CN106561719A - Efficient insectofungicide containing beauveria bassiana and pyraclostrobin and application thereof - Google Patents
Efficient insectofungicide containing beauveria bassiana and pyraclostrobin and application thereof Download PDFInfo
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- CN106561719A CN106561719A CN201610344432.3A CN201610344432A CN106561719A CN 106561719 A CN106561719 A CN 106561719A CN 201610344432 A CN201610344432 A CN 201610344432A CN 106561719 A CN106561719 A CN 106561719A
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- pyraclostrobin
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- muscardine
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- beauveria bassiana
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
- A01N63/30—Microbial fungi; Substances produced thereby or obtained therefrom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
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- General Health & Medical Sciences (AREA)
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- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Microbiology (AREA)
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Abstract
The invention discloses an efficient insectofungicide containing beauveria bassiana and pyraclostrobin. Active ingredients of the product are beauveria bassiana and pyraclostrobin. Mass content of beauveria bassiana is 10-30%, and mass content of pyraclostrobin is 10-25%. The dosage form of the insectofungicide is an oil-suspended injection, wettable powder or water dispersible granules. The insectofungicide can be used for controlling plant diseases and insect pests for crops, and has an effect of treating plant diseases and insect pests for various crops, including main vegetable pests whitefly and diamondback moth and important vegetable diseases powdery mildew, downy mildew, late blight, early blight, anthracnose, etc. What's more important is that pyraclostrobin can enhance virulence of beauveria bassiana to diamondback moth.
Description
Technical field
The invention belongs to technical field of pesticide, is related to a kind of insecticidal and bactericidal composition, and in particular to it is a kind of containing muscardine and
The efficient insecticide antibacterial of pyraclostrobin, be mainly used in preventing and treating powdery mildew, downy mildew, late blight, early blight, anthrax and
The preventing and treating of the pest and disease damages such as aleyrodid, diamondback moth.
Background technology
Muscardine be at present in the world research with using most insect pathogenic fungus, with pathogenicity it is strong, insecticidal spectrum is wide,
Do not kill natural enemy, to people and animals and ecological safety the features such as.For a long time, muscardine is at home and abroad widely used in Holotrichia diomphalia Batess, powder
The preventing and treating of various agriculture and forestry injurious insects such as louse, chrysomelid, locust, tea jassids, Pyrausta nubilalis (Hubern)., pine moth, and achieved with significant preventing and treating
Effect, becomes a kind of important replacement protective agents for agriculture green prevention and control system.Beauveria fungus preparation is a kind of live body life
Thing pesticide, effective active composition are conidium, when plant insect is prevented and treated using muscardine, inevitably with preventing and treating plant
Each series bactericidal agent of disease meets, and most researchs are thought, antibacterial conidia of beauveria bassiana is had different degrees of suppression or
Killing effect, so as to the pathogenicity for causing muscardine has different degrees of decline.But also there is scholar to think conidia of beauveria bassiana
Sprout or growth is suppressed and can not represent conidium vigor and necessarily decline.
Pyraclostrobin is new-type wide-spectrum bactericide, and the mechanism of action is mitochondrial respiratory inhibitor, with protection, treatment,
The effects such as blade infiltration conduction, not only toxicity is low for the antibacterial, to non-target organism safety, and user and environment is pacified
It is complete friendly.Pyraclostrobin is widely used in preventing and treating Fructus Cucumidis sativi, Fructus Lycopersici esculenti, Fructus Capsici, Semen sojae atricolor, Semen arachidis hypogaeae, Fructus Vitis viniferae, Rhizoma Solani tuber osi, coffee, core
On Fructus Persicae, Camellia sinensis, Nicotiana tabacum L., ornamental plant, lawn and other field crops by ascomycetess, basidiomycetes, Fungi Imperfecti and oomycetes etc. almost
The disease that all types of fungal pathogens cause.Field control effectiveness test shows pyraclostrobin missible oil to Fructus Cucumidis sativi, Citrullus vulgariss white lead
Disease and downy mildew, Fructus Lycopersici esculenti and the late blight of potato, early blight, Chinese cabbage, Fructus Cucumidis sativi, Fructus Mangifera Indicae, anthracnose of tea, leaf blight of corn etc. have
Good prevention effect.Pyraclostrobin or a kind of plant health care product, can be used as growth regulator, are conducive to plant growth,
Strengthen the tolerance of crop effect on environment, improve crop yield.Pyraclostrobin can induce many crops especially paddy in addition
The physiological change of thing, as it can strengthen the activity of nitrate (nitrification) reductase, so as to improve crop rapid growth stage to nitrogen
Absorption.Meanwhile, it can reduce the biosynthesiss of ethylene, delay crop aging.Even in the case where plant does not fall ill, pyrrole
Azoles kresoxim-methyl by controlling secondary disease and can also mitigate pressure from abiotic component improving crop yield.
Agriculture chemical compounding or mixing application technique are conducive to overcoming or delaying the Drug resistance of insect, may also reach up applied once
The effect of multi-faceted preventing and treating.But by muscardine strain and bactericide compounded use, often make antibacterial kill strain, so as to
It is unable to reach the purpose that mixing is applied.Inventor has found that muscardine is used cooperatively with pyraclostrobin, and pyraclostrobin is not only not
Muscardine can be killed, pathogenicity of the muscardine to some insects, split muscardine of this discovery and pyrazoles can be also lifted on the contrary
The insecticidal bactericide of kresoxim-methyl compounding is significant.
The content of the invention
The technical problem to be solved is to provide a kind of sterilization of the efficient insecticide containing muscardine and pyraclostrobin
Agent, pyraclostrobin therein can improve pathogenicity of the muscardine to insects such as diamondback moths, can be used for preventing and treating Fructus Cucumidis sativi white lead
Disease, downy mildew, tomato late blight, early blight, the disease of the various crop such as Chinese cabbage anthrax and aleyrodid, diamondback moth and insect pest.
To achieve these goals, the present invention is adopted the following technical scheme that：
Efficient insecticide antibacterial containing muscardine and pyraclostrobin, its effective ingredient are two kinds of groups of muscardine and pyraclostrobin
Point, the mass percent of muscardine is 10-30%, and the mass percent of pyraclostrobin is 10-25%, balance of auxiliary agent.
Preferably, the muscardine is conidia of beauveria bassiana powder, and spore content is 5 × 1010~1×1011Spore/g, spore living
Rate ＞ 90%.
Preferably, the dosage form of the above-mentioned efficient insecticide antibacterial containing muscardine and pyraclostrobin is oil suspending agent, wettability
Powder or water dispersible granules；When dosage form is oil suspending agent, the mass percent of auxiliary agent is：Emulsifying agent 2-5%, wetting agent 1-5%,
Antifreezing agent 0.5-5%, balance of carrier oil, wherein emulsifying agent are from farm chemical emulgent 2000, farm chemical emulgent AE03, pesticide breast
Dodecylbenzene sodium sulfonate, hydroxyethyl cellulose, sodium laurylsulfate or wood are selected in one or more in agent FM, wetting agent
One or more in quality sodium sulfonate, antifreezing agent are one or two in ethylene glycol or Propylene Glycol, and carrier oil is refine ore deposit
Thing oil or vegetable oil；When dosage form is wettable powder, the mass percent of auxiliary agent is：Wetting agent 1-15%, dispersant 1-10%,
Balance of filler, wherein wetting agent are from the one kind in dodecylbenzene sodium sulfonate, sodium laurylsulfate or sodium lignin sulfonate
Or it is various, from one or more in PVP, dispersing agent MF, alkylphenol-polyethenoxy base phosphate ester, filler is kaolinite to dispersant
Soil, attapulgite；When dosage form is water dispersible granules, the mass percent of auxiliary agent is：Wetting agent 1-15%, dispersant 1-15%, collapses
Solution agent 0.5-4%, binding agent 0.5-8%, balance of filler, wherein wetting agent select dodecylbenzene sodium sulfonate, lauryl alcohol sulphuric acid
PVP, dispersing agent MF, alkylphenol-polyethenoxy base phosphate ester are selected in one or more in sodium or sodium lignin sulfonate, dispersant
In one or more, disintegrating agent is bentonite, white carbon, one or more in PEG, and binding agent selects xanthan gum, polyethylene
One or more in alcohol, sodium polyacrylate, filler are Kaolin or attapulgite.
Preferably, described refined mineral oil is refine aerial kerosene or transformer oil, and the physics and chemistry of refined mineral oil refers to
Mark should meet：It is poor with respect to n-alkane carbon number to be not more than 8, should be non-between 21-24 with respect to n-alkane average carbon number
Sulfonated bodiess content should be not less than 92%；The vegetable oil is Semen Maydis oil or Oleum Helianthi or Oleum Brassicae campestriss.
It is further preferred that the muscardine is beauveria bassiana（Beauveria bassiana）HFW-05 bacterial strains, in
On January 24th, 2008 is preserved in China Committee for Culture Collection of Microorganisms's common micro-organisms center, preserving number：CGMCC
No. 2356, the bacterial strain is by application for a patent for invention " a kind of Macrophomina beauveria bassiana HFW-05 bacterial strain and its application "（Application number：
200810089529.X；Publication number：CN 101245319A）It is open.
The present invention also provides the above-mentioned efficient insecticide antibacterial containing muscardine and pyraclostrobin and is preventing and treating powdery mildew, downy mildew
Application in terms of disease, late blight, early blight, anthrax and aleyrodid, diamondback moth.
It is an advantage of the current invention that muscardine and pyraclostrobin compounding use, not only kill pyraclostrobin
Muscardine, realizes applied once while playing muscardine and pyraclostrobin is respective prevents and treats function, improves and treat efficiency,
Also pathogenicity of the muscardine to diamondback moth is improved particular by pyraclostrobin, bring.This
It is bright to be directed to vegetable important pests aleyrodid, diamondback moth and powdery mildew of cucumber, downy mildew, tomato late blight, early blight and Chinese cabbage
The pest and disease damages such as anthrax are effectively prevented and treated, and are particularly suited for the preventing and treating of green vegetables industry crop disease and insect, are reduced dispenser
Number of times, effectively reduces the dispenser cost of crop pest management, realizes.Reduce vegetable green composite simultaneously to prevent
Selection difficulty when pest and disease damage occurs simultaneously in control to pesticide, can effectively overcome or delay the insects such as aleyrodid, diamondback moth to changing
Learn to farm the Drug resistance of medicine, mitigate lethal effect of the chemical pesticide to natural enemy, be conducive to the ecological environment that protects the fields.
Specific embodiment
The present invention is further illustrated with reference to specific embodiment, but embodiment does not do any type of to the present invention
Limit.
Percentage ratio described in following examples is mass percent, and the muscardine is conidia of beauveria bassiana powder, is contained
Spore amount is 5 × 1010~1×1011Spore/g, spore rate ＞ living 90%.
Embodiment 1（The preparation method of 35% muscardine pyraclostrobin oil suspending agent）
1×1011Spore/g beauveria bassiana spore powders 10%
Pyraclostrobin 25%
Farm chemical emulgent 2,000 4%
Hydroxyethyl cellulose 2%
Ethylene glycol 1%
Refine transformer oil 58%
Preparation method is as follows：
According to formula, each component is weighed in proportion, in adding grinder, not higher than 40 DEG C of the ambient temperature of the course of processing,
5-10 minutes, mix homogeneously are ground under 1000-1500rpm speed.
Embodiment 2（The preparation method of 35% muscardine pyraclostrobin oil suspending agent）
9×1010Spore/g beauveria bassiana spore powders 15%
Pyraclostrobin 20%
Farm chemical emulgent AE03 4.5%
Sodium lignin sulfonate 2%
Carboxyethyl cellulose 1%
Ethylene glycol 1%
Semen Maydis oil 56.5%
Preparation method is as follows：
According to formula, each component is weighed in proportion, in adding grinder, not higher than 40 DEG C of the ambient temperature of the course of processing,
5-10 minutes, mix homogeneously are ground under 1000-1500rpm speed.
Embodiment 3（The preparation method of 40% muscardine pyraclostrobin wettable powder）
5×1010Spore/g beauveria bassiana spore powders 30%
Pyraclostrobin 10%
Dodecylbenzene sodium sulfonate 6%
Sodium lignin sulfonate 2%
Dispersing agent MF 5%
Kaolin 47%
Preparation method：
According to formula, each component is weighed in proportion, comminution by gas stream is carried out after adding mixer mix homogeneously, filled after the completion of crushing
Divide and stir, you can obtain wettable powder product.
4 (the preparation method of 40% muscardine pyraclostrobin water dispersible granule of embodiment）
1×1011Spore/g beauveria bassiana spore powders 20%
Pyraclostrobin 20%
Dodecylbenzene sodium sulfonate 6%
Sodium lignin sulfonate 5%
Alkylphenol-polyethenoxy base phosphate ester 5%
Polyvinyl alcohol 3%
White carbon 10%
Attapulgite 31%
Preparation method：
According to formula, each component is weighed in proportion, after adding mixer mix homogeneously, carry out comminution by gas stream, added after the completion of crushing
Enter a small amount of purified water to stir, extruder grain, water dispersible granules after drying, can be obtained.
Prevention effect：
Insecticidal bactericide containing muscardine pyraclostrobin can effectively prevent and control facilities vegetable aleyrodid and Fructus Cucumidis sativi white lead
Disease, downy mildew, the generation of the pest and disease damage such as Phytophthora infestans, early blight and Chinese cabbage diamondback moth and anthrax.As it can be seen from table 1
The insecticidal bactericide is suitable to the prevention effect of aleyrodid and the preventive effect of muscardine, is better than muscardine to the prevention effect of diamondback moth
Prevention effect, with 25% pyraclostrobin missible oil to powdery mildew of cucumber, downy mildew, tomato late blight, early blight, Chinese cabbage anthrax
Preventive effect quite, effect is controlled substantially to the simultaneous of pest and disease damage, peasant once spray can preventing and treating vegetable insect disease, alleviate peasant and apply
The workload of medicine, improves the prevention effect to pest and disease damage.
Field control effect after 13 dispensers of muscardine pyraclostrobin insecticidal bactericide of table
Above-described embodiment is not limited by above-described embodiment for the present invention preferably embodiment, but embodiments of the present invention
System, the change made under other any essence and principle without departing from the present invention, replacement, combination or simplified, should be equivalent
Substitute mode, be included within protection scope of the present invention.
Claims (6)
1. a kind of efficient insecticide antibacterial containing muscardine and pyraclostrobin, it is characterised in that：Its effective ingredient is muscardine
With two kinds of components of pyraclostrobin, the mass percent of muscardine is 10-30%, and the mass percent of pyraclostrobin is 10-
25%, balance of auxiliary agent.
2. the efficient insecticide antibacterial of muscardine and pyraclostrobin is contained as claimed in claim 1, it is characterised in that described white
Stiff bacterium is conidia of beauveria bassiana powder, and spore content is 5 × 1010~1×1011Spore/g, spore rate ＞ living 90%.
3. the efficient insecticide antibacterial of muscardine and pyraclostrobin is contained as claimed in claim 2, it is characterised in that its dosage form
For oil suspending agent, wettable powder or water dispersible granules；
When dosage form is oil suspending agent, the mass percent of auxiliary agent is：Emulsifying agent 2-5%, wetting agent 1-5%, antifreezing agent 0.5-5%, it is remaining
Measure as carrier oil, wherein emulsifying agent from the one kind in farm chemical emulgent 2000, farm chemical emulgent AE03, farm chemical emulgent FM or
Various, wetting agent is from dodecylbenzene sodium sulfonate, hydroxyethyl cellulose, sodium laurylsulfate or sodium lignin sulfonate
Kind or it is various, antifreezing agent is one or two in ethylene glycol or Propylene Glycol, and carrier oil is refined mineral oil or vegetable oil；
When dosage form is wettable powder, the mass percent of auxiliary agent is：Wetting agent 1-15%, dispersant 1-10%, it is balance of to fill out
Material, wherein wetting agent are divided from one or more in dodecylbenzene sodium sulfonate, sodium laurylsulfate or sodium lignin sulfonate
From one or more in PVP, dispersing agent MF, alkylphenol-polyethenoxy base phosphate ester, filler is Kaolin, attapulgite to powder
Soil；
When dosage form is water dispersible granules, the mass percent of auxiliary agent is：Wetting agent 1-15%, dispersant 1-15%, disintegrating agent 0.5-
4%, binding agent 0.5-8%, wherein balance of filler, wetting agent select dodecylbenzene sodium sulfonate, sodium laurylsulfate or wooden
One or more in plain sodium sulfonate, dispersant is from the one kind in PVP, dispersing agent MF, alkylphenol-polyethenoxy base phosphate ester
Or it is various, disintegrating agent is bentonite, white carbon, one or more in PEG, and binding agent selects xanthan gum, polyvinyl alcohol, polypropylene
One or more in sour sodium, filler are Kaolin or attapulgite.
4. the efficient insecticide antibacterial of muscardine and pyraclostrobin is contained as claimed in claim 3, it is characterised in that described
Refined mineral oil is refine aerial kerosene or transformer oil, and the physical and chemical index of refined mineral oil should meet：With respect to n-alkane
Carbon number difference should be not more than 8, should be between 21-24 with respect to n-alkane average carbon number, and non-sulfonated thing content should be not less than
92%；The vegetable oil is Semen Maydis oil or Oleum Helianthi or Oleum Brassicae campestriss.
5. the efficient insecticide antibacterial containing muscardine and pyraclostrobin as described in claim 1,2,3 or 4, its feature exist
In the muscardine is beauveria bassiana（Beauveria bassiana）HFW-05 bacterial strains, were preserved on January 24th, 2008
China Committee for Culture Collection of Microorganisms's common micro-organisms center, preserving number：CGMCC No. 2356.
6. the efficient insecticide antibacterial containing muscardine and pyraclostrobin as claimed in claim 5 is preventing and treating powdery mildew, downy mildew
Application in terms of disease, late blight, early blight, anthrax and aleyrodid, diamondback moth.
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| CN201610344432.3A CN106561719B (en) | 2016-05-23 | 2016-05-23 | Efficient insecticide fungicide and its application containing muscardine and pyraclostrobin |
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| CN201610344432.3A CN106561719B (en) | 2016-05-23 | 2016-05-23 | Efficient insecticide fungicide and its application containing muscardine and pyraclostrobin |
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| CN106561719A8 CN106561719A8 (en) | 2019-10-25 |
| CN106561719B CN106561719B (en) | 2019-11-19 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107156149A (en) * | 2017-05-24 | 2017-09-15 | 宁夏天瑞产业集团现代农业有限公司 | A kind of high-efficiency plant protective agent and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101245319A (en) * | 2008-04-07 | 2008-08-20 | 河北省农林科学院植物保护研究所 | Macrophomina beauveria bassiana HFW-05 bacterial strain and uses thereof |
| CN101502272A (en) * | 2009-03-31 | 2009-08-12 | 河北省农林科学院植物保护研究所 | Beauveria bassiana oil suspending agent and method for producing the same |
| CN105377040A (en) * | 2012-11-22 | 2016-03-02 | 巴斯夫公司 | Pesticidal mixtures |
-
2016
- 2016-05-23 CN CN201610344432.3A patent/CN106561719B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101245319A (en) * | 2008-04-07 | 2008-08-20 | 河北省农林科学院植物保护研究所 | Macrophomina beauveria bassiana HFW-05 bacterial strain and uses thereof |
| CN101502272A (en) * | 2009-03-31 | 2009-08-12 | 河北省农林科学院植物保护研究所 | Beauveria bassiana oil suspending agent and method for producing the same |
| CN105377040A (en) * | 2012-11-22 | 2016-03-02 | 巴斯夫公司 | Pesticidal mixtures |
Non-Patent Citations (2)
| Title |
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| 李丽莉 等: "杀菌剂对感染越冬桃小食心虫的白僵菌的抑制作用", 《微生物学通报》 * |
| 杨怀文: "《生物防治创新与实践》", 30 June 2009, 中国农业科学技术出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107156149A (en) * | 2017-05-24 | 2017-09-15 | 宁夏天瑞产业集团现代农业有限公司 | A kind of high-efficiency plant protective agent and preparation method thereof |
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| Publication number | Publication date |
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| CN106561719B (en) | 2019-11-19 |
| CN106561719A8 (en) | 2019-10-25 |
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| CI02 | Correction of invention patent application |
Correction item: Biological Conservation Information False: CGMCC No. 2356 2008.01.24 Number: 16 Page: The title page Volume: 33 Correction item: Biological Conservation Information False: CGMCC No. 2356 2008.01.24 Number: 16 Volume: 33 |
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