garbage and waste rubber goods loose and can not rot to transform in nature, again can not natural degradation, form serious pollution, generally be to burn and landfill for the present processing mode of these pollutents, wherein landfill will take a large amount of places, burns and then can produce new air pollution problems inherent
Summary of the invention
For overcoming the above-mentioned defective of prior art, the invention provides a kind of wood board bonder that adopts the waste materials preparation and preparation method thereof, it is raw material that this binding agent adopts waste or used plastics and rubber, turn waste into wealth, help reducing environmental pollution, save material goods, and production cost is low, unharmful substance.Particularly, help the bonding of wooden boards owing to added permeate agent.
The present invention realizes that the technical scheme of above-mentioned purpose is: a kind of wood board bonder that adopts the waste materials preparation, its raw material is a base-material glue mother liquor, natural emulsion, the special-purpose organic silicon coupling agent, the polypropylene hydrochlorate, potassium hydroxide, zinc oxide and lime carbonate, base-material glue mother liquor 45-55 part (mass parts wherein, down together), natural emulsion 10-15 part, special-purpose organic silicon coupling agent 5-10 part, polypropylene hydrochlorate 1.5-3 part, potassium hydroxide 0.5-1 part, zinc oxide 1.5-3 part, lime carbonate 1-6 part, the preparation method of described special-purpose base-material glue mother liquor is to adopt No. 200 solvent oils to dissolve waste and old polystyrol and waste and used rubber tyre, wherein each proportion of raw materials is waste and used rubber tyre 10-25 part, waste and old polystyrol 30-35 part, No. 200 solvent oil 45-80 parts, and make described special-purpose base-material glue mother liquor through 2 hours polyreaction, the preparation method of described special-purpose organic silicon coupling agent cleans fragmentation with the discarded glass scrubbing, drop in the high-temperature reactor by 0.3: 1 weight ratio with pitch, under 200 ℃ of-250 ℃ of temperature, be stirred to abundant solubilizing reaction and make described special-purpose organic silicon coupling agent.
The preferred addition of various raw materials is:
Base-material glue mother liquor: 48-52 part;
Special-purpose organic silicon coupling agent: 7-8 part;
Natural emulsion: 12-14 part;
Polypropylene hydrochlorate: 1.8-2.2 part;
Potassium hydroxide: 0.6-0.8 part;
Zinc oxide: 2-2.5 part;
Lime carbonate: 3-5 part.
Described base-material glue mother liquor prepares by following manner: adopt No. 200 solvent oils to dissolve waste and old polystyrol and waste and used rubber tyre, wherein each proportion of raw materials is: waste and used rubber tyre 10-25 part, waste and old polystyrol 30-35 part, No. 200 solvent oil 45-80 parts.
The preparation method of the wood board bonder of employing waste materials preparation provided by the invention comprises the steps:
(1) preparation base-material glue mother liquor: with waste and old polystyrol and waste and used rubber tyre is main raw, dissolves waste and old vinylbenzene and waste and used rubber tyre with solvent oil 200#, and base-material glue mother liquor is made in polymerization under the normal temperature;
(2) preparation special-purpose organic silicon coupling agent: fragmentation is cleaned in the discarded glass scrubbing, dropped in the high-temperature reactor by 0.3: 1 weight ratio, under 200 ℃ of-250 ℃ of temperature, be stirred to abundant solubilizing reaction and make described special-purpose organic silicon coupling agent with pitch;
(3) mixing and polymerization: various raw materials are dropped into retort, stir under 65 ℃ of-100 ℃ of temperature, make it abundant polyreaction 2 hours, cooling promptly gets binder product of the present invention.
Tackiness agent of the present invention is to utilize waste and used rubber tyre and waste and old polystyrol to make base-material glue mother liquor, these waste materials have been made full use of, realize the recovery of waste material, turned waste into wealth, saved the raw material data, do not contain objectionable impurities compositions such as benzene, formaldehyde in the various raw materials simultaneously, be a kind of environment-friendly type binding agent, and its binding property is good, the bonding strength height, water resisting property is good, can be used for the bonding of glued board, fiberboard, metal, pottery, glass material.
Embodiment
Provide several specific embodiments below:
Embodiment 1:
The adhesive component proportioning:
Base-material glue mother liquor: 45 parts;
Special-purpose organic silicon coupling agent: 5 parts;
Natural emulsion: 15 parts;
Polypropylene hydrochlorate: 3 parts;
Potassium hydroxide: 0.5 part;
Zinc oxide: 3 parts;
Lime carbonate: 6 parts.
Wherein, base-material glue mother liquor (base-material) component is as follows:
Waste and used rubber tyre: 10 parts;
Waste and old polystyrol: 35 parts;
Solvent oil 200#:60 part.
The preparation method:
(1) preparation base-material glue mother liquor: waste and used rubber tyre and waste and old polystyrol scrubbing cleaned dry, send into then and close envelope formula strong crusher and pulverize, drop in proportion in semi-enclosed container with solvent liquid oil and to stir at normal temperatures, make base-material glue mother liquor;
(2) above-mentioned each raw material is added reactor and under 65-100 ℃ temperature, stir, stir fully, carried out polyreaction 2 hours, allow its naturally cooling leave standstill, carry out the impurity separation then and promptly be prepared into the multifunction green environment protection tackiness agent.
Embodiment 2:
The adhesive component proportioning:
Base-material glue mother liquor: 55 parts;
Special-purpose organic silicon coupling agent: 10 parts;
Natural emulsion: 10 parts;
Polypropylene hydrochlorate: 1.5 parts;
Potassium hydroxide: 1 part;
Zinc oxide: 1.5 parts;
Lime carbonate: 6 parts.
Wherein, base-material glue mother liquor (base-material) component is as follows:
Waste and used rubber tyre: 25 parts;
Waste and old polystyrol: 30 parts;
Solvent oil 200#:40 part.
The preparation method is with embodiment 1.
Embodiment 3:
The adhesive component proportioning:
Base-material glue mother liquor: 50 parts;
Special-purpose organic silicon coupling agent: 7.5 parts;
Natural emulsion: 13 parts;
Polypropylene hydrochlorate: 2 parts;
Potassium hydroxide: 0.7 part;
Zinc oxide: 2.25 parts;
Lime carbonate: 4 parts.
Wherein, base-material glue mother liquor (base-material) component is as follows:
Waste and used rubber tyre: 18 parts;
Waste and old polystyrol: 32 parts;
Solvent oil 200#:80 part.
The preparation method is with embodiment 1.
Embodiment 4:
Base-material glue mother liquor: 48 parts;
Special-purpose organic silicon coupling agent: 7 parts;
Natural emulsion: 14 parts;
Polypropylene hydrochlorate: 2.2 parts;
Potassium hydroxide: 0.6 part;
Zinc oxide: 2 parts;
Lime carbonate: 5 parts.
The proportioning raw materials of base-material glue mother liquor adopts any one among the embodiment 1-3.
The preparation method is with embodiment 1.
Embodiment 5:
Base-material glue mother liquor: 52 parts;
Special-purpose organic silicon coupling agent: 8 parts;
Natural emulsion: 12 parts;
Polypropylene hydrochlorate: 1.8 parts;
Potassium hydroxide: 0.8 part;
Zinc oxide: 2.5 parts;
Lime carbonate: 3 parts.
The proportioning raw materials of base-material glue mother liquor adopts any one among the embodiment 1-3.
The preparation method is with embodiment 1.
Claims (10)
1. wood board bonder that adopts waste materials preparation, it is characterized in that its raw material is a base-material glue mother liquor, the special-purpose organic silicon coupling agent, natural emulsion, the polypropylene hydrochlorate, potassium hydroxide, zinc oxide and lime carbonate, base-material glue mother liquor 45-55 part wherein, special-purpose organic silicon coupling agent 5-10 part, natural emulsion 10-15 part, polypropylene hydrochlorate 1.5-3 part, potassium hydroxide 0.5-1 part, zinc oxide 1.5-3 part, lime carbonate 1-6 part, the preparation method of described special-purpose base-material glue mother liquor is to adopt No. 200 solvent oils to dissolve waste and old polystyrol and waste and used rubber tyre, wherein each proportion of raw materials is waste and used rubber tyre 10-25 part, waste and old polystyrol 30-35 part, No. 200 solvent oil 45-80 parts, and the process polyreaction is made described special-purpose base-material glue mother liquor, the preparation method of described special-purpose organic silicon coupling agent cleans fragmentation with the discarded glass scrubbing, drop in the high-temperature reactor by 0.3: 1 weight ratio with pitch, under 200 ℃ of-250 ℃ of temperature, be stirred to abundant solubilizing reaction and make described special-purpose organic silicon coupling agent.
2. the wood board bonder of employing waste materials preparation as claimed in claim 1 is characterized in that raw material ratio is:
Base-material glue mother liquor: 50 parts;
Special-purpose organic silicon coupling agent: 7.5 parts;
Natural emulsion: 13 parts;
Polypropylene hydrochlorate: 2 parts;
Potassium hydroxide: 0.7 part;
Zinc oxide: 2.25 parts;
Lime carbonate: 4 parts.
3. the wood board bonder of employing waste materials preparation as claimed in claim 1 is characterized in that described base-material glue mother liquor is 48-52 part.
4. the wood board bonder of employing waste materials preparation as claimed in claim 1 is characterized in that natural emulsion is 12-14 part.
5. the wood board bonder of employing waste materials preparation as claimed in claim 1 is characterized in that described special-purpose organic silicon coupling agent is 7-8 part.
6. the wood board bonder of employing waste materials preparation as claimed in claim 1 is characterized in that described polypropylene hydrochlorate is 1.8-2.2 part.
7. the wood board bonder of employing waste materials preparation as claimed in claim 1 is characterized in that zinc oxide 2-2.5 part.
8. the wood board bonder of employing waste materials preparation as claimed in claim 1 is characterized in that potassium hydroxide is 0.6-0.8 part.
9. the wood board bonder of employing waste materials preparation as claimed in claim 1 is characterized in that lime carbonate is 3-5 part.
10. the preparation method of the wood board bonder of employing waste materials preparation as claimed in claim 1 comprises the steps:
(1) preparation base-material glue mother liquor: with waste and old polystyrol and waste and used rubber tyre is main raw, dissolves waste and old vinylbenzene and waste and used rubber tyre with solvent oil 200#, and base-material glue mother liquor is made in polymerization under the normal temperature;
(2) preparation special-purpose organic silicon coupling agent: fragmentation is cleaned in the discarded glass scrubbing, dropped in the high-temperature reactor by 0.3: 1 weight ratio, under 200 ℃ of-250 ℃ of temperature, be stirred to abundant solubilizing reaction and make described special-purpose organic silicon coupling agent with pitch;
(3) mixing and polymerization: various raw materials are dropped into retort, stir under 65 ℃ of-100 ℃ of temperature, make it abundant polyreaction 2 hours, cooling promptly gets binder product of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008101065510A CN101580691A (en) | 2008-05-14 | 2008-05-14 | Wood board bonder prepared by adopting waste materials and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008101065510A CN101580691A (en) | 2008-05-14 | 2008-05-14 | Wood board bonder prepared by adopting waste materials and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101580691A true CN101580691A (en) | 2009-11-18 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008101065510A Pending CN101580691A (en) | 2008-05-14 | 2008-05-14 | Wood board bonder prepared by adopting waste materials and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106590527A (en) * | 2016-12-17 | 2017-04-26 | 浦北县建业胶合板有限责任公司 | Multifunctional environmentally friendly adhesive and preparation method thereof |
| CN106634681A (en) * | 2016-12-17 | 2017-05-10 | 浦北县建业胶合板有限责任公司 | Environment-friendly wood board adhesive and preparation method thereof |
| CN110917726A (en) * | 2019-12-12 | 2020-03-27 | 上海科格思过滤材料有限公司 | Preparation method of novel frameless filter material |
-
2008
- 2008-05-14 CN CNA2008101065510A patent/CN101580691A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106590527A (en) * | 2016-12-17 | 2017-04-26 | 浦北县建业胶合板有限责任公司 | Multifunctional environmentally friendly adhesive and preparation method thereof |
| CN106634681A (en) * | 2016-12-17 | 2017-05-10 | 浦北县建业胶合板有限责任公司 | Environment-friendly wood board adhesive and preparation method thereof |
| CN110917726A (en) * | 2019-12-12 | 2020-03-27 | 上海科格思过滤材料有限公司 | Preparation method of novel frameless filter material |
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| PB01 | Publication | ||
| DD01 | Delivery of document by public notice |
Addressee: Beijing Dorsun International Technology Development Co., Ltd. Document name: Notification that Application Deemed to be Withdrawn |
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20091118 |