CN103951467A - Preparation and usage methods of ceramic glaze nano-pore aqueous solution additive - Google Patents
Preparation and usage methods of ceramic glaze nano-pore aqueous solution additive Download PDFInfo
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- CN103951467A CN103951467A CN201410197718.4A CN201410197718A CN103951467A CN 103951467 A CN103951467 A CN 103951467A CN 201410197718 A CN201410197718 A CN 201410197718A CN 103951467 A CN103951467 A CN 103951467A
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- nanoaperture
- aqueous solution
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Abstract
The invention discloses preparation and usage methods of a ceramic glaze nano-pore aqueous solution additive. The preparation method comprises the following steps: passing water vapor through nano-pore material particles with the pore size of less than 100nm, and condensing to obtain an aqueous solution, namely a nano-pore aqueous solution additive, wherein the nano-pore material particles include SiO2, TiO2, Al2O3, Fe2O3 and zeolite at the weight ratio of 0.65:(0.08-0.12):(0.04-0.06):(0.08-0.12):(0.08-0.12), the glaze has the characteristics that the nano-pore material has high catalysis and adsorption effects by adding the nano-pore aqueous solution, so that ceramic products is easy to clean, antibacterial, smaller in water molecule cluster, high-efficiency to adsorb and catalyze, and the like.
Description
Technical field
The present invention relates to a kind of preparation method of ceramic glaze nanoaperture aqueous solution additive, particularly utilize nanoaperture material to prepare the method for preparing of ceramic glaze additive, the invention still further relates to the using method of this additive.
Background technology
At present the pottery of called function is mainly with having equally distributed micropore, porous ceramics that volume density is little, in ceramic raw material, add other material as nitride, boride, carbide, silicide and oxide compound etc., the pottery that can make to produce possesses to be had certain functionally, and all there be special material formula and the method for its making in each family; Also have and in ceramic glaze, add nanometer materials powder, to make the domestic ceramics with nanostructure glaze, as the patent No. disclosed permanently self-cleaning nano ceramic enamel of Chinese patent that is 02115404.X, by add nanometer materials powder in common glaze, make Ceramic glaze there is nanostructure, thereby make Ceramic glaze there is hydrophobic and permanent self-cleaning function, yet this patented technology is only the application of two-dimensional nano, with respect to three-dimensional manometer still defectiveness and deficiency.
Summary of the invention
The object of the invention is for the deficiencies in the prior art, a kind of preparation method and using method of ceramic glaze nanoaperture aqueous solution additive are provided, by the characteristic effect of the high catalysis of nanoaperture material tool and adsorption effect, make the functions such as ceramic product tool is easy clean, antibacterial, water molecule cluster diminishes, high-level efficiency is adsorbed, catalysis, do not need special technology just can increase the value added of ceramic product, be conducive to the multipurpose that specific implementation is used natural matter environmental protection and body-care.
Object of the present invention realizes by following technical solution:
A preparation method for ceramic glaze nanoaperture aqueous solution additive, comprises the steps:
Water vapor is less than to the nanoaperture material granule of 100 nanometers by pore dimension, the aqueous solution of obtaining after condensation is nanoaperture aqueous solution additive, and described nanoaperture material granule comprises SiO
2, TiO
2, Al
2o
3, Fe
2o
3with at least one in zeolite.
Further, described nanoaperture material granule comprises SiO
2, TiO
2, Al
2o
3, Fe
2o
3and zeolite, weight ratio is: 0.65:0.08～0.12:0.04～0.06:0.08～0.12:0.08～0.12.
Further, described nanoaperture material granule comprises SiO
2, TiO
2, Al
2o
3, Fe
2o
3and zeolite, weight ratio is: 0.65:0.10:0.05:0.10:0.10.
Further, the nanoaperture material granule that is less than 100 by pore dimension with 150 ℃ of above water vapour, the aqueous solution of obtaining after condensation.
A using method for ceramic glaze nanoaperture aqueous solution additive, comprises the steps:
(1), in glaze, add weight percent be 20～50% as arbitrary in claim 1 to 4 as described in nanoaperture aqueous solution additive, mixing and stirring;
(2), the glaze that is added with nanoaperture aqueous solution additive is applied on ceramic idiosome, through kiln, be fired into the functionality ceramic with nanoaperture material function effectiveness.
Further, step (2) is for being applied to the glaze that is added with the nanoaperture aqueous solution additive inwall of earthenware porcelain receptacle idiosome.
Further, the kiln firing temperature of step (2) is 880 ℃～1380 ℃.
Further, described ceramic body is formed by conventional ceramic blank and the nanoaperture material granule recrement mixed preparing after steam, and mixed weight ratio is: 1:0.1～0.4.
Further, described ceramic body is formed by the nanoaperture material granule recrement after steam, calcium carbonate, conventional ceramic blank mixed preparing, and mixed weight is than being 0.15:0.05～0.10:0.80～1.
The present invention has following beneficial effect:
Than prior art, the present invention makes full use of the raw materials such as oxide compound with sol-gel method, lithography, the methods such as ionic fluid make the nanoaperture material granule of particle diameter 2-5mm, the pore dimension of nanoaperture material granule is in 50-100 nanometer, 150 ℃ of above steam are by the process of nanoaperture material granule, nanoaperture material can produce three-dimensional manometer grade particles under the intermolecular shock of high temperature, and partial 3-D nano-scale particle is transferred in steam, additive with the water of condensation solution after vapor condensation as ceramic glaze, the pottery of take specifically represents the characteristic effect of the high catalysis of nanoaperture material tool and adsorption effect as carrier, make ceramic product tool easy clean, antibacterial, water molecule cluster diminishes, high-level efficiency absorption, the functions such as catalysis.Pottery industry can directly be used on unglazed ceramic semi-finished product pottery embryo, makes it to have the pottery of specific function, has improved value added and the market competitiveness and has been conducive to realize the dual purpose of environment protection and body-care.The performance that the pottery of process present method manufacture has is as follows: the functions such as ceramic product tool is easy clean, antibacterial, water molecule cluster diminishes, high-level efficiency is adsorbed, catalysis.
Per kilogram nanoaperture material can be produced 1000 liters of above nanoaperture aqueous solution, uses remaining Yu slag to mix use with kaolin and other stupalith simultaneously, does not waste completely, in material cost and material application, occupies great advantage.
Accompanying drawing explanation
Below in conjunction with accompanying drawing, the present invention is described in further details.
Fig. 1 is the pottery made of embodiment mono-shown ceramic surface under 100 power microscopes.
Fig. 2 is the pottery made of prior art shown ceramic surface under 100 power microscopes, and it is basic identical that glaze and embodiment mono-compare except color, do not add nanoaperture aqueous solution additive.
Embodiment
Embodiment mono-
(1) preparation of additive: 150 ℃ of above water vapors are less than to the nanoaperture material granule of 100 nanometers by pore dimension, the aqueous solution of obtaining after condensation is nanoaperture aqueous solution additive, and described nanoaperture material granule comprises SiO
2, TiO
2, Al
2o
3, Fe
2o
3and zeolite, weight ratio is: 0.65:0.10:0.05:0.10:0.10.
(2) preparation of glaze: the ceramic glaze of every liter adds the nanoaperture aqueous solution additive that weight percent is 20%, mixing and stirring.
(3) sintering technology: the glaze that is added with nanoaperture aqueous solution additive is applied to ceramic embryo container internal layer, is fired into ceramic product through 1230 ℃～1380 ℃ of kilns.
See figures.1.and.2, can see that the ceramic crystallization distribution of embodiment mono-is a very regular high-density, the ceramic crystallization that prior art provides distributes and presents irregular situation.
Embodiment bis-
(1) preparation of additive: 150 ℃ of above water vapors are less than to the nanoaperture material granule of 100 nanometers by pore dimension, the aqueous solution of obtaining after condensation is nanoaperture aqueous solution additive, and described nanoaperture material granule comprises SiO
2, TiO
2, Al
2o
3, Fe
2o
3and zeolite, weight ratio is: 0.65:0.12:0.04:0.09:0.12.
(2) preparation of glaze: the ceramic glaze of every liter adds the nanoaperture aqueous solution additive that weight percent is 45%, mixing and stirring.
(3) preparation of ceramic body and sintering technology: the nanoaperture material granule recrement after steam and conventional ceramic blank are mixed and make ceramic idiosome, blending ratio is 1:0.1, on ceramic body, apply the ceramic glaze that is added with nanoaperture aqueous solution additive, through 880 ℃～1380 ℃ of kilns, be fired into pottery.
Embodiment tri-
(1) preparation of additive: 150 ℃ of above water vapors are less than to the nanoaperture material granule of 100 nanometers by pore dimension, the aqueous solution of obtaining after condensation is nanoaperture aqueous solution additive, and described nanoaperture material granule comprises SiO
2, TiO
2, Al
2o
3, Fe
2o
3and zeolite, weight ratio is: 0.65:0.10:0.05:0.10:0.10.
(2) preparation of glaze: the ceramic glaze of every liter adds the nanoaperture aqueous solution additive that weight percent is 50%, mixing and stirring.
(3) preparation of ceramic body and sintering technology: the nanoaperture material granule recrement after steam, calcium carbonate, conventional ceramic blank mixed preparing form, mixed weight is than being 0.15:0.05:1, wherein calcium carbonate is a species of small clam living in fresh water shell powder.
On ceramic body, apply the ceramic glaze that is added with nanoaperture aqueous solution additive, through 1230 ℃～1380 ℃ of kilns, be fired into ceramic product.
The above, be only preferred embodiment of the present invention, therefore can not limit scope of the invention process with this, the equivalence of doing according to the present patent application the scope of the claims and description changes and modifies, and all should still remain within the scope of the patent.
Claims (9)
1. a preparation method for ceramic glaze nanoaperture aqueous solution additive, comprises the steps:
Water vapor is less than to the nanoaperture material granule of 100 nanometers by pore dimension, the aqueous solution of obtaining after condensation is nanoaperture aqueous solution additive, and described nanoaperture material granule comprises SiO
2, TiO
2, Al
2o
3, Fe
2o
3with at least one in zeolite.
2. the preparation method of a kind of ceramic glaze nanoaperture aqueous solution additive according to claim 1, is characterized in that: described nanoaperture material granule comprises SiO
2, TiO
2, Al
2o
3, Fe
2o
3and zeolite, weight ratio is: 0.65:0.08～0.12:0.04～0.06:0.08～0.12:0.08～0.12.
3. the preparation method of a kind of ceramic glaze nanoaperture aqueous solution additive according to claim 2, is characterized in that: described nanoaperture material granule comprises SiO
2, TiO
2, Al
2o
3, Fe
2o
3and zeolite, weight ratio is: 0.65:0.10:0.05:0.10:0.10.
4. the preparation method of a kind of ceramic glaze pore water solution additive according to claim 1, is characterized in that: the nanoaperture material granule that is less than 100 by pore dimension with 150 ℃ of above water vapour, the aqueous solution of obtaining after condensation.
5. a using method for ceramic glaze nanoaperture aqueous solution additive, comprises the steps:
(1), in glaze, add weight percent be 20～50% as arbitrary in claim 1 to 4 as described in nanoaperture aqueous solution additive, mixing and stirring;
(2), the glaze that is added with nanoaperture aqueous solution additive is applied on ceramic idiosome, through kiln, be fired into the functionality ceramic with nanoaperture material function effectiveness.
6. the using method of a kind of ceramic glaze nanoaperture aqueous solution additive according to claim 5, is characterized in that: step (2) is for being applied to the glaze that is added with the nanoaperture aqueous solution additive inwall of earthenware porcelain receptacle idiosome.
7. the using method of a kind of ceramic glaze pore water solution additive according to claim 5, is characterized in that: the kiln firing temperature of step (2) is 880 ℃～1380 ℃.
8. the using method of a kind of ceramic glaze nanoaperture aqueous solution additive according to claim 5, it is characterized in that: described ceramic body is formed by conventional ceramic blank and the nanoaperture material granule recrement mixed preparing after steam, and mixed weight ratio is: 1:0.1～0.4.
9. the using method of a kind of ceramic glaze nanoaperture aqueous solution additive according to claim 5, it is characterized in that: described ceramic body is formed by the nanoaperture material granule recrement after steam, calcium carbonate, conventional ceramic blank mixed preparing, mixed weight is than being 0.15:0.05～0.10:0.80～1.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104370523A (en) * | 2014-09-12 | 2015-02-25 | 福建省博创生化有限责任公司 | Production process for ceramic product capable of accelerating alcohol alcoholization, and alcohol alcoholization method |
| CN106565090A (en) * | 2016-10-21 | 2017-04-19 | 安徽青花坊瓷业股份有限公司 | Glaze for enameled cup opening part |
| CN108083850A (en) * | 2015-10-16 | 2018-05-29 | 德化县如瓷生活文化有限公司 | It can accelerate the Nano ceramic tea can of tea leaf fermentation speed |
| CN111439943A (en) * | 2019-11-27 | 2020-07-24 | 谢文富 | Environment-friendly building material and preparation method of nano pore water solution additive |
| CN112057408A (en) * | 2020-09-14 | 2020-12-11 | 谢文富 | Three-in-one aqueous solution additive with zinc ions and preparation and use methods thereof |
| CN113772953A (en) * | 2021-09-23 | 2021-12-10 | 谢文富 | Preparation method and use method of ceramic glaze with far infrared, antibacterial and antioxidant functions, high hardness and self-cleaning function |
| CN113845877A (en) * | 2021-09-23 | 2021-12-28 | 谢文富 | Preparation method and use method of adhesive with far infrared, antibacterial and antioxidant functions |
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| CN102643115A (en) * | 2012-05-03 | 2012-08-22 | 山东电盾科技有限公司 | Indoor natural-light photocatalysis antimicrobial energy-saving ceramic glaze and use method thereof |
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2014
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0669539A (en) * | 1992-08-19 | 1994-03-11 | Fujitsu Ltd | Light-emitting semiconductor device and its manufacture |
| CN102643115A (en) * | 2012-05-03 | 2012-08-22 | 山东电盾科技有限公司 | Indoor natural-light photocatalysis antimicrobial energy-saving ceramic glaze and use method thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104370523A (en) * | 2014-09-12 | 2015-02-25 | 福建省博创生化有限责任公司 | Production process for ceramic product capable of accelerating alcohol alcoholization, and alcohol alcoholization method |
| CN104370523B (en) * | 2014-09-12 | 2016-09-07 | 福建省博创生化有限责任公司 | Can the manufacture craft of ceramic of acceleration of alcohol alcoholization and alcohol method for alcoholizing |
| CN108083850A (en) * | 2015-10-16 | 2018-05-29 | 德化县如瓷生活文化有限公司 | It can accelerate the Nano ceramic tea can of tea leaf fermentation speed |
| CN108083850B (en) * | 2015-10-16 | 2021-04-06 | 德化县如瓷生活文化有限公司 | Nano ceramic tea caddy capable of accelerating tea fermentation speed |
| CN106565090A (en) * | 2016-10-21 | 2017-04-19 | 安徽青花坊瓷业股份有限公司 | Glaze for enameled cup opening part |
| CN111439943A (en) * | 2019-11-27 | 2020-07-24 | 谢文富 | Environment-friendly building material and preparation method of nano pore water solution additive |
| CN112057408A (en) * | 2020-09-14 | 2020-12-11 | 谢文富 | Three-in-one aqueous solution additive with zinc ions and preparation and use methods thereof |
| CN113772953A (en) * | 2021-09-23 | 2021-12-10 | 谢文富 | Preparation method and use method of ceramic glaze with far infrared, antibacterial and antioxidant functions, high hardness and self-cleaning function |
| CN113845877A (en) * | 2021-09-23 | 2021-12-28 | 谢文富 | Preparation method and use method of adhesive with far infrared, antibacterial and antioxidant functions |
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| CN103951467B (en) | 2015-04-08 |
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Application publication date: 20140730 Assignee: FUJIAN TAIGU CERAMICS CO., LTD. Assignor: FUJIAN BOCHUANG BIOCHEMISTRY CO., LTD. Contract record no.: 2015350000040 Denomination of invention: Preparation and usage methods of ceramic glaze nano-pore aqueous solution additive Granted publication date: 20150408 License type: Exclusive License Record date: 20150522 |
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Effective date of registration: 20171130 Address after: Chengdong Industrial Zone of Dehua County of Quanzhou City, Fujian province 362500 in Jiujiang Town Patentee after: FUJIAN TAIGU CERAMICS CO., LTD. Address before: Chengdong Industrial Park in Dehua County of Quanzhou City, Fujian province 362500 Patentee before: FUJIAN BOCHUANG BIOCHEMISTRY CO., LTD. |
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Denomination of invention: Preparation and application of nano pore water solution additive for ceramic glaze Effective date of registration: 20210707 Granted publication date: 20150408 Pledgee: China Postal Savings Bank Limited by Share Ltd. Dehua County branch Pledgor: FUJIAN TAIGU CERAMICS Co.,Ltd. Registration number: Y2021980005874 |