CN106634378A - Water-based self-cleaning textured paint and preparation method thereof - Google Patents
Water-based self-cleaning textured paint and preparation method thereof Download PDFInfo
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- CN106634378A CN106634378A CN201611268027.4A CN201611268027A CN106634378A CN 106634378 A CN106634378 A CN 106634378A CN 201611268027 A CN201611268027 A CN 201611268027A CN 106634378 A CN106634378 A CN 106634378A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/24—Homopolymers or copolymers of amides or imides
- C09D133/26—Homopolymers or copolymers of acrylamide or methacrylamide
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a water-based self-cleaning textured paint which is prepared from the following components in parts by weight: 60-150 parts of deionized water, 120-200 parts of super-hydrophilic polymer emulsion, 500-800 parts of textured sand, 30-70 parts of an inorganic filler, 3-10 parts of a photocatalyst, 1-5 parts of cellulose, 2-10 parts of a dispersing agent, 0.5-2 parts of a wetting agent, 0.5-2 parts of a multi-functional agent, 3-10 parts of a water repellent agent, 3-10 parts of wood fiber, 3-10 parts of a rheological agent and 5-15 parts of a coalescing agent. The water-based self-cleaning textured paint has excellent water resistance and stain resistance.
Description
Technical field
The present invention relates to a kind of manufacture field of building coating, specifically a kind of aqueous automatically cleaning texture paint and its preparation
Method.
Background technology
As living standard is improved constantly, people to building coating to embrocate effect requirements also increasingly strict.In numerous tools
In having the building coating of special-effect, texture paint is at present by one kind of numerous users favor.Texture paint is a kind of imitative stone dress
Decorations paint vehicle, makes metope the three-dimensional bag of parian, granite occur, because workmen can be according to difference after its construction
Texture paint kind, texture paint quality, coating basal plane and implement changeable texture paint arrangement and method for construction, so texture paint bag is almost
Can infinitely change, user can make the personalized collocation of more options according to the hobby of oneself, and make metope represent the sky of uniqueness
Between visual angle.Because texture paint has functions that metope pattern is changeable, vivid and has back to nature, so it is widely used
In high class residential development, villa, the rural building of style or the interior decoration of pastoralism.
However, texture paint itself has two great technological deficiencies.First, the coating surface of texture paint is being constructed
Electrostatic is easily produced into after, coating surface easily adsorbs charged fine pollutants, thus coating surface is used in long-time
After can be covered by dust, its stain resistant extreme difference.And because paint film itself has different concave-convex effects and less three-dimensional
Bag, causes the extremely difficult cleaning in surface of paint film.Second, the stain resistant in order to lift texture paint, existing texture paint is in construction
After the completion of one layer of varnish would generally be coated on paint film.Although varnish can have certain protection to make to the texture paint film of metope
With, but varnish itself has larger flowing viscosity, and it easily sticks to the tiny position of texture paint film.Also, varnish itself
It is poor with the compatibility of texture paint, the unsteady situation of paint vehicle boundary bonding occurs when coating on texture paint.Additionally, treating
Varnish is coated with after the completion of texture paint construction, can significantly delay the construction speed of engineering, and increased being processed into for metope japanning
This.Therefore, a kind of stain resistant is researched and developed by force and with the texture paint of stronger adhesion strength, be the skill of current texture paint development
An art difficult problem.
The content of the invention
It is an object of the invention to overcome the deficiencies in the prior art, there is provided a kind of with excellent resistance to water, stain resistant
Aqueous automatically cleaning texture paint.
Another goal of the invention of the present invention be provide it is a kind of it is with low cost, process is simple prepare it is above-mentioned aqueous from clear
The method of clean texture paint.
What the goal of the invention of the present invention was realized in：A kind of aqueous automatically cleaning texture paint, it is characterised in that：It is described aqueous
Automatically cleaning texture paint include deionized water, super hydrophilic polymer emulsion, texture sand, inorganic filler, photochemical catalyst, cellulose, point
Powder, wetting agent, multifunctional assistant, water-repelling agent, wood fibre, auxiliary rheological agents and coalescents, above-mentioned component content presses quality
Number is respectively：It is deionized water 60-150 part, super hydrophilic polymer emulsion 120-200 parts, texture sand 500-800 parts, inorganic
Filler 30-70 parts, photochemical catalyst 3-10 parts, cellulose 1-5 parts, dispersant 2-10 parts, wetting agent 0.5-2 parts, multifunctional assistant
0.5-2 parts, water-repelling agent 3-10 parts, wood fibre 3-10 parts, auxiliary rheological agents 3-10 parts, coalescents 5-15 parts.
The super hydrophilic polymer emulsion is by the monomer copolymerization comprising acrylic acid, acrylamide and hydroxyethyl
Into the mol ratio of said components：Acrylic acid：Acrylamide：Hydroxyethyl is（0.6-1）：（0.4-1）：1.
The inorganic filler includes the one kind in powdered whiting, titanium dioxide and talcum powder or with arbitrary proportion mixing.
The photochemical catalyst is nano titanium oxide.
The cellulose includes the one kind in hydroxypropyl methyl cellulose, hydroxyethyl cellulose, HEMC
Or with arbitrary proportion mixing.
The dispersant includes sodium tripolyphosphate, calgon, sodium pyrophosphate, triethyl group hexyl phosphoric acid, dodecyl
One kind in sodium sulphate, methyl anyl alcohol or with arbitrary proportion mixing.
The wetting agent is included in sulfonated oil, sulfur alcohol compound, hydrazide kind compound and mercaptan acetal compound
One kind is mixed with arbitrary proportion.
The multifunctional assistant includes the one kind in linear alcohols amine, organic amine and ammoniacal liquor or with arbitrary proportion mixing.
The water-repelling agent includes the one kind in fatty amine and amino silicones or with arbitrary proportion mixing.
The fibre length of the wood fibre is 100-600 μm.
The auxiliary rheological agents include organic clay, bentonite, xanthans, polyacrylate, polyurethane in one kind or with
Arbitrary proportion mixes.
The coalescents are included in propandiol butyl ether, propylene glycol methyl ether acetate, Lauryl Alcohol ester, propane diols phenylate
One kind is mixed with arbitrary proportion.
The preparation method of the aqueous automatically cleaning texture paint is comprised the following steps：
a：It is standby said components to be weighed according to proportioning；
b：Under normal temperature and pressure, deionized water is added in dispersion tank, then respectively toward dispersion tank in the lasting dispersion of dispersion machine
Interior addition cellulose, dispersant, wetting agent, water-repelling agent, multifunctional assistant and wood fibre, addition turns in 500-800 after finishing/
Persistently disperse 10-40 minutes under the rotating speed for dividing；
c：Inorganic filler and photochemical catalyst are separately added into toward b step gained mixture, and dispersing speed is promoted to 1500-
2000 revs/min, then persistently disperse 20-40 minutes；
d：Super hydrophilic polymer emulsion, auxiliary rheological agents and coalescents are separately added into toward step c gained mixture, and dispersion
Machine rotating speed is reduced to 1000-1300 rev/min, then persistently disperses 10-30 minutes；
e：Texture sand is added toward Step d gained mixture, and dispersing speed is down to 400-700 rev/min, then persistently divided
Aqueous automatically cleaning texture paint can be obtained after scattered 20-50 minutes.
It is of the invention compared with traditional body of wall texture paint, with advantages below：
1st, in aqueous automatically cleaning texture paint of the invention, answering for super hydrophilic polymer emulsion, photochemical catalyst and water-repelling agent is employed
Zoarium system.First, super hydrophilic polymer emulsion by including the monomer copolymerizations such as acrylic acid, acrylamide and hydroxyethyl and
Into, because acrylic acid and acrylamide have stronger reactivity and short and small type molecular chain structure, can be to hydroxyl second in copolymerization
Base is formed and surrounds structure, so as to realize the strand of the hydrophobic molecule segment that internal high crosslinking is wrapped in by surface super hydrophilic group
Structure, makes texture paint possess super hydrophilic characteristic in reaction system, so as to greatly improve the dirt-removing power of texture paint film.Its
Secondary, photochemical catalyst itself has stronger Superhydrophilic and a Strong oxdiative ability, thus quickly spot decomposed on texture paint film,
And spot is taken away in the flowing of Jing water, the self-cleaning function of texture paint film is realized.Finally, water-repelling agent is using nonpolar in aqueous
The effect that group mutually draws close, associate makes texture paint membrane molecule chain there is significant sucking action in aqueous medium, thus energy
Effectively improve the texture paint film water resistance of itself.
2nd, in aqueous automatically cleaning texture paint of the invention, the texture paint of cellulose, wood fibre and inorganic filler is employed
Internal reinforcement system.First, cellulose possesses good dispersiveness, stability and compatibility, can rise in the system of texture paint
To the effect of bonding organic matter and inorganic matter.Secondly, wood fibre itself has excellent dimensional stability and heat endurance,
The anti-cracking performance of texture paint film can be effectively improved in texture paint system.In addition, wood fibre is also equipped with the capillary of fibre structure
Pipe is acted on, and it can quickly be delivered to the moisture of internal system on coating surface, improves the uniformity of moisture in texture paint film, is subtracted
Lack the phenomenon of paint film skinning, and greatly improve the adhesion strength and surface mechanical strength of texture paint film.Meanwhile, capillarity
Effectively the moisture inside texture paint can also be discharged paint film, and reduce the surface tension inside texture paint, effectively reduce texture
The phenomenon of paint film cracking.Finally, inorganic filler has good abrasive resistance, storage stability and strengthens small molecule chain organic matter
The performance such as mechanical strength, anti-wear performance, storage stability and the paint film mechanical strength of texture paint film can be effectively improved.
3rd, aqueous automatically cleaning texture paint of the invention, is prepared by the way of stirring at normal temperature.Above-mentioned technique is according to stirring
The different chemical reactions to reaction system of rotating speed are controlled, its technique very simple, and extra without the need for relying on heating, pressurization etc.
Reaction condition can be prepared, so as to significantly reduce the processing cost of texture paint.
Specific embodiment
The aqueous automatically cleaning texture paint of the present invention includes deionized water, super hydrophilic polymer emulsion, texture sand, inorganic fills out
Material, photochemical catalyst, cellulose, dispersant, wetting agent, multifunctional assistant, water-repelling agent, wood fibre, auxiliary rheological agents and film forming are helped
Agent, above-mentioned component content is respectively by mass fraction：Deionized water 60-150 part, super hydrophilic polymer emulsion 120-200 parts,
Texture sand 500-800 parts, inorganic filler 30-70 parts, photochemical catalyst 3-10 parts, cellulose 1-5 parts, dispersant 2-10 parts, wetting
Agent 0.5-2 parts, multifunctional assistant 0.5-2 parts, water-repelling agent 3-10 parts, wood fibre 3-10 parts, auxiliary rheological agents 3-10 parts, film forming are helped
Agent 5-15 parts.By using the compound system of super hydrophilic polymer emulsion, photochemical catalyst and water-repelling agent, going for texture paint film is improved
Dirty ability, realizes the self-cleaning function of texture paint film, and improves the texture paint film water resistance of itself.
The super hydrophilic polymer emulsion of the aqueous automatically cleaning texture paint of the present invention is by comprising acrylic acid, acrylamide and ethoxy
Acrylic acid monomer copolymerization is formed, the mol ratio of said components：Acrylic acid：Acrylamide：Hydroxyethyl is（0.6-1）：
（0.4-1）：1.Using the compound molecule chain structure that the hydrophilic radical produced after said components copolymerization is shell, hydrophobic grouping is core,
Texture paint is set to possess super hydrophilic characteristic after the reaction, so as to improve the dirt-removing power of texture paint film.
The inorganic filler of the aqueous automatically cleaning texture paint of the present invention is using the one kind in powdered whiting, titanium dioxide and talcum powder
Or with arbitrary proportion mixing, powdered whiting has the advantages that strong chemical stability, heat endurance and good dispersion, and it can improve
The weatherability and chemical proofing of texture paint film.Titanium dioxide has the tinctorial property of good photostability and product, and can
Photocatalysis synergy is produced between photochemical catalyst, so as to improve the resistance to light and hydrophilicity of texture paint film.Talcum
Powder then has excellent lubricity, good fire resistance and anti-stick property, can improve the processing characteristics of texture paint film.
The photochemical catalyst of the aqueous automatically cleaning texture paint of the present invention adopts nano titanium oxide, using its Superhydrophilic, strong oxygen
It is the features such as change ability, good shielding ultraviolet rays ability, dispersiveness and weatherability, rapid decomposable to stick on texture paint film
Spot, and the flowing of Jing water takes away spot, realizes the self-cleaning function of texture paint film.
The cellulose of the aqueous automatically cleaning texture paint of the present invention adopts hydroxypropyl methyl cellulose, hydroxyethyl cellulose, hydroxyl second
One kind in ylmethyl cellulose or with arbitrary proportion mixing.Said components are respectively provided with stronger adhesive power, good lubrication
Property and dispersiveness, can improve the uniformity of each component in texture paint system, and improve the company of organic matter and inorganic matter in texture paint
Connect ability.
The dispersant of the aqueous automatically cleaning texture paint of the present invention adopts sodium tripolyphosphate, calgon, sodium pyrophosphate, three second
One kind in base hexyl phosphoric acid, lauryl sodium sulfate, methyl anyl alcohol or with arbitrary proportion mixing.Said components are good except possessing
Outside good surface-active, it also has metal and nonmetallic chelation, so as to improve system uniformity and the change of texture paint
Learn stability.
The wetting agent of the aqueous automatically cleaning texture paint of the present invention using sulfonated oil, sulfur alcohol compound, hydrazide kind compound and
One kind in mercaptan acetal compound or with arbitrary proportion mixing.It is stronger that said components can give each component in texture paint system
Penetrating power, and it is respectively provided with good surface-active, can produce with dispersant and cooperate with peptizaiton.
The multifunctional assistant of the aqueous automatically cleaning texture paint of the present invention is using the one kind in linear alcohols amine, organic amine and ammoniacal liquor
Or with arbitrary proportion mixing.PH value in the adjustable texture paint system of said components, and it is respectively provided with good binding ability and table
Face activation capacity, can improve the stability and its concatenation ability between inorganic matter of texture paint system molecular chain structure.Additionally,
Said components can also provide hydrophobic grouping for texture paint system, so as to improve the water resistance of texture paint system.
The water-repelling agent of the aqueous automatically cleaning texture paint of the present invention adopts the one kind in fatty amine and amino silicones or to appoint
Meaning ratio mixes.Said components can provide substantial amounts of hydrophobic grouping, can improve the water-resistant capacity of texture paint system.
The fibre length of the wood fibre of the aqueous automatically cleaning texture paint of the present invention is 100-600 μm, in the length range
Wood fibre can improve its moisture on the basis of texture paint system mechanical strength is ensured and discharge ability, so as to improve texture paint film
Adhesion strength.
The auxiliary rheological agents of the aqueous automatically cleaning texture paint of the present invention adopt organic clay, bentonite, xanthans, polyacrylic acid
One kind in ester, polyurethane or with arbitrary proportion mixing.The kinematic viscosity of liquid part, carries in the adjustable texture paint of said components
Covering power of the liquid part to solid portion in high texture paint, extends the pot-life of texture paint.
The coalescents of the aqueous automatically cleaning texture paint of the present invention using propandiol butyl ether, propylene glycol methyl ether acetate, 12
One kind in carbon alcohol ester, propane diols phenylate or with arbitrary proportion mixing.Said components can promote super hydrophilic polymer emulsion molecule
The agglutinating power of chain, enables texture paint system to be respectively provided with good filming performance in wider temperature range.Additionally, said components
Also with the feature of environmental protection is strong, compatibility is good, the low advantage of volatility.
The preparation method of the aqueous automatically cleaning texture paint of the present invention is comprised the following steps：
a：It is standby said components to be weighed according to proportioning；
b：Under normal temperature and pressure, deionized water is added in dispersion tank, then respectively toward dispersion tank in the lasting dispersion of dispersion machine
Interior addition cellulose, dispersant, wetting agent, water-repelling agent, multifunctional assistant and wood fibre, addition turns in 500-800 after finishing/
Persistently disperse 10-40 minutes under the rotating speed for dividing；
c：Inorganic filler and photochemical catalyst are separately added into toward b step gained mixture, and dispersing speed is promoted to 1500-
2000 revs/min, then persistently disperse 20-40 minutes；
d：Super hydrophilic polymer emulsion, auxiliary rheological agents and coalescents are separately added into toward step c gained mixture, and dispersion
Machine rotating speed is reduced to 1000-1300 rev/min, then persistently disperses 10-30 minutes；
e：Texture sand is added toward Step d gained mixture, and dispersing speed is down to 400-700 rev/min, then persistently divided
Aqueous automatically cleaning texture paint can be obtained after scattered 20-50 minutes.
Determined according to flexible texture coating material testing standard JC/T 2079-2011 for building, the present invention's is aqueous from clearly
The paint film of clean texture paint respectively in water and alkali soak 96 hours after, paint film without has occurred drum, ftracture, peeling situations such as.And
Its stain resistant coefficient is 8-12；Its adhesion strength is 1.75-1.95MPa.
It is described in detail with reference to a pair each embodiments of table, but does not therefore limit the invention to the enforcement
In the range of example：
Embodiment 1
The present invention aqueous automatically cleaning texture paint include deionized water, super hydrophilic polymer emulsion, texture sand, powdered whiting,
Nano titanium oxide, hydroxypropyl methyl cellulose, sodium tripolyphosphate, sulfonated oil, linear alcohols amine, fatty amine, wood fibre, have
Machine clay, propandiol butyl ether, above-mentioned component content is respectively by mass fraction：60 parts of deionized water, super hydrophilic polymer breast
120 parts of liquid, 500 parts of texture sand, 30 parts of powdered whiting, 3 parts of nano titanium oxide, 1 part of hydroxypropyl methyl cellulose, trimerization phosphorus
2 parts of sour sodium, 0.5 part of sulfonated oil, 0.5 part of linear alcohols amine, 3 parts of fatty amine, 3 parts of wood fibre, 3 parts of organic clay, propane diols
5 parts of butyl ether.
The super hydrophilic polymer emulsion of the present invention is by the monomer copolymerization comprising acrylic acid, acrylamide and hydroxyethyl
Form, the mol ratio of said components：Acrylic acid：Acrylamide：Hydroxyethyl is 0.6：0.4：1.And the fibre of wood fibre
Dimension length is 600 μm.
The preparation method of the aqueous automatically cleaning texture paint of the present invention is comprised the following steps：
a：It is standby said components to be weighed according to proportioning；
b：Under normal temperature and pressure, deionized water is added in dispersion tank, then respectively toward dispersion tank in the lasting dispersion of dispersion machine
Interior addition cellulose, dispersant, wetting agent, water-repelling agent, multifunctional assistant and wood fibre, add after finishing at 500 revs/min
Persistently disperse under rotating speed 10 minutes；
c：Inorganic filler and photochemical catalyst are separately added into toward b step gained mixture, and dispersing speed is promoted to 1500
Rev/min, then persistently disperse 20 minutes；
d：Super hydrophilic polymer emulsion, auxiliary rheological agents and coalescents are separately added into toward step c gained mixture, and dispersion
Machine rotating speed is reduced to 1000 revs/min, then persistently disperses 10 minutes；
e：Texture sand is added toward Step d gained mixture, and dispersing speed is down to 400 revs/min, then persistently disperse 20
Aqueous automatically cleaning texture paint can be obtained after minute.
Determined according to flexible texture coating material testing standard JC/T 2079-2011 for building, the present invention's is aqueous from clearly
The paint film of clean texture paint respectively in water and alkali soak 96 hours after, paint film without has occurred drum, ftracture, peeling situations such as.And
Its stain resistant coefficient is 12；Its adhesion strength is 1.75MPa.
Embodiment 2
The present invention aqueous automatically cleaning texture paint include deionized water, super hydrophilic polymer emulsion, texture sand, powdered whiting,
Titanium dioxide, talcum powder, nano titanium oxide, hydroxypropyl methyl cellulose, hydroxyethyl cellulose, HEMC, three
Polyphosphate sodium, calgon, sodium pyrophosphate, triethyl group hexyl phosphoric acid, lauryl sodium sulfate, methyl anyl alcohol, sulfonated oil, sulphur
Alcohol compound, hydrazide kind compound, mercaptan acetal compound, linear alcohols amine, organic amine, ammoniacal liquor, fatty amine, amino gather
Siloxanes, wood fibre, organic clay, bentonite, xanthans, polyacrylate, polyurethane, propandiol butyl ether, propane diols first
Ether acetate, Lauryl Alcohol ester, propane diols phenylate, above-mentioned component content is respectively by mass fraction：150 parts of deionized water,
200 parts of super hydrophilic polymer emulsion, 800 parts of texture sand, 20 parts of powdered whiting, 20 parts of titanium dioxide, part, nanometer two of talcum powder 30
10 parts of titanium oxide, 1 part of hydroxypropyl methyl cellulose, 2 parts of hydroxyethyl cellulose, 2 parts of HEMC, sodium tripolyphosphate
1 part, 1 part of calgon, 2 parts of sodium pyrophosphate, 2 parts of triethyl group hexyl phosphoric acid, 2 parts of lauryl sodium sulfate, methyl anyl alcohol 2
Part, 0.5 part of sulfonated oil, 0.5 part of sulfur alcohol compound, 0.5 part of hydrazide kind compound, 0.5 part of mercaptan acetal compound, straight chain
It is 0.5 part of alkanolamine, 0.5 part of organic amine, 1 part of ammoniacal liquor, 5 parts of fatty amine, 5 parts of amino silicones, 10 parts of wood fibre, organic viscous
2 parts of soil, 2 parts of bentonite, 2 parts of xanthans, 2 parts of polyacrylate, 2 parts of polyurethane, 3 parts of propandiol butyl ether, propylene glycol monomethyl ether vinegar
4 parts of acid esters, 4 parts of Lauryl Alcohol ester, 4 parts of propane diols phenylate.
The super hydrophilic polymer emulsion of the present invention is by the monomer copolymerization comprising acrylic acid, acrylamide and hydroxyethyl
Form, the mol ratio of said components：Acrylic acid：Acrylamide：Hydroxyethyl is 1：1：1.And the fiber of wood fibre is long
Spend for 100 μm.
The preparation method of the aqueous automatically cleaning texture paint of the present invention is comprised the following steps：
a：It is standby said components to be weighed according to proportioning；
b：Under normal temperature and pressure, deionized water is added in dispersion tank, then respectively toward dispersion tank in the lasting dispersion of dispersion machine
Interior addition cellulose, dispersant, wetting agent, water-repelling agent, multifunctional assistant and wood fibre, add after finishing at 800 revs/min
Persistently disperse under rotating speed 40 minutes；
c：Inorganic filler and photochemical catalyst are separately added into toward b step gained mixture, and dispersing speed is promoted to 2000
Rev/min, then persistently disperse 40 minutes；
d：Super hydrophilic polymer emulsion, auxiliary rheological agents and coalescents are separately added into toward step c gained mixture, and dispersion
Machine rotating speed is reduced to 1300 revs/min, then persistently disperses 30 minutes；
e：Texture sand is added toward Step d gained mixture, and dispersing speed is down to 700 revs/min, then persistently disperse 50
Aqueous automatically cleaning texture paint can be obtained after minute.
Determined according to flexible texture coating material testing standard JC/T 2079-2011 for building, the present invention's is aqueous from clearly
The paint film of clean texture paint respectively in water and alkali soak 96 hours after, paint film without has occurred drum, ftracture, peeling situations such as.And
Its stain resistant coefficient is 8；Its adhesion strength is 1.95MPa.
Embodiment 3
The aqueous automatically cleaning texture paint of the present invention includes deionized water, super hydrophilic polymer emulsion, texture sand, titanium dioxide, talcum
Powder, nano titanium oxide, hydroxyethyl cellulose, HEMC, calgon, sodium pyrophosphate, methyl anyl alcohol, sulphur
Alcohol compound, hydrazide kind compound, organic amine, ammoniacal liquor, amino silicones, wood fibre, bentonite, xanthans, poly- third
Olefin(e) acid ester, propylene glycol methyl ether acetate, Lauryl Alcohol ester, above-mentioned component content is respectively by mass fraction：Deionized water 90
Part, 14 parts of super hydrophilic polymer emulsion, 550 parts of texture sand, 20 parts of titanium dioxide, 20 parts of talcum powder, 5 parts of nano titanium oxide, hydroxyl
1 part of ethyl cellulose, 1 part of HEMC, 2 parts of calgon, 2 parts of sodium pyrophosphate, sulfur alcohol compound 0.5
Part, 0.5 part of hydrazide kind compound, 0.5 part of organic amine, 0.5 part of ammoniacal liquor, 5 parts of amino silicones, 5 parts of wood fibre, bentonite
2 parts, 2 parts of xanthans, 1 part of polyacrylate, 4 parts of propylene glycol methyl ether acetate, 4 parts of Lauryl Alcohol ester.
The super hydrophilic polymer emulsion of the present invention is by the monomer copolymerization comprising acrylic acid, acrylamide and hydroxyethyl
Form, the mol ratio of said components：Acrylic acid：Acrylamide：Hydroxyethyl is 0.7：0.6：1.And the fibre of wood fibre
Dimension length is 450 μm.
The preparation method of the aqueous automatically cleaning texture paint of the present invention is comprised the following steps：
a：It is standby said components to be weighed according to proportioning；
b：Under normal temperature and pressure, deionized water is added in dispersion tank, then respectively toward dispersion tank in the lasting dispersion of dispersion machine
Interior addition cellulose, dispersant, wetting agent, water-repelling agent, multifunctional assistant and wood fibre, add after finishing at 600 revs/min
Persistently disperse under rotating speed 15 minutes；
c：Inorganic filler and photochemical catalyst are separately added into toward b step gained mixture, and dispersing speed is promoted to 1600
Rev/min, then persistently disperse 25 minutes；
d：Super hydrophilic polymer emulsion, auxiliary rheological agents and coalescents are separately added into toward step c gained mixture, and dispersion
Machine rotating speed is reduced to 1100 revs/min, then persistently disperses 15 minutes；
e：Texture sand is added toward Step d gained mixture, and dispersing speed is down to 500 revs/min, then persistently disperse 30
Aqueous automatically cleaning texture paint can be obtained after minute.
Determined according to flexible texture coating material testing standard JC/T 2079-2011 for building, the present invention's is aqueous from clearly
The paint film of clean texture paint respectively in water and alkali soak 96 hours after, paint film without has occurred drum, ftracture, peeling situations such as.And
Its stain resistant coefficient is 11；Its adhesion strength is 1.8MPa.
Embodiment 4
The present invention aqueous automatically cleaning texture paint include deionized water, super hydrophilic polymer emulsion, texture sand, powdered whiting,
Titanium dioxide, talcum powder, nano titanium oxide, hydroxypropyl methyl cellulose, hydroxyethyl cellulose, HEMC, three
Polyphosphate sodium, calgon, sodium pyrophosphate, triethyl group hexyl phosphoric acid, lauryl sodium sulfate, methyl anyl alcohol, sulfonated oil, sulphur
Alcohol compound, mercaptan acetal compound, linear alcohols amine, organic amine, ammoniacal liquor, fatty amine, amino silicones, wooden fibre
Dimension, organic clay, polyacrylate, polyurethane, propandiol butyl ether, propylene glycol methyl ether acetate, Lauryl Alcohol ester, propylene glycol phenyl
Ether, above-mentioned component content is respectively by mass fraction：120 parts of deionized water, 160 parts of super hydrophilic polymer emulsion, texture sand
600 parts, 20 parts of powdered whiting, 10 parts of titanium dioxide, 20 parts of talcum powder, 7 parts of nano titanium oxide, hydroxypropyl methyl cellulose 1
Part, 1 part of hydroxyethyl cellulose, 1 part of HEMC, 1 part of sodium tripolyphosphate, 1 part of calgon, sodium pyrophosphate 1
Part, 1 part of triethyl group hexyl phosphoric acid, 1 part of lauryl sodium sulfate, 1 part of methyl anyl alcohol, 0.5 part of sulfonated oil, sulfur alcohol compound
0.5 part, 0.5 part of mercaptan acetal compound, 0.5 part of linear alcohols amine, 0.5 part of organic amine, 0.5 part of ammoniacal liquor, 3 parts of fatty amine,
4 parts of amino silicones, 7 parts of wood fibre, 2 parts of organic clay, 2 parts of polyacrylate, 3 parts of polyurethane, propandiol butyl ether 3
Part, 3 parts of propylene glycol methyl ether acetate, 2 parts of Lauryl Alcohol ester, 3 parts of propane diols phenylate.
The super hydrophilic polymer emulsion of the present invention is by the monomer copolymerization comprising acrylic acid, acrylamide and hydroxyethyl
Form, the mol ratio of said components：Acrylic acid：Acrylamide：Hydroxyethyl is 0.8：0.8：1.And the fibre of wood fibre
Dimension length is 300 μm.
The preparation method of the aqueous automatically cleaning texture paint of the present invention is comprised the following steps：
a：It is standby said components to be weighed according to proportioning；
b：Under normal temperature and pressure, deionized water is added in dispersion tank, then respectively toward dispersion tank in the lasting dispersion of dispersion machine
Interior addition cellulose, dispersant, wetting agent, water-repelling agent, multifunctional assistant and wood fibre, add after finishing at 700 revs/min
Persistently disperse under rotating speed 25 minutes；
c：Inorganic filler and photochemical catalyst are separately added into toward b step gained mixture, and dispersing speed is promoted to 1700
Rev/min, then persistently disperse 30 minutes；
d：Super hydrophilic polymer emulsion, auxiliary rheological agents and coalescents are separately added into toward step c gained mixture, and dispersion
Machine rotating speed is reduced to 1200 revs/min, then persistently disperses 20 minutes；
e：Texture sand is added toward Step d gained mixture, and dispersing speed is down to 550 revs/min, then persistently disperse 35
Aqueous automatically cleaning texture paint can be obtained after minute.
Determined according to flexible texture coating material testing standard JC/T 2079-2011 for building, the present invention's is aqueous from clearly
The paint film of clean texture paint respectively in water and alkali soak 96 hours after, paint film without has occurred drum, ftracture, peeling situations such as.And
Its stain resistant coefficient is 10；Its adhesion strength is 1.85MPa.
Embodiment 5
The present invention aqueous automatically cleaning texture paint include deionized water, super hydrophilic polymer emulsion, texture sand, powdered whiting,
Titanium dioxide, talcum powder, nano titanium oxide, hydroxypropyl methyl cellulose, hydroxyethyl cellulose, HEMC, three
Polyphosphate sodium, calgon, sodium pyrophosphate, triethyl group hexyl phosphoric acid, lauryl sodium sulfate, methyl anyl alcohol, sulfonated oil, sulphur
Alcohol compound, hydrazide kind compound, mercaptan acetal compound, linear alcohols amine, organic amine, ammoniacal liquor, fatty amine, amino gather
Siloxanes, wood fibre, organic clay, bentonite, xanthans, polyacrylate, polyurethane, propandiol butyl ether, propane diols first
Ether acetate, Lauryl Alcohol ester, propane diols phenylate, above-mentioned component content is respectively by mass fraction：140 parts of deionized water,
180 parts of super hydrophilic polymer emulsion, 700 parts of texture sand, 20 parts of powdered whiting, 20 parts of titanium dioxide, part, nanometer two of talcum powder 20
9 parts of titanium oxide, 2 parts of hydroxypropyl methyl cellulose, 1 part of hydroxyethyl cellulose, 1 part of HEMC, sodium tripolyphosphate 2
Part, 2 parts of calgon, 1 part of sodium pyrophosphate, 1 part of triethyl group hexyl phosphoric acid, 1 part of lauryl sodium sulfate, 1 part of methyl anyl alcohol,
0.5 part of sulfonated oil, 0.4 part of sulfur alcohol compound, 0.4 part of hydrazide kind compound, 0.5 part of mercaptan acetal compound, straight chain alkane
1 part of hydramine, 0.5 part of organic amine, 0.5 part of ammoniacal liquor, 5 parts of fatty amine, 4 parts of amino silicones, 9 parts of wood fibre, organic clay 1
Part, 1 part of bentonite, 2 parts of xanthans, 2 parts of polyacrylate, 2 parts of polyurethane, 4 parts of propandiol butyl ether, propylene glycol methyl ether acetate
3 parts, 3 parts of Lauryl Alcohol ester, 4 parts of propane diols phenylate.
The super hydrophilic polymer emulsion of the present invention is by the monomer copolymerization comprising acrylic acid, acrylamide and hydroxyethyl
Form, the mol ratio of said components：Acrylic acid：Acrylamide：Hydroxyethyl is 0.9：1：1.And the fiber of wood fibre
Length is 150m.
The preparation method of the aqueous automatically cleaning texture paint of the present invention is comprised the following steps：
a：It is standby said components to be weighed according to proportioning；
b：Under normal temperature and pressure, deionized water is added in dispersion tank, then respectively toward dispersion tank in the lasting dispersion of dispersion machine
Interior addition cellulose, dispersant, wetting agent, water-repelling agent, multifunctional assistant and wood fibre, add after finishing at 800 revs/min
Persistently disperse 30 clocks under rotating speed；
c：Inorganic filler and photochemical catalyst are separately added into toward b step gained mixture, and dispersing speed is promoted to 1900
Rev/min, then persistently disperse 35 clocks；
d：Super hydrophilic polymer emulsion, auxiliary rheological agents and coalescents are separately added into toward step c gained mixture, and dispersion
Machine rotating speed is reduced to 1300 revs/min, then persistently disperses 25 clocks；
e：Texture sand is added toward Step d gained mixture, and dispersing speed is down to 650 revs/min, then persistently disperse 45
Aqueous automatically cleaning texture paint can be obtained after minute.
Determined according to flexible texture coating material testing standard JC/T 2079-2011 for building, the present invention's is aqueous from clearly
The paint film of clean texture paint respectively in water and alkali soak 96 hours after, paint film without has occurred drum, ftracture, peeling situations such as.And
Its stain resistant coefficient is 9；Its adhesion strength is 1.9MPa.
Claims (13)
1. a kind of aqueous automatically cleaning texture paint, it is characterised in that：The aqueous automatically cleaning texture paint includes deionized water, super hydrophilic
Polymer emulsion, texture sand, inorganic filler, photochemical catalyst, cellulose, dispersant, wetting agent, multifunctional assistant, water-repelling agent, wood
Matter fiber, auxiliary rheological agents and coalescents, above-mentioned component content is respectively by mass fraction：It is deionized water 60-150 part, super
Hydrophilic polymer emulsion 120-200 part, texture sand 500-800 parts, inorganic filler 30-70 parts, photochemical catalyst 3-10 parts, cellulose
1-5 parts, dispersant 2-10 parts, wetting agent 0.5-2 parts, multifunctional assistant 0.5-2 parts, water-repelling agent 3-10 parts, wood fibre 3-10
Part, auxiliary rheological agents 3-10 parts, coalescents 5-15 parts.
2. aqueous automatically cleaning texture paint according to claim 1, it is characterised in that：The super hydrophilic polymer emulsion is by including
The monomer copolymerization of acrylic acid, acrylamide and hydroxyethyl is formed, the mol ratio of said components：Acrylic acid：Acrylamide：
Hydroxyethyl is（0.6-1）：（0.4-1）：1.
3. aqueous automatically cleaning texture paint according to claim 1, it is characterised in that：The inorganic filler includes heavy carbonic acid
One kind in calcium, titanium dioxide and talcum powder or with arbitrary proportion mixing.
4. aqueous automatically cleaning texture paint according to claim 1, it is characterised in that：The photochemical catalyst is nanometer titanium dioxide
Titanium.
5. aqueous automatically cleaning texture paint according to claim 1, it is characterised in that：The cellulose includes that hydroxypropyl methyl is fine
Tie up the one kind in element, hydroxyethyl cellulose, HEMC or mixed with arbitrary proportion.
6. aqueous automatically cleaning texture paint according to claim 1, it is characterised in that：The dispersant include sodium tripolyphosphate,
One kind in calgon, sodium pyrophosphate, triethyl group hexyl phosphoric acid, lauryl sodium sulfate, methyl anyl alcohol or arbitrarily to compare
Example mixing.
7. aqueous automatically cleaning texture paint according to claim 1, it is characterised in that：The wetting agent includes sulfonated oil, mercaptan
One kind in class compound, hydrazide kind compound and mercaptan acetal compound or with arbitrary proportion mixing.
8. aqueous automatically cleaning texture paint according to claim 1, it is characterised in that：The multifunctional assistant includes linear alcohols
One kind in amine, organic amine and ammoniacal liquor or with arbitrary proportion mixing.
9. aqueous automatically cleaning texture paint according to claim 1, it is characterised in that：The water-repelling agent includes fatty amine and amino
One kind in polysiloxanes or with arbitrary proportion mixing.
10. aqueous automatically cleaning texture paint according to claim 1, it is characterised in that：The fibre length of the wood fibre is
100-600μm。
11. aqueous automatically cleaning texture paints according to claim 1, it is characterised in that：The auxiliary rheological agents include organic clay,
One kind in bentonite, xanthans, polyacrylate, polyurethane or with arbitrary proportion mixing.
12. aqueous automatically cleaning texture paints according to claim 1, it is characterised in that：The coalescents include propane diols fourth
One kind in ether, propylene glycol methyl ether acetate, Lauryl Alcohol ester, propane diols phenylate or with arbitrary proportion mixing.
A kind of 13. preparation methods of aqueous automatically cleaning texture paint as claimed in claim 1, it is characterised in that：The preparation method
Comprise the following steps：
a：It is standby said components to be weighed according to proportioning；
b：Under normal temperature and pressure, deionized water is added in dispersion tank, then respectively toward dispersion tank in the lasting dispersion of dispersion machine
Interior addition cellulose, dispersant, wetting agent, water-repelling agent, multifunctional assistant and wood fibre, addition turns in 500-800 after finishing/
Persistently disperse 10-40 minutes under the rotating speed for dividing；
c：Inorganic filler and photochemical catalyst are separately added into toward b step gained mixture, and dispersing speed is promoted to 1500-
2000 revs/min, then persistently disperse 20-40 minutes；
d：Super hydrophilic polymer emulsion, auxiliary rheological agents and coalescents are separately added into toward step c gained mixture, and dispersion
Machine rotating speed is reduced to 1000-1300 rev/min, then persistently disperses 10-30 minutes；
e：Texture sand is added toward Step d gained mixture, and dispersing speed is down to 400-700 rev/min, then persistently divided
Aqueous automatically cleaning texture paint can be obtained after scattered 20-50 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611268027.4A CN106634378A (en) | 2016-12-31 | 2016-12-31 | Water-based self-cleaning textured paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611268027.4A CN106634378A (en) | 2016-12-31 | 2016-12-31 | Water-based self-cleaning textured paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106634378A true CN106634378A (en) | 2017-05-10 |
Family
ID=58839058
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201611268027.4A Pending CN106634378A (en) | 2016-12-31 | 2016-12-31 | Water-based self-cleaning textured paint and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112280386A (en) * | 2020-11-09 | 2021-01-29 | 浙江优艺雅涂料有限公司 | Water-based paste waterproof coating and preparation method thereof |
| CN114316704A (en) * | 2021-12-30 | 2022-04-12 | 深圳文华清水建筑工程有限公司 | Bare concrete protective agent and preparation method and application thereof |
| CN115626621A (en) * | 2022-10-20 | 2023-01-20 | 贵州开阳青利天盟化工有限公司 | Production method of instant sodium tripolyphosphate |
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| CN112280386A (en) * | 2020-11-09 | 2021-01-29 | 浙江优艺雅涂料有限公司 | Water-based paste waterproof coating and preparation method thereof |
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