CN106565090A - Glaze for enameled cup opening part - Google Patents

Glaze for enameled cup opening part Download PDF

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Publication number
CN106565090A
CN106565090A CN201610921002.3A CN201610921002A CN106565090A CN 106565090 A CN106565090 A CN 106565090A CN 201610921002 A CN201610921002 A CN 201610921002A CN 106565090 A CN106565090 A CN 106565090A
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CN
China
Prior art keywords
parts
glaze
fine powder
acid
milled
Prior art date
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Pending
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CN201610921002.3A
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Chinese (zh)
Inventor
许纯荣
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Anhui Blue And White Fang Ci Industry Limited-Liability Co
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Anhui Blue And White Fang Ci Industry Limited-Liability Co
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Application filed by Anhui Blue And White Fang Ci Industry Limited-Liability Co filed Critical Anhui Blue And White Fang Ci Industry Limited-Liability Co
Priority to CN201610921002.3A priority Critical patent/CN106565090A/en
Publication of CN106565090A publication Critical patent/CN106565090A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Cosmetics (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Fodder In General (AREA)

Abstract

The invention relates to the technical field of glaze, in particular to glaze for an enameled cup opening part. The glaze is prepared from, by weight, 12-16 parts of bauxite, 24-32 parts of red soil, 12-18 parts of Shaanxi soil, 2-3 parts of spodumene, 2-3 parts of gallium nitride, 2-3 parts of ox bones, 4-6 parts of vanadium pentoxide, 3-7 parts of aluminum phosphate, 3-7 parts of calcium oxide, 3-7 parts of calcium silicide, 5-10 parts of a stabilizing additive and 5-10 parts of modified zeolite. The glaze is large in surface tension, resistant to abrasion after being dried, non-volatile at the high temperature, free of toxic and side effects, allows direct contact with the human body and is especially suitable for the enameled cup opening part.

Description

A kind of Enamel jar oral area glaze
Technical field
The present invention relates to glaze technical field, and in particular to a kind of Enamel jar oral area glaze.
Background technology
The ceramic industry of China is of long standing and well established, with a long history.Pottery, the raw material used by porcelain are mostly natural inorganic Nonmetallic mineral, these raw materials by processing and refining, cooperation, shaping, high-temperature physics chemical reaction, just formed it is a kind of with original group It is ceramics into the completely different new material of material.China's pottery to porcelain development have passed through three phases:Pottery-original pottery Device-porcelain.
People are often drunk water with Enamel jar, but when Enamel jar oral area is covered with bowl cover, Enamel jar mouth of long duration Portion can grind.
The content of the invention
The technical problem to be solved is to provide a kind of Enamel jar oral area glaze, and frit surface tension force is big, It is wear-resistant after drying and non-volatile at high temperature, have no toxic side effect, Enamel jar can be particularly suitable for directly contact human body Oral area is used.
The technical problem to be solved employs the following technical solutions to realize:
A kind of Enamel jar oral area glaze, is made up of the component of following weight portion:Bauxite 12-16 parts, laterite 24-32 Part, Shaanxi soil 12-18 parts, spodumene 2-3 parts, gallium nitride 2-3 parts, Os Bovis seu Bubali 2-3 parts, vanadic anhydride 4-6 parts, aluminum phosphate 3-7 Part, calcium oxide 3-7 parts, calcium silicide 3-7 parts, stabilization aid 5-10 parts, modified zeolite 5-10 parts.
The stabilization aid is made up of the component of following weight portion:Propylene glycol monomethyl ether 2-3 parts, Calcium Carbonate 2-3 part, succinic acid 2-3 parts, glaze fruit 1-2 parts, lauric acid diethyl amide 1-2 parts;Its preparation method is the mixing of each raw material to be milled to into fine powder, so Afterwards by fine powder 60-100KHz ultrasonic Treatment 10 minutes, then the clear water stirring for being mixed into its weight portion 30%-40% to fine powder is equal It is even then slurry to be sent in dehydrator and dried into slurry, continue to be milled to fine powder to be stabilization aid after drying.
The modified zeolite preparation method is:Zeolite is blown 5 minutes with 200 DEG C of high temperature carbon dioxide gases, is then used again 80 DEG C of apple vinegars, the acid of Chinese holly edge, Palmic acid, gallic acid, myristic acid, water press 1:1:1:1:1:The immersion of 140 proportioning concentrations is protected Temperature is processed 30 minutes, then deionized water cleans zeolite, is then milled to powder.
A kind of preparation technology of Enamel jar oral area glaze, comprises the following steps:
(1) mixing of each raw material is milled to into 50-80 mesh fine powders;
(2) fine powder is wrapped up into post-heating to 80 DEG C with tinfoil, is incubated 20 minutes, then fine powder is cooled to into room temperature i.e. Obtain glaze.
The invention has the beneficial effects as follows:Frit surface tension force of the present invention is big, wear-resistant after being dried, and does not wave at high temperature Send out, have no toxic side effect, can be particularly suitable for Enamel jar oral area and use with directly contact human body.
Specific embodiment
In order that technological means, creation characteristic, reached purpose and effect that the present invention is realized are easy to understand, tie below Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of Enamel jar oral area glaze, is made up of the component of following weight portion:14 parts of bauxite, 282 parts of laterite, Shaanxi 15 parts of soil, 2.5 parts of spodumene, 2.5 parts of gallium nitride, 2.5 parts of Os Bovis seu Bubali, 5 parts of vanadic anhydride, 5 parts of aluminum phosphate, 5 parts of calcium oxide, silicon Change 5 parts of calcium, 8 parts of stabilization aid, 8 parts of modified zeolite.
The stabilization aid is made up of the component of following weight portion:2.5 parts of propylene glycol monomethyl ether, 2.5 parts of Calcium Carbonate, succinic acid 2.5 parts, glaze fruit 1.5 parts, 1.5 parts of lauric acid diethyl amide;Its preparation method is the mixing of each raw material to be milled to into fine powder, so Afterwards fine powder is stirred into into slurry with 80KHz ultrasonic Treatment 10 minutes, then the clear water for being mixed into its weight portion 35% to fine powder, Then slurry is sent in dehydrator and is dried, continue to be milled to fine powder to be stabilization aid after drying.
The modified zeolite preparation method is:Zeolite is blown 5 minutes with 200 DEG C of high temperature carbon dioxide gases, is then used again 80 DEG C of apple vinegars, the acid of Chinese holly edge, Palmic acid, gallic acid, myristic acid, water press 1:1:1:1:1:The immersion of 140 proportioning concentrations is protected Temperature is processed 30 minutes, then deionized water cleans zeolite, is then milled to powder.
A kind of preparation technology of Enamel jar oral area glaze, comprises the following steps:
(1) mixing of each raw material is milled to into 50-80 mesh fine powders;
(2) fine powder is wrapped up into post-heating to 80 DEG C with tinfoil, is incubated 20 minutes, then fine powder is cooled to into room temperature i.e. Obtain glaze.
Embodiment 2
A kind of Enamel jar oral area glaze, is made up of the component of following weight portion:12 parts of bauxite, 24 parts of laterite, Shaanxi 12 parts of soil, 2 parts of spodumene, 2 parts of gallium nitride, 2 parts of Os Bovis seu Bubali, 4 parts of vanadic anhydride, 3 parts of aluminum phosphate, 3 parts of calcium oxide, calcium silicide 3 Part, 5 parts of stabilization aid, 5 parts of modified zeolite.
The stabilization aid is made up of the component of following weight portion:2 parts of propylene glycol monomethyl ether, 2 parts of Calcium Carbonate, 2 parts of succinic acid, Glaze fruit 1 part, 1 part of lauric acid diethyl amide;Its preparation method is that the mixing of each raw material is milled to into fine powder, then uses fine powder 60KHz ultrasonic Treatment 10 minutes, then the clear water for being mixed into its weight portion 30% to fine powder is stirred into slurry, then by slurry Drying in dehydrator is sent into, continues to be milled to fine powder to be stabilization aid after drying.
The modified zeolite preparation method is:Zeolite is blown 5 minutes with 200 DEG C of high temperature carbon dioxide gases, is then used again 80 DEG C of apple vinegars, the acid of Chinese holly edge, Palmic acid, gallic acid, myristic acid, water press 1:1:1:1:1:The immersion of 140 proportioning concentrations is protected Temperature is processed 30 minutes, then deionized water cleans zeolite, is then milled to powder.
A kind of preparation technology of Enamel jar oral area glaze, comprises the following steps:
(1) mixing of each raw material is milled to into 50-80 mesh fine powders;
(2) fine powder is wrapped up into post-heating to 80 DEG C with tinfoil, is incubated 20 minutes, then fine powder is cooled to into room temperature i.e. Obtain glaze.
Embodiment 3
A kind of Enamel jar oral area glaze, is made up of the component of following weight portion:16 parts of bauxite, 32 parts of laterite, Shaanxi 18 parts of soil, 3 parts of spodumene, 3 parts of gallium nitride, 3 parts of Os Bovis seu Bubali, 6 parts of vanadic anhydride, 7 parts of aluminum phosphate, 7 parts of calcium oxide, calcium silicide 7 Part, 10 parts of stabilization aid, 10 parts of modified zeolite.
The stabilization aid is made up of the component of following weight portion:3 parts of propylene glycol monomethyl ether, 3 parts of Calcium Carbonate, 3 parts of succinic acid, Glaze fruit 2 parts, 2 parts of lauric acid diethyl amide;Its preparation method is that the mixing of each raw material is milled to into fine powder, then uses fine powder 100KHz ultrasonic Treatment 10 minutes, then the clear water for being mixed into its weight portion 40% to fine powder is stirred into slurry, then will slurry Material sends into drying in dehydrator, continues to be milled to fine powder to be stabilization aid after drying.
The modified zeolite preparation method is:Zeolite is blown 5 minutes with 200 DEG C of high temperature carbon dioxide gases, is then used again 80 DEG C of apple vinegars, the acid of Chinese holly edge, Palmic acid, gallic acid, myristic acid, water press 1:1:1:1:1:The immersion of 140 proportioning concentrations is protected Temperature is processed 30 minutes, then deionized water cleans zeolite, is then milled to powder.
A kind of preparation technology of Enamel jar oral area glaze, comprises the following steps:
(1) mixing of each raw material is milled to into 50-80 mesh fine powders;
(2) fine powder is wrapped up into post-heating to 80 DEG C with tinfoil, is incubated 20 minutes, then fine powder is cooled to into room temperature i.e. Obtain glaze.
The ultimate principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel it should be appreciated that the present invention is not restricted to the described embodiments, the simply explanation described in above-described embodiment and description this The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, these changes Change and improvement is both fallen within scope of the claimed invention.The claimed scope of the invention by appending claims and its Equivalent thereof.

Claims (4)

1. a kind of Enamel jar oral area glaze, it is characterised in that be made up of the component of following weight portion:It is bauxite 12-16 parts, red Native 24-32 parts, Shaanxi soil 12-18 parts, spodumene 2-3 parts, gallium nitride 2-3 parts, Os Bovis seu Bubali 2-3 parts, vanadic anhydride 4-6 parts, phosphorus Sour aluminum 3-7 parts, calcium oxide 3-7 parts, calcium silicide 3-7 parts, stabilization aid 5-10 parts, modified zeolite 5-10 parts.
2. a kind of Enamel jar oral area glaze according to claim 1, it is characterised in that the stabilization aid is by following heavy The component of amount part is constituted:Propylene glycol monomethyl ether 2-3 parts, Calcium Carbonate 2-3 part, succinic acid 2-3 parts, glaze fruit 1-2 parts, lauric acid diethanol Amide 1-2 parts;Its preparation method is the mixing of each raw material to be milled to into fine powder, then by fine powder 60-100KHz ultrasonic Treatment 10 minutes, then the clear water for being mixed into its weight portion 30%-40% to fine powder is stirred into slurry, then slurry is sent into into dehydrator Interior drying, continues to be milled to fine powder to be stabilization aid after drying.
3. a kind of Enamel jar oral area glaze according to claim 1, it is characterised in that the modified zeolite preparation method It is:Zeolite is blown 5 minutes with 200 DEG C of high temperature carbon dioxide gases, then again with 80 DEG C of apple vinegars, the acid of Chinese holly edge, no Palmic acid, food Sub- acid, myristic acid, water press 1:1:1:1:1:140 proportioning concentrations soak isothermal holding 30 minutes, then deionized water is cleaned Zeolite, is then milled to powder.
4. a kind of preparation technology of the Enamel jar oral area glaze described in any one of claim 1-3 is made, it is characterised in that bag Include following steps:
(1) mixing of each raw material is milled to into 50-80 mesh fine powders;
(2) fine powder is wrapped up into post-heating to 80 DEG C with tinfoil, is incubated 20 minutes, then fine powder is cooled to into room temperature and obtains final product glaze Material.
CN201610921002.3A 2016-10-21 2016-10-21 Glaze for enameled cup opening part Pending CN106565090A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610921002.3A CN106565090A (en) 2016-10-21 2016-10-21 Glaze for enameled cup opening part

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610921002.3A CN106565090A (en) 2016-10-21 2016-10-21 Glaze for enameled cup opening part

Publications (1)

Publication Number Publication Date
CN106565090A true CN106565090A (en) 2017-04-19

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100999415A (en) * 2007-01-24 2007-07-18 唐山陶瓷股份有限公司 Leadless molten block enamel for bone porcelain
CN101497496A (en) * 2008-02-02 2009-08-05 比亚迪股份有限公司 Porcelain enamel glaze composition, film coating material and preparation thereof
CN103951467A (en) * 2014-05-12 2014-07-30 福建省博创生化有限责任公司 Preparation and usage methods of ceramic glaze nano-pore aqueous solution additive
CN104058793A (en) * 2014-07-05 2014-09-24 陈新棠 Ceramic glaze
CN105293913A (en) * 2015-09-07 2016-02-03 龙泉市金宏瓷业有限公司 Celadon glaze and manufacturing method thereof
CN105712698A (en) * 2016-02-19 2016-06-29 南通蛇类治疗研究所 Technology for producing environment-friendly ceramic glazed bricks through industrial waste glass and wastes

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100999415A (en) * 2007-01-24 2007-07-18 唐山陶瓷股份有限公司 Leadless molten block enamel for bone porcelain
CN101497496A (en) * 2008-02-02 2009-08-05 比亚迪股份有限公司 Porcelain enamel glaze composition, film coating material and preparation thereof
CN103951467A (en) * 2014-05-12 2014-07-30 福建省博创生化有限责任公司 Preparation and usage methods of ceramic glaze nano-pore aqueous solution additive
CN104058793A (en) * 2014-07-05 2014-09-24 陈新棠 Ceramic glaze
CN105293913A (en) * 2015-09-07 2016-02-03 龙泉市金宏瓷业有限公司 Celadon glaze and manufacturing method thereof
CN105712698A (en) * 2016-02-19 2016-06-29 南通蛇类治疗研究所 Technology for producing environment-friendly ceramic glazed bricks through industrial waste glass and wastes

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
刘银等主编: "《无机非金属材料工艺学》", 30 September 2015, 中国科学技术大学出版社 *
张玉春编著: "《艺术釉》", 30 April 1976, 轻工业出版社 *

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Application publication date: 20170419