CN112796129B - Reactive printing anti-staining soaping agent composition and preparation method thereof - Google Patents
Reactive printing anti-staining soaping agent composition and preparation method thereof Download PDFInfo
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- CN112796129B CN112796129B CN202011541288.5A CN202011541288A CN112796129B CN 112796129 B CN112796129 B CN 112796129B CN 202011541288 A CN202011541288 A CN 202011541288A CN 112796129 B CN112796129 B CN 112796129B
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
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- Engineering & Computer Science (AREA)
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- Detergent Compositions (AREA)
Abstract
The invention discloses an active printing anti-sticking soaping agent composition and a preparation method thereof, wherein the active printing anti-sticking soaping agent composition comprises the following components in percentage by weight: 20 to 40 percent of modified polyacrylic acid copolymer; 1 to 10 percent of absorption synergist; 5 to 20 percent of builder; the balance of deionized water. The active printing anti-staining soaping agent composition has good washing effect and anti-staining effect, and has the advantages of good anti-staining soaping effect, soft hand feeling and the like when being applied to an active printing soaping process.
Description
Technical Field
The invention relates to the field of soaping agents, in particular to an active printing anti-sticking soaping agent composition and a preparation method thereof.
Background
After printing with reactive dyes, washing and soaping must be carried out strictly and fully, during the soaping process, the size, the loose color (hydrolytic dyes and unfixed dyes) and the auxiliary agents on the fabrics are washed, and the washed high polymer size, the loose color and the auxiliary agents are mixed and dissolved together and can easily stain the printed fabrics, so that the printed fabrics are not white, the color of the colored light is changed or the color fastness is reduced.
The research of many researchers on the reactive printing soaping agent still remains in the soaping process of the reactive dyed fabric, namely, the soaping agent is mainly used for fully cleaning the flooding and the auxiliary agent and preventing the anti-staining, and the soaping agent is mainly prepared by copolymerizing acrylic acid series monomers and NVP (N-vinyl pyrrolidone) or compounding polyacrylic acid polymers and PVP (polyvinyl pyrrolidone). In the reactive printing process, the high polymer slurry is an important soaping object, and for the anti-staining soaping of the reactive printing slurry, the reactive soaping agent used in the common dyeing process is not suitable, i.e. the soaping agent used in the reactive dyeing process has poor cleaning and anti-staining effects on the high polymer slurry.
How to realize the anti-sticking soaping of the sizing agent on the printed fabric is a difficult point, because the commonly used active printing sizing agent not only contains sodium alginate which is easy to wash but also CMC and CMS, the substitution degree of the sizing agent is generally low, the sizing agent is easy to react with cotton fiber, so that the binding force of the sizing agent and the fabric is stronger, the soaping is difficult, the hand feeling is poor, and the requirement of high-quality printed fabrics is difficult to meet.
Researchers have made a lot of researches on active printing soaping agent, and patent CN102876516A discloses a preparation method of a novel dark color fleece printing soaping agent, which is mainly obtained by synthesizing hydroxymethyl acrylic acid, maleic anhydride and N-vinyl pyrrolidone copolymer and compounding the copolymer with the soaping agent. Has the characteristics of good cleaning performance, excellent dispersing performance, strong anti-contamination capability, good biodegradability and the like. The invention is still based on the conventional polyacrylic soaping agent structure, and the invention does not mention the cleaning effect and the anti-sticking effect of the pulp. Patent CN101531956A discloses an environment-friendly foamless anti-staining detergent, a preparation method and an application thereof, wherein the formula mainly comprises acrylic acid copolymer, phosphorus-free alkali-resistant high-efficiency chelating dispersion stabilizer and polyvinylpyrrolidone, and the detergent has strong washing capability on loose color but has unclear soaping effect on printing paste.
In summary of published data, most researchers still research the reactive printing soaping agent by copolymerizing an acrylic monomer and NVP or compounding the acrylic monomer and PVP. The soaping agent has better washing and anti-sticking capabilities to the floating color of the active printing, and has unsatisfactory washing to the sizing agent with stronger fiber binding force, so that the printed fabric after soaping has unsatisfactory fastness or poorer hand feeling, and the requirement of the high-quality active printing anti-sticking soaping agent cannot be met, therefore, the development of the soaping agent which has excellent washing and anti-sticking effects on the floating color, the auxiliary agent and the sizing agent is very important for improving the quality of the printed fabric.
Disclosure of Invention
The invention aims to provide an active printing anti-staining soaping agent composition and a preparation method thereof aiming at the defects in the prior art and the active dye printing soaping process.
In order to achieve the purpose, the invention adopts the technical scheme that:
the invention provides an active printing anti-staining soaping agent composition, which comprises the following components in percentage by weight:
further, the modified polyacrylic acid copolymer is obtained by emulsion polymerization of an unsaturated carboxylic acid monomer and an unsaturated silicone oil monomer, and the specific equation is as follows:
wherein R is 1 is-CH 3 or-H; r is 2 is-COOH or-H; r 3 is-CH 2 COOH or-H;
Further preferably, the comonomers used in the modified polyacrylic acid copolymer are acrylic acid and/or methacrylic acid, fumaric acid and/or itaconic acid, 1,3,5,7,9,11, 13-heptacyclopentyl-15-vinyl cage type silsesquioxane and comb-shaped organosilicon comonomer respectively, and the molar ratio of each comonomer is (300-500): (30-100): (1-3): (0.1-1).
Still more preferably, the modified polyacrylic acid copolymer has a weight average molecular weight of 10 5 ~10 7 。
Further, the adsorption synergist is one or a mixture of two of nano silicon dioxide and nano titanium dioxide.
Further, the builder is a compound of betaine modified silicone oil and algal glycolipid, and the weight percentage ratio of the betaine modified silicone oil to the algal glycolipid is 1.
Further preferably, the structural formula of the betaine modified silicone oil is:
further preferably, the trehalose glycolipid has the structural formula:
wherein n =10-25,m =10-25,n + m =25-35.
The second aspect of the invention provides a preparation method of the active printing anti-staining soaping agent composition, which comprises the following steps: synthesizing modified polyacrylic acid copolymer emulsion through emulsion polymerization, then mixing with an adsorption synergist and a builder, and stirring for 30min at 40-50 ℃ and 800-1000rpm to obtain the active printing anti-sticking soaping agent composition.
By adopting the technical scheme, compared with the prior art, the invention has the following technical effects:
the modified acrylic copolymer of the invention polymerizes acrylic monomers and unsaturated organosilicon monomers, effectively combines hydrophilic groups (COO-) and hydrophobic groups (silicon-containing components), and the hydrophobic groups are also adsorbed on the surface of the sizing agent in the contact and permeation processes of the hydrophilic groups and the sizing agent, so that the hydrophilicity of the sizing agent is reduced, and further the bonding force between the sizing agent and fibers can be reduced, so that the sizing agent can be easily dropped from the fibers, and the sizing agent can be fully cleaned. The nano-structured adsorption enhancer can permeate into the slurry, so that the slurry is more loose and is easier to wash. The adsorption synergist can also adsorb polyacrylic acid copolymer and builder components, and can fully clean floating color, auxiliaries, especially pulp by virtue of the cleaning and anti-sticking functions of the copolymer and the builder. The betaine modified silicone oil in the builder can disperse the copolymer after adsorbing impurities, further avoid reverse adhesion, and the seaweed glycolipid in the builder can be further combined with the washed slurry (such as CMC and CMS), uniformly disperse and dissolve in the soap lotion, and prevent the reverse adhesion to the fabric.
Detailed Description
The present invention is further illustrated by the following examples, which are not intended to limit the scope of the invention. It should be noted that the embodiments and features of the embodiments of the present invention may be combined with each other without conflict.
Example 1
The reactive printing anti-sticking soaping agent composition 1 comprises the following components:
1 70g of modified polyacrylic acid copolymer emulsion;
10g of adsorption synergist;
and 20g of a builder.
The preparation method of the active printing anti-sticking soaping agent composition 1 comprises the following steps:
1. the preparation method of the modified polyacrylic copolymer emulsion 1 comprises the following steps: dissolving 0.4g of emulsifier AES and 0.4g of emulsifier AEO-9 in 16.7g of deionized water, then sequentially adding 28g of acrylic acid, 5g of fumaric acid, 2.6g of comb-shaped organic silicon monomer (M = 3752), 2g of 1,3,5,7,9,11, 13-heptacyclopentyl-15-vinyl cage-type silsesquioxane, heating to 50-60 ℃, and stirring at 800rpm for 30min at high speed to prepare 55.1g of comonomer pre-emulsion;
adding 20% of the pre-emulsion into a reactor, heating to 75 ℃, adding 2.08g of ammonium persulfate solution (the content is 4%), heating to 85 ℃, keeping the temperature for 20min, dropwise adding the rest of the pre-emulsion and 8g of ammonium persulfate solution (4 wt%), dropwise adding for 3h, the dropwise adding temperature is 88 ℃, supplementing 0.32g of ammonium persulfate solution (4 wt%), keeping the temperature for 2h at 90 ℃, finally cooling to 40 ℃, adding 4.5g of sodium hydroxide solution (the concentration is 33%), and neutralizing the pH value of a product to 7-9 to obtain 70g of modified polyacrylic copolymer (the weight-average molecular weight is 3 multiplied by 10, and the pH value is 3-9 6 ~5×10 6 ) Emulsion 1, solids content 57.6%.
2. The preparation method of the active printing anti-sticking soaping agent composition 1 comprises the following steps:
70g of modified polyacrylic copolymer emulsion 1, 10g of nano-silica, 10g of betaine modified silicone oil and 10g of algal glycolipid are mixed and stirred at 40 ℃ and 1000rpm for 30min to obtain the active printing anti-sticking soaping agent composition 1.
Example 2
The reactive printing anti-sticking soaping agent composition 2 comprises the following components:
2 85g of modified polyacrylic copolymer emulsion;
10g of adsorption synergist;
and 5g of a builder.
The preparation method of the active printing anti-staining soaping agent composition 2 comprises the following steps:
1. the preparation method of the modified polyacrylic copolymer emulsion 2 comprises the following steps: the preparation method of the modified polyacrylic copolymer emulsion 2 comprises the following steps: dissolving 0.5g of emulsifier AES and 0.5g of emulsifier AEO-9 in 24g of deionized water, then sequentially adding 30g of methacrylic acid, 10g of itaconic acid, 2g of comb-shaped organic silicon monomer (M = 7082), 2g1,3,5,7,9,11, 13-heptacyclopentyl-15-vinyl cage-type silsesquioxane, heating to 60 ℃, and stirring at 800rpm for 30min at high speed to prepare 69g of comonomer pre-emulsion;
adding 20% of the pre-emulsion into a reactor, heating to 75 ℃, adding 2.3g of ammonium persulfate solution (the content is 4%), heating to 85 ℃, keeping the temperature for 20min, dropwise adding the rest of the pre-emulsion and 8g of ammonium persulfate solution (4 wt%), dropwise adding for 3h, the dropwise adding temperature is 88 ℃, supplementing 0.7g of ammonium persulfate solution (4 wt%), keeping the temperature for 2h at 90 ℃, finally cooling to 40 ℃, adding 5g of sodium hydroxide solution (the concentration is 33%), and neutralizing the pH value of a product to 7-9 to obtain 85g of modified polyacrylic copolymer (the weight-average molecular weight is 4 multiplied by 10, and the pH value is 4-9 6 ~6×10 6 ) Emulsion 2, solids content 55.4%.
2. The preparation method of the active printing anti-sticking soaping agent composition 2 comprises the following steps:
85g of modified polyacrylic copolymer emulsion 2, 5g of nano-silicon dioxide, 5g of nano-titanium dioxide, 2g of betaine modified silicone oil and 3g of algal glycolipid are mixed and stirred at 50 ℃ and 800rpm for 30min to obtain the active printing anti-sticking soaping agent composition 2.
Example 3
The reactive printing anti-sticking soaping agent composition 3 comprises the following components:
3 80g of modified polyacrylic copolymer emulsion,
10g of adsorption synergist;
and 10g of a builder.
The preparation of the active printing anti-sticking soaping agent composition 3 comprises the following steps:
1. the preparation method of the modified polyacrylic copolymer emulsion 3 comprises the following steps: dissolving 0.5g of emulsifier AES and 0.5g of emulsifier AEO-9 in 24g of deionized water, then sequentially adding 20g of acrylic acid, 10g of methacrylic acid, 5g of itaconic acid, 3g of fumaric acid, 1.5g of comb-shaped organic silicon monomer (M = 5084), 1.5g of 1,3,5,7,9,11, 13-heptacyclopentyl-15-vinyl cage-type silsesquioxane, heating to 50 ℃, and stirring at 1000rpm for 30min to prepare 66g of comonomer pre-emulsion;
adding 20% of the pre-emulsion into a reactor, heating to 75 ℃, adding 1.3g of ammonium persulfate solution (the content is 4%), heating to 85 ℃, keeping the temperature for 20min, dropwise adding the rest of the pre-emulsion and 7.5g of ammonium persulfate solution (4 wt%), wherein the dropwise adding time is 3h, the dropwise adding temperature is 88 ℃, supplementing 0.7g of ammonium persulfate solution (4 wt%), keeping the temperature for 2h at 90 ℃, finally cooling to 40 ℃, adding 4.5g of sodium hydroxide solution (the concentration is 33%), neutralizing the pH value of a product to 7-9, and obtaining 80g of modified polyacrylic acid copolymer (the weight-average molecular weight is 3 multiplied by 10), wherein the weight-average molecular weight is 3 multiplied by 10 6 ~5×10 6 ) Emulsion 3, solids content 54.8%.
2. The preparation method of the active printing anti-sticking soaping agent composition 3 comprises the following steps:
80g of modified polyacrylic copolymer emulsion 3, 10g of nano titanium dioxide, 2.5g of betaine modified silicone oil and 7.5g of algal glycolipid are mixed and stirred at 50 ℃ and 800rpm for 30min to obtain the active printing anti-sticking soaping agent composition 3.
Example 4
The active printing anti-sticking soaping agent composition 4 comprises the following components:
4 94g of modified polyacrylic copolymer emulsion;
1g of adsorption synergist;
5g of a builder.
The preparation method of the active printing anti-staining soaping agent composition comprises the following steps:
1. the preparation method of the modified polyacrylic copolymer emulsion 3 comprises the following steps: 0.6g of emulsifier AES and 0.6g of emulsifier AEO-9 are dissolved by 31.2g of deionized water, then 35g of acrylic acid, 8g of fumaric acid, 2.5g of comb-shaped organic silicon monomer (M = 7082), 2g of 1,3,5,7,9,11, 13-heptacyclopentyl-15-vinyl cage-type silsesquioxane are sequentially added, the temperature is raised to 50 ℃, and the mixture is stirred at 1000rpm for 30min to prepare 79.9g of comonomer pre-emulsion;
adding 20% of the pre-emulsion into a reactor, heating to 75 ℃, adding 1.6g of ammonium persulfate solution (the content is 4%), heating to 85 ℃, keeping the temperature for 20min, dropwise adding the rest of the pre-emulsion and 7g of ammonium persulfate solution (4 wt%), wherein the dropwise adding time is 3h, the dropwise adding temperature is 88 ℃, supplementing 0.5g of ammonium persulfate solution (4 wt%) after completing dropwise adding, keeping the temperature for 2h at 90 ℃, finally cooling to 40 ℃, adding 5g of sodium hydroxide solution (the concentration is 33%), and neutralizing the pH value of a product to 7-9 to obtain 94g of modified polyacrylic acid copolymer (the weight-average molecular weight is 4 multiplied by 10, and the pH value is 4-9 6 ~5×10 6 ) Emulsion 4, solids content 54%.
2. The preparation method of the active printing anti-sticking soaping agent composition 4 comprises the following steps:
94g of modified polyacrylic copolymer emulsion 4, 1g of nano-silicon dioxide, 2.5g of betaine modified silicone oil and 2.5g of algal glycolipid are mixed and stirred at 50 ℃ and 800rpm for 30min to obtain the active printing anti-sticking soaping agent composition 4.
Comparative example
The effects of the reactive printing anti-staining soaping agent prepared in the above examples 1-4 of the present invention and a commercially available soaping agent (manufactured by a foreign company) were verified by the following tests, and the results are shown in table 1.
1. Fabric: pure cotton poplin
2. The formula of the active printing color paste comprises the following components:
the formula is as follows:
raw materials | Ratio of |
Paste (M) CMC :M CMS =1:1) | 2-4% |
Baking soda | 3% |
Resist salt S | 1% |
Urea | 10% |
Reactive Red P-4B | 3% |
Water (I) | Y% |
Is totaled | 100% |
3. Printing and soaping processes:
printing → drying → steaming (105 ℃ C.. Times.8 min) → cold water washing 3 lane → warm water washing (80 ℃ C.) 1 lane → soaping (95 ℃ C., soaping agent, 2 g/L) 2 lane → cold water washing 3 lane → drying.
4. Performance testing
4.1 color fastness to washing
According to the GB/T3921-2008 standard, the pure cotton poplin color cloth after soaping is sewn with a standard lining cloth, the pure cotton poplin color cloth and the standard lining cloth are put into prepared soap liquid, mechanical stirring is carried out at a specified temperature and time, then the pure cotton poplin color cloth is cleaned and dried, and the original shape is used as a reference object, so that the staining effect of the lining cloth is evaluated.
4.2 color fastness to rubbing
And (3) rubbing the pure cotton poplin color cloth after soaping with a piece of dry rubbing cloth and a piece of wet rubbing cloth respectively by adopting the GB/T3920-2008 standard, and evaluating the degree of rubbing staining.
4.3 staining resistance
5g of the dyed pure cotton poplin cloth sample and the bleached cloth sample (stained sample) were put in the same soaping bath for soaping. And (3) measuring the stained sample by using a computer color measuring and matching instrument and grading by using white cloth as a standard. The higher the grade is, the stronger the staining resistance of the soaping agent is; otherwise, the worse.
4.4 weight average molecular weight determination: measured by HLC-8320GPC type gel permeation chromatography (Nippon Tosoh Co., ltd.) with DMF as the mobile phase at 25 ℃ and polymethyl methacrylate (PMMA) as the reference.
4.5 hand feeling
And (4) performing a hand touch method. The softness was rated best on grade 5 and worst on grade 1 for the 5 person group, each printed fabric. The average number of 5 persons is the evaluation result.
4.6 percent of mush removal
Paste removal rate = (W) 1 -W 2 )/(W 1 -W 2 )×100%
Wherein, W 1 、W 2 And W 3 Respectively representing the dry weight of the fabric before printing, the dry weight of the fabric after printing and the dry weight of the fabric after soaping. Higher percentage values indicate better paste out.
TABLE 1
Colour fastness to washing/grade | Dry mole/grade | Wet friction/grade | Anti-staining/grading | Hand feeling/grade | De-pasting rate/%) | |
Example 1 | 4~5 | 4~5 | 4 | 4 | 4-5 | 92 |
Example 2 | 4~5 | 4~5 | 4 | 4 | 4-5 | 93 |
Example 3 | 4~5 | 4~5 | 4 | 4 | 4-5 | 95 |
Example 4 | 4~5 | 4~5 | 4 | 4 | 4-5 | 96 |
Commercially available soaping agent | 4 | 4 | 4 | 3~4 | 2-3 | 73 |
Blank space | 2 | 3 | 2 | 1 | 2 | 52 |
As can be seen from the data in Table 1, the colorfastness to washing and dry rubbing of examples 1-4 of the present invention achieved a 4-5 level, and wet rubbing and staining resistance achieved a 4 level, indicating that the soaping agent of the present invention has a very good cleaning effect on reactive printed fabrics. The hand feeling of the soaping agent is 4-5 grades, which is obviously higher than that of the commercially available soaping agent (2-3 grades) and blank (2 grades), the paste removing rate is more than 90%, which is obviously higher than that of the commercially available soaping agent and blank samples, and the soaping agent has excellent performance when being used in an active printing soaping process, and especially has outstanding washing and anti-sticking performance to slurry. Comprehensive data show that the soaping agent disclosed by the invention has excellent anti-staining soaping effect on the reactive printed fabric.
While the invention has been described with reference to a preferred embodiment, it will be understood by those skilled in the art that various changes in form and detail may be made therein without departing from the spirit and scope of the invention.
Claims (1)
1. The reactive printing anti-sticking soaping agent composition is characterized in that the preparation method of the reactive printing anti-sticking soaping agent composition comprises the following steps:
s1, preparing modified polyacrylic copolymer emulsion: 0.6g of emulsifier AES and 0.6g of emulsifier AEO-9 are dissolved by 31.2g of deionized water, then 35g of acrylic acid, 8g of fumaric acid, 2.5g of comb-shaped organic silicon monomer, 2g of 1,3,5,7,9,11, 13-heptacyclopentyl-15-vinyl cage-type silsesquioxane are sequentially added, the temperature is raised to 50 ℃, and the mixture is stirred at 1000rpm for 30min to prepare 79.9g of comonomer pre-emulsion;
adding 20% of the comonomer pre-emulsion into a reactor, heating to 75 ℃, adding 1.6g of 4% ammonium persulfate solution, heating to 85 ℃, preserving heat for 20min, dropwise adding the rest of the comonomer pre-emulsion and 7g of 4% ammonium persulfate solution, dropwise adding for 3h at 88 ℃, supplementing 0.5g of 4% ammonium persulfate solution after dropwise adding, preserving heat for 2h at 90 ℃, finally cooling to 40 ℃, adding 5g of 33% sodium hydroxide solution, and neutralizing the pH value of a product to 7-9 to obtain 94g of sodium hydroxide solution with the weight-average molecular weight of 4 x 10 6 -5×10 6 The solid content of the modified polyacrylic copolymer emulsion is 54 percent;
s2, preparing an active printing anti-sticking soaping agent composition: mixing 94g of the modified polyacrylic copolymer emulsion, 1g of nano-silicon dioxide, 2.5g of betaine modified silicone oil and 2.5g of algal glycolipid, and stirring at 50 ℃ and 800rpm for 30min to obtain the active printing anti-sticking soaping agent composition.
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