CN102199409B - Composite paper board binding agent and preparation method thereof - Google Patents
Composite paper board binding agent and preparation method thereof Download PDFInfo
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- CN102199409B CN102199409B CN201110085626A CN201110085626A CN102199409B CN 102199409 B CN102199409 B CN 102199409B CN 201110085626 A CN201110085626 A CN 201110085626A CN 201110085626 A CN201110085626 A CN 201110085626A CN 102199409 B CN102199409 B CN 102199409B
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- Prior art keywords
- tackiness agent
- water
- binding agent
- vinyl ester
- stablizer
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- 238000002360 preparation method Methods 0.000 title abstract description 36
- 239000011230 binding agent Substances 0.000 title abstract description 10
- 239000011087 paperboard Substances 0.000 title abstract description 7
- 239000002131 composite material Substances 0.000 title abstract 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 72
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 38
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 25
- 229910021538 borax Inorganic materials 0.000 claims abstract description 20
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims description 68
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 46
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 38
- 229920006241 epoxy vinyl ester resin Polymers 0.000 claims description 34
- 239000000839 emulsion Substances 0.000 claims description 31
- 238000003756 stirring Methods 0.000 claims description 26
- 229940106691 bisphenol a Drugs 0.000 claims description 19
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 16
- 229920005989 resin Polymers 0.000 claims description 16
- 239000011347 resin Substances 0.000 claims description 16
- 229920001567 vinyl ester resin Polymers 0.000 claims description 16
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 claims description 15
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 15
- 229940072056 alginate Drugs 0.000 claims description 15
- 229920000615 alginic acid Polymers 0.000 claims description 15
- 235000010443 alginic acid Nutrition 0.000 claims description 15
- -1 phenolic aldehyde Chemical class 0.000 claims description 15
- 229920003023 plastic Polymers 0.000 claims description 15
- 239000002994 raw material Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 4
- 239000003431 cross linking reagent Substances 0.000 abstract description 27
- 238000010521 absorption reaction Methods 0.000 abstract description 15
- 229920002261 Corn starch Polymers 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 3
- 239000008120 corn starch Substances 0.000 abstract 3
- 229940099112 cornstarch Drugs 0.000 abstract 3
- 239000000123 paper Substances 0.000 abstract 2
- 239000003381 stabilizer Substances 0.000 abstract 2
- 238000004132 cross linking Methods 0.000 abstract 1
- 230000032798 delamination Effects 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000011111 cardboard Substances 0.000 description 30
- 239000003292 glue Substances 0.000 description 27
- 229920002472 Starch Polymers 0.000 description 7
- 239000008107 starch Substances 0.000 description 7
- 235000019698 starch Nutrition 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 230000000284 resting effect Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Epoxy Resins (AREA)
Abstract
The invention discloses a composite paper board binding agent and a preparation method thereof. The binding agent is prepared from water, cornstarch, sodium hydroxide, a cross-linking agent, a stabilizer and borax. The preparation method of the composite paper board binding agent comprises the steps of: firstly, uniformly mixing the sodium hydroxide, part of the water and part of the cornstarch to obtain a vector; and secondly, adding the remaining water and the remaining cornstarch to a reaction pot, adding the cross-linking agent and the stabilizer to the reaction pot after uniformly mixing, continuing uniformly mixing, then adding the vector and the borax to the reaction pot, and obtaining the cross-linking composite paper board binding agent after uniformly mixing. The binding agent disclosed by the invention has the advantages of simple ingredient, stable property and long storage cycle; and the preparation method of the binding agent has the advantages of simplicity and low cost of required equipment; the bonding strength of the prepared binding agent reaches more than 900 N/m. The edge crush strength of a paper board and a paper box which are processed by adopting the binding agent disclosed by the invention can reach more than 1300 N/m, and the piercing strength can reach more than 30J; and the problems of tackless, delamination, moisture absorption, and the like of the paper board and the paper box are completely solved.
Description
Technical field
The invention belongs to technical field of adhesive, be specifically related to a kind of combination board tackiness agent and preparation method thereof.
Background technology
It is starch, scale and a small amount of borax that the tackiness agent that is used for corrugated paper board production line at present mainly adopts the Starch Adhesive of U.S. Si Taiyin Hall, its staple.Its preparation method generally is that water, starch and sodium hydroxide solution mixing and stirring are processed carrier glue; Then water, starch and borax are fully stirred and process the main body starch paste; At last carrier glue is slowly added in the main body starch paste under whipped state, stirring promptly obtains Starch Adhesive.The bond strength of this tackiness agent is merely 500N/m～580N/m; And have problems such as character is unstable, staging life is short, adopt the cardboard or the carton difference of hardness of this tackiness agent processing, the side pressure strength of the carton of production is merely 800N/m～1000N/m; Expose intensity and be merely 7J～10J; Too causing that easily cardboard comes unglued under the exsiccant environment, line ball fracture, and under too moist environment, can make cardboard because of the moisture absorption deliquescing, come unstuck, meet water stratification; Influence cardboard and carton intensity, thereby cause built-in commodity to degenerate.
Summary of the invention
Technical problem to be solved by this invention is the deficiency to above-mentioned prior art, provides a kind of composition simple, stable in properties, and resting period is long, and bond strength reaches the above combination board tackiness agent of 900N/m, and the preparation method of this tackiness agent also is provided.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: a kind of combination board tackiness agent is characterized in that; This tackiness agent is made up of following raw material by weight percentage: water 70%～85%; W-Gum 12%～25%, sodium hydroxide 0.3%～2%, glue crosslinking agent 0.5%～1.5%; Stablizer 0.1%～1%, borax 0.1%～1%; Said glue crosslinking agent is one or more in bisphenol-A epoxy vinyl ester resin, acrylic type vinyl ester resin and the phenolic aldehyde epoxy vinyl ester resin, and said stablizer is one or more in alginate, vinyl acetate between to for plastic base emulsion, Natvosol and the benzene emulsion.
Above-mentioned a kind of combination board tackiness agent, this tackiness agent is made up of following raw material by weight percentage: water 77.8%, W-Gum 19.7%, sodium hydroxide 0.67%, glue crosslinking agent 0.93%, stablizer 0.4%, borax 0.5%.
Above-mentioned a kind of combination board tackiness agent, said glue crosslinking agent is the bisphenol-A epoxy vinyl ester resin, said stablizer is a Natvosol.
The present invention also provides the preparation method of this tackiness agent, it is characterized in that, this method may further comprise the steps:
(1) sodium hydroxide, portion water and part W-Gum are mixed, obtain carrier; The mass percent of each component is in the said carrier: water 85%～90%, W-Gum 5%～12%, sodium hydroxide 1%～5%;
(2) in retort, add remainder water and W-Gum, the back that stirs adds glue crosslinking agent and stablizer in retort, continues to stir, and in retort, adds carrier described in borax and the step (1) then, and stirring obtains the combination board tackiness agent; The mass percent of each component is in the said combination board tackiness agent: water 40%～50%, W-Gum 10%～21.5%, glue crosslinking agent 0.5%～1.5%, stablizer 0.1%～1%, carrier 30 as one kind %～40%, borax 0.1%～1%.
Described in the above-mentioned steps (1) in the carrier mass percent of each component be: water 87%, W-Gum 11%, sodium hydroxide 2%.
Described in the above-mentioned steps (2) in the combination board tackiness agent mass percent of each component be: water 48.6%, W-Gum 16%, glue crosslinking agent 1%, stablizer 0.4%, carrier 33.5%, borax 0.5%.
The present invention compared with prior art has the following advantages:
1, binder constituents of the present invention is simple, stable in properties, and resting period is long.
2, preparation method of the present invention is simple, and the required equipment cost is low.Adopt preparation carrier earlier, add raw material and carrier then in a certain order, the bond strength of the tackiness agent of preparation reaches more than the 900N/m.
3, adopt the cardboard and the carton side pressure strength of tackiness agent processing of the present invention can reach more than the 1300N/m, expose intensity and can reach more than the 30J, solved problems such as the coming unglued of cardboard and carton, layering and moisture absorption fully.
Through embodiment, technical scheme of the present invention is done further detailed description below.
Embodiment
Embodiment 1
The combination board tackiness agent of present embodiment is made up of following raw material by weight percentage: water 77%, W-Gum 19.7%, sodium hydroxide 0.3%, glue crosslinking agent 1%, stablizer 1%, borax 1%; Wherein glue crosslinking agent is the bisphenol-A epoxy vinyl ester resin, and stablizer is alginate.
Its preparation method is:
(1) 270 kg of water, 3 kilograms of sodium hydroxide and 27 kilograms of W-Gums are mixed, obtain carrier;
(2) in retort, add 500 kg of water and 170 kilograms of W-Gums; Back 10 kilograms of bisphenol-A epoxy vinyl ester resins of adding and 10 kilograms of alginate in retort stir; Continue to stir; In retort, add carrier described in 10 kilograms of boraxs and the step (1) then, stirring obtains the combination board tackiness agent.
The bond strength of the combination board tackiness agent of present embodiment preparation reaches more than the 900N/m; Adopt the cardboard and the carton side pressure strength of this tackiness agent processing can reach more than the 1300N/m; Expose intensity and can reach more than the 30J, solved problems such as the coming unglued of cardboard and carton, layering and moisture absorption fully.
Embodiment 2
Present embodiment is identical with the preparation method of embodiment 1; Wherein difference is: said glue crosslinking agent is acrylic type vinyl ester resin or phenolic aldehyde epoxy vinyl ester resin, perhaps is at least two kinds in bisphenol-A epoxy vinyl ester resin, acrylic type vinyl ester resin and the phenolic aldehyde epoxy vinyl ester resin; Said stablizer is vinyl acetate between to for plastic base emulsion, Natvosol or benzene emulsion, perhaps is at least two kinds in alginate, vinyl acetate between to for plastic base emulsion, Natvosol and the benzene emulsion.
The bond strength of the combination board tackiness agent of present embodiment preparation reaches more than the 900N/m; Adopt the cardboard and the carton side pressure strength of this tackiness agent processing can reach more than the 1300N/m; Expose intensity and can reach more than the 30J, solved problems such as the coming unglued of cardboard and carton, layering and moisture absorption fully.
Embodiment 3
The combination board tackiness agent of present embodiment is made up of following raw material by weight percentage: water 77.8%, W-Gum 19.7%, sodium hydroxide 0.67%, glue crosslinking agent 0.93%, stablizer 0.4%, borax 0.5%; Said glue crosslinking agent is the bisphenol-A epoxy vinyl ester resin, and stablizer is a Natvosol.
Its preparation method is:
(1) 291 kg of water, 6.7 kilograms of sodium hydroxide and 37 kilograms of W-Gums are mixed, obtain carrier;
(2) in retort, add 486 kg of water and 160 kilograms of W-Gums; Back 9.3 kilograms of bisphenol-A epoxy vinyl ester resins of adding and 4 kilograms of Natvosols in retort stir; Continue to stir; In retort, add carrier described in 5 kilograms of boraxs and the step (1) then, stirring obtains the combination board tackiness agent.
The bond strength of the combination board tackiness agent of present embodiment preparation reaches more than the 900N/m; Adopt the cardboard and the carton side pressure strength of this tackiness agent processing can reach more than the 1300N/m; Expose intensity and can reach more than the 30J, solved problems such as the coming unglued of cardboard and carton, layering and moisture absorption fully.
Embodiment 4
Present embodiment is identical with the preparation method of embodiment 3; Wherein difference is: said glue crosslinking agent is acrylic type vinyl ester resin or phenolic aldehyde epoxy vinyl ester resin, perhaps is at least two kinds in bisphenol-A epoxy vinyl ester resin, acrylic type vinyl ester resin and the phenolic aldehyde epoxy vinyl ester resin; Said stablizer is alginate, vinyl acetate between to for plastic base emulsion or benzene emulsion, perhaps is at least two kinds in alginate, vinyl acetate between to for plastic base emulsion, Natvosol and the benzene emulsion.
The bond strength of the combination board tackiness agent of present embodiment preparation reaches more than the 900N/m; Adopt the cardboard and the carton side pressure strength of this tackiness agent processing can reach more than the 1300N/m; Expose intensity and can reach more than the 30J, solved problems such as the coming unglued of cardboard and carton, layering and moisture absorption fully.
Embodiment 5
The combination board tackiness agent of present embodiment is made up of following raw material by weight percentage: water 74%, W-Gum 21%, sodium hydroxide 2%, glue crosslinking agent 1.5%, stablizer 0.5%, borax 1%; Wherein glue crosslinking agent is the phenolic aldehyde epoxy vinyl ester resin, and stablizer is a Natvosol.
Its preparation method is:
(1) 340 kg of water, 20 kilograms of sodium hydroxide and 40 kilograms of W-Gums are mixed, obtain carrier;
(2) in retort, add 400 kg of water and 170 kilograms of W-Gums; Back 15 kilograms of phenolic aldehyde epoxy vinyl ester resins of adding and 5 kilograms of Natvosols in retort stir; Continue to stir; In retort, add carrier described in 10 kilograms of boraxs and the step (1) then, stirring obtains the combination board tackiness agent.
The bond strength of the combination board tackiness agent of present embodiment preparation reaches more than the 900N/m; Adopt the cardboard and the carton side pressure strength of this tackiness agent processing can reach more than the 1300N/m; Expose intensity and can reach more than the 30J, solved problems such as the coming unglued of cardboard and carton, layering and moisture absorption fully.
Embodiment 6
Present embodiment is identical with the preparation method of embodiment 5; Wherein difference is: said glue crosslinking agent is bisphenol-A epoxy vinyl ester resin or acrylic type vinyl ester resin, perhaps is at least two kinds in bisphenol-A epoxy vinyl ester resin, acrylic type vinyl ester resin and the phenolic aldehyde epoxy vinyl ester resin; Said stablizer is alginate, vinyl acetate between to for plastic base emulsion or benzene emulsion, perhaps is at least two kinds in alginate, vinyl acetate between to for plastic base emulsion, Natvosol and the benzene emulsion.
The bond strength of the combination board tackiness agent of present embodiment preparation reaches more than the 900N/m; Adopt the cardboard and the carton side pressure strength of this tackiness agent processing can reach more than the 1300N/m; Expose intensity and can reach more than the 30J, solved problems such as the coming unglued of cardboard and carton, layering and moisture absorption fully.
Embodiment 7
The combination board tackiness agent of present embodiment is made up of following raw material by weight percentage: water 85%, W-Gum 12%, sodium hydroxide 2%, glue crosslinking agent 0.8%, stablizer 0.1%, borax 0.1%; Wherein glue crosslinking agent is the bisphenol-A epoxy vinyl ester resin, and stablizer is a benzene emulsion.
Its preparation method is:
(1) 360 kg of water, 20 kilograms of sodium hydroxide and 20 kilograms of W-Gums are mixed, obtain carrier;
(2) in retort, add 490 kg of water and 100 kilograms of W-Gums; Back 8 kilograms of bisphenol-A epoxy vinyl ester resins of adding and 1 kilogram of benzene emulsion in retort stir; Continue to stir; In retort, add carrier described in 1 kilogram of borax and the step (1) then, stirring obtains the combination board tackiness agent.
The bond strength of the combination board tackiness agent of present embodiment preparation reaches more than the 900N/m; Adopt the cardboard and the carton side pressure strength of this tackiness agent processing can reach more than the 1300N/m; Expose intensity and can reach more than the 30J, solved problems such as the coming unglued of cardboard and carton, layering and moisture absorption fully.
Embodiment 8
Present embodiment is identical with the preparation method of embodiment 7; Wherein difference is: said glue crosslinking agent is acrylic type vinyl ester resin or phenolic aldehyde epoxy vinyl ester resin, perhaps is at least two kinds in bisphenol-A epoxy vinyl ester resin, acrylic type vinyl ester resin and the phenolic aldehyde epoxy vinyl ester resin; Said stablizer is alginate, vinyl acetate between to for plastic base emulsion or Natvosol, perhaps is at least two kinds in alginate, vinyl acetate between to for plastic base emulsion, Natvosol and the benzene emulsion.
The bond strength of the combination board tackiness agent of present embodiment preparation reaches more than the 900N/m; Adopt the cardboard and the carton side pressure strength of this tackiness agent processing can reach more than the 1300N/m; Expose intensity and can reach more than the 30J, solved problems such as the coming unglued of cardboard and carton, layering and moisture absorption fully.
Embodiment 9
The combination board tackiness agent of present embodiment is made up of following raw material by weight percentage: water 70%, W-Gum 25%, sodium hydroxide 1.5%, glue crosslinking agent 1.5%, stablizer 1%, borax 1%; Wherein glue crosslinking agent is the acrylic type vinyl ester resin, and stablizer is the vinyl acetate between to for plastic base emulsion.
Its preparation method is:
(1) 300 kg of water, 15 kilograms of sodium hydroxide and 35 kilograms of W-Gums are mixed, obtain carrier;
(2) in retort, add 400 kg of water and 215 kilograms of W-Gums; Back 15 kilograms of acrylic type vinyl ester resins of adding and 10 kilograms of vinyl acetate between to for plastic base emulsions in retort stir; Continue to stir; In retort, add carrier described in 10 kilograms of boraxs and the step (1) then, stirring obtains the combination board tackiness agent.
The bond strength of the combination board tackiness agent of present embodiment preparation reaches more than the 900N/m; Adopt the cardboard and the carton side pressure strength of this tackiness agent processing can reach more than the 1300N/m; Expose intensity and can reach more than the 30J, solved problems such as the coming unglued of cardboard and carton, layering and moisture absorption fully.
Embodiment 10
Present embodiment is identical with the preparation method of embodiment 9; Wherein difference is: said glue crosslinking agent is bisphenol-A epoxy vinyl ester resin or phenolic aldehyde epoxy vinyl ester resin, perhaps is at least two kinds in bisphenol-A epoxy vinyl ester resin, acrylic type vinyl ester resin and the phenolic aldehyde epoxy vinyl ester resin; Said stablizer is alginate, Natvosol or benzene emulsion, perhaps is at least two kinds in alginate, vinyl acetate between to for plastic base emulsion, Natvosol and the benzene emulsion.
The bond strength of the combination board tackiness agent of present embodiment preparation reaches more than the 900N/m; Adopt the cardboard and the carton side pressure strength of this tackiness agent processing can reach more than the 1300N/m; Expose intensity and can reach more than the 30J, solved problems such as the coming unglued of cardboard and carton, layering and moisture absorption fully.
Embodiment 11
The combination board tackiness agent of present embodiment is made up of following raw material by weight percentage: water 80%, W-Gum 17.1%, sodium hydroxide 0.4%, glue crosslinking agent 0.5%, stablizer 1%, borax 1%; Wherein glue crosslinking agent is the acrylic type vinyl ester resin, and stablizer is a benzene emulsion.
Its preparation method is:
(1) 348 kg of water, 4 kilograms of sodium hydroxide and 48 kilograms of W-Gums are mixed, obtain carrier;
(2) in retort, add 452 kg of water and 123 kilograms of W-Gums; Back 5 kilograms of acrylic type vinyl ester resins of adding and 10 kilograms of benzene emulsions in retort stir; Continue to stir; In retort, add carrier described in 10 kilograms of boraxs and the step (1) then, stirring obtains the combination board tackiness agent.
The bond strength of the combination board tackiness agent of present embodiment preparation reaches more than the 900N/m; Adopt the cardboard and the carton side pressure strength of this tackiness agent processing can reach more than the 1300N/m; Expose intensity and can reach more than the 30J, solved problems such as the coming unglued of cardboard and carton, layering and moisture absorption fully.
Embodiment 12
Present embodiment is identical with the preparation method of embodiment 11; Wherein difference is: said glue crosslinking agent is bisphenol-A epoxy vinyl ester resin or phenolic aldehyde epoxy vinyl ester resin, perhaps is at least two kinds in bisphenol-A epoxy vinyl ester resin, acrylic type vinyl ester resin and the phenolic aldehyde epoxy vinyl ester resin; Said stablizer is alginate, vinyl acetate between to for plastic base emulsion or Natvosol, perhaps is at least two kinds in alginate, vinyl acetate between to for plastic base emulsion, Natvosol and the benzene emulsion.
The bond strength of the combination board tackiness agent of present embodiment preparation reaches more than the 900N/m; Adopt the cardboard and the carton side pressure strength of this tackiness agent processing can reach more than the 1300N/m; Expose intensity and can reach more than the 30J, solved problems such as the coming unglued of cardboard and carton, layering and moisture absorption fully.
The above; It only is preferred embodiment of the present invention; Be not that the present invention is done any restriction, every technical spirit changes any simple modification, change and the equivalent structure that above embodiment did according to the present invention, all still belongs in the protection domain of technical scheme of the present invention.
Claims (4)
1. a combination board tackiness agent is characterized in that, this tackiness agent is made up of following raw material by weight percentage: water 70%～85%; W-Gum 12%～25%, sodium hydroxide 0.3%～2%, linking agent 0.5%～1.5%; Stablizer 0.1%～1%, borax 0.1%～1%; Said linking agent is one or more in bisphenol-A epoxy vinyl ester resin, acrylic type vinyl ester resin and the phenolic aldehyde epoxy vinyl ester resin, and said stablizer is one or more in alginate, vinyl acetate between to for plastic base emulsion, Natvosol and the benzene emulsion.
2. a kind of combination board tackiness agent according to claim 1 is characterized in that this tackiness agent is made up of following raw material by weight percentage: water 77.8%; W-Gum 19.7%, sodium hydroxide 0.67%, linking agent 0.93%; Stablizer 0.4%, borax 0.5%.
3. a kind of combination board tackiness agent according to claim 1 is characterized in that said linking agent is the bisphenol-A epoxy vinyl ester resin, and said stablizer is a Natvosol.
4. a method for preparing combination board tackiness agent as claimed in claim 1 is characterized in that, this method may further comprise the steps:
(1) sodium hydroxide, portion water and part W-Gum are mixed, obtain carrier; The mass percent of each component is in the said carrier: water 87%, W-Gum 11%, sodium hydroxide 2%;
(2) in retort, add remainder water and W-Gum; Back adding linking agent and stablizer in retort stir; Continue to stir, in retort, add carrier described in borax and the step (1) then, stirring obtains the combination board tackiness agent; The mass percent of each component is in the said combination board tackiness agent: water 48.6%, W-Gum 16%, linking agent 1%, stablizer 0.4%, carrier 33.5%, borax 0.5%.
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| CN201110085626A CN102199409B (en) | 2011-04-07 | 2011-04-07 | Composite paper board binding agent and preparation method thereof |
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| CN201110085626A CN102199409B (en) | 2011-04-07 | 2011-04-07 | Composite paper board binding agent and preparation method thereof |
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| CN102199409B true CN102199409B (en) | 2012-10-03 |
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| CN103114490B (en) * | 2013-01-18 | 2015-07-08 | 浙江希望包装有限公司 | Processing method of fiber strengthening composite corrugated board |
| CN104293237A (en) * | 2014-09-28 | 2015-01-21 | 合肥东彩印刷科技有限公司 | Composite board adhesive for carton |
| CN105969244A (en) * | 2016-05-25 | 2016-09-28 | 合肥东彩印刷科技有限公司 | Composite adhesive for paperboards |
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| CN106753083A (en) * | 2017-01-09 | 2017-05-31 | 广东绿之彩印刷科技股份有限公司 | A kind of wrapping paper adhesive and preparation method thereof |
| CN109487615A (en) * | 2018-12-10 | 2019-03-19 | 上海宏图尚威环保科技股份有限公司 | A kind of chipboard production technology using 3D printing glue spraying |
| CN110103517A (en) * | 2019-05-21 | 2019-08-09 | 江苏升灿汽车配件有限公司 | A kind of corrugated type filter paper of air cleaner adhesive bonding method |
| CN112457801A (en) * | 2020-11-24 | 2021-03-09 | 张家港市欣发包装有限责任公司 | Low-temperature glue making method for reducing heat of composite forming of paperboard |
| JP7202019B2 (en) | 2020-12-08 | 2023-01-11 | 林六株式会社 | Method for manufacturing cardboard adhesive |
| CN113683981B (en) * | 2021-09-11 | 2023-05-02 | 杭州永晶科技有限公司 | Starch adhesive for corrugated board compounding and preparation method thereof |
| CN114808551A (en) * | 2022-04-28 | 2022-07-29 | 宝艺新材料股份有限公司 | Preparation process of high-strength alkali-resistant corrugated board |
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