CN106566674A - Pesticide residue detergent and preparation method thereof - Google Patents
Pesticide residue detergent and preparation method thereof Download PDFInfo
- Publication number
- CN106566674A CN106566674A CN201611003783.4A CN201611003783A CN106566674A CN 106566674 A CN106566674 A CN 106566674A CN 201611003783 A CN201611003783 A CN 201611003783A CN 106566674 A CN106566674 A CN 106566674A
- Authority
- CN
- China
- Prior art keywords
- parts
- sodium
- essence
- pesticide residues
- pesticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/32—Ranunculaceae [Buttercup family], e.g. hepatica, hydrastis or goldenseal
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2096—Heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/384—Animal products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Health & Medical Sciences (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Environmental Sciences (AREA)
- Dentistry (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Emergency Medicine (AREA)
- Biotechnology (AREA)
- Inorganic Chemistry (AREA)
- Molecular Biology (AREA)
- Pest Control & Pesticides (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to a pesticide residue detergent which is prepared from the following raw materials in parts by weight: 35-45 parts of liquorice, 40-45 parts of houttuynia cordata, 40-45 parts of wild chrysanthemum flowers, 13-17 parts of sodium caseinate, 35-40 parts of Fructus Arctii, 15-19 parts of tea saponin, 30-35 parts of rhizoma cimicifugae, 16-20 parts of tea polyphenol, 30-35 parts of folium isatidis, 16-20 parts of a glucoside bactericide, 25-30 parts of vitamin C, 12-16 parts of natural essence, 11-15 parts of sodium carbonate, 11-15 parts of sodium bicarbonate, 24-28 parts of deionized water and 16-20 parts of sodium chloride and the invention further discloses a preparation method of the pesticide residue detergent. The raw materials of the pesticide residue detergent are natural food ingredients, so that the pesticide residue detergent is safe, healthy and environment-friendly, can quickly and efficiently clean pesticide residue on crops, and is safe to crops and free of toxic and side effects.
Description
Technical field
The invention belongs to abluent technical field, and in particular to pesticide residues cleaning agent and preparation method thereof.
Background technology
Pesticide while prevention and elimination of disease and pests, weeding and coordinate plant growth, also remain in organism, agricultural byproducts and
In environment, pesticide residues are caused.So-called pesticide residues are remained in after referring to Pesticide use in organism, agricultural byproducts and environment
The general name of trace pesticide substance toxic metabolite, degradation product and impurity.The time of pesticide residues has length to have short, and quantity has to be had more
It is few.And the source of pesticide material, predominantly organic agricultural chemicals, inorganic pesticide, botanical pesticide, microbial pesticide and insect hormone
Deng.Wherein, chemical pesticide is used in a large number.As the chemical constitution of pesticide is different, toxicity difference is very big, drop in the environment
Solution accretion rate has very big difference, and same pesticide different application methods and different formulation rates, its residual quantity also have very
Big big difference.Pesticide residues not only directly have impact on the quality of agricultural byproducts, and be directly connected to the body of the people
Health.
Pesticide Residue is as pesticide is produced in a large number and is widely used and is produced.So far, it is chemical in the world
2,000,000 tons or so of pesticide annual production, there are about more than 1000 kinds of artificial-synthetic compound and is used as insecticide, antibacterial, algicide, removes
The class pesticide such as worm agent, defoliant.Pesticide especially apply in a large number by organic agricultural chemicals, causes serious Pesticides Residues, becomes right
The serious threat of health.
Food safety is the forefront of human life's safety and Health of concerning, and natural green vegetable fruit is that people be unable to do without
The standing food of mouth, but pesticide above and residual, are the health risk even lurker of life of objective reality.Existing market
On detergent for washing out agricultural chemicals, be, into being grouped into, have different degrees of wound to human body by petrochemical industry such as chemical surfactant, pigments
Evil, some abluents even can also produce new secondary hazards.A kind of safely and effectively pesticide residue scavenging agent is needed at present.
The content of the invention
It is an object of the invention to：For above-mentioned deficiency, the invention provides a kind of pesticide residues cleaning agent and
Its preparation method.Raw material of the present invention is natural food ingredient, safe and healthy, environmentally friendly, efficiently, quickly not only can remove
Pesticide residues on crops, and common bacteria, general mycete and parasite can be effectively killed, to crop safety, nontoxic pair
The novel agrochemical residue removal agent of effect.
In order to achieve the above object, present invention employs technical scheme below：
A kind of pesticide residues cleaning agent, is made up of the raw material of following weight portion：35～45 parts of Radix Glycyrrhizae, 40～45 parts of Herba Houttuyniae, open country
40～45 parts of Flos Chrysanthemi, 13～17 parts of sodium caseinate, 35～40 parts of Fructus Arctii, 15～19 parts of tea saponin, 30～35 parts of Rhizoma Cimicifugae, tea
16～20 parts of polyphenol, 30～35 parts of Folium Isatidiss, 16～20 parts of glucoside antibacterial, vitamin C _ 25～30 part, natural essence
16～20 parts of 12～16 parts, 11～15 parts of sodium carbonate, 11～15 parts of sodium bicarbonate, 24～28 parts of deionized water and Sodium Chloride.
Further, described pesticide residues cleaning agent, is made up of the raw material of following weight portion：40 parts of Radix Glycyrrhizae, Herba Houttuyniae
43 parts, 42 parts of Flos Chrysanthemi Indici, 15 parts of sodium caseinate, 37 parts of Fructus Arctii, 17 parts of tea saponin, 33 parts of Rhizoma Cimicifugae, 18 parts of tea polyphenols, Folium Isatidis
32 parts of leaf, 18 parts of glucoside antibacterial, vitamin C _ 28 part, 14 parts of natural essence, 13 parts of sodium carbonate, 13 parts of sodium bicarbonate,
18 parts of 26 parts of deionized water and Sodium Chloride.
Further, described pesticide residues cleaning agent, is made up of the raw material of following weight portion：37～43 parts of Radix Glycyrrhizae, fish
41～44 parts of raw meat grass, 41～44 parts of Flos Chrysanthemi Indici, 14～16 parts of sodium caseinate, 36～39 parts of Fructus Arctii, 16～18 parts of tea saponin,
31～34 parts of Rhizoma Cimicifugae, 17～19 parts of tea polyphenols, 31～34 parts of Folium Isatidiss, 17～19 parts of glucoside antibacterial, vitamin C _ 26
～29 parts, 13～15 parts of natural essence, 12～14 parts of sodium carbonate, 12～14 parts of sodium bicarbonate, 25～27 parts of deionized water and chlorine
Change 17～19 parts of sodium.
Further, the molecular weight of the sodium caseinate is 61000～370000.
Further, the natural essence is agrocyb eaegerita essence, Fructus Citri Limoniae essence, flavoring pineapple essence, Fructus Citri grandiss essence, Pericarpium Citri tangerinae essence
In one kind.
Further, the preparation method of described pesticide residues cleaning agent, comprises the steps of：
（1）Weigh Radix Glycyrrhizae according to parts by weight, roguing, clean, dry after, be dipped in the ethanol solution of 3～5 times of weight of Radix Glycyrrhizae
In, 7～13h is soaked, 8～10h of reflux, extract, at 75～80 DEG C, natural filtration slagging-off obtain Radix Glycyrrhizae extract；According to identical
Method respectively Herba Houttuyniae, Flos Chrysanthemi Indici, Fructus Arctii, Rhizoma Cimicifugae, Folium Isatidiss are extracted, by gained extracting solution mix, mixed
Close extracting solution；
（2）First deionized water is added in reactor, 35～40 DEG C of insulations is heated to, is added sodium caseinate, sodium carbonate, carbon
Sour hydrogen sodium, stirs to all materials after being completely dissolved, and under the mixing speed of 200～300r/min, is slowly added to glucoside
Antibacterial, tea polyphenols and tea saponin, it is in gelatin-like liquid to stir to solution；
（3）Under the mixing speed of 350～400r/min, to step（2）Gelatin-like liquid be slowly added to step（1）Mixing
Extracting solution, after stirring, sequentially adds Sodium Chloride, vitamin C, natural essence, stirs, obtain final product the pesticide residues clear
Clean dose.
Wherein, sodium caseinate described above, is the milky or yellow fraction from refining refinement in pure natural milk
Color powdered proteins, with the physicochemical property such as good emulsifying, thermally-stabilised, thickening, moisturizing, film forming, and the balance of aminoacid
Nutritive peculiarity and the antimutagenic physiologically active such as property, high protein, property easy to digest, low antigen.
Using method：Jia 4 in 1kg water～5mL the present invention pesticide residues cleaning agent be made into diluent, crops are soaked
10～15min in diluent, is then cleaned with tap water 2～3 times；Or previous week is being harvested, Jia 4 in 1kg water
The pesticide residues cleaning agent of～5mL present invention is made into diluent, and diluent is sprayed on leaf or the fruit of the crops of maturation
It is real.
The pesticide residues cleaning agent of the present invention meets GB/T 24691-2009《Fruit and vegerable abluent》And GB/T 26396-
2011《Articles for washing technical specification of security》National promoting standards.Wherein, the detection method of caseinic acid sodium content：Foundation
GB10797 is performed；Parasite detection method：20 power microscope frame count checks；Pesticide concentration after washing before washing is detected respectively
Method：Perform according to GB/T 19648；Mycete detection method：Perform according to GB4789.15 and GB5413.37；Bacteria Detection side
Method：Perform according to GB4789.2, GB4789.3 and GB2761.
Test：Spray different pesticide on same crops respectively and different crops are sprayed with different pesticide, 3
After～5d, this pesticide residue scavenging agent water preparation directly being sprayed by the dosage of 60kg/mu, crops censorship being gathered after one week, which is clear
Except effect such as table 1 below：
Table 1
| Tested crops | Spray insecticide title | The crops persticide residue of censorship after the sprinkling present invention（mk/kg) | The crops persticide residue of the same period censorship of the present invention is not sprayed（mk/kg) |
| Caulis et Folium Lactucae Sativae | Cypermethrin | Do not detect | 1.5 |
| Metrifonate | 0.04 | 0.15 | |
| Glufosinate-ammonium | 0.10 | 0.37 | |
| Fragrant pear | Carbendazim | 0.35 | 1.89 |
| Decises | 0.03 | 0.12 |
Show from 1 test data of table：The pesticide residue scavenging agent of the present invention is sprayed directly on the crops in growth, can be fast
Speed, efficient removing remain in the persticide residue on crops, and the persticide residue Jing after its removing is less than national regulation
Limit standard；Meanwhile, this pesticide residue scavenging agent not only can efficiently, quickly be removed and is sprayed on same crops not
With the pesticide residues of pesticide, and it is residual efficiently, quickly to remove the pesticide of the different pesticide being sprayed in different crops
Stay, it was demonstrated which has the pesticide residues elimination effect of wide spectrum；And found by estimating, the leaves of plants after high concentration agricultural chemical sprinkling 5d
Face is in yellow, and Jing after the pesticide residue scavenging agent of the sprinkling present invention, the blade face of plant returns to blue color, shows this scavenger to planting
Thing safety, has no toxic side effect.
In sum, the present invention is had the positive effect that as a result of such scheme：Raw material of the present invention is natural
Composition of food, it is safe and healthy, environmentally friendly, the pesticide residues on crops not only can efficiently, be quickly removed, and can be effective
Common bacteria, general mycete and parasite are killed, to crop safety, the novel agrochemical residue removal agent having no toxic side effect, material
Easily purchase, it is with low cost, prepare, easy to use, be the green scavenger of crops pesticide residues.
Specific embodiment
With reference to embodiment to pesticide residues cleaning agent of the present invention and preparation method thereof, it is described further.
Embodiment 1
A kind of pesticide residues cleaning agent, is made up of the raw material of following weight portion：35 parts of Radix Glycyrrhizae, 40 parts of Herba Houttuyniae, 40 parts of Flos Chrysanthemi Indici,
13 parts of sodium caseinate, 35 parts of Fructus Arctii, 15 parts of tea saponin, 30 parts of Rhizoma Cimicifugae, 16 parts of tea polyphenols, 30 parts of Folium Isatidiss, glucoside
16 parts of antibacterial, vitamin C _ 25 part, 12 parts of natural essence, 11 parts of sodium carbonate, 11 parts of sodium bicarbonate, 24 parts of deionized water and chlorine
Change 16 parts of sodium.
Further, the molecular weight of the sodium caseinate is 61000～370000；The natural essence is that agrocyb eaegerita is fragrant
Essence.
The preparation method of pesticide residues cleaning agent described above, comprises the steps of：
（1）Weigh Radix Glycyrrhizae according to parts by weight, roguing, clean, dry after, be dipped in the ethanol solution of 3 times of weight of Radix Glycyrrhizae,
Immersion 7h, reflux, extract, 8h at 75 DEG C, natural filtration slagging-off obtain Radix Glycyrrhizae extract；In the same manner respectively to fish
Raw meat grass, Flos Chrysanthemi Indici, Fructus Arctii, Rhizoma Cimicifugae, Folium Isatidiss are extracted, and gained extracting solution is mixed, mixed extract is obtained；
（2）First deionized water is added in reactor, 35 DEG C of insulations is heated to, is added sodium caseinate, sodium carbonate, bicarbonate
Sodium, stirs to all materials after being completely dissolved, and under the mixing speed of 200r/min, is slowly added to glucoside antibacterial, tea
Polyphenol and tea saponin, it is in gelatin-like liquid to stir to solution；
（3）Under the mixing speed of 350r/min, to step（2）Gelatin-like liquid be slowly added to step（1）Mixed extraction
Liquid, after stirring, sequentially adds Sodium Chloride, vitamin C, natural essence, stirs, and obtains final product the pesticide residues cleaning
Agent.
Cleaned after crops with pesticide residue scavenging agent obtained in embodiment 1, contained by the detections of GB/T 19648 pesticide residues
Amount, acquired results are listed in Table 2 below.
Embodiment 2
A kind of pesticide residues cleaning agent, is made up of the raw material of following weight portion：45 parts of Radix Glycyrrhizae, 45 parts of Herba Houttuyniae, 45 parts of Flos Chrysanthemi Indici,
17 parts of sodium caseinate, 40 parts of Fructus Arctii, 19 parts of tea saponin, 35 parts of Rhizoma Cimicifugae, 20 parts of tea polyphenols, 35 parts of Folium Isatidiss, glucoside
20 parts of antibacterial, vitamin C _ 30 part, 16 parts of natural essence, 15 parts of sodium carbonate, 15 parts of sodium bicarbonate, 28 parts of deionized water and chlorine
Change 20 parts of sodium.
Further, the molecular weight of the sodium caseinate is 61000～370000；The natural essence is NINGMENGXIANG
Essence.
The preparation method of pesticide residues cleaning agent described above, comprises the steps of：
（1）Weigh Radix Glycyrrhizae according to parts by weight, roguing, clean, dry after, be dipped in the ethanol solution of 5 times of weight of Radix Glycyrrhizae,
Immersion 13h, reflux, extract, 10h at 80 DEG C, natural filtration slagging-off obtain Radix Glycyrrhizae extract；It is right respectively in the same manner
Herba Houttuyniae, Flos Chrysanthemi Indici, Fructus Arctii, Rhizoma Cimicifugae, Folium Isatidiss are extracted, and gained extracting solution is mixed, mixed extract is obtained；
（2）First deionized water is added in reactor, 40 DEG C of insulations is heated to, is added sodium caseinate, sodium carbonate, bicarbonate
Sodium, stirs to all materials after being completely dissolved, and under the mixing speed of 300r/min, is slowly added to glucoside antibacterial, tea
Polyphenol and tea saponin, it is in gelatin-like liquid to stir to solution；
（3）Under the mixing speed of 400r/min, to step（2）Gelatin-like liquid be slowly added to step（1）Mixed extraction
Liquid, after stirring, sequentially adds Sodium Chloride, vitamin C, natural essence, stirs, and obtains final product the pesticide residues cleaning
Agent.
Cleaned after crops with pesticide residue scavenging agent obtained in embodiment 2, contained by the detections of GB/T 19648 pesticide residues
Amount, acquired results are listed in Table 2 below.
Embodiment 3
A kind of pesticide residues cleaning agent, is made up of the raw material of following weight portion：40 parts of Radix Glycyrrhizae, 43 parts of Herba Houttuyniae, 42 parts of Flos Chrysanthemi Indici,
15 parts of sodium caseinate, 37 parts of Fructus Arctii, 17 parts of tea saponin, 33 parts of Rhizoma Cimicifugae, 18 parts of tea polyphenols, 32 parts of Folium Isatidiss, glucoside
18 parts of antibacterial, vitamin C _ 28 part, 14 parts of natural essence, 13 parts of sodium carbonate, 13 parts of sodium bicarbonate, 26 parts of deionized water and chlorine
Change 18 parts of sodium.
Further, the molecular weight of the sodium caseinate is 61000～370000；The natural essence is that Fructus Ananadis comosi is fragrant
Essence.
The preparation method of pesticide residues cleaning agent described above, comprises the steps of：
（1）Weigh Radix Glycyrrhizae according to parts by weight, roguing, clean, dry after, be dipped in the ethanol solution of 4 times of weight of Radix Glycyrrhizae,
Immersion 10h, reflux, extract, 9h at 77 DEG C, natural filtration slagging-off obtain Radix Glycyrrhizae extract；In the same manner respectively to fish
Raw meat grass, Flos Chrysanthemi Indici, Fructus Arctii, Rhizoma Cimicifugae, Folium Isatidiss are extracted, and gained extracting solution is mixed, mixed extract is obtained；
（2）First deionized water is added in reactor, 37 DEG C of insulations is heated to, is added sodium caseinate, sodium carbonate, bicarbonate
Sodium, stirs to all materials after being completely dissolved, and under the mixing speed of 250r/min, is slowly added to glucoside antibacterial, tea
Polyphenol and tea saponin, it is in gelatin-like liquid to stir to solution；
（3）Under the mixing speed of 370r/min, to step（2）Gelatin-like liquid be slowly added to step（1）Mixed extraction
Liquid, after stirring, sequentially adds Sodium Chloride, vitamin C, natural essence, stirs, and obtains final product the pesticide residues cleaning
Agent.
Cleaned after crops with pesticide residue scavenging agent obtained in embodiment 3, contained by the detections of GB/T 19648 pesticide residues
Amount, acquired results are listed in Table 2 below.
Embodiment 4
A kind of pesticide residues cleaning agent, is made up of the raw material of following weight portion：37 parts of Radix Glycyrrhizae, 41 parts of Herba Houttuyniae, 41 parts of Flos Chrysanthemi Indici,
14 parts of sodium caseinate, 36 parts of Fructus Arctii, 16 parts of tea saponin, 31 parts of Rhizoma Cimicifugae, 17 parts of tea polyphenols, 31 parts of Folium Isatidiss, glucoside
17 parts of antibacterial, vitamin C _ 26 part, 13 parts of natural essence, 12 parts of sodium carbonate, 12 parts of sodium bicarbonate, 25 parts of deionized water and chlorine
Change 17 parts of sodium.
Further, the molecular weight of the sodium caseinate is 61000～370000；The natural essence is that Fructus Citri grandiss are fragrant
Essence.
The preparation method of pesticide residues cleaning agent described above, comprises the steps of：
（1）Weigh Radix Glycyrrhizae according to parts by weight, roguing, clean, dry after, be dipped in the ethanol solution of 3.5 times of weight of Radix Glycyrrhizae
In, 9h is soaked, reflux, extract, 8.5h at 76 DEG C, natural filtration slagging-off obtain Radix Glycyrrhizae extract；Distinguish in the same manner
Herba Houttuyniae, Flos Chrysanthemi Indici, Fructus Arctii, Rhizoma Cimicifugae, Folium Isatidiss are extracted, gained extracting solution is mixed, mixed extract is obtained；
（2）First deionized water is added in reactor, 36 DEG C of insulations is heated to, is added sodium caseinate, sodium carbonate, bicarbonate
Sodium, stirs to all materials after being completely dissolved, and under the mixing speed of 220r/min, is slowly added to glucoside antibacterial, tea
Polyphenol and tea saponin, it is in gelatin-like liquid to stir to solution；
（3）Under the mixing speed of 360r/min, to step（2）Gelatin-like liquid be slowly added to step（1）Mixed extraction
Liquid, after stirring, sequentially adds Sodium Chloride, vitamin C, natural essence, stirs, and obtains final product the pesticide residues cleaning
Agent.
Cleaned after crops with pesticide residue scavenging agent obtained in embodiment 4, contained by the detections of GB/T 19648 pesticide residues
Amount, acquired results are listed in Table 2 below.
Embodiment 5
A kind of pesticide residues cleaning agent, is made up of the raw material of following weight portion：43 parts of Radix Glycyrrhizae, 44 parts of Herba Houttuyniae, 44 parts of Flos Chrysanthemi Indici,
16 parts of sodium caseinate, 39 parts of Fructus Arctii, 18 parts of tea saponin, 34 parts of Rhizoma Cimicifugae, 19 parts of tea polyphenols, 34 parts of Folium Isatidiss, glucoside
19 parts of antibacterial, vitamin C _ 29 part, 15 parts of natural essence, 14 parts of sodium carbonate, 14 parts of sodium bicarbonate, 27 parts of deionized water and chlorine
Change 19 parts of sodium.
Further, the molecular weight of the sodium caseinate is 61000～370000；The natural essence is that Pericarpium Citri tangerinae is fragrant
Essence.
The preparation method of pesticide residues cleaning agent described above, comprises the steps of：
（1）Weigh Radix Glycyrrhizae according to parts by weight, roguing, clean, dry after, be dipped in the ethanol solution of 4.5 times of weight of Radix Glycyrrhizae
In, 12h is soaked, reflux, extract, 9.5h at 79 DEG C, natural filtration slagging-off obtain Radix Glycyrrhizae extract；Divide in the same manner
It is other that Herba Houttuyniae, Flos Chrysanthemi Indici, Fructus Arctii, Rhizoma Cimicifugae, Folium Isatidiss are extracted, gained extracting solution is mixed, mixed extract is obtained；
（2）First deionized water is added in reactor, 39 DEG C of insulations is heated to, is added sodium caseinate, sodium carbonate, bicarbonate
Sodium, stirs to all materials after being completely dissolved, and under the mixing speed of 280r/min, is slowly added to glucoside antibacterial, tea
Polyphenol and tea saponin, it is in gelatin-like liquid to stir to solution；
（3）Under the mixing speed of 390r/min, to step（2）Gelatin-like liquid be slowly added to step（1）Mixed extraction
Liquid, after stirring, sequentially adds Sodium Chloride, vitamin C, natural essence, stirs, and obtains final product the pesticide residues cleaning
Agent.
Cleaned after crops with pesticide residue scavenging agent obtained in embodiment 5, contained by the detections of GB/T 19648 pesticide residues
Amount, acquired results are listed in Table 2 below.
Comparative example 1：Commercially naughty shellfish is than board crops abluent, by the inspection of 1 pesticide residues content of embodiment
Survey method is detected that acquired results are listed in Table 2 below.
Comparative example 2：Commercially Melaleuca board crops abluent, by the detection of 1 pesticide residues content of embodiment
Method is detected that acquired results are listed in Table 2 below.
Table 2
Show from 2 test data of table：The present invention is removing the ability of pesticide residues, antibacterial, mycete, parasite than commercially available pesticide
Residue removal agent effect is more preferable.
In sum, raw material of the present invention is natural food ingredient, safe and healthy, environmentally friendly, not only can efficiently, quickly
The pesticide residues removed on crops, and can effectively kill common bacteria, general mycete and parasite, to crop safety,
The novel agrochemical residue removal agent having no toxic side effect, material is easily purchased, with low cost, prepare, it is easy to use, be that crops pesticide is residual
The green scavenger stayed.
The preferred embodiment of invention is the foregoing is only, not to limit the present invention, all spirit in the present invention
Within principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.
Claims (6)
1. a kind of pesticide residues cleaning agent, it is characterised in that be made up of the raw material of following weight portion：35～45 parts of Radix Glycyrrhizae, fish raw meat
40～45 parts of grass, 40～45 parts of Flos Chrysanthemi Indici, 13～17 parts of sodium caseinate, 35～40 parts of Fructus Arctii, 15～19 parts of tea saponin, liter
Fiber crops 30～35 parts, 16～20 parts of tea polyphenols, 30～35 parts of Folium Isatidiss, 16～20 parts of glucoside antibacterial, vitamin C _ 25～
30 parts, 12～16 parts of natural essence, 11～15 parts of sodium carbonate, 11～15 parts of sodium bicarbonate, 24～28 parts of deionized water and chlorination
16～20 parts of sodium.
2. pesticide residues cleaning agent according to claim 1, it is characterised in that be made up of the raw material of following weight portion：It is sweet
40 parts of grass, 43 parts of Herba Houttuyniae, 42 parts of Flos Chrysanthemi Indici, 15 parts of sodium caseinate, 37 parts of Fructus Arctii, 17 parts of tea saponin, 33 parts of Rhizoma Cimicifugae, tea
18 parts of polyphenol, 32 parts of Folium Isatidiss, 18 parts of glucoside antibacterial, vitamin C _ 28 part, 14 parts of natural essence, 13 parts of sodium carbonate,
18 parts of 13 parts of sodium bicarbonate, 26 parts of deionized water and Sodium Chloride.
3. pesticide residues cleaning agent according to claim 1, it is characterised in that be made up of the raw material of following weight portion：It is sweet
37～43 parts of grass, 41～44 parts of Herba Houttuyniae, 41～44 parts of Flos Chrysanthemi Indici, 14～16 parts of sodium caseinate, 36～39 parts of Fructus Arctii, tea
16～18 parts of Saponin, 31～34 parts of Rhizoma Cimicifugae, 17～19 parts of tea polyphenols, 31～34 parts of Folium Isatidiss, glucoside antibacterial 17～19
Part, vitamin C _ 26～29 part, 13～15 parts of natural essence, 12～14 parts of sodium carbonate, 12～14 parts of sodium bicarbonate, deionized water
25～27 parts and 17～19 parts of Sodium Chloride.
4. the pesticide residues cleaning agent according to any one of claims 1 to 3, it is characterised in that：The sodium caseinate
Molecular weight is 61000～370000.
5. pesticide residues cleaning agent according to claim 4, it is characterised in that：The natural essence be agrocyb eaegerita essence,
One kind in Fructus Citri Limoniae essence, flavoring pineapple essence, Fructus Citri grandiss essence, Pericarpium Citri tangerinae essence.
6. the preparation method of pesticide residues cleaning agent according to claim 5, it is characterised in that comprise the steps of：
（1）Weigh Radix Glycyrrhizae according to parts by weight, roguing, clean, dry after, be dipped in the ethanol solution of 3～5 times of weight of Radix Glycyrrhizae
In, 7～13h is soaked, 8～10h of reflux, extract, at 75～80 DEG C, natural filtration slagging-off obtain Radix Glycyrrhizae extract；According to identical
Method respectively Herba Houttuyniae, Flos Chrysanthemi Indici, Fructus Arctii, Rhizoma Cimicifugae, Folium Isatidiss are extracted, by gained extracting solution mix, mixed
Close extracting solution；
（2）First deionized water is added in reactor, 35～40 DEG C of insulations is heated to, is added sodium caseinate, sodium carbonate, carbon
Sour hydrogen sodium, stirs to all materials after being completely dissolved, and under the mixing speed of 200～300r/min, is slowly added to glucoside
Antibacterial, tea polyphenols and tea saponin, it is in gelatin-like liquid to stir to solution；
（3）Under the mixing speed of 350～400r/min, to step（2）Gelatin-like liquid be slowly added to step（1）Mixing
Extracting solution, after stirring, sequentially adds Sodium Chloride, vitamin C, natural essence, stirs, obtain final product the pesticide residues clear
Clean dose.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611003783.4A CN106566674A (en) | 2016-11-15 | 2016-11-15 | Pesticide residue detergent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611003783.4A CN106566674A (en) | 2016-11-15 | 2016-11-15 | Pesticide residue detergent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106566674A true CN106566674A (en) | 2017-04-19 |
Family
ID=58541962
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611003783.4A Pending CN106566674A (en) | 2016-11-15 | 2016-11-15 | Pesticide residue detergent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106566674A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111264522A (en) * | 2018-12-05 | 2020-06-12 | 北京康为天生物科技有限公司 | Pesticide residue remover and preparation method and application thereof |
| CN111264521A (en) * | 2018-12-05 | 2020-06-12 | 北京康为天生物科技有限公司 | Pesticide residue remover and preparation method and application thereof |
| CN114467580A (en) * | 2022-01-12 | 2022-05-13 | 山东潍坊烟草有限公司 | Insect prevention method for tobacco leaves |
| WO2024103217A1 (en) * | 2022-11-14 | 2024-05-23 | 苏州大学 | Cleaning agent for removing pesticide residue from mulberry leaves, preparation method therefor and use thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104342294A (en) * | 2013-07-29 | 2015-02-11 | 青岛艾华隆生物科技有限公司 | Novel pesticide residue scavenger |
| CN104450225A (en) * | 2014-11-03 | 2015-03-25 | 唐翊珲 | Pesticide residue scavenging agent and preparation method thereof |
-
2016
- 2016-11-15 CN CN201611003783.4A patent/CN106566674A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104342294A (en) * | 2013-07-29 | 2015-02-11 | 青岛艾华隆生物科技有限公司 | Novel pesticide residue scavenger |
| CN104450225A (en) * | 2014-11-03 | 2015-03-25 | 唐翊珲 | Pesticide residue scavenging agent and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111264522A (en) * | 2018-12-05 | 2020-06-12 | 北京康为天生物科技有限公司 | Pesticide residue remover and preparation method and application thereof |
| CN111264521A (en) * | 2018-12-05 | 2020-06-12 | 北京康为天生物科技有限公司 | Pesticide residue remover and preparation method and application thereof |
| CN114467580A (en) * | 2022-01-12 | 2022-05-13 | 山东潍坊烟草有限公司 | Insect prevention method for tobacco leaves |
| WO2024103217A1 (en) * | 2022-11-14 | 2024-05-23 | 苏州大学 | Cleaning agent for removing pesticide residue from mulberry leaves, preparation method therefor and use thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103999884B (en) | A kind ofly prevent and treat biologic product of Radix Astragali powdery mildew and preparation method thereof | |
| CN104397058B (en) | A kind of Chinese herbal medicine green pesticide and preparation method thereof | |
| CN103875722B (en) | Chinese herbal medicine merges the botanical fungicide extracted | |
| CN106566674A (en) | Pesticide residue detergent and preparation method thereof | |
| CN102239894B (en) | Compound botanical agricultural bactericide and preparation method thereof | |
| CN105248489B (en) | A kind of biological agent for tea place preventing and treating pest and disease damage and preparation method thereof | |
| CN101209062A (en) | Compound plant source agricultural fungicide and preparation thereof | |
| CN103202321A (en) | Plant and animal-derived green environment-friendly pesticide and preparation method thereof | |
| JPH10245312A (en) | Plant protecting agent and its production | |
| CN106165705A (en) | A kind of green plant pesticide and preparation method thereof | |
| CN104872218B (en) | A kind of natural family's insecticide containing Tsubaki-saponin | |
| CA2712463A1 (en) | Environmentally friendly plant protection agents | |
| CN105685140A (en) | An insect-resist agent and a preparing method thereof | |
| CN101213963A (en) | Composite herbicide for preventing and controlling rice weed moleplant seed and barnyard grass | |
| CN105613589A (en) | Herbicide as well as preparation method and use method thereof | |
| CN106561717A (en) | Pesticide for preventing and controlling ginger blast, and preparation method thereof | |
| CN106665673A (en) | Wood preservative and preparation method thereof | |
| CN102379316B (en) | Traditional Chinese medicine composition preventing stalk penicillium digitatum and sclerotinia sclerotiorum, preparation method and application thereof | |
| CN107873755A (en) | Vegetable source pesticide, bactericidal microemulsion and preparation method thereof and application method | |
| CN108967454A (en) | A kind of plant source extracts crop bactericide and its preparation process | |
| CN1948253B (en) | Application of methyl syringanol in preventing and treating plant disease | |
| CN104886189A (en) | Plant-sourced pesticide microemulsion and preparation method thereof | |
| CN106689229A (en) | Botanical pesticide and preparation method thereof | |
| CN106259559A (en) | One vegetative insecticide and preparation method thereof | |
| CN106234442A (en) | A kind of Fructus Litchi antibacterial and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170419 |