CN106566726A - Low-temperature reactive dye soaping agent as well as preparation method and application thereof - Google Patents
Low-temperature reactive dye soaping agent as well as preparation method and application thereof Download PDFInfo
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- CN106566726A CN106566726A CN201610997207.XA CN201610997207A CN106566726A CN 106566726 A CN106566726 A CN 106566726A CN 201610997207 A CN201610997207 A CN 201610997207A CN 106566726 A CN106566726 A CN 106566726A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/16—Phosphates including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/12—Carbonates bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/14—Silicates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Textile Engineering (AREA)
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Abstract
The invention discloses a low-temperature reactive dye soaping agent as well as a preparation method and an application thereof. The low-temperature reactive dye soaping agent comprises the following components in percentage by mass: 10%-20% of a maleic-methyl acrylate copolymer, 2%-5% of an alkaline substance, 10%-20% of an oxidant and the balance of water.
Description
Technical field
The technology field the present invention relates to dyeing and finishing is soaped, more particularly to a kind of reactive dye low temperature soaping agent and preparation method thereof
And application.
Background technology
In fabric or cellulose dyeing, the dyestuff that great majority are used all is reactive dye, is not only because activity
Dyestuff color kind is complete, cheap, but also because being reaction type dye, with fabulous color fastness.In reactive dye structure
Containing substantial amounts of active group, these groups are in dyeing course in combination with the hydroxyl in fiber, and such as generation nucleophilic displacement of fluorine is anti-
Should, or there is nucleophilic addition, therefore with preferable dyefastness.
Although the species of reactive dye is more, comprising s-triazine type, the dilute sulfone type of second, pyrimidine Type etc., these dyestuffs are not
Can completely react with cellulose fibre, always there are some reactive dye and hydrolised dye for having neither part nor lot in reaction on fabric.These
The dyestuff for having neither part nor lot in reaction has to Jing and soaps removal, can otherwise affect fabric color fastness.Additionally, in dye multi-color system fabric or tool
During having the fabric of white background, dark color has neither part nor lot in the dyestuff of reaction and may proceed in combination with light coloured fabrics or white background fabric, cause
It is counter to be stained with, Washing and colorfastness to rubbing can be affected, therefore, soaping agent plays critically important effect to the color fastness of fabric.
Soaping agent is one of conventional auxiliary agent of dyeing, acts primarily as to remove and contaminates with fiber set dyestuff loosely and hydrolysis
Material.Traditional technique of soaping, is all soaped more than 95 DEG C, and can be only achieved client after multiple washing
This aspect consumes the resources such as substantial amounts of water, electricity and gas, on the other hand increased the pollution to water to be required to the fastness of fabric.
At present, soaping agent species is many on market, and some are formed with surfactant compound, this kind of soaping agent foam
Height, needs repeatedly washing；Some are individually to be formulated with horse propylene copolymer, and this kind of soaping agent has preferable removal floating color energy
Power, but do not possess good anti-staining ability；Some are constituted with substantial amounts of alkaline matter, and this kind of soaping agent is due to alkalescence
It is too big, it is larger to the complexion changed of cellulose fibre, while having damaged to fastness.
Therefore, how to provide a kind of neutrality or weak alkaline low-temperature anti-staining soaping agent is one and needs what is solved to ask at present
Topic.
The content of the invention
It is an object of the invention to provide a kind of reactive dye low temperature soaping agent, is applied to fabric or fibre-reactive dye dye
Soaping in technique after color, can not be taken into account with solving both releasing normal complexion removal floating colors that existing soaping agent occurs during soaping
Problem, while, it is adaptable to low temperature soaping, foam is not produced during soaping, and residual liquid colourity of soaping is low, can reduce follow-up
Washing times.
Realize that above-mentioned purpose technical scheme is：Present invention firstly provides reactive dye low temperature soaping agent, be applied to fabric or
Technique of soaping after fibre-reactive dye dyeing.The reactive dye low temperature soaping agent is included by mass fraction：
In an embodiment of the present invention, the horse propylene copolymer is maleic acid and acrylic acid copolymer.
In an embodiment of the present invention, the alkaline matter is sodium tripolyphosphate, anhydrous sodium metasilicate, five water metasilicic acid
At least one in sodium, sodium carbonate, sodium bicarbonate.
In an embodiment of the present invention, the oxidant is sodium peroxydisulfate, potassium peroxydisulfate, Ammonium persulfate., hydrogen peroxide, mistake
At least one in sodium carbonate, sodium hypochlorite.
The present invention also provides the preparation method of above-mentioned reactive dye low temperature soaping agent.Methods described includes：By formula as below
Configuration each component：Horse propylene copolymer 10%-20%, alkaline matter 2%-5%, oxidant 10%-20% are taken by mass fraction；Put
In entering reactor, the water of surplus is added by mass fraction, dissolving is sufficiently stirred at normal temperatures, obtain final product reactive dye low temperature soaping
Agent.
In a preferred embodiment of the present invention, there is provided the preparation method of above-mentioned reactive dye low temperature soaping agent.Methods described
Including：By formula as below proportioning each component：Horse propylene copolymer 10%-20% is weighed by mass fraction；Alkaline matter 2%-5%；
Oxidant 10%-20%, in being then placed in reactor, by mass fraction the water of surplus is added, and dissolving is sufficiently stirred at normal temperatures,
Obtain final product reactive dye low temperature soaping agent.
The present invention also provides the application that the agent of above-mentioned reactive dye low temperature soaping is soaped in technique in fabric or fiber.
In an embodiment of the present invention, the consumption of the reactive dye low temperature soaping agent is 0.3%owf-1%owf；Using
Temperature is at 60 DEG C -80 DEG C.
It is understood that if no special instructions, reagent of the present invention has known preparation method or commercial goods.
It is an advantage of the invention that：The present invention the reactive dye low temperature soaping agent during soaping, alkaline matter
The reactive dye for having neither part nor lot in reaction can be further hydrolyzed, to prevent reactive dye from being combined with fiber-reactive, and at 60 DEG C -80 DEG C
Under the conditions of, its hydrolysis effect is optimal；There is the good compatibility and Synergistic to make for horse propylene copolymer and other water treatment agents
With, in the low temperature soaping agent of this dyestuff be used for remove hydrolised dye and loose colour；Oxidant is used for aoxidizing having neither part nor lot in working solution
The reactive dye and hydrolised dye of reaction, destroy its chromophoric group, to ensure anti-staining effect；Oxidant is according to working solution
Temperature and itself oxidability and select, selected oxidant is only capable of aoxidizing the reactive dye and hydrolysis dye in working solution
Material, and can not aoxidize the reactive dye with fiber strong bonded, thus ensure that cellulose fibre soap after colourity and color jail
Degree.Three's collective effect, serves good compounding effect, it is ensured that soap effect of this soaping agent in low temperature soaping technique
Really, the working effect at particularly 60-80 DEG C is optimal.
Specific embodiment
Hereinafter, with reference to specific embodiment, the technology of the present invention is described in detail.It is appreciated that the various following tool
Body embodiment is only used for helping skilled in the art to understand the present invention, rather than limitation of the present invention.
The reactive dye low temperature soaping agent of the present invention, is included by mass fraction：Horse propylene copolymer 10%-20%；Basic species
Matter 2%-5%；Oxidant 10%-20%；Balance of water.Wherein, the horse propylene copolymer is maleic acid and acrylic copolymer.
The alkaline matter be sodium tripolyphosphate, anhydrous sodium metasilicate, metasilicate pentahydrate sodium, sodium carbonate, sodium bicarbonate in one kind or
Several mixture.The oxidant is sodium peroxydisulfate, potassium peroxydisulfate, Ammonium persulfate., hydrogen peroxide, SODIUM PERCARBONATE, sodium hypochlorite
In one or more mixture.With reference to preparation method embodiment, the reactive dye low temperature soaping agent of the present invention is made into
One step explanation.
Embodiment 1
In the present embodiment, there is provided a kind of preparation method of reactive dye low temperature soaping agent, configuration is followed the steps below：Step
Rapid S1) following each component is configured by mass percentage：Horse propylene copolymer 20%, sodium tripolyphosphate 5%, sodium peroxydisulfate 10% and
The water of surplus.Step S2) by step S1) in configuration horse propylene copolymer 20%, sodium tripolyphosphate 5%, sodium peroxydisulfate 10% throws
Enter in reactor, add the water of surplus, room temperature to be sufficiently stirred for dissolving, obtain final product new reactive dyes low temperature soaping agent.
Embodiment 2
In the present embodiment, in the present embodiment, there is provided a kind of preparation method of reactive dye low temperature soaping agent, according to following step
Suddenly configured：Step S1) following each component is configured by mass percentage：Horse propylene copolymer 15%, soda 2%, sodium peroxydisulfate
15% and the water of surplus.Step S2) by step S1) in configuration horse propylene copolymer 15%, soda 2%, sodium peroxydisulfate 15%
Put in reactor, add the water of surplus, room temperature to be sufficiently stirred for dissolving, obtain final product new reactive dyes low temperature soaping agent.
Embodiment 3
In the present embodiment, in the present embodiment, in the present embodiment, there is provided a kind of preparation side of reactive dye low temperature soaping agent
Method, follows the steps below configuration：Step S1) following each component is configured by mass percentage：Horse propylene copolymer 15%, five water
The water of sodium metasilicate 5%, sodium hypochlorite 15% and surplus.Step S2) by step S1) in configuration horse propylene copolymer 15%,
Metasilicate pentahydrate sodium 5%, sodium hypochlorite 15% adds the water of surplus, room temperature to be sufficiently stirred for dissolving, obtain final product new reactive dyes low
Warm soaping agent.
Application Example
To verify that reactive dye low temperature soaping of the present invention agent is soaped in technique after fabric or fibre-reactive dye dyeing
Effect, in this application embodiment, with commercially available conventional soaping agent sample with the present invention the agent of reactive dye low temperature soaping make
The chromatic aberration contrast of anti-staining, washing fastness, fastness to rubbing and washing poststaining cotton fiber.
Below pin is explained so that cotton cellulose fiber soaps technique after reactive dyeing as an example, wherein, soap
Lotion consumption 0.3%owf-1%owf (for the gross mass of pending fabric), technological temperature of soaping is 70 DEG C.
Anti- Crockmeter Test
In Application Example measure of merit of the present invention, the fabric for adopting is for cotton fabric.
First a monoblock cotton reactive turquoise blue KG-L, Reactive Brilliant Blue KN-R are dyeed.The process conditions of reactive dyeing
It is as follows.
Reactive dyeing.
Reactive turquoise blue KG-L：2%owf (relative to the gross mass of pending fabric).
Reactive Brilliant Blue KN-R：2%owf (relative to the gross mass of pending fabric).
Sodium sulfate：60g/l.
Sodium carbonate：20g/l.
Bath raio：1：20.
Cloth specimen processed is contaminated by above-mentioned Recipe, dye is entered under the conditions of 65 DEG C, 1 DEG C/min of heating rate is incubated at 98 DEG C
50min。
The undyed byssuss for taking cotton and equal quality after the dyeing of equal quality respectively are put in same round-bottomed flask
Soaped, reactive dye low temperature soaping agent is directly added into soaps in liquid.
Engineer testing of soaping condition is as follows.
Soaping agent：1g/l is not added with soaping.
Bath raio：1：20
Soap temperature：70 DEG C or 50 DEG C or 90 DEG C.
Soap the time：20min.
Undyed white cotton K/S values are tested after soaping, for evaluating releasing pornographic condition.K/S values are bigger, and staining is tighter
Weight, shows that the anti-staining effect of soaping agent is poorer；Conversely, K/S values are less, staining is fewer, shows that the anti-staining effect of soaping agent is better.
K/S value testers device is DOTACOLOR testers (500UV), and test temperature is room temperature, the test result such as institute of table 1
Show.
Table 1：The agent of reactive dye low temperature soaping and the anti-staining test of soaping agent on the market in embodiment 1 to embodiment 3
As a result.
As it can be seen from table 1 when reactive dye low temperature soaping agent involved in the present invention is soaped for reactive dye, with city
Sell horse propylene copolymer class soaping agent and alkaline matter soaping agent compares, with preferable anti-staining ability.
Meanwhile, at 50 DEG C, 70 DEG C, 90 DEG C, when the reactive dye low temperature soaping agent in embodiment 1 to embodiment 3 is soaped,
With 70 DEG C of best results.
Washing fastness is tested
Test technology：With reference to GB/T3921.3-1997《Textile WASHING COLOR FASTNESS method of testing》.
Every liter of water standard containing 4g soap powder and 1g natrium carbonicum calcinatums, bath raio 1：50, technological temperature is 60 DEG C, and the process time is
30min。
The K/S values of testing standard cotton patch lining.Standard cotton patch lining K/S values are bigger, and staining is more serious, shows that soaping agent is water-fastness
Fastness is poorer；Conversely, K/S values are less, staining is fewer, shows that soaping agent washing fastness is better.K/S value tester devices are
DOTACOLOR testers (500UV), test temperature is room temperature, and test result is as shown in table 2.
Table 2：Embodiment 1 is to reactive dye low temperature soaping agent in embodiment 3 and soaping agent washing fastness test on the market
As a result.
From table 2 it can be seen that when new reactive dyes low temperature soaping agent involved in the present invention is soaped for reactive dye,
Compare with commercially available horse propylene copolymer class soaping agent and alkaline matter soaping agent, washing fastness is better than commercially available horse propylene copolymer class
Soaping agent, but it is poorer than commercial available alkaline material soaping agent.
Meanwhile, at 50 DEG C, 70 DEG C, 90 DEG C, when the reactive dye low temperature soaping agent in embodiment 1 to embodiment 3 is soaped,
With 70 DEG C of best results.
Rubbing fastness test
Reference standard GB/T3920-1997《Textile color stability tests fastness to rubbing》.
Fastness to rubbing test instrunment is that Y571 types dye Crockmeter, and test temperature is room temperature, and test result is such as
Shown in table 3.
Table 3：Embodiment 1 is to reactive dye low temperature soaping agent in embodiment 3 and soaping agent fastness to rubbing test on the market
As a result.
From table 3 it can be seen that when reactive dye low temperature soaping agent involved in the present invention is soaped for reactive dye, with city
Sell horse propylene copolymer class soaping agent and alkaline matter soaping agent compares, resistance to dry fastness is soaped in commercially available horse propylene copolymer class
Agent is suitable, but poorer than commercial available alkaline material soaping agent；Wet rubbing fastness is suitable with commercial available alkaline material soaping agent, and better than city
Sell horse propylene copolymer class soaping agent.
The chromatic aberration test of washing poststaining cotton fiber
The K/S values of test washing poststaining cotton fiber.Washing poststaining cotton fiber K/S values are bigger, show soaping agent to fabric
Chromatic aberration affects less；Conversely, K/S values are less, show that soaping agent affects bigger to the chromatic aberration of fabric.K/S values are tested
Instrument is DOTACOLOR testers (500UV), and test temperature is room temperature, and test result is as shown in table 4.
Table 4：To reactive dye low temperature soaping agent in embodiment 3 and on the market, soaping agent becomes embodiment 1 to cotton fiber aberration
Changing affects test result.
From table 4, it can be seen that when new reactive dyes low temperature soaping agent involved in the present invention is soaped for reactive dye,
Compare with commercially available horse propylene copolymer class soaping agent and alkaline matter soaping agent, wash chromatic aberration and the city of poststaining cotton fiber
Sell horse propylene copolymer class soaping agent quite, be more or less the same with blank, and after commercial available alkaline material soaping agent is soaped, chromatic aberration is bright
It is aobvious.
Meanwhile, at 50 DEG C, 70 DEG C, 90 DEG C, when the reactive dye low temperature soaping agent in embodiment 1 to embodiment 3 is soaped,
With 70 DEG C of best results.
In sum, the present invention is applied to pure cotton fiber, cotton-polyester blend fiber and other soaping containing cotton blended fiber
Technique, is particularly well-suited to low temperature (60-80 DEG C) and soaps at technique, particularly 70 DEG C, compares with commercially available conventional soaping agent, can be with
Meet plant produced requirement.Because reactive dye low temperature soaping agent non-foam involved in the present invention is produced, washing time can be reduced
Number, simultaneously because oxidant destroys the chromophoric group of the dyestuff and hydrolised dye soaped in working solution, reduces residual liquid colourity.This
Outward, temperature of soaping belongs to low temperature soaping (60-80 DEG C), has saved water, electricity and gas equal energy source, effectively shortens process time, meets section
The environmental requirement that can be reduced discharging.
The present invention is been described by by above-mentioned related embodiment, but above-described embodiment only implements the example of the present invention.
It must be noted that, it has been disclosed that embodiment be not limiting as the scope of the present invention.On the contrary, being contained in the spirit of claims
And scope modification and impartial setting be included in the scope of the present invention.
Claims (10)
1. a kind of reactive dye low temperature soaping agent, it is characterised in that the reactive dye low temperature soaping agent is included by mass fraction：
Horse propylene copolymer 10%-20%；
Alkaline matter 2%-5%；
Oxidant 10%-20%；
Water surplus.
2. reactive dye low temperature soaping agent as claimed in claim 1, it is characterised in that the horse propylene copolymer be maleic acid with
Acrylic copolymer.
3. reactive dye low temperature soaping agent as claimed in claim 1, it is characterised in that the alkaline matter includes tripolyphosphate
At least one in sodium, anhydrous sodium metasilicate, metasilicate pentahydrate sodium, sodium carbonate, sodium bicarbonate.
4. reactive dye low temperature soaping agent as claimed in claim 1, it is characterised in that the oxidant include sodium peroxydisulfate,
At least one in potassium peroxydisulfate, Ammonium persulfate., hydrogen peroxide, SODIUM PERCARBONATE, sodium hypochlorite.
5. a kind of preparation method of reactive dye low temperature soaping agent as claimed in claim 1, it is characterised in that methods described bag
Include：Each component is configured by formula as below：Horse propylene copolymer 10%-20%, alkaline matter 2%-5% are taken by mass fraction, is aoxidized
Agent 10%-20%；In being put into reactor, the water of surplus is added by mass fraction, dissolving is sufficiently stirred at normal temperatures, obtain final product activity
Dyestuff low temperature soaping agent.
6. the preparation method of reactive dye low temperature soaping agent as claimed in claim 5, it is characterised in that the horse propylene copolymer
For maleic acid and acrylic acid copolymer.
7. the preparation method of reactive dye low temperature soaping agent as claimed in claim 5, it is characterised in that the alkaline matter bag
Include at least one in sodium tripolyphosphate, anhydrous sodium metasilicate, metasilicate pentahydrate sodium, sodium carbonate, sodium bicarbonate.
8. the preparation method of reactive dye low temperature soaping agent as claimed in claim 5, it is characterised in that the oxidant includes
At least one in sodium peroxydisulfate, potassium peroxydisulfate, Ammonium persulfate., hydrogen peroxide, SODIUM PERCARBONATE, sodium hypochlorite.
9. a kind of reactive dye low temperature soaping as claimed in claim 1 agent is soaped the application in technique in fabric or fiber.
10. reactive dye low temperature soaping as claimed in claim 9 agent is soaped the application in technique in fabric or fiber, its feature
It is that the consumption of the reactive dye low temperature soaping agent is 0.3%owf-1%owf；Using temperature at 60 DEG C -80 DEG C.
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Cited By (8)
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| CN107201679A (en) * | 2017-06-13 | 2017-09-26 | 淄博大染坊丝绸集团有限公司 | A kind of reactive dye contaminate cellulose fibre low temperature soaping technique |
| CN107779275A (en) * | 2017-09-21 | 2018-03-09 | 无锡德冠生物科技有限公司 | A kind of soaping agent and preparation method thereof |
| CN109705999A (en) * | 2019-01-09 | 2019-05-03 | 常熟东南相互电子有限公司 | Cleaning agent and its application method |
| CN109914133A (en) * | 2019-03-11 | 2019-06-21 | 湖南工程学院 | A kind of anti-staining low temperature soaping agent of reactive dye and soaping method |
| CN110004748A (en) * | 2018-01-04 | 2019-07-12 | 泉州蓝鸟贸易有限公司 | A kind of preparation and application of energy conservation soaping agent |
| CN111733022A (en) * | 2020-07-21 | 2020-10-02 | 何结平 | Cleaning agent for printing and dyeing soaping and preparation method thereof |
| CN112127183A (en) * | 2020-09-03 | 2020-12-25 | 苏州联胜化学有限公司 | Low-foam anti-staining soaping agent and preparation method thereof |
| CN112796129A (en) * | 2020-12-23 | 2021-05-14 | 太仓宝霓实业有限公司 | Reactive printing anti-staining soaping agent composition and preparation method thereof |
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