CN104293237A - Composite board adhesive for carton - Google Patents
Composite board adhesive for carton Download PDFInfo
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- CN104293237A CN104293237A CN201410509671.0A CN201410509671A CN104293237A CN 104293237 A CN104293237 A CN 104293237A CN 201410509671 A CN201410509671 A CN 201410509671A CN 104293237 A CN104293237 A CN 104293237A
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Abstract
The invention discloses a composite board adhesive for a carton. The composite board adhesive for the carton is prepared from the following raw materials in parts by weight: 65-75 parts of water, 18-24 parts of corn starch, 2-6 parts of calcium carbonate, 1-2 parts of sodium hydroxide, 3-4 parts of sepiolite powder, 0.12-0.16 part of a naphthalenesulfonate formaldehyde condensation compound, 0.15-0.18 part of sodium carboxymethylcellulose, 0.40-0.52 part of bisphenol A epoxy vinyl ester resin, 0.20-0.24 part of acrylic vinyl ester resin and 0.82-0.96 part of hydroxyethyl cellulose. The adhesive is prepared by the following steps: uniformly mixing sodium hydroxide, part of water and part of corn starch; adding residual water and the corn starch into a container; after uniformly stirring, adding the sepiolite powder, the naphthalenesulfonate formaldehyde condensation compound, sodium carboxymethylcellulose, the bisphenol A epoxy vinyl ester resin, the acrylic vinyl ester resin and hydroxyethyl cellulose and uniformly stirring; and adding a backing material and calcium carbonate and uniformly stirring. The composite board adhesive for the carton disclosed by the invention is strong in adhesive capacity, stable in performance and long in storage period.
Description
Technical field
The invention belongs to technical field of adhesive, particularly relate to a kind of carton composite paper board binding agent.
Background technology
Tackiness agent is the requisite material of Carbon enterprise, and it is mainly used on the compound working procedure of face Paper or cardboard.At present, the bonding for cardboard mainly adopts amylan.But because this type of adhesives power is weak, crushing resistance, moisture protection are poor, and the quality product therefore produced can not be guaranteed.In prior art, exist and in amylan, add other one-tenth assign to improve its performance, but this type of added ingredients often containing to human body composition excitatory, needs to improve.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide a kind of carton composite paper board binding agent, its adhesive capacity is strong, and stable performance, resting period is long.
The present invention proposes a kind of carton composite paper board binding agent, be made up of the raw material of following weight part: water: 65-75 part; W-Gum: 18-24 part; Calcium carbonate: 2-6 part; Sodium hydroxide: 1-2 part; Sepiolite powder: 3-4 part; Naphthalenesulfonate formaldehyde condensation compound: 0.12-0.16 part; Xylo-Mucine: 0.15-0.18 part; Bisphenol-A epoxide vinylester resin: 0.40-0.52 part; Acrylic type vinyl ester resin: 0.20-0.24 part; Natvosol: 0.82-0.96 part;
According to above-mentioned raw materials proportioning, prepare described carton composite paper board binding agent according to the following steps:
S1: sodium hydroxide, part water and part W-Gum are mixed and obtains bed material, wherein, sodium hydroxide: water: the mass ratio of W-Gum is 1:12-15:2-3;
S2: remaining water and W-Gum are added in container, sepiolite powder, naphthalenesulfonate formaldehyde condensation compound, Xylo-Mucine, bisphenol-A epoxide vinylester resin, acrylic type vinyl ester resin, Natvosol stirring is added after stirring, to be mixed evenly after add the bed material obtained in calcium carbonate and S1, obtain described carton composite paper board binding agent after stirring.
Preferably, be made up of the raw material of following weight part: water: 68-73 part; W-Gum: 19-22 part; Calcium carbonate: 3-5 part; Sodium hydroxide: 1.4-1.8 part; Sepiolite powder: 3.4-3.7 part; Naphthalenesulfonate formaldehyde condensation compound: 0.13-0.15 part; Xylo-Mucine: 0.15-0.17 part; Bisphenol-A epoxide vinylester resin: 0.45-0.50 part; Acrylic type vinyl ester resin: 0.22-0.23 part; Natvosol: 0.85-0.90 part.
Preferably, be made up of the raw material of following weight part: water: 70 parts; W-Gum: 20 parts; Calcium carbonate: 4 parts; Sodium hydroxide: 1.6 parts; Sepiolite powder: 3.5 parts; Naphthalenesulfonate formaldehyde condensation compound: 0.14 part; Xylo-Mucine: 0.16 part; Bisphenol-A epoxide vinylester resin: 0.46 part; Acrylic type vinyl ester resin: 0.23 part; Natvosol: 0.88 part.
Preferably, water: the mass ratio of W-Gum is 3-4:1.
Preferably, in S1, sodium hydroxide: water: the mass ratio of W-Gum is 2:27:5.
Carton composite paper board binding agent of the present invention, in its raw material, the weight part of water can be 65.6,66,66.8,67,67.3,68,69,70,70.5,71,71.4,72,72.5,73,74,74.6 parts; The weight part of W-Gum can be 18.5,19,19.3,20,20.6,21,21.4,22,22.3,23,23.6 parts; The weight part of calcium carbonate can be 2.3,2.8,3,3.5,4,4.2,5,5.3 parts; The weight part of sodium hydroxide can be 1.2,1.4,1.5,1.6,1.7,1.85,1.9 parts; The weight part of sepiolite powder can be 3.2,3.3,3.4,3.45,3.5,3.6,3.78,3.9 parts; The weight part of naphthalenesulfonate formaldehyde condensation compound can be 0.125,0.13,0.134,0.14,0.146,0.15,0.152 part; The weight part of Xylo-Mucine can be 0.155,0.16,0.164,0.17,0.172 part; The weight part of bisphenol-A epoxide vinylester resin can be 0.42,0.43,0.45,0.46,0.48,0.49,0.51,0.515 part; The weight part of acrylic type vinyl ester resin can be 0.21,0.215,0.22,0.234 part; The weight part of Natvosol can be 0.83,0.84,0.86,0.88,0.90,0.92,0.93,0.94,0.95 part.
In the present invention, by carrying out choose reasonable to the components by weight percent of carton composite paper board binding agent, and adopt suitable order to allocate, make that the cohesive strength of tackiness agent is high, resting period is long, the bond strength of tackiness agent can reach 920N/m, the carton side pressure strength of processing can reach 1360N/m, and Punctured Strength can reach 32J; Meanwhile, obtained tackiness agent is nontoxic, carton not easily produce after using come unglued, layering and sucting wet problem.
Embodiment
Below in conjunction with specific examples, the present invention is described in detail; should understand; embodiment is only for illustration of the present invention, instead of for limiting the present invention, any amendment, equivalent replacement etc. made on basis of the present invention is all in protection scope of the present invention.
Embodiment 1
A kind of carton composite paper board binding agent, is made up of the raw material of following weight part: water: 70 parts; W-Gum: 20 parts; Calcium carbonate: 4 parts; Sodium hydroxide: 1.6 parts; Sepiolite powder: 3.5 parts; Naphthalenesulfonate formaldehyde condensation compound: 0.14 part; Xylo-Mucine: 0.16 part; Bisphenol-A epoxide vinylester resin: 0.46 part; Acrylic type vinyl ester resin: 0.23 part; Natvosol: 0.88 part;
According to above-mentioned raw materials proportioning, and prepare described carton composite paper board binding agent according to the following steps:
S1: sodium hydroxide, part water and part W-Gum are mixed, obtains bed material, wherein, sodium hydroxide: water: the mass ratio of W-Gum is 2:27:5;
S2: remaining water and W-Gum are added in container, sepiolite powder, naphthalenesulfonate formaldehyde condensation compound, Xylo-Mucine, bisphenol-A epoxide vinylester resin, acrylic type vinyl ester resin, Natvosol stirring is added after stirring, to be mixed evenly after, add the bed material obtained in calcium carbonate and S1, stir and obtain described carton composite paper board binding agent.
Embodiment 2
A kind of carton composite paper board binding agent, is made up of the raw material of following weight part: water: 75 parts; W-Gum: 18 parts; Calcium carbonate: 6 parts; Sodium hydroxide: 1 part; Sepiolite powder: 4 parts; Naphthalenesulfonate formaldehyde condensation compound: 0.12 part; Xylo-Mucine: 0.18 part; Bisphenol-A epoxide vinylester resin: 0.40 part; Acrylic type vinyl ester resin: 0.24 part; Natvosol: 0.82 part;
According to above-mentioned raw materials proportioning, and prepare described carton composite paper board binding agent according to the following steps:
S1: sodium hydroxide, part water and part W-Gum are mixed, obtains bed material, wherein, sodium hydroxide: water: the mass ratio of W-Gum is 1:15:2;
S2: remaining water and W-Gum are added in container, after stirring, add sepiolite powder, naphthalenesulfonate formaldehyde condensation compound, Xylo-Mucine, bisphenol-A epoxide vinylester resin, acrylic type vinyl ester resin, Natvosol stirring, to be mixed evenly after, add the bed material obtained in calcium carbonate and S1, stir and obtain described carton composite paper board binding agent.
Embodiment 3
A kind of carton composite paper board binding agent, is made up of the raw material of following weight part: water: 65 parts; W-Gum: 24 parts; Calcium carbonate: 2 parts; Sodium hydroxide: 2 parts; Sepiolite powder: 3 parts; Naphthalenesulfonate formaldehyde condensation compound: 0.16 part; Xylo-Mucine: 0.15 part; Bisphenol-A epoxide vinylester resin: 0.52 part; Acrylic type vinyl ester resin: 0.20 part; Natvosol: 0.96 part;
According to above-mentioned raw materials proportioning, and prepare described carton composite paper board binding agent according to the following steps:
S1: sodium hydroxide, part water and part W-Gum are mixed, obtains bed material, wherein, sodium hydroxide: water: the mass ratio of W-Gum is 1:12:3;
S2: remaining water and W-Gum are added in container, after stirring, add sepiolite powder, naphthalenesulfonate formaldehyde condensation compound, Xylo-Mucine, bisphenol-A epoxide vinylester resin, acrylic type vinyl ester resin, Natvosol stirring, to be mixed evenly after, add the bed material obtained in calcium carbonate and S1, stir and obtain described carton composite paper board binding agent.
Embodiment 4
A kind of carton composite paper board binding agent, is made up of the raw material of following weight part: water: 71 parts; W-Gum: 19.3 parts; Calcium carbonate: 3.4 parts; Sodium hydroxide: 1.7 parts; Sepiolite powder: 3.3 parts; Naphthalenesulfonate formaldehyde condensation compound: 0.129 part; Xylo-Mucine: 0.157 part; Bisphenol-A epoxide vinylester resin: 0.48 part; Acrylic type vinyl ester resin: 0.23 part; Natvosol: 0.91 part;
According to above-mentioned raw materials proportioning, prepare described carton composite paper board binding agent according to the following steps:
S1: sodium hydroxide, part water and part W-Gum are mixed and obtains bed material, wherein, sodium hydroxide: water: the mass ratio of W-Gum is 1:13:2.6;
S2: remaining water and W-Gum are added in container, sepiolite powder, naphthalenesulfonate formaldehyde condensation compound, Xylo-Mucine, bisphenol-A epoxide vinylester resin, acrylic type vinyl ester resin, Natvosol stirring is added after stirring, to be mixed evenly after add the bed material obtained in calcium carbonate and S1, obtain described carton composite paper board binding agent after stirring.
Claims (5)
1. a carton composite paper board binding agent, is characterized in that, is made up: water of the raw material of following weight part: 65-75 part; W-Gum: 18-24 part; Calcium carbonate: 2-6 part; Sodium hydroxide: 1-2 part; Sepiolite powder: 3-4 part; Naphthalenesulfonate formaldehyde condensation compound: 0.12-0.16 part; Xylo-Mucine: 0.15-0.18 part; Bisphenol-A epoxide vinylester resin: 0.40-0.52 part; Acrylic type vinyl ester resin: 0.20-0.24 part; Natvosol: 0.82-0.96 part;
According to above-mentioned raw materials proportioning, prepare described carton composite paper board binding agent according to the following steps:
S1: sodium hydroxide, part water and part W-Gum are mixed and obtains bed material, wherein, sodium hydroxide: water: the mass ratio of W-Gum is 1: 12-15: 2-3;
S2: remaining water and W-Gum are added in container, sepiolite powder, naphthalenesulfonate formaldehyde condensation compound, Xylo-Mucine, bisphenol-A epoxide vinylester resin, acrylic type vinyl ester resin, Natvosol stirring is added after stirring, to be mixed evenly after add the bed material obtained in calcium carbonate and S1, obtain described carton composite paper board binding agent after stirring.
2. carton composite paper board binding agent according to claim 1, is characterized in that, is made up: water of the raw material of following weight part: 68-73 part; W-Gum: 19-22 part; Calcium carbonate: 3-5 part; Sodium hydroxide: 1.4-1.8 part; Sepiolite powder: 3.4-3.7 part; Naphthalenesulfonate formaldehyde condensation compound: 0.13-0.15 part; Xylo-Mucine: 0.15-0.17 part; Bisphenol-A epoxide vinylester resin: 0.45-0.50 part; Acrylic type vinyl ester resin: 0.22-0.23 part; Natvosol: 0.85-0.90 part.
3. carton composite paper board binding agent according to claim 1 and 2, is characterized in that, is made up: water of the raw material of following weight part: 70 parts; W-Gum: 20 parts; Calcium carbonate: 4 parts; Sodium hydroxide: 1.6 parts; Sepiolite powder: 3.5 parts; Naphthalenesulfonate formaldehyde condensation compound: 0.14 part; Xylo-Mucine: 0.16 part; Bisphenol-A epoxide vinylester resin: 0.46 part; Acrylic type vinyl ester resin: 0.23 part; Natvosol: 0.88 part.
4. carton composite paper board binding agent according to claim 1, is characterized in that, water: the mass ratio of W-Gum is 3-4: 1.
5. the carton composite paper board binding agent according to any one of claim 1-4, is characterized in that, in S1, and sodium hydroxide: water: the mass ratio of W-Gum is 2: 27: 5.
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CN201410509671.0A CN104293237A (en) | 2014-09-28 | 2014-09-28 | Composite board adhesive for carton |
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CN201410509671.0A CN104293237A (en) | 2014-09-28 | 2014-09-28 | Composite board adhesive for carton |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106915123A (en) * | 2017-04-17 | 2017-07-04 | 宁波和宝盛包装有限公司 | A kind of corrugated board production technique of energy-conserving and environment-protective |
CN108165232A (en) * | 2017-12-07 | 2018-06-15 | 明光市永德包装有限公司 | A kind of preparation method of corrugated board water-resistant adhesives |
CN113981746A (en) * | 2021-10-28 | 2022-01-28 | 山东天和纸业有限公司 | Process method for prolonging storage time of composite paper |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1850929A (en) * | 2006-06-05 | 2006-10-25 | 钱沛良 | Paper board production water-proof adhesive |
CN101054501A (en) * | 2007-06-18 | 2007-10-17 | 邹栋华 | Cardboard starch gum activating agent and cardboard starch gum |
CN102199409A (en) * | 2011-04-07 | 2011-09-28 | 西安西北纸箱包装有限责任公司 | Composite paper board binding agent and preparation method thereof |
-
2014
- 2014-09-28 CN CN201410509671.0A patent/CN104293237A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1850929A (en) * | 2006-06-05 | 2006-10-25 | 钱沛良 | Paper board production water-proof adhesive |
CN101054501A (en) * | 2007-06-18 | 2007-10-17 | 邹栋华 | Cardboard starch gum activating agent and cardboard starch gum |
CN102199409A (en) * | 2011-04-07 | 2011-09-28 | 西安西北纸箱包装有限责任公司 | Composite paper board binding agent and preparation method thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106915123A (en) * | 2017-04-17 | 2017-07-04 | 宁波和宝盛包装有限公司 | A kind of corrugated board production technique of energy-conserving and environment-protective |
CN108165232A (en) * | 2017-12-07 | 2018-06-15 | 明光市永德包装有限公司 | A kind of preparation method of corrugated board water-resistant adhesives |
CN113981746A (en) * | 2021-10-28 | 2022-01-28 | 山东天和纸业有限公司 | Process method for prolonging storage time of composite paper |
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Application publication date: 20150121 |