CN106810989A - A kind of aqueous environment protection anticorrosive paint and preparation method thereof - Google Patents
A kind of aqueous environment protection anticorrosive paint and preparation method thereof Download PDFInfo
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- CN106810989A CN106810989A CN201710115810.5A CN201710115810A CN106810989A CN 106810989 A CN106810989 A CN 106810989A CN 201710115810 A CN201710115810 A CN 201710115810A CN 106810989 A CN106810989 A CN 106810989A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention provides a kind of aqueous environment protection anticorrosive paint, it is made up of the raw material of following weight portion：80 100 parts of epoxy resin modification silicone acrylic emulsion, 20 40 parts of amine-modified epoxy resin curing agent, 15 25 parts of polyethylene glycol, 36 parts of Graphene powder, 12 parts of nano silicon, 0.5 1 parts of biological preservative, 6 12 parts of rust resisting pigment, 15 25 parts of color stuffing, 20 30 parts of deionized water；The present invention uses the silicone acrylic emulsion of high-quality, itself there is weather-proof, water-fast and chemical-resistant, and also with preferable film-forming attributes, the glued membrane densification that is formed, gloss, adhesive force are good, and silicone acrylic emulsion is modified further with epoxy, so that silicone acrylic emulsion is more stronger to the penetrating power of base material than the film forming matter of aqueous polymer emulsion class, corrosion bottom can be penetrated deep into, be acted on corrosion layer and play splendid antiseptic effect.
Description
Technical field
The invention belongs to water paint field, more particularly to a kind of aqueous environment protection anticorrosive paint and preparation method thereof.
Background technology
World today's environmental problem is increasingly severe, and substantial amounts of harmful substance is discharged in the processing of coating and production process
Environmental pollution can be caused and the healthy of workmen is damaged.In order to control to pollute and protect the health of workmen, China
Formulate the use that a series of measures limits VOC coating high.So environment friendly anti-corrosive paint turns into the emphasis of paint development.Numerous
In environment-friendly type coating, water paint is the important directions of development.But current water paint also has that some are technical,
So improve water paint anti-corrosive properties oneself turn into the developing emphasis of environmental protection coating material.
In performance requirement anticorrosive coating industry higher, Water-borne modification is also done step-by-step.But at present from Corrosion Protection
From the point of view of aspect, water paint also has certain gap compared to solvent based coating, the main optimization in resin of present people, resin with it is solid
Agent is used cooperatively, the selection aspect effort of nontoxic type color stuffing.The addition of anticorrosion filler is having one to antiseptic property just
The influence in face, but the aspect such as caking property in coating, its effect is but negative, before Corrosion Protection is ensured
Put, the appropriate addition for reducing filler, the combination property of lifting coating that just can be by a relatively large margin.
Ma Lina etc. is without exception using the water-fast 24h of water alcohol acid priming paint, the salt spray resistance 240h that water alcohol acid is made；It is aqueous
Alkyd finish artificial ageing resistance performance can reach 500h, with solvent-borne alkyd paint indifference.Environmentally friendly aspect VOCs only has 1688/L,
Heavy metal lead, chromium, good fortune and mercury are not contained.But there are some obvious shortcomings in water alcohol acid:Dried coating film is slow, hardness is low,
Water resistance and corrosion-resistant, outdoor weathe resistance be not good etc.；In addition aqueous alkide resin key during storage can be hydrolyzed,
Performance has much room for improvement.Wang Ruihong etc.《The development of self-drying acrylic modified alkyd paint》The water-based anticorrosive paint for being done uses third
Olefin(e) acid modified alkyd resin improves water alcohol acid coating and dries the slow, shortcoming that hardness is low, water-fast corrosion-resistant weatherability is not good, its
Water-fast and artificial ageing resistance respectively reaches 94h and 900h, but its drying property or unsatisfactory.
No. CN200710047452.5 application provides a kind of water paint for steel band, is the crosslinking agent by epoxy modified polyester resin,
Pigment, curing catalysts and water are uniformly mixed.The water paint has rapid draing, and paint film is hard, and metal adhesion is strong,
Pliability is good, and solvent resistance is good, and anticorrosion is excellent, and content of beary metal meets the excellent performance of ROHS environmental protection standards.And VOC contains
Amount is low, eliminates the pollution to environment, belongs to Green Product.But the coating solvent resistance stability also needs further raising.
From the point of view of the research of existing water paint, water paint also exists compared to solvent based coating in terms of commercial Application
A certain distance, its combination property is the key factor for limiting its large-scale application, therefore, exploitation have excellent coating performance,
The coating of the excellent combination property such as weather-proof, corrosion-resistant is the emphasis studied at this stage.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of aqueous environment protection anticorrosive paint and preparation method thereof, this hair
On the one hand bright prepared coating will not bubble, whiten, being cracked and the problems such as delamination, can be firmly attached to metal surface,
With good pliability and adhesive force；On the other hand it is aqueous environment protection coating, it is environmentally friendly, with very good anti-corrosion
And weathering characteristics.
To solve the above problems, the technical solution adopted by the present invention is：
A kind of aqueous environment protection anticorrosive paint, is made up of the raw material of following weight portion：Epoxy resin modification silicone acrylic emulsion 80-
100 parts, 20-40 parts of amine-modified epoxy resin curing agent, polyethylene glycol 15-25 parts, Graphene powder 3-6 parts, nano silicon
1-2 parts, biological preservative 0.5-1 parts, rust resisting pigment 6-12 parts, color stuffing 15-25 parts, deionized water 20-30 parts.
Preferably, 90 parts of epoxy resin modification silicone acrylic emulsion, 30 parts of amine-modified epoxy resin curing agent, polyethylene glycol 20
Part, 5 parts of Graphene powder, 1.5 parts of nano silicon, 0.6 part of biological preservative, 8 parts of rust resisting pigment, 20 parts of color stuffing, go from
25 parts of sub- water.
Wherein, the biological preservative is selected from the one kind in essential oil and person's Tea Polyphenols or its combination.
The rust resisting pigment is trbasic zinc phosphate, aluminium triphosphate, zinc aluminophosphate, Ion exchange anticorrosive pigment and phosphorus zinc silicate
In one or more mixing.
The molecular weight of the polyethylene glycol is 2000-6000.
The color stuffing is selected from one or more in rutile titanium dioxide, blanc fixe, talcum powder, calcium carbonate.
The amine-modified epoxy resin curing agent is polyamide modified epoxy curing agent.
Also, present invention also offers the preparation method of the aqueous environment protection anticorrosive paint, specifically include following steps：
(1) preparation of epoxy resin modification silicone acrylic emulsion：10-20 parts of emulsifier op-10,10-20 is taken by weight
The acrylic monomer of part, appropriate NaHCO3 and 20-30 parts of deionized water are added in reaction vessel, and quick stirring heats up
0.5-1h is incubated after to 70-80 DEG C；Then 40-60 parts of acrylic monomer, 10-30 parts of epoxy resin E-44 and 30-60 are taken again
Part organosilicon VTES is configured to mixed solution, and this mixed solution and appropriate initiator are added drop-wise in foregoing mixed liquor simultaneously, and
1-2h is incubated after being warming up to 80-85 DEG C, 30 DEG C are cooled to afterwards, the epoxy resin modification silicon is obtained final product after ammonification water regulation pH value
Acrylic emulsion；
(2) preparation of aqueous environment protection anticorrosive paint：First by Graphene powder, nano silicon addition deionized water
Decentralized processing is carried out, amine-modified epoxy resin curing agent, biological preservative, rust resisting pigment and color stuffing is subsequently adding and is mixed
Obtain mixed liquor A；Then epoxy resin modification silicone acrylic emulsion prepared by step (1) is well mixed with polyethylene glycol and is mixed
Liquid B；Finally by mixed liquor A and mixed liquid B be stirred mixing the regular hour obtain final product the aqueous environment protection anticorrosive paint.
Wherein, the initiator is ammonium persulfate solution, and its mass fraction is 1-2%.
Technique effect of the invention is：(1) present invention itself is had weather-proof, water-fast using the silicone acrylic emulsion of high-quality
And chemical-resistant, and also with preferable film-forming attributes, the glued membrane that is formed is fine and close, tough and tensile, gloss, adhesive force are good,
And the present invention is modified further with epoxy to silicone acrylic emulsion so that film forming of the silicone acrylic emulsion than aqueous polymer emulsion class
Thing is stronger to the penetrating power of base material, can penetrate deep into corrosion bottom, is acted on corrosion layer and plays splendid antiseptic effect；
(2) Environment friendly anti-corrosion paint of the present invention and function additive, asepsis environment-protecting, meet enterprise safety operation and constructor
The healthy demand of member；(3) present invention carries out cross-linking modified using aqueous polyamine curing agent to epoxy silicone acrylic emulsion, effectively carries
Paint film initial stage water resistance high, corrosion resistance, paint film combination property reach same type solvent based product industry index；(4) present invention
Addition biological preservative, its environmental protection characteristic is excellent, free from environmental pollution, further enhances the antiseptic property of coating of the present invention；(5)
By selecting suitable raw material, the content for adjusting raw material is in optimal ratio to the present invention, makes the performance of each raw material mutually coordinated
Coordinate, obtain the very excellent anticorrosive paint of combination property, its performance, in close proximity to industrial solvent-based coatings, is water paint
Application provide may.
Specific embodiment
Technical scheme is further elaborated with reference to embodiment：
Embodiment 1
A kind of aqueous environment protection anticorrosive paint, is made up of the raw material of following weight portion：Epoxy resin modification silicone acrylic emulsion 90
Part, 30 parts of polyamide modified epoxy curing agent, 10 parts of polyethylene glycol, 5 parts of Graphene powder, 1.5 parts of nano silicon is raw
0.8 part of thing preservative essential oil, 9 parts of rust resisting pigment trbasic zinc phosphate, 20 parts of color stuffing rutile titanium dioxide, 25 parts of deionized water.
Embodiment 2
A kind of aqueous environment protection anticorrosive paint, is made up of the raw material of following weight portion：Epoxy resin modification silicone acrylic emulsion 80
Part, 20 parts of polyamide modified epoxy curing agent, 15 parts of polyethylene glycol, 3 parts of Graphene powder, 1 part of nano silicon is biological
0.5 part of preservative essential oil, 6 parts of rust resisting pigment trbasic zinc phosphate, 15 parts of color stuffing talcum powder, 20 parts of deionized water.
Embodiment 3
A kind of aqueous environment protection anticorrosive paint, is made up of the raw material of following weight portion：Epoxy resin modification silicone acrylic emulsion 100
Part, 40 parts of polyamide modified epoxy curing agent, 25 parts of polyethylene glycol, 6 parts of Graphene powder, 2 parts of nano silicon is biological
1 part of preservative Tea Polyphenols, 12 parts of rust resisting pigment aluminium triphosphate, 25 parts of color stuffing rutile titanium dioxide, 30 parts of deionized water.
Embodiment 4
A kind of aqueous environment protection anticorrosive paint, is made up of the raw material of following weight portion：Epoxy resin modification silicone acrylic emulsion 85
Part, 25 parts of polyamide modified epoxy curing agent, 18 parts of polyethylene glycol, 4 parts of Graphene powder, 1.2 parts of nano silicon is raw
0.7 part of thing preservative Tea Polyphenols, 8 parts of rust resisting pigment aluminium triphosphate, 18 parts of color stuffing talcum powder, 24 parts of deionized water.
Embodiment 5
A kind of aqueous environment protection anticorrosive paint, is made up of the raw material of following weight portion：Epoxy resin modification silicone acrylic emulsion 95
Part, 35 parts of polyamide modified epoxy curing agent, 22 parts of polyethylene glycol, 5 parts of Graphene powder, 1.6 parts of nano silicon is raw
0.8 part of thing preservative Tea Polyphenols, 10 parts of rust resisting pigment zinc aluminophosphate, 22 parts of color stuffing blanc fixe, 28 parts of deionized water.
Embodiment 6
A kind of aqueous environment protection anticorrosive paint, is made up of the raw material of following weight portion：Epoxy resin modification silicone acrylic emulsion 87
Part, 32 parts of polyamide modified epoxy curing agent, 19 parts of polyethylene glycol, 5 parts of Graphene powder, 1.7 parts of nano silicon is raw
0.8 part of thing preservative essential oil, 11 parts of rust resisting pigment phosphorus zinc silicate, 17 parts of color stuffing blanc fixe, 23 parts of deionized water.
Comparative example 1
A kind of aqueous environment protection anticorrosive paint, is made up of the raw material of following weight portion：90 parts of silicone acrylic emulsion, it is polyamide modified
30 parts of epoxy curing agent, 10 parts of polyethylene glycol, 5 parts of Graphene powder, 1.5 parts of nano silicon, biological preservative essence
0.8 part of oil, 9 parts of rust resisting pigment trbasic zinc phosphate, 20 parts of color stuffing rutile titanium dioxide, 25 parts of deionized water.
Embodiment 7
The preparation method of embodiment 1-6 and aqueous environment protection anticorrosive paint described in comparative example 1, comprises the following steps：
(1) preparation of epoxy resin modification silicone acrylic emulsion：15 parts of emulsifier op-10, the third of 15 parts is taken by weight
Alkene acrylic monomer, appropriate NaHCO3 and 25 part of deionized water are added in reaction vessel, after quick stirring is warming up to 75 DEG C
Insulation 0.7h；Then 50 parts of acrylic monomers, 20 parts of epoxy resin E-44s are taken again to be configured to mix with 50 parts of organosilicon VTES
Solution, this mixed solution and appropriate initiator ammonium persulfate solution is added drop-wise in foregoing mixed liquor simultaneously, and be warming up to 82 DEG C
After be incubated 1.5h, be cooled to 30 DEG C afterwards, obtain final product the epoxy resin modification silicone acrylic emulsion after ammonification water regulation pH value；
(2) preparation of aqueous environment protection anticorrosive paint：Graphene powder, nano silicon are added first by formula rate
Decentralized processing is carried out in deionized water, amine-modified epoxy resin curing agent, biological preservative, rust resisting pigment and face is subsequently adding and is filled out
Material carries out being mixed to get mixed liquor A；Then epoxy resin modification silicone acrylic emulsion prepared by step (1) is mixed with polyethylene glycol
It is even to obtain mixed liquid B；Finally by mixed liquor A and mixed liquid B be stirred mixing the regular hour obtain final product the aqueous environment protection
Anticorrosive paint.
To embodiment of the present invention 1-6 and described in comparative example 1, the performance of coating is tested, as a result such as table 1 below：
Finally it should be noted that：The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention,
Although being described in detail to the present invention with reference to the foregoing embodiments, for a person skilled in the art, it still may be used
Modified with to the technical scheme described in foregoing embodiments, or equivalent is carried out to which part technical characteristic.
All any modification, equivalent substitution and improvements within the spirit and principles in the present invention, made etc., should be included in of the invention
Within protection domain.
Claims (9)
1. a kind of aqueous environment protection anticorrosive paint, it is characterised in that be made up of the raw material of following weight portion：Epoxy resin modification silicon
Acrylic emulsion 80-100 parts, 20-40 parts of amine-modified epoxy resin curing agent, polyethylene glycol 15-25 parts, Graphene powder 3-6 parts, nanometer
- 2 parts of silica 1, biological preservative 0.5-1 parts, rust resisting pigment 6-12 parts, color stuffing 15-25 parts, deionized water 20-30 parts.
2. aqueous environment protection anticorrosive paint according to claim 1, it is characterised in that epoxy resin modification silicone acrylic emulsion 90
Part, 30 parts of amine-modified epoxy resin curing agent, 20 parts of polyethylene glycol, 5 parts of Graphene powder, 1.5 parts of nano silicon, biology is anti-
0.6 part of rotten agent, 8 parts of rust resisting pigment, 20 parts of color stuffing, 25 parts of deionized water.
3. aqueous environment protection anticorrosive paint according to claim 2, it is characterised in that the biological preservative is selected from perfume (or spice)
One kind or its combination in essential oil or Tea Polyphenols.
4. aqueous environment protection anticorrosive paint according to claim 3, it is characterised in that the rust resisting pigment be trbasic zinc phosphate,
One or more mixing in aluminium triphosphate, zinc aluminophosphate, Ion exchange anticorrosive pigment and phosphorus zinc silicate.
5. the aqueous environment protection anticorrosive paint according to claim any one of 3-4, it is characterised in that the polyethylene glycol
Molecular weight is 2000-6000.
6. the aqueous environment protection anticorrosive paint according to claim any one of 3-4, it is characterised in that the color stuffing is selected from
One or more in rutile titanium dioxide, blanc fixe, talcum powder, calcium carbonate.
7. the aqueous environment protection anticorrosive paint according to claim any one of 3-5, it is characterised in that the amine modified epoxy
Resin curing agent is polyamide modified epoxy curing agent.
8. according to claim any one of 1-7 aqueous environment protection anticorrosive paint preparation method, it is characterised in that including such as
Lower step：
(1) preparation of epoxy resin modification silicone acrylic emulsion：Take by weight 10-20 parts emulsifier op-10,10-20 part
Acrylic monomer, appropriate NaHCO3 and 20-30 parts of deionized water are added in reaction vessel, and quick stirring is warming up to
0.5-1h is incubated after 70-80 DEG C；Then 40-60 parts of acrylic monomer, 10-30 parts of epoxy resin E-44 and 30-60 parts are taken again
Organosilicon VTES is configured to mixed solution, this mixed solution and appropriate initiator is added drop-wise in foregoing mixed liquor simultaneously, and risen
1-2h is incubated after warm to 80-85 DEG C, 30 DEG C are cooled to afterwards, the epoxy resin modification silicon third is obtained final product after ammonification water regulation pH value
Emulsion；
(2) preparation of aqueous environment protection anticorrosive paint：Carried out during Graphene powder, nano silicon are added into deionized water first
Decentralized processing, is subsequently adding amine-modified epoxy resin curing agent, biological preservative, rust resisting pigment and color stuffing and is mixed to get
Mixed liquor A；Then epoxy resin modification silicone acrylic emulsion prepared by step (1) is well mixed with polyethylene glycol and obtains mixed liquid B；
Finally by mixed liquor A and mixed liquid B be stirred mixing the regular hour obtain final product the aqueous environment protection anticorrosive paint.
9. the preparation method of aqueous environment protection anticorrosive paint according to claim 8, it is characterised in that the initiator was
Ammonium sulfate, its mass fraction is 1-2%.
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107384127A (en) * | 2017-08-17 | 2017-11-24 | 广东省珠海市质量计量监督检测所 | A kind of anti-aging antirust paint and preparation method thereof |
| CN107556492A (en) * | 2017-09-28 | 2018-01-09 | 厦门凯纳石墨烯技术股份有限公司 | A kind of aqueous epoxy resin emulsion of graphene-containing and preparation method thereof |
| CN108219558A (en) * | 2018-01-02 | 2018-06-29 | 佛山实瑞先导材料研究院（普通合伙） | A kind of waterborne antibacterial anti-corrosion Dyclo paint and preparation method thereof |
| CN108359342A (en) * | 2018-03-25 | 2018-08-03 | 王丽燕 | A kind of aqueous environment protection coating and its preparation method and application |
| CN109021621A (en) * | 2018-07-25 | 2018-12-18 | 广东好邦石墨烯新材料科技有限公司 | A kind of zinc powder of graphene modified, preparation method and its application in water-based anticorrosive paint |
| CN110294987A (en) * | 2019-06-11 | 2019-10-01 | 常州烯源纳米科技有限公司 | Organic silicon modified acrylic ester aqueous heat radiation coating of a kind of graphene-with core-shell structure and preparation method thereof |
| CN110423541A (en) * | 2019-09-10 | 2019-11-08 | 广东涂百年新型材料有限公司 | A kind of ecology water paint and preparation method thereof |
| WO2019217402A1 (en) | 2018-05-07 | 2019-11-14 | Nanotek Instruments, Inc. | Graphene-enabled anti-corrosion coating |
| CN110564266A (en) * | 2019-09-26 | 2019-12-13 | 西南石油大学 | Anticorrosive composite coating material with self-repairing function and coating preparation method |
| CN111117397A (en) * | 2019-12-27 | 2020-05-08 | 广东梵竹水性涂料有限公司 | Water-based anticorrosive paint |
| CN113174158A (en) * | 2021-04-16 | 2021-07-27 | 虎皇新材料科技集团有限公司 | Modified epoxy phosphonate accelerant for coating and preparation method and application thereof |
| CN115141533A (en) * | 2021-08-27 | 2022-10-04 | 郑州格莱菲高铁新材料科技有限公司 | Environment-friendly corrosion-resistant water-based graphene coating and preparation method thereof |
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107384127A (en) * | 2017-08-17 | 2017-11-24 | 广东省珠海市质量计量监督检测所 | A kind of anti-aging antirust paint and preparation method thereof |
| CN107556492A (en) * | 2017-09-28 | 2018-01-09 | 厦门凯纳石墨烯技术股份有限公司 | A kind of aqueous epoxy resin emulsion of graphene-containing and preparation method thereof |
| CN107556492B (en) * | 2017-09-28 | 2020-02-14 | 厦门凯纳石墨烯技术股份有限公司 | Graphene-containing waterborne epoxy resin emulsion and preparation method thereof |
| CN108219558A (en) * | 2018-01-02 | 2018-06-29 | 佛山实瑞先导材料研究院（普通合伙） | A kind of waterborne antibacterial anti-corrosion Dyclo paint and preparation method thereof |
| CN108359342A (en) * | 2018-03-25 | 2018-08-03 | 王丽燕 | A kind of aqueous environment protection coating and its preparation method and application |
| US11680173B2 (en) | 2018-05-07 | 2023-06-20 | Global Graphene Group, Inc. | Graphene-enabled anti-corrosion coating |
| WO2019217402A1 (en) | 2018-05-07 | 2019-11-14 | Nanotek Instruments, Inc. | Graphene-enabled anti-corrosion coating |
| CN109021621A (en) * | 2018-07-25 | 2018-12-18 | 广东好邦石墨烯新材料科技有限公司 | A kind of zinc powder of graphene modified, preparation method and its application in water-based anticorrosive paint |
| CN110294987A (en) * | 2019-06-11 | 2019-10-01 | 常州烯源纳米科技有限公司 | Organic silicon modified acrylic ester aqueous heat radiation coating of a kind of graphene-with core-shell structure and preparation method thereof |
| CN110423541A (en) * | 2019-09-10 | 2019-11-08 | 广东涂百年新型材料有限公司 | A kind of ecology water paint and preparation method thereof |
| CN110564266A (en) * | 2019-09-26 | 2019-12-13 | 西南石油大学 | Anticorrosive composite coating material with self-repairing function and coating preparation method |
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Application publication date: 20170609 |