CN106566402A - Waterborne wine bottle paint - Google Patents

Waterborne wine bottle paint Download PDF

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Publication number
CN106566402A
CN106566402A CN201610987576.0A CN201610987576A CN106566402A CN 106566402 A CN106566402 A CN 106566402A CN 201610987576 A CN201610987576 A CN 201610987576A CN 106566402 A CN106566402 A CN 106566402A
Authority
CN
China
Prior art keywords
waterborne
water
paint
resistance
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610987576.0A
Other languages
Chinese (zh)
Inventor
董善刚
王伯凤
赵吉波
潘金婷
殷晓燕
冯言朋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Yiqun Paint Industry Group Co Ltd
Original Assignee
Qingdao Yiqun Paint Industry Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Yiqun Paint Industry Group Co Ltd filed Critical Qingdao Yiqun Paint Industry Group Co Ltd
Priority to CN201610987576.0A priority Critical patent/CN106566402A/en
Publication of CN106566402A publication Critical patent/CN106566402A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • C09D5/103Anti-corrosive paints containing metal dust containing Al
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/47Levelling agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses waterborne glass paint. The waterborne glass paint is prepared from the following specific components in percentage by weight: 58% of waterborne polyurethane resin, 9% of waterborne adhesion improvement resin, 15% of epoxy modified self-cross-linked waterborne organic silicon emulsion, 2% of a film forming aid, 12.5% of pure water, 0.5% of a dispersant, 0.3% of a defoamer, 0.3% of a wetting agent, 0.6% of a water-resistant alcohol-resistant waterborne adhesion promoter, 0.4% of a leveling agent, and 0.4% of a thickener. The invention aims to provide the waterborne glass paint. The waterborne glass paint has the advantages that the waterborne glass paint is excellent in adhesion performance, water resistance and alcohol resistance, is relatively good in weather resistance and salt spray resistance, is nontoxic and pollution-free, is simple and convenient in construction, takes the pure water as a diluent, and is safe, fireproof, non-combustible, non-explosible and convenient for flow line production.

Description

A kind of aqueouss bottle paint
Technical field:The present invention relates to a kind of paint, more particularly to a kind of protection and decoration for glass surface, and have The water paint of certain premium properties, belongs to technical field of chemical paint.
Background technology:As people give birth to the lifting and the highest attention to health of words grade, following bottle base material and wine Bottle paint market must be the world of aqueous environment protection paint.
With the expanding day of the application of water paint, the exploitation of aqueouss bottle paint is inexorable trend.Traditionally glass Decoration be by adding pigment during founding glass or reaching art with carving the techniques such as frosted after casting in glass Effect.But traditional decoration process is time-consuming to take a lot of work.Recently as coating technology development in the direct application of glass surface Increasingly increased with increasing properties of product or reaching the trend of desired decorative effect.Glass coating be widely used in ambetti, Lighting glass, furniture glass, vial and glass industry.Wherein waterborne glass coatings are grown up most fast neck in being even more glass coating Domain.Simultaneously can directly to apply to other such as ceramics, plated item, cold aluminiums etc. wider for the related developing principle of waterborne glass coatings Apply in market.Therefore research and development aqueouss bottle paint is very important.
It is an object of the invention to provide a kind of aqueouss bottle paint, the product is full aqueous environment protection paint to the content of the invention, its color Bright-coloured, hardness is excellent, not only has excellent adhesion property and resistance to water and alcohol resistance to glass, while weatherability, salt tolerant Mist preferably, nontoxic, pollution-free, easy construction, and using water purification as diluent, safety, fire prevention, do not fire it is not quick-fried, be easy to flowing water The advantages of line is produced.
A kind of concrete component and part by weight of aqueouss bottle paint be:Waterborne polyurethane resin:58%;Aqueous adhesive force increases Enter resin:9%;Epoxide modified self-crosslinking aqueous organic silicon emulsion 15%;Coalescents:2%;Pure water:12.5%;Dispersant: 0.5%;Defoamer:0.3%;Wetting agent:0.3%;The water-fast aqueous adhesive force of resistance to alcohol accelerator:0.6%;Levelling agent:0.4%; Thickening agent:0.4%.
The aqueous polyurethane that the present invention is used, because its specific functional groups has, the adhesive force of brilliance is strong, hardness is high, corrosion resistant Erosion, the advantages of solvent resistance is good, therefore it is eminently suitable in aqueous glass paint formula, increases the adhesion property of paint film.
The resin that the present invention is used is formed by copolymerization such as methacrylic resin, acrylate, specific function monomers, is both had The adhesive force for having polyurethane resin splendid and wearability, and with extraordinary cold-resistant heated aqueous, excellent weather-proof of acrylic resin Property, chemical resistance and preferable pigment wettability and mechanical stability.The shortcoming that polyurethane resin easily turns yellow is avoided simultaneously And the problem of acrylic acid, polyurethane mixed emulsion poor compatibility and poor chemical stability, product is in the material such as glass, ABS, PS There is good adhesive force on base material.
The aqueous adhesive force accelerator that this project is used, by 0.1-3% weight than adding aqueous acrylic emulsion or poly- ammonia In ester dispersion liquid, the resistance to water of resin, chemical-resistant, high temperature resistant can be improved.Suitable for aqueous paint, water color ink, aqueouss Leather finishing agent and aqueouss print paste it is normal temperature crosslinked, but cured effect is more preferably under 60-80 degree.The cross-linking agent can be with water And common solvents dissolve each other, therefore, directly it can be mixed in system with vigorous stirring under normal circumstances, it is also possible to first by which It is then added in system after being dissolved in water and solvent.The cross-linking agent belongs to environment-friendly type cross-linking agent, formaldehydeless after crosslinking to wait nuisance Matter is released, and finished product is nontoxic, tasteless after being crosslinked.
This project has used dispersion resin, is the nonionic high molecular dispersion resin manufactured using Particular craft, has There are dispersion, the stability characteristic (quality) of uniqueness, good aluminium powder orientation is served in water paint bottle, aqueouss bottle paint is changed Easily grow dim in low viscosity, the problems such as multi angle view gloss difference is big.
This project has used modified polyorganosiloxane levelling agent, with very high interfacial activity, good to the wettability of ground, Film cissing, volcanic crater, bottom sand milling showing trace etc. can be eliminated, is promoted film levelling, is made painting face
Aqueouss bottle paint is applied to all kinds of decorative winebottles, Glass Craft, furniture glass, lighting glass, building decoration Glass, teacup, bottle for cosmetics etc., range of application is widely.
Specific embodiment is presented herein below one embodiment of scratch-resistant aqueouss bottle paint of the invention.
Aqueouss bottle paint composition (percentage by weight) of the present invention and production technology are:Compound concentration first is, in low speed Stirring is lower to add 58 parts of waterborne polyurethane resins and 9 parts of aqueous adhesive forces to promote resin, and stirring is uniformly dispersed for 10 minutes.In low speed Add under conditions of stirring 12.5 parts of water, 2 parts of coalescents, 15 parts of epoxide modified self-crosslinking aqueous organic silicon emulsions, 0.5 part 655 dispersants, 0.3 part of defoamer, 0.3 part of wetting agent, 0.4 part of levelling agent, 0.4 part of thickening agent, be eventually adding 0.6 part it is water-fast The aqueous adhesive force of resistance to alcohol accelerator, stirring are uniformly dispersed for 30 minutes, and Jing is checked, filtered, packaging of weighing.
The aqueouss bottle paint of the invention employs waterborne polyurethane resin and aqueous adhesive force promotes resin, in body series Effect, it is beautiful colourful that its film can allow glass more to be dazzled, and has excellent adhesion property and resistance to water and alcohol resistance to glass, Simultaneously weatherability, salt spray resistance preferably, nontoxic, pollution-free, easy construction, and using water purification as diluent, safety, fire prevention, no Combustion is quick-fried, the advantages of be easy to production line balance.

Claims (4)

1. a kind of concrete component and part by weight of waterborne glass coatings of the present invention is:
Waterborne polyurethane resin:58%;Aqueous adhesive force promotes resin:9%;Epoxide modified self-crosslinking aqueous organic silicon emulsion 15%;Coalescents:2%;Pure water:12.5%;Dispersant:0.5%;Defoamer:0.3%;Wetting agent:0.3%;Water-fast resistance to alcohol Aqueous adhesive force accelerator:0.6%;Levelling agent:0.4%;Thickening agent:0.4%.
2. a kind of waterborne glass coatings according to claim 1, is characterized in that present invention uses aqueous polyurethane, because its Specific functional groups have the advantages that the adhesive force of brilliance is strong, hardness is high, corrosion-resistant, solvent resistance is good, therefore are eminently suitable for water Property glass paint formula in, increase paint film adhesion property.
3. a kind of waterborne glass coatings according to claim 1, is characterized in that present invention uses aqueous adhesive force accelerator, The resistance to water of resin, chemical-resistant, high temperature resistant can be improved.The cross-linking agent belongs to environment-friendly type cross-linking agent, formaldehydeless etc. after crosslinking Harmful substance is released, and finished product is nontoxic, tasteless after being crosslinked.
4. a kind of waterborne glass coatings according to claim 1, is characterized in that present invention uses dispersion resin, is using only The nonionic high molecular dispersion resin of secret service skill manufacture, with unique dispersion, stability characteristic (quality), rises in water paint bottle Arrived good aluminium powder orientation, change aqueouss bottle paint easily grow dim in low viscosity, multi angle view gloss difference it is big The problems such as.
CN201610987576.0A 2016-11-10 2016-11-10 Waterborne wine bottle paint Pending CN106566402A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610987576.0A CN106566402A (en) 2016-11-10 2016-11-10 Waterborne wine bottle paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610987576.0A CN106566402A (en) 2016-11-10 2016-11-10 Waterborne wine bottle paint

Publications (1)

Publication Number Publication Date
CN106566402A true CN106566402A (en) 2017-04-19

Family

ID=58540906

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610987576.0A Pending CN106566402A (en) 2016-11-10 2016-11-10 Waterborne wine bottle paint

Country Status (1)

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CN (1) CN106566402A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107986614A (en) * 2017-12-17 2018-05-04 苏州浩焱精密模具有限公司 A kind of processing technology of instrument cloche
CN109704576A (en) * 2018-12-26 2019-05-03 成都市锐欣昊科技有限公司 A kind of zero VOC S water-based metal glaze and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107986614A (en) * 2017-12-17 2018-05-04 苏州浩焱精密模具有限公司 A kind of processing technology of instrument cloche
CN109704576A (en) * 2018-12-26 2019-05-03 成都市锐欣昊科技有限公司 A kind of zero VOC S water-based metal glaze and preparation method thereof

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WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170419

WD01 Invention patent application deemed withdrawn after publication