CN106592211A - 一种阻燃毛织物柔软剂及其制备方法 - Google Patents

一种阻燃毛织物柔软剂及其制备方法 Download PDF

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CN106592211A
CN106592211A CN201611154469.6A CN201611154469A CN106592211A CN 106592211 A CN106592211 A CN 106592211A CN 201611154469 A CN201611154469 A CN 201611154469A CN 106592211 A CN106592211 A CN 106592211A
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叶冬明
陈菊珍
陈菊媛
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Suzhou Chen Heng Weaves Co Ltd
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Abstract

本发明公开了一种阻燃毛织物柔软剂，该柔软剂按质量份数计包括以下组分：环氧大豆油丙烯酸酯：30‑40份，二甲基二硅氧烷：10‑15份，八甲基四硅氧烷：7‑9份，二月桂酸二丁基锡：5‑7份，聚乙烯醇：10‑15份，酒石酸：9‑11份，硝酸银：7‑9份，复配阻燃剂：8‑12份，硅藻土：3‑5份，去离子水：15‑20份；本发明还涉及一种阻燃毛织物柔软剂的制备方法，该制备方法简单易行，制备出的柔软剂使得毛织物具有一定的阻燃性以及抗菌性，有利于皮肤的健康。

Description

一种阻燃毛织物柔软剂及其制备方法
技术领域
本发明属于纺织助剂技术领域，具体涉及一种阻燃毛织物柔软剂及其制备方法。
背景技术
近年来，随着社会生活的快速发展，人们的生活水平也随之提高，对衣食、住、行的要求也越来越高。对穿着，人们不仅要求衣物要有遮体、保温等功能，还要求衣物要有舒适、透湿、排汗、抗皱、防水防油、易去污、防紫外线、抗静电等功能，要求越来越高；然而对于纺织原材料及印染加工过程的剖析，合成纤维与天然纤维的差异及在印染加工中对于纺织品原有优势风格和手感的破坏，使得印染加工的各类型后整理助剂成为必须，特别是对于柔软剂来说，它的应用更加普遍。
由于柔软剂能赋予织物以柔软、舒适的手感，因此能提高织物的质量和附加价值，已经成为纺织品后整理的主要助剂，随着人们生活水平的提高，环保和健康意识的增强，对纺织特种材料的要求也越来越高，要求面料具有一定的柔软、抗皱等特性，对柔软剂的品质要求也越来越高，这也促进了柔软剂品种的快速发展。
发明内容
本发明所要解决的技术问题是，针对以上现有技术存在的缺点，提出一种阻燃毛织物柔软剂及其制备方法，该制备方法简单易行，制备出的柔软剂使得毛织物具有一定的阻燃性以及抗菌性，有利于皮肤的健康。
本发明解决以上技术问题的技术方案是：
一种阻燃毛织物柔软剂，该柔软剂按质量份数计包括以下组分：
环氧大豆油丙烯酸酯 30-40份
二甲基二硅氧烷 10-15份
八甲基四硅氧烷 7-9份
二月桂酸二丁基锡 5-7份
聚乙烯醇 10-15份
酒石酸 9-11份
硝酸银 7-9份
复配阻燃剂 8-12份
硅藻土 3-5份
去离子水 15-20份；
复配阻燃剂为无醛阻燃剂与的混合物，其中，无醛阻燃剂与磷氮硅三元阻燃剂按质量比2:1的比例混合；
环氧大豆油丙烯酸酯的制备方法如下：
将环氧大豆油和阻聚剂4-甲氧基苯酚加入到装有温度计、电动搅拌器与回流冷凝管的四颈烧瓶中，搅拌10-15min，并升温至30-50℃，同时向烧瓶中加入丙烯酸和三苯基膦的混合物，反应20-40min，继续升温至80℃，反应40-50min，得到粗品，将粗品用丁酮溶解，再加入石油醚产生沉淀，分离出沉淀物，即可得到环氧大豆油丙烯酸酯。
本发明进一步限定的技术方案为：
前述阻燃毛织物柔软剂中，该柔软剂按质量份数计包括以下组分：
环氧大豆油丙烯酸酯：30份，二甲基二硅氧烷：10份，八甲基四硅氧烷：7份，二月桂酸二丁基锡：5份，聚乙烯醇：10份，酒石酸：9份，硝酸银：7份，复配阻燃剂：8份，硅藻土：3份，去离子水：5份。
前述阻燃毛织物柔软剂中，该柔软剂按质量份数计包括以下组分：
环氧大豆油丙烯酸酯：40份，二甲基二硅氧烷：15份，八甲基四硅氧烷：9份，二月桂酸二丁基锡：7份，聚乙烯醇：15份，酒石酸：11份，硝酸银：9份，复配阻燃剂：12份，硅藻土：5份，去离子水：20份。
前述阻燃毛织物柔软剂中，该柔软剂按质量份数计包括以下组分：
环氧大豆油丙烯酸酯：35份，二甲基二硅氧烷：13份，八甲基四硅氧烷：8份，二月桂酸二丁基锡：6份，聚乙烯醇：13份，酒石酸：10份，硝酸银：8份，复配阻燃剂：11份，硅藻土：4份，去离子水：11份。
前述阻燃毛织物柔软剂，复配阻燃剂的制备方法具体如下：
（1）将无醛阻燃剂、磷氮硅三元阻燃剂混合并加入丙三醇溶液中搅拌均匀；
（2）向上述步骤（1）中加入植酸和尿素，再加入少量的去离子水，在超声波振荡器中完全溶解；
其中，所述的植酸和尿素的质量比为3:1；
（3）向上述步骤（2）中加入浓氨水，调节PH为5-6，最后即得到复配阻燃剂。
本发明还涉及了一种阻燃毛织物柔软剂的制备方法，该柔软剂的具体制备方法如下：
（一）将环氧大豆油丙烯酸酯和二甲基二硅氧烷、八甲基四硅氧烷投入反应器，在40-50℃下反应20-30min；
（二）向步骤（一）中加入二月桂酸二丁基锡维持搅拌10min后加入聚乙烯醇，继续于55℃搅拌50-70 min；
（三）将步骤（二）中体系温度以大约2℃/min的速度降低至30℃，在25min内缓慢加入二月桂酸二丁基锡及硅藻土，并维持搅拌温度在20-30℃之间，之后搅拌保持25min，然后加入酒石酸及硝酸银继续搅拌20-30min，最后加入复配阻燃剂继续搅拌均匀，分批次加入去离子水，即可制得毛织物柔软剂，灌装。
本发明的有益效果是：
本发明中加入了硝酸银、酒石酸具有一定的抗菌性，增强了柔软剂的抗菌性，对人体皮肤具有一定的好处，有利于人体的健康。
本发明中以植酸作为酸源、丙三醇作为碳源、尿素作为气源、配制成的新型棉用膨胀阻燃剂，可以有效的对织物进行阻燃整理，阻燃效果较好，对织物损伤小，并且原料环保、价格便。
本发明中加入的磷元素协同阻燃剂的合成工艺简单、产率高、阻燃效果好，具有广阔的前景。
本发明中将几种不同的阻燃剂混合形成一种新的阻燃体系，共同阻燃效果大于各阻燃成分单独作用之和，协同效应不仅能提高阻燃体系的效率，而且能减少体系中某种成分或全部成分的用量。
本发明中添加了硅系阻燃剂，在经过硅系阻燃系整理织物后，织物阻燃性能明显提高，且对织物的柔软性没有大的影响。
本发明中加入环氧大豆油丙烯酸酯，以环氧大豆油为原料经多步反应制的，大豆油本身具有拒水性，得到的柔软剂也具有不错的拒水性。
具体实施方式
实施例1
本实施例提供一种阻燃毛织物柔软剂，该柔软剂按质量份数计包括以下组分：
环氧大豆油丙烯酸酯：30份，二甲基二硅氧烷：10份，八甲基四硅氧烷：7份，二月桂酸二丁基锡：5份，聚乙烯醇：10份，酒石酸：9份，硝酸银：7份，复配阻燃剂：8份，硅藻土：3份，去离子水：5份。
复配阻燃剂为无醛阻燃剂与的混合物，其中，无醛阻燃剂与磷氮硅三元阻燃剂按质量比2:1的比例混合；
环氧大豆油丙烯酸酯的制备方法如下：
将环氧大豆油和阻聚剂4-甲氧基苯酚加入到装有温度计、电动搅拌器与回流冷凝管的四颈烧瓶中，搅拌10min，并升温至30℃，同时向烧瓶中加入丙烯酸和三苯基膦的混合物，反应20min，继续升温至80℃，反应40min，得到粗品，将粗品用丁酮溶解，再加入石油醚产生沉淀，分离出沉淀物，即可得到环氧大豆油丙烯酸酯。
前述阻燃毛织物柔软剂，复配阻燃剂的制备方法具体如下：
（1）将无醛阻燃剂、磷氮硅三元阻燃剂混合并加入丙三醇溶液中搅拌均匀；
（2）向上述步骤（1）中加入植酸和尿素，再加入少量的去离子水，在超声波振荡器中完全溶解；
其中，植酸和尿素的质量比为3:1；
（3）向上述步骤（2）中加入浓氨水，调节PH为5，最后即得到复配阻燃剂。
上述阻燃毛织物柔软剂的制备方法，该柔软剂的具体制备方法如下：
（一）将环氧大豆油丙烯酸酯和二甲基二硅氧烷、八甲基四硅氧烷投入反应器，在40℃下反应20min；
（二）向步骤（一）中加入二月桂酸二丁基锡维持搅拌10min后加入聚乙烯醇，继续于55℃搅拌50min；
（三）将步骤（二）中体系温度以大约2℃/min的速度降低至30℃，在25min内缓慢加入二月桂酸二丁基锡及硅藻土，并维持搅拌温度在20℃之间，之后搅拌保持25min，然后加入酒石酸及硝酸银继续搅拌20min，最后加入复配阻燃剂继续搅拌均匀，分批次加入去离子水，即可制得毛织物柔软剂，灌装。
实施例2
本实施例提供一种阻燃毛织物柔软剂，该柔软剂按质量份数计包括以下组分：
环氧大豆油丙烯酸酯：40份，二甲基二硅氧烷：15份，八甲基四硅氧烷：9份，二月桂酸二丁基锡：7份，聚乙烯醇：15份，酒石酸：11份，硝酸银：9份，复配阻燃剂：12份，硅藻土：5份，去离子水：20份。
复配阻燃剂为无醛阻燃剂与的混合物，其中，无醛阻燃剂与磷氮硅三元阻燃剂按质量比2:1的比例混合；
环氧大豆油丙烯酸酯的制备方法如下：
将环氧大豆油和阻聚剂4-甲氧基苯酚加入到装有温度计、电动搅拌器与回流冷凝管的四颈烧瓶中，搅拌15min，并升温至50℃，同时向烧瓶中加入丙烯酸和三苯基膦的混合物，反应40min，继续升温至80℃，反应50min，得到粗品，将粗品用丁酮溶解，再加入石油醚产生沉淀，分离出沉淀物，即可得到环氧大豆油丙烯酸酯。
前述阻燃毛织物柔软剂，复配阻燃剂的制备方法具体如下：
（1）将无醛阻燃剂、磷氮硅三元阻燃剂混合并加入丙三醇溶液中搅拌均匀；
（2）向上述步骤（1）中加入植酸和尿素，再加入少量的去离子水，在超声波振荡器中完全溶解；
其中，植酸和尿素的质量比为3:1；
（3）向上述步骤（2）中加入浓氨水，调节PH为6，最后即得到复配阻燃剂。
上述阻燃毛织物柔软剂的制备方法，该柔软剂的具体制备方法如下：
（一）将环氧大豆油丙烯酸酯和二甲基二硅氧烷、八甲基四硅氧烷投入反应器，在50℃下反应30min；
（二）向步骤（一）中加入二月桂酸二丁基锡维持搅拌10min后加入聚乙烯醇，继续于55℃搅拌70 min；
（三）将步骤（二）中体系温度以大约2℃/min的速度降低至30℃，在25min内缓慢加入二月桂酸二丁基锡及硅藻土，并维持搅拌温度在30℃之间，之后搅拌保持25min，然后加入酒石酸及硝酸银继续搅拌30min，最后加入复配阻燃剂继续搅拌均匀，分批次加入去离子水，即可制得毛织物柔软剂，灌装。
实施例3
本实施例提供一种阻燃毛织物柔软剂，该柔软剂按质量份数计包括以下组分：
环氧大豆油丙烯酸酯：35份，二甲基二硅氧烷：13份，八甲基四硅氧烷：8份，二月桂酸二丁基锡：6份，聚乙烯醇：13份，酒石酸：10份，硝酸银：8份，复配阻燃剂：11份，硅藻土：4份，去离子水：11份。
复配阻燃剂为无醛阻燃剂与的混合物，其中，无醛阻燃剂与磷氮硅三元阻燃剂按质量比2:1的比例混合；
环氧大豆油丙烯酸酯的制备方法如下：
将环氧大豆油和阻聚剂4-甲氧基苯酚加入到装有温度计、电动搅拌器与回流冷凝管的四颈烧瓶中，搅拌13min，并升温至40℃，同时向烧瓶中加入丙烯酸和三苯基膦的混合物，反应30min，继续升温至80℃，反应45min，得到粗品，将粗品用丁酮溶解，再加入石油醚产生沉淀，分离出沉淀物，即可得到环氧大豆油丙烯酸酯。
前述阻燃毛织物柔软剂，复配阻燃剂的制备方法具体如下：
（1）将无醛阻燃剂、磷氮硅三元阻燃剂混合并加入丙三醇溶液中搅拌均匀；
（2）向上述步骤（1）中加入植酸和尿素，再加入少量的去离子水，在超声波振荡器中完全溶解；
其中，植酸和尿素的质量比为3:1；
（3）向上述步骤（2）中加入浓氨水，调节PH为5，最后即得到复配阻燃剂。
上述阻燃毛织物柔软剂的制备方法，该柔软剂的具体制备方法如下：
（一）将环氧大豆油丙烯酸酯和二甲基二硅氧烷、八甲基四硅氧烷投入反应器，在45℃下反应25min；
（二）向步骤（一）中加入二月桂酸二丁基锡维持搅拌10min后加入聚乙烯醇，继续于55℃搅拌60 min；
（三）将步骤（二）中体系温度以大约2℃/min的速度降低至30℃，在25min内缓慢加入二月桂酸二丁基锡及硅藻土，并维持搅拌温度在25℃之间，之后搅拌保持25min，然后加入酒石酸及硝酸银继续搅拌25min，最后加入复配阻燃剂继续搅拌均匀，分批次加入去离子水，即可制得毛织物柔软剂，灌装。
除上述实施例外，本发明还可以有其他实施方式。凡采用等同替换或等效变换形成的技术方案，均落在本发明要求的保护范围。

Claims (6)

1.一种阻燃毛织物柔软剂，其特征在于：该柔软剂按质量份数计包括以下组分：
环氧大豆油丙烯酸酯 30-40份
二甲基二硅氧烷 10-15份
八甲基四硅氧烷 7-9份
二月桂酸二丁基锡 5-7份
聚乙烯醇 10-15份
酒石酸 9-11份
硝酸银 7-9份
复配阻燃剂 8-12份
硅藻土 3-5份
去离子水 15-20份；
所述的复配阻燃剂为无醛阻燃剂与的混合物，其中，所述无醛阻燃剂与磷氮硅三元阻燃剂按质量比2:1的比例混合；
所述环氧大豆油丙烯酸酯的制备方法如下：
将环氧大豆油和阻聚剂4-甲氧基苯酚加入到装有温度计、电动搅拌器与回流冷凝管的四颈烧瓶中，搅拌10-15min，并升温至30-50℃，同时向烧瓶中加入丙烯酸和三苯基膦的混合物，反应20-40min，继续升温至80℃，反应40-50min，得到粗品，将粗品用丁酮溶解，再加入石油醚产生沉淀，分离出沉淀物，即可得到环氧大豆油丙烯酸酯。
2.根据权利要求1所述的所述阻燃毛织物柔软剂，其特征在于：该柔软剂按质量份数计包括以下组分：
环氧大豆油丙烯酸酯：30份，二甲基二硅氧烷：10份，八甲基四硅氧烷：7份，二月桂酸二丁基锡：5份，聚乙烯醇：10份，酒石酸：9份，硝酸银：7份，复配阻燃剂：8份，硅藻土：3份，去离子水：5份。
3.根据权利要求1所述的所述阻燃毛织物柔软剂，其特征在于：该柔软剂按质量份数计包括以下组分：
环氧大豆油丙烯酸酯：40份，二甲基二硅氧烷：15份，八甲基四硅氧烷：9份，二月桂酸二丁基锡：7份，聚乙烯醇：15份，酒石酸：11份，硝酸银：9份，复配阻燃剂：12份，硅藻土：5份，去离子水：20份。
4.根据权利要求1所述的所述阻燃毛织物柔软剂，其特征在于：该柔软剂按质量份数计包括以下组分：
环氧大豆油丙烯酸酯：35份，二甲基二硅氧烷：13份，八甲基四硅氧烷：8份，二月桂酸二丁基锡：6份，聚乙烯醇：13份，酒石酸：10份，硝酸银：8份，复配阻燃剂：11份，硅藻土：4份，去离子水：11份。
5.根据权利要求1-4中任一权利要求所述的阻燃毛织物柔软剂，其特征在于：所述复配阻燃剂的制备方法具体如下：
（1）将无醛阻燃剂、磷氮硅三元阻燃剂混合并加入丙三醇溶液中搅拌均匀；
（2）向上述步骤（1）中加入植酸和尿素，再加入少量的去离子水，在超声波振荡器中完全溶解；
其中，所述的植酸和尿素的质量比为3:1；
（3）向上述步骤（2）中加入浓氨水，调节PH为5-6，最后即得到复配阻燃剂。
6.如权利要求1所述的阻燃毛织物柔软剂的制备方法，其特征在于，该柔软剂的具体制备方法如下：
（一）将环氧大豆油丙烯酸酯和二甲基二硅氧烷、八甲基四硅氧烷投入反应器，在40-50℃下反应20-30min；
（二）向步骤（一）中加入二月桂酸二丁基锡维持搅拌10min后加入聚乙烯醇，继续于55℃搅拌50-70 min；
（三）将步骤（二）中体系温度以大约2℃/min的速度降低至30℃，在25min内缓慢加入二月桂酸二丁基锡及硅藻土，并维持搅拌温度在20-30℃之间，之后搅拌保持25min，然后加入酒石酸及硝酸银继续搅拌20-30min，最后加入复配阻燃剂继续搅拌均匀，分批次加入去离子水，即可制得毛织物柔软剂，灌装。
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